• Title/Summary/Keyword: agitation rate

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Effect of the rheological properties of aqueous xanthan gum solution on chemical absorption of carbon dioxide with diisopropanolamine

  • Son, Young-Sik;Park, Sang-Wook;Park, Dae-Won;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.21 no.2
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    • pp.109-117
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    • 2009
  • Absorption rate of carbon dioxide was measured in the aqueous xanthan gum (XG) solution in the range of 0~0.15 wt% containing diisopropanolamine (DIPA) of $0{\sim}2\;kmol/m^3$ in a flat-stirred vessel with an impeller of 0.05 m and agitation speed of 50 rpm at $25^{\circ}C$ and 101.3 kPa. The volumetric liquid-side mass transfer coefficient ($k_La$) of $CO_2$, which was obtained by the measured physical absorption rate, was correlated with the viscosity and the elastic behavior of XG solution such as Deborah number as an empirical formula. The chemical absorption rate of $CO_2$ ($R_A$), which was estimated by the film theory using the measured $k_La$ and the known kinetics of reaction between $CO_2$ and DIPA, was compared with the measured rate. The aqueous XG solution with elastic property of non-Newtonian liquid made $k_La$ and $R_A$ increased compared with Newtonian liquid based on the same viscosity of the solution.

A Study on Coolant Mixing in Multirod Bundle Subchannels

  • Cha, Jong-Hee;Cho, Moon-Haeng
    • Nuclear Engineering and Technology
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    • v.2 no.1
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    • pp.19-25
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    • 1970
  • A study was conducted on the coolant mixing between water flowing in two adjacent subchannels. Measurements were made of the quantity of mass transferred between a larger rectangular channel and a smaller triangular channel in a 19-rod fuel bundle under the conditions of single phase flow and air-water two-phase flow. The results of the experiments showed that the low mixing rate appears in single phase flow, and high mixing rate was measured in air-water two-phase flow Mixing rate decreases with the increasing of air void fraction during the air-water flow. It seems that the high mixing rate in the air-water flow was caused due to adequate agitation of the chaotic air void.

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Effect of elasticity of aqueous xanthan gum solution with 2-amino-methyl-1-propanol on chemical absorption of carbon dioxide

  • Park, Sang-Wook;Choi, Byoung-Sik;Song, Ki-Won;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.20 no.1
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    • pp.1-6
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    • 2008
  • Absorption rate of carbon dioxide was measured in the aqueous xanthan gum (XG) solution in the range of 0-0.15 wt% containing 2-amino-2-methyl-1-propanol (AMP) of $0-2\;kmol/m^3$ in a flat-stirred vessel with an impeller of 0.05m and agitation speed of 50rpm at $25^{\circ}C$ and 0.101 MPa. The volumetric liquid-side mass transfer coefficient ($k_La$) of $CO_2$, which was correlated with the viscosity and the elastic behavior of XG solution containing Deborah number as an empirical formula, was used to estimate the chemical absorption rate of $CO_2\;(R_A)$. $R_A$, which was estimated by mass transfer mechanism based on the film theory using the physicochemical properties and the kinetics of reaction between $CO_2$ and AMP, was compared with the measured rate. The aqueous XG solution with elastic property of non-Newtonian liquid made $R_A$ increased compared with Newtonian liquid based on the same viscosity of the solution.

Chemical Absorption of Carbon Dioxide into Non-Newtonian Polyacrylamide Solution (Polyacrylamide 비뉴튼액체에서의 이산화탄소의 화학흡수)

  • Hwang, Byung-Jin;Park, Sang-Wook
    • Clean Technology
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    • v.14 no.4
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    • pp.281-286
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    • 2008
  • Absorption rate of carbon dioxide was measured in the aqueous polyacrylamide (PAA) solution containing triethanolamine (TEA) of $0{\sim}2.0\;kg\;mol/m^3$ in a flat-stirred vessel with an impeller of 0.05 m and agitation speed of 50 rpm at $25^{\circ}C$ and 101.3 kPa. The chemical absorption rate of $CO_2$ was estimated by mass transfer mechanism based on the film theory using the physicochemical properties containing the liquid-side mass transfer coefficient of $CO_2$ and the kinetics of reaction between $CO_2$ and TEA to compare with the measured rate. The aqueous PAA solution acted as a reducing agent by viscoelastic property of non-Newtonian liquid based on the same viscosity of the solution.

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Effects of Silicone Contents and Flow Rates on the Formation and Mechanical Properties of Hard Anodized Film of Al-Si alloys (Al-Si 합금의 경질양극산화피막의 형성과 기계적 성질에 미치는 Si 함량과 전해액의 유속의 영향)

  • 김경택;안명규;이진형;권혁상
    • Journal of Surface Science and Engineering
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    • v.24 no.4
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    • pp.179-186
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    • 1991
  • The effects of silicone contents and flow rates(agitation rates) of electrolyte on the formation and mechanical properties of hard anodized film of Al-Si alloy have been studied in 12% H2SO4 + 1% Oxalic acid with varying the silicone contents in the rance of 0 to 11.6% and the flow rates of electrolyte in the range of 0 to 90cm/sec. The film forming voltage required to maintain an equivalent current density significantly increase with the silicone content of Al-Si alloys due to a low conductivity of silicone. Hardness and wear resistance of the anodized film of Al-Si alloys decreases wit increasing the silicone content. The increase in the flow rate of electrolyte has a similar influence on the formation and mechanical properties of anodized film as does the decrease in bath temperature. Hardness of anodized film is rapidly increased with the flow rate being increased from 10cm/sec. It is observed that the increase in the flow rate from 11cm/sec. It is observed that the increase in the flow from 11cm/sec to 48cm/sec is more effective in enhancing the hardness of film than is the decrease in bath temperature from 1$0^{\circ}C$ to $0^{\circ}C$.

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Liquid culture condition of Tremella fuciformis mycelia (흰목이 균사 액체배양 조건)

  • Chang, Hyun-You;Lee, Chan;Choi, Sung-Woo;Yun, Jong Won
    • Journal of Mushroom
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    • v.6 no.1
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    • pp.27-31
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    • 2008
  • The optimization of submerged culture conditions for mycelial growth and exopolysaccharide (EPS) production in an edible mushroom Tremella fuciformis were studied in shake flasks and bioreactors. The temperature of $28^{\circ}C$ and pH 8 in the beginning of fermentation in agitated flasks was the most efficient condition to obtain maximum mycelial biomass and EPS. The optimal medium constituents were as follows (g l-1): glucose 20, tryptone 2, $KH_2PO_4$ 0.46, $K_2HPO_4$ 1 and $MgSO_4H_2O$ 0.5. The fungus was cultivated under various agitation and aeration conditions in a 5L stirred-tank bioreactor. The maximum cell mass and EPS production were obtained at a relatively high agitation speed of 200 rpm and at an aeration rate of 2 vvm. The flow behavior of the fermentation broth was Newtonian and the maximum apparent viscosity (35 cP) was observed at a highly aerated condition (2 vvm). The EPS productivity in an airlift reactor was higher than that in the stirred-tank reactor. The EPS was protein-bound polysaccharides consisted of mainly mannose, xylose, and fructose. The molecular weights of EPS were determined to be $1.3{\sim}1.5{\times}10^6$.

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High Cell Density Culture of Micro-algal Dunaliella bardawil (미세조류 Dunaliella bardawil의 고농도 세포배양)

  • 정욱진;왕만식;최승인;정병철;김주곤
    • KSBB Journal
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    • v.14 no.2
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    • pp.160-166
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    • 1999
  • High cell density cultivation of microalga Dunaliella bardawil using nitrogen fed-batch cultures was studied in batch flask. Optimum environmental conditions include concentrated nutrients except NaCl and carbon sources, carbon sources, pH, light, agitation, nitrate and phosphate ions. Cell growth, consumption rates of nitrate and phosphate ions were monitored. Optimal conditions for higher cell density were found to be(in the range tested): 5 times concentrated media(1 times-10 times concentrated media) pH 8.0 (7.0-9.0) white light(blue and red light) 15mM of nitrate (0.94-15mM) 250mM $NaHCO_3$ and $CO_2$ gas. However, the addition of phosphate ions did not enhance the algal maximum cell density and specific growth rate. Nitrate was found to be effective for the cell growth. The maximum cell density of fed-batch culture using nitrate ions in $8.955{\times}106$cells/ml after 189hr incubation.

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Effects of Mixing Performance and Conditioned Medium on hCTLA4Ig Production in Transgenic Rice Cell Suspension Cultures (형질전환 벼 현탁세포 배양에서 혼합효율과 조정배지가 hCTLA4Ig 생산에 미치는 영향)

  • Choi, Hong-Yeol;Park, Jun-Yong;Nam, Hyung-Jin;Gong, Mi-Kyung;Yoo, Ye-Ri;Kim, Dong-Il
    • KSBB Journal
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    • v.30 no.6
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    • pp.307-312
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    • 2015
  • Transgenic rice cells using RAmy3D promoter can provide high productivity, and the production of recombinant protein is induced by sugar starvation. In this system, productivity was reduced during the scale-up processes. To ensure the influences of shear stress and oxygen transfer rate, working volume and mixing performances were investigated under various agitation speeds and working volumes. In addition, inoculation methods including suspended cells and filtered cells were compared. Working volumes and shaking speeds were 300, 450 mL and 80, 120 rpm, respectively. Hydrodynamic environment of each condition was measured numerically like mixing time and $k_La$. Good mixing performance and high shear stress were measured at high agitation speed and low volume. The highest level of hCTLA4Ig was 30.7 mg/L at 120 rpm, 300 mL. When conditioned medium was used for inoculation, increased cell growth was noticed during the day 0~4 and decreased slower than filtered cells. Compared with filtered cells, the maximum hCTLA4Ig level reached 37.8 mg/L at 120 rpm, 300 mL and lower protease activity level was observed. In conclusion mixing performance is critical factor for productivity and conditioned medium can have a positive effect on damaged cells caused by hydrodynamic shear stress.

Leaching Kinetics of Yttrium Extraction from Coal Fly Ash using Sulfuric Acid

  • Kim, Jae-kwan;Park, Seok-un;Hong, Jun-seok;Shin, Dong-ik;Jeong, Jae-hyeok
    • KEPCO Journal on Electric Power and Energy
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    • v.3 no.1
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    • pp.29-34
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    • 2017
  • Leaching kinetics for extracting yttrium from the coal fly ash was investigated in the presence of sulfuric acid during extraction. The leaching kinetics of yttrium were conducted at reactant densities of 5~1,000 g coal fly ash per L of $1.0{\sim}10.0N\;H_2SO_4$, agitation speed of 250 rpm and temperature ranging from 30 to $90^{\circ}C$. As a result, the leaching kinetic model was determined in a two-step model based on the shrinking core model with spherical particles. The first step was proceeded by chemical reaction at ash surface, and the second step was proceeded by ash layer diffusion because the leaching conversion of yttrium by the first chemical reaction increases with increased the time irrelevant to the temperature whereas it increases with increased the leaching temperature. The activation energy of the first chemical leaching step was determined to be $1.163kJmol^{-1}$. After the first chemical reaction, the activation energy of ash layer diffusion leaching was derived to be $41.540kJmol^{-1}$. The optimum conditions for leaching the yttrium metal of 60 % were found to be the slurry density of 250 g fly ash per L of $H_2SO_4$, solvent concentration of $2.0N\;H_2SO_4$, second step leaching of temperatures of $30^{\circ}C$ for 3 hours and then $90^{\circ}C$ for 3 hours at agitation rate of 250 rpm.

Numerical Investigation of Factors affecting Photoresist Stripping Process on the ITO Surface using the Spray Method (노즐 분사 방식의 ITO 표면 포토레지스트 박리과정 요인의 수치해석)

  • Kim, Joon Hyun;Lee, Joon Hyuck;Kang, Tae Seong;Joo, Gi-Tae;Kim, Young Sung;Jeong, Byung Hyun;Lee, Dae Won
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.26 no.2
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    • pp.158-165
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    • 2017
  • This study investigated spraying factors applicable to stripper usage. Cyclodextrine, as environment-friendly material, was included in the stripper composition. An efficient spray technology was applied for the Photoresist strip. For industrial applications, stripping requires a temperature below $50^{\circ}C$, a strip time within 50 s, and chemically stable activation. Spraying factors were organized considering many conditions-orifice diameter, working pressure (inlet speed), spray distance, and spray angle. For commercial practicability, the flow rate was limited to 3 L/min. The nozzle parameters were nozzle orifice diameter of 1.8-2.2 mm, spray distance of 40-60 mm, and injection speed of 0.7-1.2 m/s. Through the thermal spray movement of the fluid, the thermal boundary layer for a chemical reaction just above the ITO-glass surface and momentum region for sufficient agitation (above 4 m/s) was achieved.