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Characterization of Respirable Suspended Particles and Polycyclic Aromatic Hydrocarbons associated with Environmental Tobacco Smoke

  • Baek, Sung-Ok;Park, Jin-Soo;Kim, Mi-Hyun;Roger A, Jenkins
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.E
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    • pp.1-17
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    • 2000
  • In this study, the concentrations of particulate organic constituents of environmental tobacco smoke(ETS) were determined using an environmental smog chamber, where ETS is the sole source of target compounds. ETS was generated in a 30 ㎥ environmental chamber by a number of different cigarettes, including the Kentucky 1R4F reference cigarette and eight commercial brands. A total of 12 experimental runs was conducted, and target analytes included a group of ETS markers both in vapor and particulate phase and a class of polycylic aromatic hydrocarbos(PAHs) associated with ETS particles. The mass concentrations of PAH in ETS particles were also determined. The average contents of benzo(a) pyrene and benzo(a) anthracene in ETS particles for the commercial brands were 12.8 and 21.5$\mu\textrm{g}$/g, respectively, There values are all somewhat higher than those determined previously by other studies. Results form the chamber study are further used to estimate the average and variability of cigarette yields for target compounds associated with ETS. Finally, ratios of RSP to the surrogate standards of UVPM, FPM and solanesol were calculated for each sample. The average conversion factors factors for the eight commercial brands were 7.3, 38, and 41 for UVPM, EPM, and solanesol, respectively. The UVPM and FPM factors are in good agreement with the recently published values. Whereas there might be a substantial difference in the solanesol content among cigarettes produced in different countries, the variability is somewhat greater than those of UVPM and FPM, Unfortunately, comparison of the PAH yield data from this study with literature values was complicated by a lack of consistency in cigarette smoke generating methodology. Validation of the PAH yields was also difficult due to a lack of information on the ETS related PAH in the literature. From and engineering viewpoint , however, these data on the cigarette yields of ETS components may still provide useful information to studies on the mathematical modeling of indoor air quality management regarding tobacco smoke as a source of interest, or to studies on the assessment of human exposure to ETS.

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A Comparative Study of Housing Cultures between Korean-Immigrants and Australians in Melbourne, Australia (호주인과 호주교민의 주공간 사용 및 주생활을 통한 주거문화 비교에 관한 연구 - 멜버른(Melbourne)을 중심으로)

  • Lee Young-Shim
    • Journal of Families and Better Life
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    • v.24 no.1 s.79
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    • pp.159-179
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    • 2006
  • Each ethnic group has different cultural backgrounds and each culture has developed with its own traditions. The interaction between different cultures is getting more active through acculturation and cultural contacts. The purpose of this study was to compare domestic living of Korean immigrants with Australians in the form of a Cross-Cultural study. For this, usage of domestic space and seating style of 52 Korean households and 53 Australian households in Melbourne were analyzed. Ethnographic research with questionnaire was used. The results of the research were as follows. 1. The most popular type of Living-Dining-Kitchen arrangement was L+ K. D for Koreans and L. D . K for Australians. 2. A laundry room was indispensable for both and they all wanted to do ironing in there as well as dry. Both were satisfied with the type which toilet was separated from the bathroom Drain hole on the floor of the bathroom was not indispensable for most Koreans and Australians. 3. Koreans and Australians were doing various activities in living area and both were getting together around kitchen(dining) area. The particular thing of Koreans was that they were using the main bedroom with multiple purpose. 4. The seating style of Koreans and Australians belong to chair-seating style generally. But Koreans were using floor seating style in making bed for the guest and making Kimchi. Koreans and Australians were using mixed style of floor seating and chair-seating in relaxing time with watching TV, treating guest or so. 5. Koreans were not satisfied with using carpet cause of dust but Australians were satisfied with the carpet cause of warmness. 6. Most Koreans and Australians were take off shoes inside of the house. Koreans were organize shoes around the front door of the house usually and Australians were organize shoes in bedroom usually. 7. The most popular heating system was ducted heating for both. The level of satisfaction about ducted heating was low for Koreans because they though that it could contaminate air. Australians were satisfied with ducted heating because they though that this one was fit on the weather of this area. 8. Living room was the most important one for Koreans and Australians and they also thought it should be decorated well for entertaining guests. Most Koreans were estimate that the brightness of the light of the house was not enough but it was estimated to moderate for Australians on the contrary.

Initial Risk Assessment of Acetanilide in OECD High Production Volume Chemical Program

  • Park, Hye-Youn;Park, Yoonho;Sanghwan Song;Kwon, Min-Jeoung;Koo, Hyun-Ju;Jeon, Seong-Hwan;Na, Jin-Gyun;Park, Kwangsik
    • Toxicological Research
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    • v.18 no.1
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    • pp.13-22
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    • 2002
  • In Korea, 2,320 tonnes of acetanilide were mostly wed as intermediates for synthesis in phar-maceuticals or additives in synthesizing hydrogen peroxide, varnishes, polymers and rubber. Only small amount of 120 kg were wed as a stabilizer for hydrogen peroxide solution for hair colouring agents in 1998. Readily available environmental or human exposure data do not exist in Korea at the present time. However, potential human exposures from drinking water, food, ambient water and in work places are expected to be negligible because this chemical is produced in the closed system in only one company in Korea and the processing factory is equipped with local ventilation and air filtering system. Acetanilide could be distributed mainly to water based on EQC model. This substance is readily biodegradable and its bioaccumulation is low. Acute toxicity of acetanilide is low since the L $D_{50}$ of oral exposure in rats is 1,959 mg/kg bw. The chemical is not irritating to skin, but slightly irritating to the eyes of rabbits. horn repeated dose toxicity, the adverse effects in rats were red pulp hyperplasia of spleen, bone marrow hyperplasia of femur and decreased hemoglobin, hematocrit and mean corpuscular hemoglobin concentration. The LOAEL for repeated dose toxicity in rats was 22 mg/kg/day for both sexes. Acetanilide is not considered to be genotoxic. In a reproductive/developmental toxicity study, no treatment-related changes in precoital time and rate of copulation, impregnation, pregnancy were shown in all treated groups. The NOAELs for reproduction and developmental toxicity (off-spring toxicity) are considered to be 200 mg/kg bw/day and 67 mg/kg bw/day, respectively. Ecotoxicity data has been generated in a limited number of aquatic species of algae (72 hr- $E_{b}$ $C_{50}$; 13.5 mg/l), daphnid (48hr-E $C_{50}$ > 100 mg/l) and fish (Oryzias latipes, 96hr-L $C_{50}$; 100 mg/l). Form the acute toxicity values, the predicted no effect concentration (PNEC) of 0.135 mg/1 was derived win an assessment factor of 100. On the basis of these data, acetanilide was suggested as currently of low priority for further post-SIDS work in OECD.in OECD.D.

Physical and Mechanical Properties of Magnesium Oxide Matrix depending on Addition Ratio of Magnesium Chloride (염화마그네슘 첨가율에 따른 산화마그네슘 경화체의 물리 및 역학적 특성)

  • Kim, Heon-Tae;Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.308-313
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    • 2014
  • Recently, for longevity of resident building, the main trend is that the change of the inside space organization of resident building from wall construction to rhamen construction, which resulted in increase in use of lightweight composite panel. Thus, in this study, authors analyzed the engineering property of oxide of magnesium depending on the magnesium chloride addition ratio. The results of this research is expected to contribute on providing a fundamental material for the surface materials of lightweight composite panel. As the result of the experiment, as fluidity increased, air content decreased and initial set and final set as the magnesium chloride addition ratio increase. In the aspect of flexural strength and compressive strength, the test specimen showed the highest strength at 40% of the magnesium chloride addition ratio. At 20% of the magnesium chloride addition ratio, the test specimen showed the lowest water absorption rate. As the magnesium chloride addition ratio increases, the expansibility tends to increase as well in the aspect of shrinkage strain. After observing microstructure, we can see hydration products in the form of needle. It appeared high flexural strength because the hydration products have mineral fibrous tissue shape, which also contribute to the cause of the expansibility.

A Study on the Model Test for Pneumatic Mine-Filling (공압식 갱내충전을 위한 모형실험 연구)

  • Yang, In-Jae;Shin, Dong-Choon;Yoon, Byung-Sik;Mok, Jin-Ho;Kim, Hak-Sung;Lee, Sang-Eun
    • Tunnel and Underground Space
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    • v.24 no.6
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    • pp.449-463
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    • 2014
  • There are many case studies and application cases in abandoned mines for hydraulic filling method filled by slurry or paste form, but research on the pneumatic filling is not applied in Korea. The damage of steel pipe is occurred by wear due to the flow of filling material in the bent area of steel pipe in traditional pneumatic filling method. In this study, the new pneumatic filling method was developed using a newly devised improved nozzle to improve the above problem. The model test for mine filling was performed in the laboratory for the simulated accessible or inaccessible mine cavities, and the filling efficiency by the results obtained from the test was calculated. The filling efficiency was analyzed from the variation of outlet angle, feed rate and grain size of sand in model test of simulated accessible mine cavity. The superiority of improved pneumatic filling method was proved through the analysis of filling efficiency by the results obtained from each model tests of gravitational, traditional, and improved filling method in simulated inaccessible mine cavity.

Characteristics for Consolidation and Shear Strength of Bottom Ash Compaction Pile According to Replacement Ratio in Clay (점토지반에 적용된 저회다짐말뚝의 치환율에 따른 압밀침하특성 및 전단특성)

  • Park, Sehyun;Jee, Sunghyun;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.7
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    • pp.57-63
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    • 2010
  • The necessity of effective and economical improvement for soft ground is required more and more as mountains form 70% of country. The soft ground improvement methods for ocean development are sand compaction pile method, displacement method are applied to the soft ground improvement from ocean development pre-loading method, air pressure method, well point method, pack drain method, quicklime pile method etc. Among them, the sand compaction pile method, has many problems such as the economical problem on importing materials due to the lack of sand and destroying the nature while collecting sand. To replace the sand with other alternative materials, a study on the bottom ash compaction pile method because the bottom ash has the similar engineering properties with sand. Therefore, in this study, after compose the complex soil with a replacement rate of 10~80% and a large direct shear test, shear test, consolidation test with replacement rates of bottom ash are performed to estimate whether its shear and consolidation characteristics are suitable for the alternative material of compaction pile method. As a result of test, Shear Strength Parameters tend to be increased in accordance with the increase of replacement ratio of bottom compaction pile, and Settlement Reduction Factor and $t_{90}$ tend to be decreased.

Effect of Metal Chloride Coloring Liquids on Color and Strength Changes of Tetragonal Zirconia Polycrystals (금속염화물 착색제 침투가 정방정 지르코니아 다결정체의 색조와 강도 변화에 미치는 영향)

  • Oh, Jong-Jin;Noh, Hyeong-Rok
    • Journal of dental hygiene science
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    • v.15 no.5
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    • pp.577-584
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    • 2015
  • The purpose of this study was to evaluate the effect of metal chloride infiltration treatment on color and strength changes of the yttria-stabilized tetragonal zirconia polycrystals (Y-TZP). Fifty disc specimens were prepared with a Y-TZP powder (ZPEX; Tosoh, Japan). Thirty different metal chloride solutions containing 0.03~0.08 wt% chromium and 0.03~0.07 wt% terbium ions were prepared. Presintered Y-TZP specimens were soaked in metal chloride coloring liquids for 3 minutes and sintered in air at $1,450^{\circ}C$ for 2 hours. The color of the specimens was measured with spectrophotometer and color difference (${\Delta}E^*$) was obtained based on the CIE $L^*$, $a^*$, $b^*$ color coordinate values. To evaluate the effect of metal chloride infiltration strength changes, the biaxial flexural test was performed at crosshead speed 0.5 mm/min. Colors of the sintered Y-TZP showed the colors of Vita shade guide A1, A2 and A3 with the infiltration of chromium and terbium chloride solutions. Density of the sintered Y-TZP increased by the infiltration of chromium and terbium chloride solutions. Bi-axial flexural strength of the sintered Y-TZP did not show statistically significant differences by the infiltration of chromium and terbium chloride solutions (p>0.05). Chromium and terbium chloride did not affect the crystal phase of zirconia, and all specimens showed tetragonal phase. Accordingly, this study suggests that chromium and terbium chlorides can make colored zirconia while adding in a liquid form. The color of colored zirconia differ from that of vita shade guide but it can use all ceramic restoration as substructure in dental clinic.

Study on the Complaint ratio of Respiratory Symptoms of Dental Laboratory Technician in Small Cities in Jullabuk-do (전라북도(全羅北道) 중소도시(中小都市) 치과기공사(齒科技工士)의 호흡기장애(呼吸器障碍) 호소율(呼訴率)에 대한 조사(調査))

  • Lee, In-Kye
    • Journal of Technologic Dentistry
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    • v.17 no.1
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    • pp.26-40
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    • 1995
  • A survey has been performed for the dental technicians and office workers in small cities of Julla buk-do on theis problem of cough, phlegm, wheezing, nasal cattarrh & cold, and breathlessness by using SUN-81-AL survey form which is a guletionaire on respiratory symptons The results of the analysis are as follaus. 1. The complaint on cough was made by 15 dental technicians(21.4% and by 10 office workerr(16.7%). Dental technicians showed higher complaint on cough than office workers. The predietor variable for cough was the working hours for dental technicians and the period of smoking for the office sorkess. 2. The complaints on phelgm was made by 34 dental technicians(48.6%) and by 9 office workers(15.0%). The predictor variable on phelgm was the working hour for dental techniume and the period of smoking for the office workers. There was no statistically significant difference between two group on their complaint level. 3. The complaint on the breathlessnesr was made by 24 dental technicians(34.3%) and by 22 office workers(36.7%). The predictor variable on breathlessness was the period of smoking for dental technicians and the working hour for office workers. 4. The wmplaing on nasal catarrh & cold wax made by 29 dental technicians(41.4%) and 22 office workers(36.7%). The predictr variable on nasal catarrh & cold was the working hour for dental workerr, and the perird of smoking for the office workers. 5. The complaint on wheezing was made by 9 dental technicians(12.9%) and 8 office workers(13.3%). The primary predictor variable on wheezing was the working hour for both groups, and the secondary predictor variable was the period of smoking. 6. The complaint on the chest and lung dislase was made by 12 dental technicians(17.1%) and 4 office workers(6.7%) dental technicians showed bigher complaint. on chest and lung disease than the office workers. Bronchitis was the higher frequency illuess reported from both of the groups among chest and lung disease. 7. In conclusion, the predictor variable on respiratory illness was the working hour for dental techniciane, and the period of smoking for the office workers 8. 25 dental technicians(35.7%) and 9 office workers(15.0%) selected air pllution as the most urgent problem that working environment, has had. There was statistically significant difference between two groups(P<0.001)

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A Study on Characteristics of Durability for Plunger of High Speed and Ultra-High Pressure Reciprocating Pump Using High Velocity Oxygen Fuel Spraying (초고속 용사 적용 고속 초고압 왕복동 펌프 플런저의 내구성 특성에 관한 연구)

  • Bae, Myung-Whan;Park, Byoung-Ho;Jung, Hwa;Park, Hui-Seong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.5
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    • pp.20-28
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    • 2014
  • The high velocity oxygen fuel spraying (HVOF) is a kind of surface modification process technology to form the sprayed coating layer after spraying the powder to molten or semi-molten state by the ultra-high speed at the high-temperature heat source and conflicting with a substrate. It is desirable to melt completely the thermal spray powder in order to produce the coating layer with an optimal adhesion, however, because a semi-molten powder in a spray process has the low efficiency and become a factor that degrades the mechanical property by the inducement of pore-forming within the coating layer. To improve the wear resistance, corrosion resistance and heat resistance, in this study, the plungers of high-speed and ultra-high pressure reciprocating hydraulic pumps for oil and water used in ironwork are produced with $420J_2$ and the coating layers of plungers are formed by the powders of WC-Co-Cr and WC-Cr-Ni including the high hardness WC. The surface of these plungers is modified by the super-mirror face grinding machine using variable air pressure developed in this laboratory, and then the characteristics of cross-sectional microstructure, and surface roughness and hardness values between no operation and 100 days-operation are examined and made a comparison. The fine tops and bottoms on surface roughness curve of oil-hydraulic pump plunger sprayed by WC-Cr-Ni are molded more and higher than those of water-hydraulic pump sprayed by WC-Co-Cr because the plunger diameter of oil-hydraulic pump is 0.4 times smaller than that of water-hydraulic pump and the pressure of oil-hydraulic pump exerted on the plunger is operated with the 70 bars higher than that of water-hydraulic pump. As a result, it is found that the values of centerline average surface roughness and maximum height for oil-hydraulic pump plunger are bigger than those of water-hydraulic pump plunger.

A Case Study on the Easterly Wind Characteristics around Gangneung City (강릉지역 동풍 기류 특성에 대한 사례 분석 연구)

  • Lee, Sun-Gi;Kim, Won-Gi;Kim, Sang-Kook;Kim, Do-Soo;Ryu, Shi-Chan;Jeon, Sang-Sik;Park, Kee-Won;Bang, So-Young;Kim, Yeon-Hee;Nam, Jae-Cheol
    • Atmosphere
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    • v.15 no.4
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    • pp.191-202
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    • 2005
  • This study was conducted to estimate how vertically high and horizontally long a sea breeze occurred around Gangneung of the Korean peninsula would be reached to an inland. Geographically, gangneung is located on the center of the east coast shaping an arc, and a coastal line around gangneung has a form extending northwestward and southeastward, respectively. Therefore, an inflow of the northerly has similar effects of the sea breeze since a deep valley of Daegwallyeong, which is one of main ridges of the Taebaek mountains, not only reaches northeastward up to this region but also plays the part of the steering gear changing a wind direction from northerly to easterly, this is, the wind from sea. First of all, the study had defined the sea breeze as a wind blown from NNE to ESE, clockwise. And then, we analyzed characteristics of the sea breeze occurred around gangneung in view of the maximum wind speed and the wind direction for October 1st, 2003 through September 30th, 2004, the upper air database for May through June of 2004, and the wind vector database of AWS (Automatic Weather System). All meteorological information is collected at the weather station of gangneung and by the AWS which is being scattered around this region. Finally, the study figures out that how horizontally long a sea breeze would be reached depends on a level of the easterly inflow. At the first step of the inflow of the sea breeze, the wind from NNW blows into this region by keeping up the speed $3m{\cdot}s^{-1}$, and effects of the northerly are dominated with time and the wind at the inland blows out southwestward cause of the surface friction at the next step. On the other hand, there is no change of wind direction in the inflow at Daegwallyeong because a surface friction of there is smaller than around gangneung, relatively. In other word, the easterly blows toward Daegwallyeong. However, the wind speed is not higher than that of the coast around gangneung.