• Title/Summary/Keyword: alkali solution

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Experimental Study on Durability Performance of GFRP Composite for Alkali Solution (충진제 종류에 따른 GFRP 복합체의 내알카리성 실험)

  • You, Young-Jun;Park, Young-Hwan;Kim, Hyeang-Yeal;Moon, Chang-Kwon;Lee, Seong-Ryul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.585-588
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    • 2006
  • This paper presents experimental results for durability performance of GFRP composite exposed to the $80^{\circ}C$ alkali solution. A total of 280 specimens for 4 types of additive and 7 cases of immersion time were prepared and tested. Additives used in this study were PVA, kaolin clay, and alumina powder. Specimens were immerged up to 30 days and tested for tensile strength for each immersion time. The results indicate that it is important to fill the inner space of GFRP composite densely to avoid the decrease of tensile strength. In this study, PVA additive showed better performance than other additives.

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Effects of NaOH and Na2SiO3·9H2O Addition on Strength Development of Class F Fly Ash-Mortar (F급 플라이 애쉬-모르타르의 강도발현에 대한 NaOH과 Na2SiO3·9H2O 첨가의 영향)

  • Park, Sang-Sook;Kang, Hwa-Young;Han, Sang-Ho;Kang, Hee-Bog
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.4
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    • pp.261-269
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    • 2005
  • The object of this research is to produce alkali activated fly ash-cement using low calcium fly ash as substitute for portland cement. The experimental program included activation of fly ash by a strong base(NaOH) at different concentration, temperature, and liquid-to-fly ash ratios. To achieve for higher compressive strength of the hardened product, sodium meta silicate is added to the alkaline solution. From the factors considered on strength development, the ratio of liquid/fly ash, the activator concentration and temperature always result to be significative factors. The optimization studied show that the alkaline solution concentration of $NaOH(210g)+Na_2SiO_3{\cdot}9H_2O(30g)+H_2O=1L$ at $50^{\circ}C$ produces the best alkali activation effect for the low calcium fly ash. SEM and XRD patterns showed that the components of alkali-activated fly ash consist mainly of mullite, quartz and amorphous aluminosilicate.

Dye Adsorption Ability of Chitin in Reactive Dyebath (반응염료염액에서의 키틴의 염료흡착성능)

  • 유혜자;김정희;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.2
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    • pp.349-354
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    • 2002
  • In order to decolorize the reactive dye wastewater, we investigated the dye-adsorption ability of chitin, which was natural polymer obtained from shrimp shell. Chitin particle(less than 250 ${\mu}{\textrm}{m}$n) was prepared from shrimp shells in the processes of decalcification in aqueous hydrochloric acid solution and deproteination in aqueous sodium hydroxide solution. The particle size of chitin was controlled to less than 250 ${\mu}{\textrm}{m}$. Three tripes of the reactive dyes-C.I. Reactive Red 120, C.I. Reactive red 241 and C.I. Reactive Black 5-were used. Dye adsorption ability of chitin was investigated by dipping the particle in the dyebaths of concentration of 0.0l%, 0.03% and 0.05% for various periods of time(1,3,5, 10,20,40,80,160minutes). The influence of addition of salt(Na$_2$SO$_4$) and alkali to the dyebaths on dye-absorption was also investigated. We obtained the following results fur the dye-absolution ability of chitin in the dyebaths of three types of reactive dyes. 1) The amount of dye uptake by chitin was increased by addition of salt to the dyebaths. 2) As the concentration of alkali became higher than 3g/I, the amount of dye uptake by chitin was increased. Chitin showed good dye-adsorption ability, when the alkali concentration was high. 3) Chitin showed equal dye uptake in the three types of dyebaths when the dye concentration was 0.0l%. Over 90% of dyestuffs was adsorbed from the dyebaths in ten minutes. When the dye concentration was higher, better adsorption ability was showed in a dye bath of Reactive black 5 than in the others. When the dye concentration was 0.03%, 90% of Reactive red 120 and Reactive red 241 was adsorbed in 40 minutes and the same of Reactive black 5 in 10 minutes. When the dye concentration was 0.05%, 9()% of Reactive red 120 was adsorbed in 80 minutes, and Reactive black 5 in to minutes.

Effects of Alkali-protease Treatments on Acidity, Viscosity and Color of Anchovy Extracts (알칼리 및 효소처리가 멸치추출액의 산도, 점도 및 색에 미치는 영향)

  • Park, Joo-Young;Kim, Hye-Kyung;Kim, Woo-Jung;Yun, Shuk-Ja
    • Korean Journal of Food Science and Technology
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    • v.20 no.4
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    • pp.488-492
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    • 1988
  • The physicochemical properties of viscosity, color, acidity and volume of anchovy extract were measured for their changes during extraction with alkali solution and/or proteolytic enzymes. The dried anchovies were ground in 0.3N NaOH solution followed by hydrolysis with neutral or alkaline protease and centrifuged to obtain anchovy extract. The results showed that the volume of supernatant after centrifugation increased from 70% of water only extraction to 89% by combined alkali-enzyme treatment. Titratable acidity of the extract showed a tendency of a little increase while viscosiy decreased with prolonged enzymic hydrolysis. Changes in Hunter value of 'L', 'a', 'b' showed that the extract became darker and less yellowish as protease treatment prolonged.

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Improvement of Dimensional Stability of Tropical Light-Wood Ceiba pentandra (L) by Combined Alkali Treatment and Densification

  • Deded Sarip NAWAWI;Andita MARIA;Rizal Danang FIRDAUS;Istie Sekartining RAHAYU;Adesna FATRAWANA;Fadlan PRAMATANA;Pamona Silvia SINAGA;Widya FATRIASARI
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.2
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    • pp.133-144
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    • 2023
  • Densification is an effective method for improving the physical and mechanical properties of low-density wood. However, the set-recovery of dimensions was found to be the problem of densified wood due to low fixation during the densification process. Alkali pretreatment before densification is thought to be a modification process to improve the dimensional stability of densified wood. In this research, the wood samples used were boiled in a 1.25 N sodium hydroxide (NaOH) solution at different times, followed by densification for 5 h at 100℃. The alkali pretreatment for 1, 3, and 5 h of boiling increased the dimensional stability of densified woods and anti-swelling efficiency values were 8.52%, 63.24%, and 48.94%, respectively. The boiling of wood in NaOH solution decreased the holocellulose content, as well as lignin to a lesser degree, and a lower crystallinity index was observed. The lower hydroxyl groups and a higher proportion of lignin in treated samples seem to have contributed to the high dimensional stability detected.

Sulfate Resistance of Alkali Activated Pozzolans

  • Bondar, Dali;Lynsdale, C.J.;Milestone, N.B.;Hassani, N.
    • International Journal of Concrete Structures and Materials
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    • v.9 no.2
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    • pp.145-158
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    • 2015
  • The consequence of sulfate attack on geopolymer concrete, made from an alkali activated natural pozzolan (AANP) has been studied in this paper. Changes in the compressive strength, expansion and capillary water absorption of specimens have been investigated combined with phases determination by means of X-ray diffraction. At the end of present investigation which was to evaluate the performance of natural alumina silica based geopolymer concrete in sodium and magnesium sulfate solution, the loss of compressive strength and percentage of expansion of AANP concrete was recorded up to 19.4 % and 0.074, respectively.

Research for the production of blast furnace cement mortar using an alkaline activation method (알칼리 활성화 방법에 따른 고로슬래그 경화체 제조 연구)

  • Shin, Jae-Ran;Lee, Ju-Yeol;Park, Byung-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.293-297
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    • 2016
  • This study was performed in order to obtain the effect of the compressive strength of the cured product with manufacturing conditions (amounts of fine aggregate and different types of alkali activator). Material which is the basis of the cured product was used for the blast furnace slag, which has a latent hydraulic activity. Consequently, when using sodium hydroxide as the alkali activator, it is possible to obtain a higher compressive strength than using the calcium hydroxide. And also, it can be added a 10% of fine aggregate with blast furnace slag to improve the compressive strength.

Radiolysis of Methanol and Methanolic Solutions by Co-60 Gamma-Rays (Co-60 갬마線에 의한 Methanol 및 Methanolic Solution 의 Radiolysis)

  • Choi, Sang-Up
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.73-77
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    • 1962
  • Yields of hydrogen, methane, carbon monoxide, formaldehyde and ethylene glycol by gamma-radiolysis of methanol have been determined at room temperature and compared with values reported in the literature. The G-values obtained by the present studies are as follows: $G(H_2)=4.98,\;G(CH_4)=0.28,\;G(CO)=0.09,\;G(HCHO)=2.14\;and\;G(C_2H_6O_2)=3.07.$ The effects of water, methyl borate and alkali halides added to methanol prior to radiolysis have also been investigated. It is observed that alkali iodides and bromides affect the G-values, particularly, of hydrogen, formaldehyde and/or ethylene glycol, whereas alkali chlorides and fluorides have less pronounced effects.

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Investigation on the spectroscopic characteristics for Pu oxidation state in acid and alkali medium (산 및 알칼리 매질에서 Pu 산화수에 대한 분광학적 특성 조사)

  • Lee, Myung-Ho;Kim, Jong-Yun;Kim, Won-Ho;Jung, Euo-Chang;Jee, Kwang-Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.2
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    • pp.103-108
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    • 2007
  • The absorption spectra of Pu in stock solution were measured using a UV-Vis-NIR spectrophotometer after dissolving $PuO_2\;with\;HNO_3$, HF and $HClO_4$. The spectroscopic characteristics of Pu (III, IV, VI) in acidic, neutral and alkali media were investigated. Also, the intensities and position of major peaks for Pu(VI) were observed with increasing acidic and alkali concentration. The variation of oxidation states of Pu(VI) with an adding reducing reactant was investigated in HCl and NaOH medium.

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Automatic pH Control of Nutrient Solution by Physiological Fertilizers in Lettuce Hydroponics (상추 수경재배시 생리적 산, 알칼리를 이용한 배양액 pH의 자동 조절)

  • 김혜진;김영식
    • Journal of Bio-Environment Control
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    • v.5 no.2
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    • pp.145-151
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    • 1996
  • The effectiveness of physiological or chemical acid - alkali solution was investigated as the method to control pH value of nutrient solution in hydroponics dynamically. Lettuces were cultivated using NH$_4$H$_2$PO$_4$ as physiological acid and NaNO$_3$ as physiological alkali or H$_2$SO$_4$ as chemical acid in dynamic control system. The pH of nutrient solution was controlled satisfactorily in the range of pH 5.5-6.5, regardless of treatments. Chemical acid changed pH of solution faster than chemical acid when supplied to the nutrient solution. Any of them did not show any harmful symptom. It is recommended that chemical acid is preferred during the growing stage and physiological acid like as NH$_4$H$_2$PO$_4$ is preferred from several days before harvest stage.

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