• Journal of Korean Society for Atmospheric Environment
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• v.24 no.4
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• pp.470-482
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• 2008

Seasonal variations of chemical composition and optical properties of aerosols at Seoul and Gosan were investigated using the ground-based aerosol measurements and an optical model calculation. The mass fraction of elemental carbon was $8{\sim}17%$, but its contribution on light absorption was high up to $29{\sim}48%$ in Seoul. In Gosan, the contribution of water soluble aerosols on aerosol extinction was $83{\sim}94%$ due to the high mass fraction of these particles in the range of $56{\sim}88%$. Model calculation showed that the water holding capacity of aerosols was larger in Gosan than in Seoul because of higher relative humidity and temperature along with abundant water soluble aerosols. Difference between measured and calculated aerosol optical depths was the highest in summer. This was because aerosol optical depth calculated from ground-based measurements could not consider aerosol loadings at high altitude in spite of high column-integrated aerosol loadings observed by Sun photometer. Although hygroscopic growth was expected to be dominant in summer, the mass concentration of water soluble aerosols was too low to permit this growth.

• Asian Journal of Atmospheric Environment
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• v.9 no.1
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• pp.91-99
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• 2015

The Multi-wavelength Raman LIDAR (MRL) system was developed to enable a better understanding of the complex properties of aerosols in the atmosphere. In this study, the microphysical, optical, and radiative properties of mixed aerosols were retrieved using the discrete aerosol observation products from the MRL. The dust mixing ratio, which is the proportion of dust particles to the total mixed, was derived using the particle depolarization ratio. It was employed in the retrieval of backscattering and extinction coefficient profiles for dust and non-dust particles. The vertical profiles of aerosol optical properties were then used as input parameters in the inversion algorithm for the retrieval of microphysical parameters including the effective radius, refractive index, and the single scattering albedo (SSA). Those products were successfully applied to an analysis of radiative flux using a radiative transfer model. The relationship between the MRL derived extinction and aerosol radiative forcing (ARF) in short-wavelength was assessed over Gwangju, Korea. The results clearly demonstrate that the MRL-derived extinction profiles are a good surrogate for use in the estimation of optical, microphysical, and radiative properties of aerosols. It is considered that the analytical results shown in this study can be used to provide a better understanding of air quality and the variation of local radiative effects due to aerosols.

• Journal of the Optical Society of Korea
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• v.14 no.3
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• pp.215-220
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• 2010

Aerosol observation with Raman LIDAR in NIES (National Institute for Environmental Studies, Japan) LIDAR network was conducted from 17 April to 12 June 2008 over Beijing, China. The aerosol optical properties derived from Raman LIDAR were compared with the retrieved data from sun photometer and sky radiometer observations in the Aerosol Robotic Network (AERONET). The comparison provided the complete knowledge of aerosol optical and physical properties in Beijing, especially in pollution and Asian dust events. The averaged aerosol optical depth (AOD) at 675 nm was 0.81 and the Angstrom exponent between 440 nm and 675 nm was 0.99 during experiment. The LIDAR derived AOD at 532 nm in the planetary boundary layer (PBL) was 0.48, which implied that half of the total AOD was contributed by the aerosol in PBL. The corresponding averaged LIDAR ratio and total depolarization ratio (TDR) were 48.5sr and 8.1%. The negative correlation between LIDAR ratio and TDR indicated the LIDAR ratio decreased with aerosol size because of the high TDR associated with nonspherical and large aerosols. The typical volume size distribution of the aerosol clearly demonstrated that the coarse mode radius located near 3 ${\mu}m$ in dust case, a bi-mode with fine particle centered at 0.2 ${\mu}m$ and coarse particle at 2 ${\mu}m$ was the characteristic size distribution in the pollution and clean cases. The different size distributions of aerosol resulted in its different optical properties. The retrieved LIDAR ratio and TDR were 41.1sr and 19.5% for a dust event, 53.8sr and 6.6% for a pollution event as well as 57.3sr and 7.2% for a clean event. In conjunction with the observed surface wind field near the LIDAR site, most of the pollution aerosols were produced locally or transported from the southeast of Beijing, whereas the dust aerosols associated with the clean air mass were transported by the northwesterly or southwesterly winds.

• Journal of Environmental Science International
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• v.28 no.1
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• pp.107-123
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• 2019

The aerosol chemical components in $PM_{2.5}$ in several regions (Seoul, Busan, Daejeon, and Jeju Island) were investigated with regard to their concentration characteristics and optical properties. The optical properties of the various aerosol components (e.g., water-soluble, insoluble, Black Carbon (BC), and sea-salt) were estimated using hourly and daily aerosol sampling data from the study area via a modeling approach. Overall, the water-soluble component was predominant over all other components in terms of concentration and impact on optical properties (except for the absorption coefficient of BC). The annual mean concentration and Aerosol Optical Ddepth (AOD) of the water-soluble component were highest in Seoul (at the Gwangjin site) ($26{\mu}g/m^3$ and 0.29 in 2013, respectively). Further, despite relatively moderate BC concentrations, the annual mean absorption coefficient of BC ($21.7Mm^{-1}$) was highest in Busan (at the Yeonsan site) in 2013, due to the strong light absorbing ability of BC. In addition, high AODs for the water-soluble component were observed most frequently in spring and/or winter at most of the study sites, while low values were noted in summer and/or early fall. The diurnal variation in the AOD of each component in Seoul (at the Gwangjin site) was slightly high in the morning and low in the afternoon during the study period; however, such distinctions were not apparent in Jeju Island (at the Aweol site), except for a slightly high AOD of the water-soluble component in the morning (08:00 LST). The monthly and diurnal differences in the AOD values for each component could be attributed to the differences in their mass concentrations and Relative Humidities (RH). In a sensitivity test, the AODs estimated under RH conditions of 80 and 90% were factors of 1.2 and 1.7 higher, respectively, than the values estimated using the observed RH.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.5
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• pp.458-472
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• 2017

The optical properties and direct aerosol radiative forcing (DARF) of different aerosol components in $PM_{2.5}$ (water-soluble, insoluble, black carbon (BC), and sea-salt) were estimated using the hourly resolution data measured at Aewol intensive air monitoring site on Jeju Island during 2013, based on a modeling approach. In general, the water-soluble component was predominant over all other components with respect to its impact on the optical properties(except for absorbing BC) and DARF. The annual mean aerosol optical depth (AOD) at 500 nm for the water-soluble component was $0.14{\pm}0.14$ ($0.04{\pm}0.01$ for BC). The total DARF at the surface ($DARF_{SFC}$) and top of the atmosphere ($DARF_{TOA}$), and in the atmosphere ($DARF_{ATM}$) for most aerosol components(except for sea-salt) during the daytime were highest in spring and lowest in fall and/or summer. The maximum $DARF_{SFC}$ of most aerosol components occurred around noon (12:00~14:00 LST) during all seasons, while the maximum $DARF_{TOA}$ occurred in the afternoon (13:00~16:00 LST) during most seasons (except for spring). In addition, the estimated $DARF_{SFC}$ and $DARF_{ATM}$ of the water-soluble component were -20 to $-59W/m^2$ and +3.5 to $+14W/m^2$, respectively, while those of BC were -18 to $-29W/m^2$ and +23 to $+37W/m^2$, respectively.

• Proceedings of the KSRS Conference
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• 2002.10a
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• pp.12-16
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• 2002

The clear sky radiative forcings of aerosols were evaluated over East Asia. We first investigated optical characteristics of aerosol using sky radiation measurements. An algorithm of Nakajima et al. (1996) is used for retrieving aerosol parameters such as optical thickness, ${\AA}$ngstr$\"{O}$m exponent, single scattering albedo, and size distribution from sky-radiation measurements, which then can be used for examining spatial and temporal variations of aerosol. Obtaining aerosol radiative forcing at TOA and surface, a radiative transfer model is used with inputs of obtained aerosol parameters and GMS-5 satellite-based cloud optical properties. Results show that there is a good agreement of simulated downwelling radiative flux at the surface with observation within 10 W m$^{-2}$ rms errors under the clear sky condition. However, a relatively large difference up to 40 W m$^{-2}$ rms error is found under the cloudy sky condition. The computed aerosol radiative forcing at the surface shows downward flux changes ranging from -100 to -170 W m$^{-2}$ per unit aerosol optical thickness at 0.7 $\mu$m. The different values of aerosol radiative forcing among the stations is mainly due to the differences in single scattering albedo ($\omega$$_{0.7}$) and asymmetric parameter (g$_1$) related to the geographical and seasonal variations.

• Journal of the Optical Society of Korea
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• v.14 no.3
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• pp.174-177
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• 2010

The rotational Raman LIDAR technique has been used to accurately measure aerosol optical properties such as backscatter coefficient, extinction coefficient, and LIDAR ratio. In the case of the vibrational Raman technique, the ${\AA}$ngstr$\ddot{o}$om exponent, which has wavelength dependence on the particle properties, is assumed to obtain the extinction coefficient. However, this assumed ${\AA}$ngstr$\ddot{o}$m exponent can cause systematic errors in retrieving aerosol optical properties. In the case of the rotational Raman technique, the aerosol optical properties can be measured without any assumptions about the ${\AA}$ngstr$\ddot{o}$m exponent. In this paper, the LIDAR ratio was measured by using the rotational Raman LIDAR and vibrational Raman LIDAR in the troposphere. And, the LIDAR ratios measured by these two methods were compared.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.232-235
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• 2003

In general, the parameters of climate change include aerosol chemical compounds, aerosol optical depth, greenhouse gases(carbon dioxide, CFCs, methane, nitrous oxide, tropospheric ozone), ozone distribution, precipitation acidity and chemical compounds, persistent organic pollutants and heavy metals, radioactivity, solar radiation including ultra-violet and standard meteorological parameters. Over the last ten years, the monitoring activities of Korea regarding to the climate change have been progressed within the WMO GAW and ACE-Asia IOP programs centered at the observation sites of Anmyeon and Jeju Gosan islands respectively. The Greenhouse gases were pointed out that standard air quality monitoring techniques are required to enhance data comparability and that data presentation formats need to be harmonized and easily understood. Especially, the impact of atmospheric aerosols on climate depends on their optical properties, which, in turn, are a function of aerosol size distribution and the spectral reflective indices. Aerosol optical depth and single scattering albedo in the visible are used as the two basic parameters in the atmospheric temperature variation studies. The former parameter is an indicator of the attenuation power of aerosols, while the latter represents the relative strength of scattering and absorption by aerosols. For aerosols with weak absorption, surface temperature decreases as the optical depth increases because of the domination of backscattering. For aerosols with strong absorption, however, warming could occur as the optical depth increases. The objective of the study is to characterize the means, variability, and trends of Greenhouse gases and aerosol properties on a regional basis using data from its baseline observatories in Korea peninsula. A further goal is to understand the factors that control radiative forcing of the greenhouse and aerosol.

• Korean Journal of Remote Sensing
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• v.24 no.6
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• pp.559-569
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• 2008

The Geostationary Ocean Color Imager (GOCI) on board the Communication Ocean Meteorological Satellite (COMS), the first geostationary ocean color sensor, requires accurate atmospheric correction since its eight bands are also affected by atmospheric constituents such as gases, molecules and atmospheric aerosols. Unlike gases and molecules in the atmosphere, aerosols can interact with sunlight by complex scattering and absorption properties. For the purpose of qualified ocean remote sensing, understanding of aerosol-radiation interactions is needed. In this study, we show micro-physical and optical properties of aerosols using the Optical Property of Aerosol and Cloud (OPAC) aerosol models. Aerosol optical properties, then, were used to analysis the relationship between theoretical satellite measured radiation from radiative transfer calculations and aerosol optical thickness (AOT) under various environments (aerosol type and loadings). It is found that the choice of aerosol type makes little different in AOT retrieval for AOT<0.2. Otherwise AOT differences between true and retrieved increase as AOT increases. Furthermore, the differences between the AOT and angstrom exponent from standard algorithms and this study, and the comparison with ground based sunphotometer observations are investigated. Over the northeast Asian region, these comparisons suggest that spatially averaged mean AOT retrieved from this study is much better than from standard ocean color algorithm. Finally, these results will be useful for aerosol retrieval or atmospheric correction of COMS/GOCI data processing.

• Journal of Magnetics
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• v.12 no.3
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• pp.129-132
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• 2007

Bismuth-substituted yttrium iron garnet (Bi:YIG, $Bi_{0.5}Y_{2.5}Fe_5O_{12}$) films were deposited with aerosol deposition method and their magnetic and optical properties were investigated as a function of annealing temperature. Since the ceramic films deposited with aerosol deposition method have not a perfect crystal structure due to non-uniform internal stress occurred by mechanical collision during their deposition, the post annealing could be a key process to release its internal stress and to improve its micro structure for optimizing the magnetic and magneto-optic properties of films. The crystallinity of Bi: YIG film was improved with increase of annealing temperature, and the saturation magnetization increased up to 87 emu/cc at $800^{\circ}C$. The Faraday rotation increased up to $1.4deg/{\mu}m$ by annealing at $700^{\circ}C$ around the wavelength of $0.5{\mu}m$. The optical transmittance of the Bi:YIG film was also improved in visible region.