• Title/Summary/Keyword: aged material

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The Structural and Electrochemical Properties of Thermally Aged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 Cathodes

  • Park, Yong-Joon;Lee, Ju-Wook;Lee, Young-Gi;Kim, Kwang-Man;Kang, Man-Gu;Lee, Young-Il
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2226-2230
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    • 2007
  • As a cathode material of lithium rechargeable batteries, charged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 electrodes, which were aged thermally at 25 oC and 90 oC respectively, were characterized by means of charge/discharger, impedance spectroscopy, and X-ray diffraction. The discharge capacity diminution of the electrodes aged at 25 oC and 90 oC for 1 week was 4% and 23%, respectively. The cell aged at 25 oC was recovered on cycling. However, the capacity loss after ageing at 90 oC was not recovered in a subsequent cycling test, which demonstrates that the reaction occurring during ageing at 90 oC is irreversible. A significant impedance increase of aged electrode at 90 oC is associated with irreversible capacity loss. The structural changes including phase transformation were not detected by XRD analysis, because it could be due to out of detection limit. After ageing, impedance was slightly decreased during subsequent cycling test. It could be explained the cyclic performance of aged sample is stable. The thermal stability was not deteriorated by ageing even at the high temperature of 90 oC.

Deterioration Characteristics of Naturally Aged AA 2026 due to ExpoSure to High Temperatures (자연 시효 처리된 AA 2026의 고온 노출에 따른 물성 열화 특성에 대한 연구)

  • HaNeul Kim;HyeonWoo Kang;ByoungLok Jang;HeeKook Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.3
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    • pp.114-120
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    • 2024
  • AA 2026, which is used as an aviation material, is an improved version of 2024 and has higher physical properties, and is a material that has the potential to be applied to supersonic aircraft to be developed in the future. However, when an aircraft exceeds supersonic speeds, the surface heats up and the material must be resistant to this. Therefore, this study confirmed the high-temperature properties of AA 2026, an aviation structural material. AA 2026, solution treated at 500℃ for 4hr, was naturally aged at room temperature for more than 168 hr. Changes in microstructure and physical properties were confirmed over several hours of exposure to 100℃, 200℃, and 300℃, respectively. As a result of microstructure analysis, there was no significant change at 100℃, and from 200℃, GPB, a strengthening mechanism, grew and formed an S Phase. It was confirmed that the S Phase grew as the exposure time increased. Through a tensile test, it was confirmed that physical properties deteriorated as the precipitates grew. However, it was confirmed that the properties were stably maintained at 100℃, which is the temperature when the speed of a supersonic aircraft is less than Mach 2.

The Effects of Physical Aging of PSF/AS4 Laminate on Fatigue (PSE/AS4 복합재료의 가속노화가 피로강도에 미치는 영향)

  • Kim, Hyung-Won
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.39-44
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    • 2005
  • The effects of aging of PSF/AS4 laminates on fatigue was studied using the new energy release rate analysis. The analysis by the variational mechanics has been useful in providing fracture mechanics interpretation of matrix microcracking in cross-ply laminates. This paper describes the changes of the critical energy release rate (microcracking toughness) according to the aging period under fatigue loading. The master plot by modified Paris-law gives a characterization of a material system's resistance to microcrack formation. PSF $[0/90_{s}]_{s}$ laminates were aged at four different temperature based on the glass transition temperature for 0 to 60 days. At all temperatures, the toughness decreased with aging time. The decrease of the toughness at higher temperature was faster than at lower temperature. To assess the effects of aging on fatigue, the unaged laminates were compared with the laminates which had been aged for 60 days at 170$^{\circ}C$ near 180 $^{\circ}C$ t$_g$. The slope of dD/dN versus ${\Delta}G_m$. of the aged laminates was lower than that of the unaged laminates. There was a significant shift of the aged data to formation of microcracks at the lower values of ${\Delta}G_m$.

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Development and Evaluation of Functional Group Activity Program on Institutionalized Aged (시설 노인을 위한 기능적 그룹활동 프로그램의 개발 및 운영 평가)

  • Bang, Yo-Soon;Kim, Hee-Young
    • Journal of muscle and joint health
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    • v.18 no.1
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    • pp.83-92
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    • 2011
  • Purpose: The purpose of this study was to identify the changes of physical function, perceptual and cognitive function, emotional function, and functional independence in the institutionalized aged according to functional group activity program (self help Tai Chi exercise plus functional task). Methods: Study subjects were 20 institutionalized aged from June to October in 2010. The subjects received functional group activity program two times a week for 15 weeks. Physical function (grip strength, coordination, lower extremity strength, balance, gait, trunk flexibility), perceptual and cognitive function, emotional function(depression, social skill), and functional independence were measured before and after the program. Results: The subjects showed significantly increased physical function (coordination, lower extremity strength, gait, trunk flexibility), perceptual and cognitive function, emotional function (depression, social skill), and functional independence. The functional group activity program may be an effective strategy for institutionalized elders to enhance their functions. Conclusion: The functional group activity program may be effective on elderly institutions which have limitation in human, material, environmental resources.

A Study on the Statistical Analysis of HDPE films` Breakdown Strength using Weibull Statistical Function (Weibull통계함수를 이용 HDPE필름 절연파괴강토 통계적해석에 관한 연구)

  • 강무성;오재형;박대희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.106-108
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    • 1997
  • In this paper, the breakdown strength of Pure HDPE(High density polyethylene) films and aged HDPE films were evaluated using 2-parameter Weibull distribution function. The result show that both were fitted 2-parameter Weibull distribution. This method could be used to be the diagnostic tool to evalute the insulation performance and endurance under the multiple stresses.

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Monitoring in-service performance of fibre-reinforced foamed urethane sleepers/bearers in railway urban turnout systems

  • Kaewunruen, Sakdirat
    • Structural Monitoring and Maintenance
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    • v.1 no.1
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    • pp.131-157
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    • 2014
  • Special track systems used to divert a train to other directions or other tracks are generally called 'railway turnout'. A traditional turnout system consists of steel rails, switches, crossings, steel plates, fasteners, screw spikes, timber bearers, ballast and formation. The wheel rail contact over the crossing transfer zone has a dip-like shape and can often cause detrimental impact loads on the railway track and its components. The large impact also emits disturbing noises (either impact or ground-borne noise) to railway neighbors. In a brown-field railway track where an existing aged infrastructure requires renewal or maintenance, some physical constraints and construction complexities may dominate the choice of track forms or certain components. With the difficulty to seek for high-quality timbers with dimensional stability, a methodology to replace aged timber bearers in harsh dynamic environments is to adopt an alternative material that could mimic responses and characteristics of timber in both static and dynamic loading conditions. A critical review has suggested an application of an alternative material called fibre-reinforced foamed urethane (FFU). The full-scale capacity design makes use of its comparable engineering characteristics to timber, high-impact attenuation, high damping property, and a longer service life. A field trial to investigate in-situ behaviours of a turnout grillage system using an alternative material, 'fibre-reinforced foamed urethane (FFU)' bearers, has been carried out at a complex turnout junction under heavy mixed traffics at Hornsby, New South Wales, Australia. The turnout junction was renewed using the FFU bearers altogether with new special track components. Influences of the FFU bearers on track geometry (recorded by track inspection vehicle 'AK Car'), track settlement (based on survey data), track dynamics, and acoustic characteristics have been measured. Operational train pass-by measurements have been analysed to evaluate the effectiveness of the replacement methodology. Comparative studies show that the use of FFU bearers generates higher rail and sleeper accelerations but the damping capacity of the FFU help suppress vibration transferring onto other track components. The survey data analysis suggests a small vertical settlement and negligible lateral movement of the turnout system. The static and dynamic behaviours of FFU bearers appear to equate that of natural timber but its service life is superior.

A Case Study of Lead-free Thick Film Conductors with Lead-containing and Lead-free Solders

  • Yu Yeon Su;Bokalo Peter;Shahbazi Samson;Matier Colleen
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.04a
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    • pp.1-19
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    • 2003
  • The electronic market thrust for many hybrid circuit manufacturers is changing because commercial market segments such as telecommunications, automotive and consumer electronics have increased the demand world wide for environmentally friendly thick film products. This, in turn, places a stronger emphasis on the material suppliers within the circuit fabrication industry to provide toxin free products with equal or higher performance than traditional technology. A new group of silver based thick film conductors, which are totally free of such toxins as cadmium, nickel and Bead have been developed to meet new environmental requirements. Traditional thick film products and newly developed toxin free compositions will be compared and data will be presented. To evaluate their performance, both groups of conductors were tested for solder acceptance, leach resistance and aged adhesion with standard lead-containing solder and higher temperature lead-free solder.

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A Study on the Evaluation of Material Degradation of 1Cr-1Mo-0.25V Steel using Ultrasonic Techniques (초음파법을 이용한 1Cr-1Mo-0.25V강의 열화도 평가에 관한 연구)

  • Kim, Jeong-Pyo;Seok, Chang-Sung
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.78-83
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    • 2001
  • It's required mechanical properties of in-service facilities to maintain safety operation in power plants as well as chemical plants. In this study the four classes of the thermally aged 1Cr-1Mo-0.25V specimens were prepared using an artificially accelerated aging method at $630^{\circ}C$. Ultrasonic tests, tensile tests, $K_{IC}$ tests and hardness tests were performed in order to evaluate the degree of degradation of the material. The mechanical properties were decreased as degraded, but the attenuation coefficient and the harmonic generation level of a ultrasonic signal were increased. Expecially the nonlinear parameter of the signal is sensitive and will be a good parameter to evaluate the material degradation.

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An Nondestructive Evaluation of Degraded Damage for Superaustenitic Stainless Steel (슈퍼 오스테나이트 스테인리스강의 열화손상에 대한 비파괴적 평가)

  • Kwon, Il-Hyun;Baek, Seung-Se;Iino, Y.;Yu, Hyo-Sun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1332-1339
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    • 2002
  • This research was undertaken to clarify effects of thermal aging on electrochemical and mechanical properties of superaustenitic stainless steel and to detect the material degradation nondestructively. The steel was artificially aged at $300{\sim}650^{\circ}C$ for $240{\sim}10,000h$ and the mechanical properties were investigated at $-196{\sim}650^{\circ}C$ using small punch(SP) test. Also, the change in electrochemical properties caused by effects of thermal aging on superaustenitic stainless steel was investigated using electrochemical anodic polarization test in a KOH electrolyte. Carbides and ${\eta}-phase(Fe_2Mo)$ precipitated in the grain boundaries seem to deteriorate the mechanical properties by decreasing cohesive strength in the grain boundaries and to promote the current density observed in electrochemical polarization curves, The electrochemical and mechanical properties of superaustenitic stainless steel decreased significantly in the specimen aged at $650^{\circ}C$ corresponding to the sensitization temperature for conventional austenitic stainless steels.

Study on Erosion Characteristics of Aged HK40 Steel (열화된 HK40강의 마식특성에 관한 연구)

  • Kim, Am-Kee;Chun, Yong-Du;Lee, Kum-Bae;Kim, Chang-Hoon;Nahm, Seung-Hoon
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.403-408
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    • 2003
  • The erosion behavior of :artificially aged HK40 steel was investigated. Erosion tests were conducted at room temperature, $200^{\circ}C$ and $400^{\circ}C$ using $Al_2O_3$ particles. Erosion rates increased with increment of temperature. The maximum erosion rate increased with the impingement angle of 30 degree. The erosion rate increased, reached the maximum at 1000 hours, and after that, decreased with heat treatment time. The mechanism of erosion seems to be the cutting wear which is very much associated with the strength of material. As results, the erosion rates were rather affected by the tensile strength and the strain hardening coefficient than the hardness and the yield strength. Such changes of material properties would be caused by the change of micro-structure due to the precipitation of carbide and the dissolution of solid element within matrix during the heat treatment.

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