• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1995년도 하계학술대회 논문집 C
• /
• pp.1196-1198
• /
• 1995

In this paper, stability improvement of fragile LB films was attempted by monolayers at the air-water interface and crosslinking of the resulting LB films. The spreading polymers were synthesized by radical copolymerization of monoalkyl with oligoethyleneglycol methyl ether, and poly(allylamine) was employed as the subphase polymer. The monolayer properties have been studied by the surface pressure-area($\pi$-A) isotherms. Interaction between polymers and metal ions at the air-water interface and in their LB films were investigated. From the FT-IR(Reflection and Transmission) spectra, the formation of carboxylate ions and the relative orientation of the side chains could be confined. The monolayers were transferable on various substrates, and the resulting LB films were characterized by SEM and VIS-UV absorbance.

• Tribology and Lubricants
• /
• 제35권2호
• /
• pp.94-98
• /
• 2019

The riblet structure like shark skin has been widely studied owing to its drag reduction and anti-fouling properties. In this study we simulated the wettability of an oil droplet on a riblet surface. We developed a numerical analysis method using the Wenzel equation and Cassie-Baxter equation that can estimate the contact angle with a penetrated depth of the droplet on rough surfaces. Riblet surfaces with nine scales composed of five hemi-elliptical ribs are generated numerically. The variation of contact angles with fractional depth of penetration for the generated riblet surfaces with and without coatings is demonstrated in the condition of solid-air-oil and solid-water-oil interfaces. The contact angle for the uncoated surface decreases with increasing fractional depth of penetration more drastically than that for the coated surface. For the effect of surface roughness on the contact angle of the droplet, the oleophilic surface gives lower contact angle when the surface is rougher, whereas the oleoophobic surface gives higher contact angle with higher roughness To verify the analysis results, the wetting angle was measured in the solid-air-oil interface and solid-water-oil interface for the shark-skin template and shark-skin replica. The effects of teflon coating were also evaluated. It is shown that the simulation results cover the experimental ones.

• Restorative Dentistry and Endodontics
• /
• 제28권6호
• /
• pp.498-503
• /
• 2003

The purpose of this study was to evaluate the rewetting effect of water-based primer on the air-dried dentin. In this in vitro study, freshly extracted non-caries human molars and three-step adhesive system(SBMP) were used. Freshly extracted non-caries human molars and three-step adhesive system(SBMP) were used. Flat occlusal dentin surface were prepared using low-speed diamond saw, Prepared teeth were randomly divided into three groups. Group 1.(W): etched(35% phosphoric acid for 15s) and blot-dried, Group 2.(5D): 5s air-dried, Group 3.(30D): 30s ail-dried, To obtain color contrast in CLSM observation, primer was mixed with rhodamine B and bonding resin was mixed with fluorescein. Microscopic sample of each group were obtained after longitudinal section. Morphological investigation of resin-dentin interface and thickness of hybrid layer measurement using CLSM were done. Microtensile bond strength for each specimen was measured. Specimen were observed under microscope to examine the failure patterns of interface between resin and dentin. The results of this study were as follows: 1. The results(mean) of Thickness of hybrid layer were W:19.67, 5D:20.9, 30D:10$\mu\textrm{m}$. Only 30D had statistically significant differences to Wand 5D(P<0.05). 2. The results(mean) of Microtensile bond strength were W:16.02, 5D:14.69, 30D:11.14MPa. Only 30D had statistically significant differences to Wand 5D(P<0.05). 3. There were positive correlation between Thickness of hybrid layer and microtensile bond strength(P<0.05).

• Corrosion Science and Technology
• /
• 제22권2호
• /
• pp.115-122
• /
• 2023

This study aimed to elucidate causes of corrosion of heat transport pipes and air vents installed under a manhole of heat transport facilities and suggest effective anticorrosive measures by applying paints or adhesive tapes. It was found that air vent corrosion was attributed to corrosion under insulation caused by the inflow of water and the enrichment of chloride ions. The infiltrated water caused a hydrolysis of polyurethane foam (PUF) insulation by concentrating chloride ions at the interface between a pipe and the PUF. As insulator deteriorated, more chloride ions were eluted as confirmed by ion chromatograph (IC) analysis. As an effective method to prevent air vent corrosion, different types of paints and adhesive tapes with higher corrosion resistance on chloride ions were applied and environmental resistance tests were performed with those samples. Based on environmental test results of samples exposed to 10% HCl solution, it was revealed that a wax tape was the most adequate from a viewpoint of stability at operating condition, environmental resistance, surface treatment, and field applicability.

• 한국가시화정보학회지
• /
• 제10권2호
• /
• pp.14-19
• /
• 2012

An optical fiber probe system for measuring the local void fraction in the air-water two-phase flow was developed with a 1550 nm light source. Air was injected through a nozzle placed in the center of the bottom wall of a water-filled cylindrical tank. The optical fiber probe having a diameter of $125{\mu}m$ was sufficiently thin to resolve the air-water interface of the bubbly flows. To verify the performance of the optical fiber probe, the synchronized high speed visualization study using a high speed camera was carried out. Comparison between the optical signals and the instantaneous bubble diffraction images confirms that the optical fiber probe is very accurate to measure the void fraction in two-phase flows. The estimated bubble diameter and the rising velocity by the optical fiber probe have 1% and 5% of accuracy, respectively.

• KIEE International Transactions on Electrophysics and Applications
• /
• 제11C권3호
• /
• pp.49-52
• /
• 2001

The derivatives of spironaphthooxazine gause photoisomerization when they are illuminate with UV light. We investigated the photoisomerization of spironaphthooxazine derivatives for holographic memory. Langmuir-Blodgett (LB) films contain amphiphile spironaphthooxazine derivatives which can be applied in molecular devices by a change of molecular level energy and a refractive index. In order to investigate the photoisomerization of spironaphthooxazine derivatives at the air/water energy and a refractive index. In order to investigate the photoisomerization of spironaphthooxazine derivatives at the air/water interfaces, spironaphthooxazine derivatives with side alkyl chains were synthesized. The films of the spironaphthooxazine derivatives were characterized by the measurement of UV/vis spectroscopy, Brewster Angle Microscopy (BAM) and Atomic Force Microscopy (AFM). The monolayers of the spironaphthooxazine derivatives mixed with stearic acid were stable at the air/water interface and visualized by the measurement of BAM. The spironaphthooxazine derivative monolayers on the glass surface showed the maximum efficiency of diffraction as 0.99% by the measurement of holography.

• 한국항만학회지
• /
• 제13권1호
• /
• pp.167-174
• /
• 1999

Numerical analysis of two-fluid flows for both water and air is carried out. Free-Surface flows with an arbitrary deformation have been simulated around two dimensional submerged hydrofoil. The computation is performed using a finite volume method with unstructured meshes and an interface capturing scheme to determine the shape of the free surface. The method uses control volumes with an arbitrary number of faces and allows cell-wise local mesh refinement. the integration in space is of second order based on midpoint rule integration and linear interpolation. The method is fully implicit and uses quadratic interpolation in time through three time levels The linear equation systems are solved by conjugate gradient type solvers and the non-linearity of equations is accounted for through picard iterations. The solution method is of pressure-correction type and solves sequentially the linearized momentum equations the continuity equation the conservation equation of one species and the equations or two turbulence quantities.

• 대한조선학회논문집
• /
• 제47권1호
• /
• pp.1-10
• /
• 2010

In the present paper, a numerical method based on the constraint interpolation profile (CIP) method is applied for simulating two-dimensional violent sloshing problems. The free surface boundary value problem is considered as a multiphase problem which includes water and air. A stationary Cartesian grid system is adopted, and an interface capturing method is used to trace the shape of free surface profile. The CIP combined unified procedure (CCUP) scheme is applied for flow solver, and the tangent of hyperbola for interface capturing (THINC) scheme is used for interface capturing. Numerical simulations have been carried out for partially-filled 2D tanks under forced sway and roll motions at various filling depths and frequencies. The computational results are compared with experiments and/or the other numerical results to validate the present numerical method.

• Macromolecular Research
• /
• 제12권1호
• /
• pp.127-133
• /
• 2004

We have studied the surface micelle formation of polystyrene-b-poly(2-vinyl pyridine) (PS-b-P2VP) at the air-water interface. A series of four PS-b-P2VPs were synthesized by anionic polymerization, keeping the PS block length constant (28 kg/㏖) and varying the P2VP block length (1, 11, 28, or 59 kg/㏖). The surface pressure-area ($\pi$-A) isotherms were measured and the surface morphology was studied by atomic force microscopy (AFM) after Langmuir-Blodgett film deposition onto silicon wafers. At low surface pressure, the hydrophobic PS blocks aggregate to form pancake-like micelle cores and the hydrophilic P2VP block chains spread on the water surface to form a corona-like monolayer. The surface area occupied by a block copolymer is proportional to the molecular weight of the P2VP block and identical to the surface area occupied by a homo-P2VP. It indicates that the entire surface is covered by the P2VP monolayer and the PS micelle cores lie on the P2VP monolayer. As the surface pressure is increased, the $\pi$-A isotherm shows a transition region where the surface pressure does not change much with the film compression. In this transition region, which displays high compressibility, the P2VP blocks restructure from the monolayer and spread at the air-water interface. After the transition, the Langmuir film becomes much less compressible. In this high-surface-pressure regime, the PS cores cover practically the entire surface area, as observed by AFM and the limiting area of the film. All the diblock copolymers formed circular micelles, except for the block copolymer having a very short P2VP block (1 kg/㏖), which formed large, non-uniform PS aggregates. By mixing with the block copolymer having a longer P2VP block (11 kg/㏖), we observed rod-shaped micelles, which indicates that the morphology of the surfaces micelles can be controlled by adjusting the average composition of block copolymers.

• 에너지공학
• /
• 제12권4호
• /
• pp.259-266
• /
• 2003

안전감압계통 작동시 수조에서 발생하는 공기 기포군의 진동 하중을 줄이기 위해 ABB-Atom sparger에 는 하중저감 링이 설치되어 있다. 하중저감 링이 압력장에 미치는 영향을 알아보기 위해, 본 연구에서는 하중저감 링이 없는 ABB-Atom sparger를 통해 수조 내로 방출되는 공기 기포군의 진동에 대한 수치해석을 상용 열수력 해석 코드인 FLUENT 4.5를 사용하여 수행하였다. 코드에 내재된 다상유동 모델 중 VOF(Volume Of Fluid)모델을 사용하여 물, 공기 및 증기 유동을 모의하였다. 해석결과를 기존의 해석결과와 비교하여 하중저감 링은 벽면 압력 하중을 줄이는 효과가 있음을 확인하였다. 아울러 배관내의 공기량과 배관 입구 조건이 벽면 압력 진동에 미치는 영향도 분석하였다.