• Title/Summary/Keyword: ageing degradation

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Intraoral ageing of aligners and attachments: Adverse effects on clinical efficiency and release of biologically-active compounds

  • Theodore Eliades;George Eliades
    • The korean journal of orthodontics
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    • v.54 no.4
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    • pp.199-209
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    • 2024
  • The clinical application of aligners is accompanied by the ageing of the polymer appliances and the attachments used, which may result in inefficiency in reaching the predicted range of tooth movement, and release of compounds and microplastics in the oral cavity as a result of the friction, wear and attrition of the aligner and composite attachment. The purpose of this review is to present the mechanism and effects of in vivo ageing; describe the hydrolytic degradation of aligners and enzymatic degradation of composite attachments; examine the ageing pattern of aligners in vivo, under actual clinical scenarios; and identify a link to the discrepancy between predicted and actual clinical outcome. Lastly, strategies to deal with three potentially critical issues associated with the use of aligners, namely the necessity of weekly renewal, the dissimilar mechanical properties of aligner and attachment resulting in wear and plastic deformation of the aligner, and the development of integuments and biofilms with microbial colonization of the appliance, are discussed.

Assessment of Material Risk and Residual Life of CrMoV Turbine Rotor Considering High Temperature Material Degradation (고온 재질 열화도를 반영한 CrMoV 터빈로터의 재료 위험도 및 잔여수명 평가)

  • Ma, Young-Wha;Lee, Jin-Sang;Yoon, Kee-Bong
    • Journal of the Korean Society of Safety
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    • v.21 no.4 s.76
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    • pp.33-41
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    • 2006
  • Material degradation should be considered to assess integrity and residual life of high temperature equipments. However, the property data reflecting degradation are not sufficient for practical use. In this study measuring properties for 1Cr-1Mo-0.25V forging steel generally used for turbine rotor was carried out. Degradation was simulated by isothermal ageing. heat treatment and variation of microstructure was observed. Mechanical properties such as tensile strength, impact energy, hardness and fracture toughness were measured. Assuming a semi-elliptical surface crack at the bore hole in a turbine rotor, material risk was estimated by using the aged material property data obtained in this study. Safety margin was decreased and life of the rotor was exhausted. This procedure can be used in assessing the residual life of a turbine rotor due to material degradation.

Dielectric Relaxation Properties for following the Ageing of Polyetheretherketone (열화에 따른 Polyetheretherketone의 유전완화특성)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung;Lim, Kee-Joe
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.396-403
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    • 2004
  • The dielectric properties of Y-ray irradiated and thermally aged polyetheretherketone (PEEK) have been investigated. Results of the temperature dependency of dielectric properties indicated that the glass transition temperature of aged PEEK increased as radiative and thermal ageing. The frequency dependency of dielectric properties implied that the magnitude of radiation and thermal induced dipoles, ions increased as radiative and thermal ageing. The values of relaxation intensity calculated using Cole-Cole's circular arc can be useful for evaluation of degradation level of PEEK.

An Electro-chemical Combined-stress Degradation Test of Rubber for Automotive Radiator Hoses (자동차 냉각기 호스용 고무의 전기화학적 복합노화시험)

  • Kwak, Seung-Bum;Seo, Boo-Seok;Choi, Nak-Sam
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.4
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    • pp.107-113
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    • 2011
  • Coolant rubber hoses for automotive radiators under thermal and mechanical loadings can be degraded and thus failed due to the influences of the locally formed electricity. In this study, an advanced test method was developed to simulate the failure problem of the rubber hose. For carbon black filled EPDM (ethylene-propylene dine monomer) rubber used as a radiator hose material the ageing behaviors by the electro-chemical stresses combined with a tensile strain were analyzed. As the tensile strain increased, the current of the rubber specimen reduced indicating an increase of the internal defects and electrical resistance of the rubber specimen. Elongation at break and IRHD hardness rapidly decreased with increasing the ageing time. Both electro-chemical stress and mechanical tensile stress clearly accelerated the degradation of EPDM rubber.

Assessment of concrete degradation in existing structures: a practical procedure

  • Porco, Francesco;Uva, Giuseppina;Fiore, Andrea;Mezzina, Mauro
    • Structural Engineering and Mechanics
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    • v.52 no.4
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    • pp.701-721
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    • 2014
  • In the assessment of existing RC buildings, the reliable appraisal of the compressive strength of in-situ concrete is a fundamental step. Unfortunately, the data that can be obtained by the available testing methods are typically affected by a high level of uncertainty. Moreover, in order to derive indications about the degradation and ageing of the materials by on site tests, it is necessary to have the proper terms of comparison, that is to say, to know the reference data measured during the construction phases, that are often unavailable when the building is old. In the cases when such a comparison can be done, the in situ strength values typically turn out to be lower than the reference strength values (tests performed on taken samples during the construction). At this point, it is crucial to discern and quantify the specific effect induced by different factors: ageing of the materials; poor quality of the placement, consolidation or cure of the concrete during the construction phases; damage due to drilling. This paper presents a procedure for correlating the destructive compressive tests and non-destructive tests (ultrasonic pulse velocity tests) with the data documenting the compressive strength tested during the construction phases. The research work is aimed at identifying the factors that induce the difference between the in-situ strength and cubes taken from the concrete casting, and providing, so, useful information for the assessment procedure of the building.

Charge transport and electroluminescence in insulating polymers (절연물 폴리머의 전하이동과 전계발광)

  • Yun, Ju-Ho;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.351-352
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    • 2007
  • Polymers submitted to thermo/electrical stress suffer from ageing that can drastically affect their functional behaviour. Understanding the physico/chemical processes at play during ageing and defining transport regimes in which these mechanisms start to be critical is therefore a prime goal to prevent degradation and to develop new formulation or new materials with improved properties. It is thought that a way to define these critical regimes is to investigate under which conditions (in terms of stress parameters) light is generated in the material by electroluminescence (EL). This can happen through impact excitation/ionization involving hot carriers or upon bi-polar charge recombination (a definition that excludes light from partial discharges, which would sign an advanced stage in the degradation process). After a brief review of the EL phenomenology under DC, we introduce a numerical model of charge transport postulating a recombination controlled electroluminescence. The model output is critically evaluated with special emphasize on the comparison between simulated and experimental light emission. Finally, we comment some open questions and perspectives.

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Evaluation of the Beeswax Applying and Dewaxing Technique of Hanji, and Their Ageing Behaviors (한지의 밀랍 및 탈랍처리 기법과 열화거동 평가)

  • Kang, Kwang-Ho;Lee, Geum-Ja;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.58-66
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    • 2010
  • The Annals of beeswax applied-Joseon Dynasty have some serious damages such as cracks, brown, red or black spots, and discolorations by chemical and biological degradation, but others without any beeswax application have still been keeping good quality during over several hundred years. It would be convinced that the beeswax applied in the Annals resulted in these deteriorations. Therefore, in order to focus on the aging mechanism and conservation techniques for the beeswax-applied Annals of Joseon Dynasty, the beeswax applying and dewaxing techniques of Hanji were tried by auto bar coater with a hot plate, and by heat-pressure sensitive extracting treatments. The ageing behaviors of beeswaxed Hanji and dewaxed Hanji were investigated by measuring the changes of physical, optical, morphological, and chemical properties, through accelerated ageing treatment in dry oven at $150^{\circ}C$ during 48 hours. Consequently, the ageing actions of beeswaxed Hanji were even faster than that of Hanji. The optimum dewaxed amounts from beeswaxed Hanji was also obtained in pressure of $40\;kg_f$ under heating conditions.

HTPB Propellant Ageing Property and HFC Base Shelf-Life Evaluation Method (HTPB 추진제 노화 특성 및 HFC 기반 수명 평가 기법)

  • Cho, Wonho;Westerlund, M.;Ryoo, Baek-Neung;Jung, Gyoo-Dong;Yoo, Ji-Chang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.148-153
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    • 2017
  • During natural ageing of HTPB propellant undergoes a series of slow physico-chemical degradation reactions. By using accelerated ageing conditions it is possible to simulate the material behaviour at different time-temperature conditions especially focused on the in-service conditions. Ageing behaviour of HTPB propellant were investigated using HFC(Micro-Heat Flow Calorimeter) is universal technique for measuring the rate of slow chemical and physical processes in long-term storage.

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Evaluation of Material Degradation of 1Cr-1Mo-0.25V Turbine Casing Steel Aged Artificially by Isothermal Heat Treatment (등온열처리법에 의해 모의 열화된 1Cr-1Mo-0.25V 터빈케이싱 강의 재질열화 평가)

  • Ma, Young-Wha;Kim, Do-Hyung;Yoon, Kee-Bong
    • Journal of the Korean Society of Safety
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    • v.25 no.1
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    • pp.22-26
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    • 2010
  • Material degradation should be considered to assess integrity and residual life of high temperature equipments. However, the property data reflecting degradation are not sufficient for practical use. In this study, mechanical properties of 1Cr-1Mo-0.25V casting steel generally used for turbine casing were measured and variation of microstructure was observed. Degradation was simulated by isothermal heat treatment.

Charge Transport and Electroluminescence in Insulating Polymers (절연층 폴리머의 전하 전송 및 EL 특성)

  • Choi, Yong-Sung;Ahn, Seong-Soo;Kim, Byung-Chul;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.91-97
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    • 2008
  • Polymers submitted to thermo/electrical stress suffer from ageing that can drastically affect their functional behaviour. Understanding the physico/chemical processes at play during ageing and defining transport regimes in which these mechanisms start to be critical is therefore a prime goal to prevent degradation and to develop new formulation or new materials with improved properties. It is thought that a way to define these critical regimes is to investigate under which conditions (in terms of stress parameters) light is generated in the material by electroluminescence (EL). This can happen through impact excitation/ionization involving hot carriers or upon bi-polar charge recombination (a definition that excludes light from partial discharges, which would sign an advanced stage in the degradation process). After a brief review of the EL phenomenology under DC, we introduce a numerical model of charge transport postulating a recombination controlled electroluminescence. The model output is critically evaluated with special emphasize on the comparison between simulated and experimental light emission. Finally, we comment some open questions and perspectives.

  • PDF