• Title/Summary/Keyword: alkali soluble

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Preparation of Water-Soluble Syndiotacticity-Rich Low Molecular Weight Poly(vinyl alcohol) by Solution Copolymerization of Vinyl Pivalate/Vinyl Acetate in Tetrahydrofuran and Saponification (피발산비닐과 아세트산비닐의 테트라히드로푸란계 용액공중합에 의한 수용성 저분자량 교대배열 폴리비닐알코올의 제조)

  • Lyo, Won-Seok;Yeum, Jeong-Hyun;Ji, Byung-Chul
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.187-190
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    • 2002
  • Poly(vinyl alcohol) (PVA) is a representative hydrophilic and water-soluble polymer and widely employed in various applications such as fibers for clothes and industries, films, membranes, medicines for drug delivery system, and cancer cell-killing embolic materials. Moreover, PVA fibers, gels, and films are potentially high-performance materials because they have high tensile and impact strengths, high tensile modulus, high abrasion resistance, excellent alkali resistance, and oxygen barrier property which are superior to those of any known polymers[1,2]. (omitted)

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Evaluation of the Ripening Degree and Functional Properties on Enzyme Modified cheese (Enzyme Modified Cheese의 숙성도 및 기능성 평가)

  • Seo, Hyeong-Ju;Hong, Jae-Hun;Son, Jong-Yeon
    • The Korean Journal of Food And Nutrition
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    • v.9 no.2
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    • pp.143-150
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    • 1996
  • The studies was carried out to investigate ripening degree and functional properties of EMC produced with pancreatic protease and palatase ML. During production of EMC, the amounts of free amino acid and free fatty acid were increased with increasing the reaction time. The amount of total nitrogen(T-N) and water soluble nitrogen(WSN) were increased with increasing time. EMC had contents of 1.79eA T-N and 0.52o WSN at 60 min of hydrolysis time. SRI and FRI value had also a similar correlationship. On the gel filtration, 2 kinds of soluble proteining capacity was also shown in alkali solution. Furthermore the foaming stability had the same result as that of the solubility. The water absorption of EMC showed the highest level at pH 4.0 and 5.0.

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Analysis of Chemical and Physical Characteristics of Log Woods for Oak Mushroom Production Depending on Cultivation Periods and Steam Explosion Treatment (표고버섯 골목의 사용연수에 따른 화학적, 물리적 성상 및 폭쇄처리 후 변화 관찰)

  • Koo, Bon-Wook;Park, Jun-Yeong;Lee, Soo-Min;Choi, Don-Ha;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.1 s.129
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    • pp.77-86
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    • 2005
  • In order to investigate the ability of log wood for oak mushroom production as a source of an alternative energy, both chemical and physical characteristics of log wood were investigated according to the cultivation periods. Also, both chemical and physical characteristics of material that treated by steam explosion were investigated to confirm the pretreatment effect by remaining enzyme as a control. The contents of ash, water-, alkali- and organic soluble extracts have been increased after the inoculation. It appeard that holocellulose contents substantially decreased and the contents of lignin as another main component of wood remained constant after the inoculation. However this result implied that indeed, a sufficient amount of lignin has been degraded paritially by enzymes of oak mushroom Lentinus edodes if we consider that the amount of holocelulose was substantially reduced. It also indicated that the degree of degradation gradually progressed but crystallinity decreased after the inoculation. The contents of water-, alkali- and organic soluble extracts have been increased by steam explosion. Holocellulose contents increased within narrow limits and lignin contents remained constant. However the contents of holocellulose and lignin have been decreased by steam explosion, considering that the amount of other extractives was relatively increased. The degree of crystallinity and lignin contents reduction by steam explosion was almost similar to the result obtained by increasing cultivation periods. According to the results, log woods for mushroom production have a potential as material for developing alternative energy.

Fermentative Hydrogen Production from the Pretreated Food-Processing Waste and Sewage Sludge using Chemical/Ultra-Sonication (두부제조폐기물과 하수슬러지의 화학/초음파 전처리에 의한 가용화 및 혐기발효 수소생산)

  • Kim, Mi-Sun;Lee, Dong-Yeol;Kim, Dong-Hun;Kim, Ok-Sun;Lim, So-Yung
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.580-586
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    • 2010
  • Acid and alkali pretreatments were applied to tofu processing waste (TPW) to increase the solubility of ingredients in TPW. Pretreatment at 1.0% of HCl and 2.5% of NaOH condition resulted in the increase of SCOD concentration from 3.2 g COD/L to 27 g COD/L and 33 g COD/L, respectively. The acid and alkali-pretreated TPW was studied for its fermentative $H_2$ production capacity in batch mode using a thermophillic mixed culture. Alkali pretreatment on presence of 2.5% NaOH exhibited more soluble portion released compared to acid pretreatment using HCl, however the $H_2$ production from acid pretreated TPW was better than alkali-pretreated TPW probably due to the sodium inhibition on microbial activity. In addition, sewage sludge was externally added to the acid-pretreated (1.0% HCl) TPW by 20% (on volume basis). Average H2 production rate was increased from 31 to 78 ml/L-broth/hr, and it was attributed to the high buffer capacity and abundant nutrients especially divalent cation in sewage sludge.

Effects of Various Amendments on Heavy Metal Stabilization in Acid and Alkali Soils (여러 안정화제가 산성 및 알칼리 토양에서 중금속 안정화에 미치는 영향)

  • Kim, Min-Suk;Min, Hyungi;Kim, Jeong-Gyu;Koo, Namin;Park, Jeong Sik;Bak, Gwan In
    • Korean Journal of Environmental Agriculture
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    • v.33 no.1
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    • pp.1-8
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    • 2014
  • BACKGROUND: Recent studies using many amendments for heavy metal stabilization in soil were conducted in order to find out new materials. But, the studies accounting for the use of appropriate amendments considering soil pH remain incomplete. The aim of this study was to investigate the effects of initial soil pH on the efficiency of various amendments. METHODS AND RESULTS: Acid soil and alkali soil contaminated with heavy metals were collected from the agricultural soils affected by the abandoned mine sites nearby. Three different types of amendments were selected with hypothesis being different in stabilization mechanisms; organic matter, lime stone and iron, and added with different combination. For determining the changes in the extractable heavy metals, water soluble, Mehlich-3, Toxicity Characteristic Leaching Procedure, Simple Bioavailability Extraction Test method were applied as chemical assessments for metal stabilization. For biological assessments, soil respiration and root elongation of bok choy (Brassica campestris ssp. Chinensis Jusl.) were determined. CONCLUSION: It was revealed that lime stone reduced heavy metal mobility in acid soil by increasing soil pH and iron was good at stabilizing heavy metals by supplying adsorption sites in alkali soil. Organic matter was a good source in terms of supplying nutrients, but it was concerning when accounting for increasing metal availability.

Modification of Sweet Potato $\beta$-Amylase with Periodate-Oxidized Soluble Starch (과요소산 산화 전분에 의한 고구마 $\beta$-아밀라제의 수식)

  • 안룡근;지의상
    • The Korean Journal of Food And Nutrition
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    • v.3 no.2
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    • pp.123-132
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    • 1990
  • Sweet potato $\beta$-amylase is a tetrameric enzyme consisting of four identical polypeptide chains with a molecular weight of 5.6$\times$104, though most of the other $\beta$-amylases are monomeric enzymes. But, the relationship between subunit structure and catalytic function of the enzyme is not known. This study was done to know what the function of the subunit structure of the enzyme is. We obtained the monomer from the enzyme by the treatment of SDS, alkali pH buffer and urea. But the monomer had not activity. We tried to prepare the active monomer from the enzyme by the modification with periodate-oxidized soluble starch , In the result, we succeeded in isolating an active monomer as an oxidized soluble starch-conjugated form The active monomer had 57% of the original activity, 13.2% of the sugar and the molecular weight was estimated to be 5.4$\times$104. This results suggest that the tetrameric form of the enzyme is a most stable one and exists in nature, and the subunit structure of the enzyme Plays an important role in stabilization but not catalytic function.

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Effect of Low Molecular Alginates on Cholesterol Levels and Fatty Acid Compositions of Serum and Liver Lipids in Cholesterol-Fed Rats (저분자화알긴산이 콜레스테롤식이 흰쥐의 혈청과 간장지질의 콜레스테롤 수준 및 지방산 조성에 미치는 영향)

  • LEE Dong-Soo;NAM Taek-Jeong;PYEUN Jae-Hyeung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.3
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    • pp.399-408
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    • 1998
  • The effect of low molecular alginates feeding on the cholesterol levels and fatty acid compositions of rat serum and liver lipid were investigated. After one week basal diet feeding, four week old Sprague-Dawley male rats were fed with water soluble and acid $\cdot$alkali soluble alginate extracted from sea mustard (Undaria pinnatifida) and giant kelp (Macrocystis pyrifera), and their low molecular alginates prepared by the HCl partial hydrolysis. The feeding efficiency of the alginate fed group was ranged in 0.37$\~$0.44, which was 0.03$\~$0.05 lower than that of the basal diet group. Also, there was much less increase of liver weight in the alginate fed group. The water soluble alginate showed more significant effect in reducing the total cholesterol, free cholesterol, LDL-cholesterol, triglyceride and phospholipid of serum and liver lipid than the acid$\cdot$alkali soluble alginate. The effect was much better with low molecular alginate (reducing effect by the low-molecularization : Water soluble alginate - serum lipid; total cholesterol $59\%$, free cholesterol $65\%$, LDL-cholesterol $96\%$, triglyceride $50\%$, and phospholipid $36\%$. liver lipid: total cholesterol $4\%$, free cholesterol $62\%$, LDL-cholesterol $44\%$, triglyceride $33\%$, and phospholipid $44\%$. acid$\cdot$alkali soluble alginate - serum lipid; total cholesterol $52\%$: free cholesterol $97\%$, LDL-cholesterol $78\%$ triglyceride $32\%$, and phospholipid $64\%$. liver lipid; total cholesterol $11\%$, free cholesterol $12\%$, LDL-cholesterol $10\%$, triglyceride $27\%$, and phospholipid $21\%$). The effect of low molecular alginate feeding on the fatty acid composition of serum and liver lipid reflects the remarkable increase of polyenoic acid, over $44\%$ in serum lipid and about $70\%$ in liver lipid, comparing to the cholesterol fed group. The overall results indicated that feeding of low molecular alginates improves physiological function of rats by changing the serum and liver lipid composition.

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Modification of Papain with $IO_4-Oxidized$ Soluble Starch ($IO_4$-산화 가용성 전분에 의한 파파인의 변형)

  • Ann, Yong-Geun
    • The Korean Journal of Food And Nutrition
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    • v.20 no.4
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    • pp.349-355
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    • 2007
  • Periodate-oxidized soluble starch was reacted with papain at pH 4.0, pH 7.0, and pH 9.7, and an oxidized soluble starch-papain conjugate was produced. When compared with native papain, the specific activity decreased to 60%, in both the modified papain reacted with 0.4% $NaBH_4$ and in the modified papain not reacted with $NaBH_4$. The specific activity decreased to 70% in the modified papains reacted with 1.5% $NaBH_4$ and 4.0% $NaBH_4$, respectively. The reduction by $NaBH_4$ did not have an effect in the thermal stability of either the modified or nonmodified papain. An activity of 54.7% remained in the papain modified at pH 4.0, which was incubated at $80^{\circ}C$ for 40 min. The papains modified at pH 7.0 and pH 9.7 and incubated for 40 min at two different temperatures, respectively, were stable to $60^{\circ}C$, and at $80^{\circ}C$ their activities at 56.3% and 44.1 %, respectively. The modified papain's thermal stability pattern was similar to that of native papain, with no increase in its statbility. In the range of pH $2.0{\sim}13.0$, the stability of the papain modified at pH 4.0 decreased greatly between pH $3.0{\sim}5.0$, but it was similar to the native papain at other pH values. The stability of the papain modified at pH 7.0 showed a similar pattern to the native papain at pH $2.0{\sim}6.0$, while its stability increased when moving into the alkali pH range. The papain modified at pH 9.7 also had increased stability, when moving into the alkali range. The results of Hammerstein milk casein, which was reacted with the papains modified at pH 4.0, pH 7.0, and pH 9.7, respectively, and analyzed by FPLC, showed different peaks according to the different modification pHs, and the greatest peak differences were observed with the modification at pH 9.7.

A Comparative Study on Physical Properties and Gel formation abilities of Hot- water Extractable Material, Water-Soluble Alginate and Alkali-soluble Alginate Extracted from Laminaria japonica in East Sea, Korea (한국산 다시마로부터 추출된 열수추출물, 수용성알긴산 및 알칼리가용성 알긴산의 물리적 성상과 겔 형성능)

  • CHO Soon-Yeong;KANG Hyun-Joo;JOO Dong-Sik;LEE Jung-Suck;KIM Sang Moo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.6
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    • pp.774-778
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    • 1999
  • Tee yields, physical properties and gel formation abilities or hot-water extractable material (HWEM) and water-soluble alginate (WSA) extracted from Laminaria japonica were estimated and compared with those of the alginate (ASA) extracted with alkali solution in the routine procedure. The contents of HWEM, WSA and ASA in Laminaria japonica were 8.3, 2.5 and $19.1\%$, respectively. The HWEM and WSA had no gel formation ability, whereas the ASA had a good gol formation ability. The HWEM and WSA were almost not viscous even in $1.5\%$ of the sample solution, whereas the ASA was very highly viscous in above $0.5\%$ of sample solution. The melting points of $1\%$ solution of HWEM, WSA and ASA sample were 31, 24 and $14^{\circ}C$, respectively. The solubility at melting point of each samples varied from 2.3 to 2.6 g/100 g water, and a few differences were observed.

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Study of Hair Melanins in Various Hair Color Alpaca (Lama Pacos)

  • Fan, Ruiwen;Yang, Gang;Dong, Changsheng
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.4
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    • pp.444-449
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    • 2010
  • The aim of this study was to measure the hair melanins of various colors and to find the relationship between the quantity of melanins and hair color phenotypes in alpacas. According to the Munsell color system, 3 healthy alpacas were selected for each of the 22 different hair color phenotypes (66 alpacas altogether). Alpaca hair was taken from the lateral thoracic region and then dissolved with different solutions to obtain melanins. The values of alkali-soluble melanins (ASM), eumelanin (EM) and pheomelanin (PM) were measured by spectrophotometric assay, and labeled as Sp.ASM, Sp.EM and Sp.PM, respectively. Data were analyzed using SPSS11.5 software. Results showed that average Sp.ASM and Sp.PM were increased as the color deepened from white to black, ranging from 0.500 to 4.543 for Sp.ASM and from 0.268 to 1.457 for Sp.EM. However, average Sp.PM had no such apparent relationship with color. Based on the value of Sp.ASM and EM, 7 hues were produced and gray was a single hue. Most of the data were in a normal distribution (p>0.10). ANOVA analysis showed that mean values of Sp.ASM, Sp.EM and Sp.PM were significantly different (p<0.05). The results also showed that Sp.ASM was positively correlated with Sp.EM but the correlation between Sp.ASM and Sp.PM was not significantly different from 0. It is concluded that EM is the major constituent of alpaca hair melanin; there is a significant correlation among ASM, EM and alpaca hair colors, and EM is the most reliable parameter for distinguishing these groups.