• Korea-Australia Rheology Journal
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• 제15권1호
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• pp.19-25
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• 2003

Since the microstructure of functional thin films depends on the dispersion characteristics of dense slurry, it is important to control the agglomerative nature of slurries under processing. The present authors have been discussing the model prediction of agglomerative nature and local rate of agglomeration in dense suspensions. The experiments have been peformed under shear flow using the nearly spherical and oblate type graphite particles. In this study, the experiment has been conducted using water and glycerol as dispersion media. Stress control type rheometer was used to measure the slurry rheology. Local agglomeration of graphite particles has been predicted by using Usui's model. The experimental results show that both the shape and slurry processing method affect on the local dispersion condition. The agglomeration formed by oblate type graphite particles seems to be more difficult to break up than that of spherical particles.

• 한국분말재료학회지
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• 제25권5호
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• pp.395-401
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• 2018

The improvement of dispersion stability for the primary polishing slurry in a CMP process is achieved to prevent defects produced by agglomeration of the slurry. The dispersion properties are analyzed according to the physical characteristics of each silica sol sample. Further, the difference in the dispersion stability is confirmed as the surfactant content. The dispersibility results measured by Zeta potential suggest that the dispersion properties depend on the content and size of the abrasive in the primary polishing slurry. Moreover, the optimum ratio for high dispersion stability is confirmed as the addition content of the surfactant. Based on the aforementioned results, the long-term stability of each slurry is analyzed. Turbiscan analysis demonstrates that the agglomeration occurs depending on the increasing amount of surfactant. As a result, we demonstrate that the increased particle size and the decreased content of silica improve the dispersion stability and long-term stability.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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• pp.58-58
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• 2011

Nickel-ceramics nanocomposite coatings can be applied as the wear resistance coating, corrosion protection of underlying materials, and decorative coatings. Hence, Nickel based nanocomposite coatings, especially Ni-SiC, have been extensively studied in recent years. However, more often agglomeration problem of the nanoparticles in the nickel matrix can cause deterioration of the mechanical properties rather than improvement. The homogeneous distribution of the nanoparticles in the matrix coating is still being challenging. In this experiment, electrochemical deposition of Ni-SiC composite coating was done in presence of ultrasound. The effects of different ultrasonic powers and frequencies on the nanoparticle dispersion were studied. The electrodeposition was carried out in nickel sulfamate bath by applying pulse current technique. Compared to the conventional mechanical stirring technique to prevent nanoparticles agglomeration and sedimentation during composite electrodeposition, the aid of ultrasonic dispersion along with mechanical stirring has been found to be more effective not only for the nanoparticles dispersion, but also for the mechanical properties of the electrodeposited coatings. Nanoparticles were found to be distributed homogeneously with reduced agglomeration. The microstructure of the composite coating has also been changed, allowing some random orientations of the nickel crystallite grain growths, smooth surface, and finer grains. As a consequence, better mechanical properties of the composites were observed.

• 응용통계연구
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• 제17권1호
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• pp.13-26
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• 2004

경제성장이론에 의하면 특정 산업에 종사하는 사업체들의 입지 행태는 업종별로 서로 공간적 관련성을 갖는다. 본 연구에서는 음이항분포의 산포모수의 특성을 이용하여 산업 활동의 공간집적도를 계량화하기 위한 산업집중지수를 정의하고 이를 이용하여 특정업종에 종사하는 사업체들의 입지행태에 있어서 공간적 변화경향을 통계적으로 규명하고자 하였다. 1995년도와 2000년도의 사업체 기초통계조사 자료를 이용하여 충북지역의 지식기반산업 7개 업종과 주력기간산업 9개 업종에 대해 산업집중지수를 추정하여 이를 기반으로 업종별 사업체들의 공간적 입지행태 변화경향을 분석하였고 지역산업 활성화에 필요한 업종의 선택 및 집중화문제해결에 산업집중지수가 활용될 수 있음을 보였다.

• 한국세라믹학회지
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• 제25권4호
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• pp.357-363
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• 1988

Ccompaction and sintering behavior of highly pure PSZ powders were investigated by laying the stress on the granulation processes. The particle size of coprecipitated PSZ powder was so fine that the agglomeration was severely formed during drying and calcing step and by this agglomeration differential sinering was occurred. The methanol dispersion of precipitates was the good method of avoiding severe agglomeration formed during drying process because of small surface tension than water. But perfect deagglomeraton was not possible due to high surface area of powders. So homogenization by granulation was needed, and among the method spray granulation was the most desirable to obtain homogeneous compacts and subsequent flaw-free ceramics.

• 대한화장품학회지
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• 제24권3호
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• pp.73-80
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• 1998

This Study was performed to get the suitable oil dispersion agent by assessment of color strength of organic pigment in non-aqueous systems. Organic pigment is used as a color expression material with other body pigments in the make-up products. But occasionally aggregation or agglomeration occurs for the lack of affinity with medium, This function is the cause of disturbing homogeneous dispersion, and then bring about an instability of products. Our study, research of dispersion mechanism between the pigment and oil phase, has been executed to solve this problem, and find a oil dispersion agent having optimum dispersion condition. Generally dispersion is related to between the solid-liquid mutual properties and electrical phenomena associated with solid-liquid interface. This factor is determined to input energy, milling time, optical properties, particle size, rheological properties, etc. Ideal dispersion state is told that coloring primary solid particle is homogeneously dispersed in medium. Good dispersed colorants are strongly and clearly appeared. We are already known that the particle size of organic pigment, chemical properties and viscosity of medium, refractive index. Consequently We determine the affinity of medium and organic pigment by measuring of color strength in the same mechanical condition. UV-VISIBLE RECORDING SPECTRO PHOTOMETER is used for measuring apparatus. We can decided the dispersion level of oil dispersion agent by measuring absorbance of color strength in the visible range that diluted medium for colloid colorant particles.

• 한국정밀공학회지
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• 제27권7호
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• pp.49-54
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• 2010

The cryogenic ball milling was performed on carbon nanotubes (CNTs) at an extremely low temperature to increase the dispersion of CNTs. The effects of milling speed and time on the deagglomeration and structural changes of CNTs were studied. FESEM was used to analyze the dispersion and the change of particle size before and after milling process. Transmission electron microscopic (TEM) analysis was also investigated the effect of cryogenic ball milling on the morphological characteristics of CNTs. The structural changes by the cryogenic ball milling process were further confirmed by x-ray diffraction (XRD) and Raman spectroscopic analysis. The results showed that the agglomeration of CNTs was significantly reduced and amorphous structure was observed at high milling speed. However, the milling time has no great effect on the dispersion property and structural change of CNTs compared with milling speed.

• 한국해양공학회지
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• 제28권4호
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• pp.338-344
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• 2014

The purpose of this study was to evaluate the dispersion degree of particles using a nanoindentation test for titanium oxide nanoparticles/epoxy resin nanocomposites. Thus, the effects of the particle size and weight fraction, dispersion agent, and position of the sample on the modulus and degree of particle dispersion in the nanocomposites were investigated. As a result, the dispersion degree of large particles was found to be better than that of smaller particles in composites. It could be found that the aggregation or agglomeration of small particles with large surface energy occurred more easily in nanocomposites because of the large specific surface area. The moduli of the upper side of the film-shaped sample obtained from a nanoindentation test were low scattering, while the values for the bottom side were high scattering. Thus, the dispersion situation of the nanoparticles on the upper side of film-shaped samples could be considered to be better than that for the bottom side. This could be concluded due to the non-uniform nanoparticle dispersion in the same sample. The modulus obtained from nanoindentation test increased slightly with the content of nanoparticles and increased with the indented depth for the same sample. The latter is presumably due to the increase in the accumulated particles facing the indenter with the indented depth. The nanoindentation test was found to be a useful method to evaluate the dispersion status of nanoparticles in nanocomposites.

• 대한지리학회지
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• 제41권6호
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• pp.639-656
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• 2006

본 연구는 지식정보사회에서 신경제공간 형성의 메커니즘을 살펴보고 향후 지리학연구의 방향을 제시하고자 하였다. 정보화 사회에서 신경제공간의 형성 배경에 대해 개관하고, 그 메커니즘으로 네트워크, 착근성, 집적 및 분산에 대해서 설명하였다. 또한 한국에서 혁신활동이 활발한 서울의 강남지역과 낙후지역 중의 하나인 전북 순창지역에 대한 사례연구를 통하여 한국의 낙후지역에서도 신경제공간의 형성이 이루어지고 있음을 지적하였다. 이러한 이론적 논의와 사례연구를 바탕으로 앞으로 지리학연구의 방향을 크게 통합적 관점에서의 연구, 지리학연구 방법론 개발, 정책관련연구의 세 가지 측면에서 논의하였다.

• 대한지리학회지
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• 제52권1호
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• pp.55-71
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• 2017

이 논문은 산업클러스터의 개념과 요건을 밝히고 이러한 요건에 비추어 산업클러스터의 범위를 구체화 하는데 목적을 두고 있다. 나아가 산업클러스터와 관련된 용어들을 전반적으로 비교 검토하여 그것들의 의미를 명확히 하고 그 차이를 규명하려 한다. 필자는 M. Porter의 클러스터 개념이 전문화된 산업집적지를 설명하는 가장 간명하고 적실한 개념으로서, 산업지구와 신산업지구, 유연적 생산집적지를 포괄하는 광의적 개념이라고 파악한다. 하지만 그것이 집적과 동일한 의미나 범주를 갖는다고는 보지 않는바, 클러스터 현상은 집적 중에서 산업집적에 해당하며 산업집적 중에서 동종 혹은 연관 산업의 집적과 연계를 의미하는 것이다. 한편으로 필자는 이 특징적인 산업집적 현상에 대해 클러스터 보다는 산업클러스터라는 용어가 적실하다고 판단한다. 클러스터라는 용어는 그 개념에 비해 지나치게 포괄적이어서 오해와 오용의 소지가 적지 않은 것이다. 클러스터는 산업클러스터 이외에 정치 행정클러스터, 예술클러스터, 과학연구클러스터 등을 포함할 수 있다. 더하여 본 연구는 산업클러스터와 비산업클러스터 사이에 준산업클러스터 개념을 도입하여 산업클러스터의 범주를 보다 구체화하려 하였으며 이러한 관점에서 다양한 산업클러스터 사례들을 분석하였다.