• 한국입자에어로졸학회지
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• 제4권1호
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• pp.9-20
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• 2008

The effect of light intensity on the ozone formation and the aerosol number concentration during the photochemical reactions of ambient air was investigated in an indoor smog chamber. The smog chamber consists of a housing, 64 blacklights, and a $2.5-m^3$ reaction bag made of Teflon film. The bag was filled with the unfiltered ambient air in Seoul from January 10 to March 18, 2002. In this work, the photolysis rate of $NO_2$, $k_1$ was used as an index of light intensity. Three levels of light intensity were controlled by changing the number of blacklights turned on among 64 blacklights: $0.29min^{-1}$ (50%), $0.44min^{-1}$ (75%), $0.57min^{-1}$ (100%). The ozone concentration increased rapidly within 10 minutes after irradiation irrespective of light intensity, thereafter it increased linearly during the irradiation. The ozone production rate seems to be dependent on both the light intensity and the quality of ambient air introduced into the reaction bag. The change in aerosol number concentration also depended on both the light intensity and the ambient air quality, especially aerosol size distribution. Based on the initial ambient aerosol size distributions, the photochemical potential for aerosol formation and growth is classified into two cases. One is the case showing aerosol formation and growth processes, and the other is the case showing no apparent change in particle size distribution.

• 한국대기환경학회지
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• 제2권2호
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• pp.41-50
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• 1986

Urban aerosol concentrations in the size range of $0.01 \sim 1.0 \mum$ have been measured by using an electrical aerosol analyzer from May through October, 1984. The total diurnal variation of the number concentration indicates that a minimum value is observed at 3 hr and a sharp increase is noticed early in the morning with a subsequent slow and continuous increase from around 7 hr until 20 hr. After that it is decreased to reach its minimum by dawn. However, both surface and volume concentrations have shown that their first maxima at 8 hr and their second at about 20 hr simultaneously. It is found that the aerosol number is mainly governed by the particles in the size range of $0.01 \sim 0.1 \mum$, while most volume is in $0.1 \sim 1.0 \mum$ size range. It is known fact that particles of $0.1 \sim 1.0 \mum$ size range affect the visibility reduction in the atmosphere. The monthly variation of aerosol concentration remarks its minimum in summer. The main factors influencing the aerosol concentration are emission of autoexhausts, various processes of production and removal, and meteorological parameters.

• Journal of Korean Society for Atmospheric Environment
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• 제20권E2호
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• pp.61-68
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• 2004

Aerosol losses in a 100L Tedlar$^{(R)}$ bag were investigated for the aerosols with number median diameter of 0.05 ${\mu}{\textrm}{m}$ and number concentration of 6.4 ${\times}$ 10$^4$ cm$^{-3}$ . Over a 1 hr period, loss of particles in the bag is apparent, and the volume decrease with time is significant. The number concentration, surface area, and volume concentration of the aerosols decreased to 34, 50, and 52% of the initial value in 30 min, respectively. This indicates that deposition to the walls was the main loss process for aerosols in the Tedlar$^{(R)}$ bag. Theoretical calculations showed that coagulations and deposition by diffusion and gravitational sedimentation would not change aerosol characteristics significantly, and the electrical force was the dominant loss process for particles in the Tedlar$^{(R)}$ bag over a 1 hr period.eriod.

• 한국대기환경학회지
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• 제21권1호
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• pp.27-38
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• 2005

An experimental investigation of the gas-phase photooxidation of toluene-NO$_{x}$-air mixtures at sub-ppm concentrations has been carried out in a 6.9 ㎥, indoor smog chamber irradiated by blacklights. Measured parameters in the toluene-NO$_{x}$ experiments included aerosol, $O_3$, NO, NO$_2$, NO$_{x}$ CO, SO$_2$ toluene, and air temperature. The initial toluene concentration ranged from 225 ppb to 991 ppb and the initial concentration ratio of toluene/NO$_{x}$ in ppbC/ppb was in the range of 5～20. It was found that the variation of aerosol number concentration with irradiation time caused by the photooxidation of toluene-NO$_{x}$-air mixtures depended on the initial toluene concentration for similar concentration ratio of toluene/NO$_{x}$. The dependency of initial toluene concentration on the photooxidation of toluene-NO$_{x}$-air mixtures for toluene/NO$_{x}$= 5～6 seemed to be opposite to that for toluene/NO$_{x}$=10～11. The maximum number concentration of aerosols formed by photooxidation and the aerosol yield depended on both initial toluene concentration and initial concentration ratio of toluene/NO$_{x}$. In this study, the aerosol yield, defined as aerosol formed per unit toluene consumed, was found to be 0.01～0.16.und to be 0.01～0.16.

• 한국대기환경학회지
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• 제19권2호
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• pp.167-177
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• 2003

The number size distribution of urban aerosols ranging from 0.02 to 20 ${\mu}{\textrm}{m}$ in diameter was measured by using a scanning mobility particle sizer (SMPS) system and an aerodynamic particle sizer spectrometer (APS) at Seoul from November 30,2001 to January 14, 2002. The gaseous species such as CO, NO, NO$_2$, and $O_3$ were also continuously monitored. The daily average concentration of urban aerosols sorted into three groups (0.02~0.1 ${\mu}{\textrm}{m}$, 0.1~1 ${\mu}{\textrm}{m}$ and 1~10 ${\mu}{\textrm}{m}$) and the typical number, surface, and volume distributions of urban aerosols were discussed in this paper. The weekly variation of aerosol concentration was compared with those of gaseous concentrations. relative humidity, and visibility. The results showed that the particle number concentration seemed to increase in the morning and the number concentration of fine particles less than 1 fm in diameter seemed to increase when the concentrations of CO, NO, and NO$_2$ were high. The number concentration of fine particles was relatively high when the relative humidity was greater than 70％ during the increasing period of relative humidity. The visibility was weakly correlated with the concentration of aerosols ranging 0.1 to 1 ${\mu}{\textrm}{m}$, and the number size distribution for high visibility episode was apparently different from that for low visibility episode.

• 한국입자에어로졸학회지
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• 제6권2호
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• pp.91-103
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• 2010

Size-segregated number concentration and scattering coefficient of urban aerosols were measured using an SMPS (scanning mobility particle sizer) and a nephelometer, respectively in Seoul, Korea, during the winter season of 2003. The average number concentrations of ultrafine particles (20~100 nm) and accumulation mode particles (100~600 nm) were $2,170\;particles\;cm^{-3}$ and $1,521\;particles\;cm^{-3}$, respectively. The scattering coefficient at the wavelength of 550 nm ranged from $62.6Mm^{-1}$ to $330.1Mm^{-1}$ and average value was $163.4Mm^{-1}$. The peak concentrations of ultrafine particles and accumulation mode particles were simultaneously recorded between 6:00 and 9:00 A.M., indicating the effect of vehicle emissions which are major air pollution sources in the urban atmosphere. On average, the number concentration of ultrafine particles was 1.4 times higher than that of accumulation mode particles, although it was a little higher during the morning peak time. The variation of aerosol scattering coefficient was in good agreement with that of accumulation mode particle number concentration rather than that of ultrafine particle number concentration.g coefficient was in good agreement with that of accumulation mode particle number concentration rather than that of ultrafine particle number concentration.

• 한국산업보건학회지
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• 제32권2호
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• pp.163-171
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• 2022

Objectives: Fit performance may vary depending on the ambient aerosol number and ratio in respective test environment. Although several instrument can measure it, they differ with respect to the measurement principle and the range of ambient aerosols collected to calculate the fit factor. Methods: In this study, the fit performance between a condensation nuclei counter(CNC) and an optical particle counter(OPC) was compared according to ambient aerosol number concentration, and evaluated consistency. One type respirators(N95 masks) was worn by 50 participants PortaCount®(Pro+ 8038) and MT®(05U) were connected with one probe to one mask, and Fit Factors(FFs) were measured simultaneously. Results: The interclass correlation coefficient of the fit factor and ambient aerosol number, as measured by the two instrument, was 0.82 and 0.79, respectively, indicating a high consistency level. On the other hand there was a significant correlation between the successful test performance of the OPC instrument and the ambient aerosol number. Conclusions: The test was passed with the CNC and OPC instruments when the ambient aerosol number was 635-3,332 particles/cm³ and 368-1,976 particles/cm³, respectively. Thus, the ideal ambient aerosol number of particles differed between the two instrument.

• Asia-Pacific Journal of Atmospheric Sciences
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• 제54권4호
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• pp.587-598
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• 2018

The impacts of aerosol loading on surface precipitation from mid-latitude deep convective systems are examined using a bin microphysics model. For this, a precipitation case over north central Mongolia, which is a high-altitude inland region, on 21 August 2014 is simulated with aerosol number concentrations of 150, 300, 600, 1200, 2400, and $4800cm^{-3}$. The surface precipitation amount slightly decreases with increasing aerosol number concentration in the range of $150-600cm^{-3}$, while it notably increases in the range of $600-4800cm^{-3}$ (22% increase with eightfold aerosol loading). We attempt to explain why the surface precipitation amount increases with increasing aerosol number concentration in the range of $600-4800cm^{-3}$. A higher aerosol number concentration results in more drops of small sizes. More drops of small sizes grow through condensation while being transported upward and some of them freeze, thus increasing the mass content of ice crystals. The increased ice crystal mass content leads to an increase in the mass content of small-sized snow particles largely through deposition, and the increased mass content of small-sized snow particles leads to an increase in the mass content of large-sized snow particles largely through riming. In addition, more drops of small sizes increase the mass content of supercooled drops, which also leads to an increase in the mass content of large-sized snow particles through riming. The increased mass content of large-sized snow particles resulting from these pathways contributes to a larger surface precipitation amount through melting and collision-coalescence.

• 한국대기환경학회지
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• 제19권5호
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• pp.515-528
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• 2003

The characteristics of one year observation aerosol data in Seoul, 200 I was studied using an OPC (Optical Particle Counter). The size resolved aerosol number concentrations of 0.3 ∼ 25 11m were measured. The results were compared with PM$_{10}$ mass concentration data under various meteorological conditions including dust and precipitation events. For fine particles whose diameter is less than 2.23 ${\mu}{\textrm}{m}$, the number concentration increases in the early morning which is considered due to transportation. while the coarse mode particles increase during daytime. This increase can be explained as local sources and human activities near sampling site. Hourly averaged data show that there exists diurnal variation. Generally, PM$_{10}$ data showed a similar tendency with OPC data. The size resolved OPC data showed that the particles of 0.5 ∼ 3.67 ${\mu}{\textrm}{m}$ are positively correlated with PM$_{10}$ data. The accumulated volume fraction of size resolved aerosol concentration in 0.5 ∼ 10 ${\mu}{\textrm}{m}$ showed that 0.5 ∼ 2.23 ${\mu}{\textrm}{m}$ particles occupied 59.2% of total aerosol volume of 0.5 ∼ 10 ${\mu}{\textrm}{m}$./TEX>.

• 한국지구과학회지
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• 제33권3호
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• pp.259-268
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• 2012

해양에서 발달하는 강수시스템의 연직풍에 따라 변동하는 해양성 에어러솔의 입경별 특성을 알아보기 위하여 마라도에서 남서쪽으로 419 km 지점에 위치한 이어도 해양종합과학기지에서 2009년 6월 8일부터 22일까지 에어러솔수 농도와 연직풍 관측을 실시하였다. 에어러솔 수 농도와 연직풍은 레이저입자계수기와 초음파 3차원 풍향 풍속계를 이용하였으며, 지상일기도, NCEP/NCAR 재분석자료, 라디오존데 자료를 이용하여 종관상태를 분석하였다. 그 결과, 전체적으로 1.0 ${\mu}m$ 이상의 크기의 에어러솔 수 농도 분포가 강수 중에 크게 변동하였으며, 하강류에서 상승류로 연직풍이 변함에 따라 크게 증가하였다. 강수 중에는 큰 입자(1.0 ${\mu}m$ 이상)의 에어러솔 수 농도가 약 5배 증가하였고, 이때 상승류가 약 0.4 $ms^{-1}$로 나타났다. 또한 축적모드(1.0 ${\mu}m$ 미만)와 큰 입자(1.0 ${\mu}m$ 이상)의 에어러솔 수 농도는 강수 중과 비교하여 약 45%와 92%가 제거되었다. 이는 독립된 해양지역에서의 큰 입자(1.0 ${\mu}m$ 이상) 에어러솔 수 농도 증가는 수평풍 보다는 상승류에 의해 크게 영향을 받고, 강수에 의한 세정효과도 나타났다. 따라서 해양경계층 내 에어러솔의 생성 및 발달 메커니즘에 상승류의 영향이 크게 기인함을 알 수 있었다.