• 한국세라믹학회지
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• 제28권11호
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• pp.917-925
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• 1991

For the present experiment five Portland cement mortars are in order: mortars with two different water/ cement ratios (W/C=0.45 and 0.50, each having no chemical additive), and those with an additive such as superplasticizer, air-entraining agent or water-repelling agent. We fix the W/C ratio of mortars having additive so that their pastes can yield the same workability as that of the cement mortar of W/C=0.50 with no additive. It is shown that the freeze-thaw resistivity depends heavily on the characteristic of wide pores. Despite a good deal of wide pores, the air-entrained specimen shows a good freeze-thaw resistivity due to appropriate air-pores. And also the specimen with water-repelling agent, which proves to cause the microstructure to become hydrophobic, make good resistance to freeze-thaw cycles in spite of its high wide-porosity. Our suggestion is that the freeze-thaw durability of Portland cement mortar/concrete can be more effectively enhanced by using air-entraining agent or water-repelling agent, and simutaneously by taking proper measures against foaming and/or the increased tendency of wide-pore building due to additive.

• 한국세라믹학회지
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• 제27권3호
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• pp.437-443
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• 1990

The resistivity of cement paste and mortar for freezing and thawing was investigated for densifying the structure of cement paste and mortor, slag, diatomaceous earth and fly ash as blending materials and superplasticizer were used, and air entraining agent was added to absorb the volume expansion by freezing and thawing reaction. And then the specimens were subjected to freeze-thaw in water. When both of air entraining agent and superplasticizer as additives were mixed to specimens, their freeze-thaw resistance was enhanced by the air entraining effect and the water reduction effect. When 4% of slag were added to cement, freeze-thaw resistance was especially excellent. In addition, it was found that the specimens with blending materials were more influenced by curing periods than those without admixture. It is assumed that the curing periods contribute to exibit the potential hydraulicity and pozzolanic reactivity of blending materials and to densify their texture.

• 한국도로학회논문집
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• 제18권1호
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• pp.63-72
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• 2016

PURPOSES : The use of roller-compacted concrete pavement (RCCP) is an environmentally friendly method of construction that utilizes the aggregate interlock effect by means of a hydration reaction and roller compacting, demonstrating a superb structural performance with a relatively small unit water content and unit cement content. However, even if an excellent structural performance was secured through a previous study, the verification research on the environmental load and long-term durability was conducted under unsatisfactory conditions. In order to secure longterm durability, the construction of an appropriate internal air-void structure is required. In this study, a method of improving the long-term durability of RCCP will be suggested by analyzing the internal air-void structure and relevant durability of roller-compacted concrete. METHODS : The method of improving the long-term durability involves measurements of the air content, air voids, and air-spacing factor in RCCP that experiences a change in terms of the kind of air-entraining agent and chemical admixture proportions. This test should be conducted on the basis of test criteria such as ASTM C 457, 672, and KS F 2456. RESULTS : Freezing, thawing, and scaling resistance tests of roller compacted concrete without a chemical admixture showed that it was weak. However, as a result of conducting air entraining (AE) with an AE agent, a large amount of air was distributed with a range of 2~3%, and an air void spacing factor ranging from 200 to $300{\mu}m$ (close to $250{\mu}m$) coming from PCA was secured. Accordingly, the freezing and thawing resistance was improved, with a relative dynamic elastic modulus of more than 80%, and the scaling resistance was improved under the appropriate AE agent content rate. CONCLUSIONS : The long-term durability of RCCP has a direct relationship with the air-void spacing factor, and it can be secured only by ensuring the air void spacing factor through air entraining with the inclusion of an AE agent.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.97-98
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• 2023

In this study, comparison of the quality standard of chemical admixtures between Korea and China is conducted. It is classified into three types of water reducing agents: standard, delayed, and accelerated according to the sensitivity and strength improvement of the sensitivity and strength of the agent. However, Chinese standards classify reducing agents only as standard, high efficiency, and high performance, and do not add AE agents into water reducing agent. On the other hand, that of Korea has a classification regulation for reducing agents added with AE agents.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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• pp.423-424
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• 2009

최근 자원의 재활용 및 알칼리-골재반응의 대책으로 F/a의 사용이 증가하는 추세이다. 그러나 F/a 치환량 증가에 따른 미연소탄소의 AE제 흡착으로 인하여 공기연행성능이 저하되어, 동결융해 작용에 의한 내구성 저하의 위험성이 고조되고 있다. 따라서 본 연구에서는 F/a 치환량 및 AE제 종류변화에 따른 굳지 않은 콘크리트의 공기연행성능을 분석함으로써 F/a를 다량 사용한 콘크리트의 기포안정성 향상을 위한 기초자료로 제시하고자 한다.

• 한국세라믹학회지
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• 제27권7호
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• pp.833-840
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• 1990

For the development of multi-functional materials which has water reducing power, air entraining power and waterproofing power as well as blending additive in cement mortar the coal ash was modified with asphalt-stearic acid or asphalt-boiled oil mixtures by mechanical treatment. And the physical properties of cement mortar blended with modified coal ashes were compared with those of the water-tightness-cement mortar and the ordinary-portland-cement mortar added with AE.water reducing agent. The mortar of coalash-blend-cement modified with asphalt-stearic mixture was increased acid about 20% in initial strengths and decreased about 20% in water absorption ratio than those of ordinary coalash-blend-cement. The mortar of coalash-blend-cement modified with asphalt-bolied oil mixture was similar to the cement mortar added with AE.water reducing agent in water reduction ratio, air entraining conents and the initial strengths, also was similar to the water-tightness-cement mortar in water absorption and water permeability ratios.

• 콘크리트학회지
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• 제14권1호
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• pp.38-43
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• 2002

전 세계에서 콘크리트 관련 기술의 변천사를 살펴보면 공기 연행제(air entraining agent), 감수제 (water reducing agent), 고성능 감수제(superplasticizer high range water reducing agent)로 대변되는 콘크리트용 화학 혼화제의 개발이 콘크리트의 성능 향상의 큰 전기 중의 하나 라고 할 수 있다. 1930년대 미국에서 우연히 발견된 공기 연행제의 사용으로 콘크리트의 동결 융해 저항 성능을 획기적으로 개선할 수 있게 되었으며 또한 펄프 폐액에서 추출되는 리그닌(lignosulfonates)이 시멘트의 분산성을 높여 주는 것을 발견하게 되었다.(중략)

• 콘크리트학회논문집
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• 제13권5호
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• pp.484-490
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• 2001

본 연구는 라텍스 혼입률을 5, 10, 15, 20%로 변화함에 따른 염소이온 투수성과 동결융해저항성 관점에서 라텍스 개질 콘크리트의 내구특성을 고찰하고자 한다 콘크리트에 라텍스가 혼입되고 양생되었을 때 콘크리트는 라텍스 입자의 필름막에 의해 서로 연결된 시멘트수화물과 골재가 구성된다. 이때 라텍스의 양이 증가함에 따라 콘크리트의 휨강도는 증진되나, 압축강도는 다소 저하된다. 이와 같은 휨강도의 증가는 시멘트수화물과 골재사이의 라텍스 필름막에 기인한 것이며 압축강도의 감소는 라텍스의 성분 중 부타디엔의 유연성 때문에 발생되는 것으로 판단된다. 라텍스 개질 콘크리트와 보통콘크리트의 상대 투수성을 측정하기 위하여 염소이온투과시험법을 사용하였다. 실험 결과 라텍스 개질 콘크리트의 투수성은 보통콘크리트의 투수성보다 매우 낮음을 알 수 있었다. 이것은 라텍스 미립자가 미세공극을 충전하고 라텍스 입자의 필름막에 의해 골재와 시멘트수화물이 연결되었기 때문이다. 그리고 라텍스 개질 콘크리트의 동결융해저항성은 보통콘크리트에 비해 매우 높으며, 보통콘크리트에서는 동결융해저항성을 증가시키기 위해 공기연행제를 필요로 하지만, 라텍스 개질 콘크리트에서는 적절한 양생이 이루어지면 추가적인 공기연행제는 요구되지 않는다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.48-53
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• 2003

The steel slag, a by-product which is produced on the process of manufacturing steel by refining pig iron is mainly used as road materials after aging it. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the volume expanded. Due to this reason it prevents steel slag from being used as aggregate of concrete. But steel slag used in this study is controled by a air-jet method which rapidly cools substance melted at a high temperature. Rapid cooling prevents from generating of free-CaO in steel slag. In this study, it was investigated that steel slag manufactured by air-jet method affects on concrete in the freezing and thawing. As results of this study, concrete mixed with steel slag was worse in the freezing and thawing than concrete mixed with sand in spite of using air entraining agent. To obtain durability of concrete in the freezing and thawing, it is desirable to mix 50% of steel slag in concrete per unit weight of volume.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.183-188
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• 2002

When Concrete work during winter is placed, it has anxiety that concrete freeze at low temperature. As concrete's freezing cause reduction of durability, it is necessary for mixing to pay attention to Air content and W/C ratios. Accordingly, in this study, we set up three series and evaluate a frost-resistance of concrete with admixture, like fly-ash and blast-furnace slag, for early curing method and types of chemical admixture..The study is composed as; I series : Analysis for early curing method and types of chemical admixture in laboratory II series : Analysis for early curing method and types of chemical admixture in batcher plant and measured concrete' temperature. The result of this study, it was more effective the use of super-plasticizers than air entraining agent.