• Title/Summary/Keyword: advanced thermal analysis

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The Characteristics for BNCT facility in Hanaro Reactor

  • Soheigh Suh;Lee, Dong-Han;Ji, Young-Hoon;Lee, Dong-Hoon;Yoo, Seong-Yul;Rhee, Chang-Hun;Rhee, Soo-Yong;Jun, Byung-Jin
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2002.09a
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    • pp.161-163
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    • 2002
  • The BNCT(Boron Neutron Capture Therapy) facility has been developed in Hanaro(High-flux Advanced Neutron Application Reactor), a research reactor of Korea Atomic Energy Research Institute. A typical tangenial beam port is utilized with this BNCT facility. Thermal neutrons can be penetrated within the limits of the possible maximum instead of being filtered fast neutrons and gamma rays as much as possible using the silicon and bismuth single crystals. In addition to, the liquid nitrogen (LN$_2$) is used to cool down the silicon and bismuth single crystals for the increase of the penetrated thermal neutron flux. Neutron beams for BNCT are shielded using the water shutter. The water shutter was designed and manufactured not to interfere with any other subsystem of Hanaro when the BNCT facility is operated. Also, it is replaced with conventional beam port plug in order to cut off helium gas leakage in the beam port. A circular collimator, composed of $\^$6/Li$_2$CO$_3$ and polyethylene compounds, is installed at the irradiation position. The measured neutron flux with 24 MW reactor power using the Au-198 activation analysis method is 8.3${\times}$10$\^$8/ n/cm$^2$ s at the collimator, exit point of neutron beams. Flatness of neutron beams is proven to ${\pm}$ 6.8% at 97 mm collimator. According to the result of acceptance tests of the water shutter, the filling time of water is about 190 seconds and drainage time of it is about 270 seconds. The radiation leakages in the irradiation room are analyzed to near the background level for neutron and 12 mSv/hr in the maximum for gamma by using BF$_3$ proportional counter and GM counter respectively. Therefore, it is verified that the neutron beams from BNCT facility in Hanaro will be enough to utilize for the purpose of clinical and pre-clinical experiment.

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Free-Radical Polymerization and Copolymerization of N-Acetyl ${\alpha}$-Aminoacrylic Acid (N-Acetyl ${\alpha}$-aminoacrylic Acid의 자유라디칼 중합 및 혼성중합)

  • Il Hyun Park;Chong Kwnag Lee;Jae Ho Choi;Jung-Il Jin
    • Journal of the Korean Chemical Society
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    • v.26 no.4
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    • pp.235-246
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    • 1982
  • The free radical polymerization and copolymerization of N-acetyl ${\alpha}$-aminoacrylic acid were investigated. From the result of kinetic investigation of N-acetyl ${\alpha}$-aminoacrylic acid in DMF at $60^{\circ}C$, a rate equation of $R_p$ = $k_p[M]^{0.97}[I]^{0.59}$ was obtained. The overall activation energy for the polymerization was found to be 25.2 kcal/mole. Copolymerization of N-acetyl ${\alpha}$-aminoacrylic acid with acrylic acid and styrene was carried out for the determination of monomer reactivity ratios. The monomer reactivity ratios for the monomer pairs determined at 70.0{\pm}0.1^{\circ}C$ using benzoyl peroxide as an initiator are; $r_1$(N-acetyl ${\alpha}$-aminoacrylic acid) = 0.49, $r_2$(acrylic acid) = 1.41, $r_1$(N-acetyl ${\alpha}$-aminoacrylic acid) = 0.44, $r_2$(styrene) = 0.91. The values of Alfrey-Price's Q and e parameters for N-acetyl ${\alpha}$-aminoacrylic acid were calculated to be 0.51 and 0.16 for the both systems. Differential thermal analysis and thermogravimetry showed that acrylic acid copolymers have poorer thermal stability as compared with the homopolymer of N-acetyl ${\alpha}$-aminoacrylic acid.

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Effect of modifiers on the properties of glass-ceramics containing coal bottom ash (석탄 바닥재가 포함된 결정화 유리의 특성에 미치는 수식제의 영향)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.53-57
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    • 2010
  • The influence of CaO addition on the crystallization temperature, crystal types, and microstructure of L-A-S ($Li_2O-Al_2O_3-SiO_2$) glass-ceramics system fabricated from a coal bottom ash, produced at thermal power plant, was studied. The glass transition and crystallization temperatures were shifted to the higher temperature position with increasing CaO content in a non-isothermal analysis using a DTA. The major crystalline phases of L-A-S glass-ceramics system produced were identified as ${\beta}$-spodumene ($LiAlSi_2O_6$) and eucryptite ($LiAlSiO_4$). The glass-ceramics showed a bulk and surface crystallization behavior at a time. With increasing CaO content, the ${\beta}$-spodumene peak in XRD increased and some CaO-related phases were formed. The surface crystal grown from the exterior to the center in glass-ceramics showed various shapes by amount of CaO added. Some cracks were generated at the glass-ceramics containing CaO above 9 wt% due to the mismatch of thermal expansion coefficients between a ${\beta}$-spodumene and CaO-related crystal phases.

Analysis on Insulation of Wind Environment and Greenhouse Cover Materials Insulation for Advanced Greenhouse Energy Design in Saemangeum Reclaimed Land (새만금 간척지 첨단온실 에너지 설계를 위한 풍환경 및 온실 피복재의 영향 분석)

  • Hyo-Jae Seo;Il-Hwan Seo;Deuk-ha Noh;Haksung Lee
    • Journal of Bio-Environment Control
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    • v.32 no.1
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    • pp.57-63
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    • 2023
  • The external weather conditions including temperature and wind speed in the Saemangeum reclaimed land is different from that of the inland, affecting the internal environment of the greenhouse. Therefore, it is important to select an appropriate covering material considering the insulation effect according to the type and characteristics of the covering material considering the weather condition in the Saemangeum reclaimed land. A hexahedral insulation chamber was designed to evaluate the insulation efficiency of each glass-clad material in the outside weather condition in reclaimed land. In order to evaluate the insulation effect of each covering material, a radiator was installed and real-time power consumption was monitored. 16-mm PC (polycarbonate), 16-mm PMMA (polymethyl methacrylate), 4-mm greenhouse glass, and 16-mm double-layered glass were used as the covering materials of the chamber. In order to understand the effect of the external wind directions, the windward and downwind insulation properties were evaluated. As a result of comparing the thermal insulation effect of each greenhouse cover material to single-layer glass, the thermal insulation effect of double-layer glass was 16.9% higher, while PMMA and PC were 62.5% and 131.2% higher respectively. On average the wind speed on the windward side was 53.1% higher than that on the lee-wind side, and the temperature difference between the inside and outside of the chamber at the wind ward side was found to be 52.0% larger than that on the lee ward side. During the experiment period, the overall heating operation time for PC was 39.2% lower compared to other insulation materials. Showing highest energy efficiency, and compared to PC, single-layer glass power consumption was 37.4% higher.

Analysis of Vapor Compression Refrigeration Cycle Performance Depending on Different Joining Method of Non-adiabatic Capillary Tube (비단열 모세관 접합방법이 증기압축식 냉동사이클 성능에 미치는 영향 해석)

  • Yi, Dae-Yong;Park, Sang-Goo;Kim, Hyun-Jung;Jeong, Ji-Hawn
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.8
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    • pp.1144-1151
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    • 2009
  • Refrigeration systems can be incorporated with non-adiabatic capillary tubes to improve their efficiency. The non-adiabatic capillary tube is constructed by joining the capillary tube with suction pipe to allow heat transfer between them, which is called capillary tube-suction line heat exchanger(SLHX). There are various joining methods and they may influence the characteristics of the refrigeration cycle. The present work aims to analyze the effect of widely-used two joining methods on the refrigeration cycle. The results show that soldered SLHX has much less thermal resistance than tapered SLHX but slightly outperforms in terms of coefficient of performance(COP) and cooling capacity. The soldered SLHX increased COP and cooling capacity of a refrigerator by 5.09% and 14.77% while the tapered SLHX did by 5.05% and 14.75%, respectively.

A Study on the Cycle Analyzing and Intake Valve Control by the Miller Method with a High Expansion into Low-Speed Diesel Engine (저속 디젤기관에서 고팽창의 밀러방식에 의한 사이클 해석 및 흡기밸브제어에 대한 연구)

  • Jag, Tae-Ik
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.8
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    • pp.1100-1106
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    • 2009
  • Recently, there are quite a lot of attention is drown on the researches related to of Miller method applied high expansion cycle. For this study, high expansion cycles are formed and analyzed with the base view point of thermodynamics, and the features of each factors are also investigated. As a result of analysis, the expansion-compression ratio is expected with a decrease of effective compression ratio as intake valve closing time retarded, however, the decrease of mean effective pressure and its output is accompanied with the counterflow of intake air. Accordingly, as the consequence of such failure, it is expected that an alternative is needed for the realization of high expansion cycles, and the improvement over thermal efficiency. To materialize such cycle, the control system to delay the closing time of intake valve was designed and VVT, the 3 S/B low speed diesel engine, is applied to evaluate the efficiency. The result of the trial shows that there was no significant errors.

Real-time Contaminant Particle Monitoring for Chemical Vapor Deposition of Borophosphosilicate and Phosphosilicate Glass Film by using In-situ Particle Monitor and Particle Beam Mass Spectrometer (ISPM 및 PBMS를 이용한 BPSG 및 PSG CVD 공정 중 발생하는 오염입자의 실시간 측정)

  • Na, Jeong Gil;Choi, Jae Boong;Moon, Ji Hoon;Lim, Sung Kyu;Park, Sang Hyun;Yi, Hun Jung;Chae, Seung Ki;Yun, Ju Young;Kang, Sang Woo;Kim, Tae Sung
    • Particle and aerosol research
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    • v.6 no.3
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    • pp.139-145
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    • 2010
  • In this study, we investigated the particle formation during the deposition of borophosphosilicate glass (BPSG) and phosphosilicate glass (PSG) films in thermal chemical vapor deposition reactor using in-situ particle monitor (ISPM) and particle beam mass spectrometer (PBMS) which installed in the reactor exhaust line. The particle current and number count are monitored at set-up, stabilize, deposition, purge and pumping process step in real-time. The particle number distribution at stabilize step was measured using PBMS and compared with SEM image data. The PBMS and SEM analysis data shows the 110 nm and 80 nm of mode diameter for BPSG and PSG process, respectively.

Electrically conductive nano adhesive bonding: Futuristic approach for satellites and electromagnetic interference shielding

  • Ganesh, M. Gokul;Lavenya, K.;Kirubashini, K.A.;Ajeesh, G.;Bhowmik, Shantanu;Epaarachchi, Jayantha Ananda;Yuan, Xiaowen
    • Advances in aircraft and spacecraft science
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    • v.4 no.6
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    • pp.729-744
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    • 2017
  • This investigation highlights rationale of electrically conductive nano adhesives for its essential application for Electromagnetic Interference (EMI) Shielding in satellites and Lightning Strike Protection in aircrafts. Carbon Nano Fibres (CNF) were functionalized by electroless process using Tollen's reagent and by Plasma Enhanced Chemical Vapour Deposition (PECVD) process by depositing silver on CNF. Different weight percentage of CNF and silver coated CNF were reinforced into the epoxy resin hardener system. Scanning Electron Microscopy (SEM) micrographs clearly show the presence of CNF in the epoxy matrix, thus giving enough evidence to show that dispersion is uniform. Transmission Electron Microscopy (TEM) studies reveal that there is uniform deposition of silver on CNF resulting in significant improvement in interfacial adhesion with epoxy matrix. There is a considerable increase in thermal stability of the conductive nano adhesive demonstrated by Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). Four probe conductivity meters clearly shows a substantial increase in the electrical conductivity of silver coated CNF-epoxy composite compared to non-coated CNF-epoxy composite. Tensile test results clearly show that there is a significant increase in the tensile strength of silver coated CNF-composites compared to non-coated CNF-epoxy composites. Consequently, this technology is highly desirable for satellites and EMI Shielding and will open a new dimension in space research.

Study on the Microstructural Degradation of the Boiler Tubes for Coal-Fired Power Plants

  • Yoo, Keun-Bong;He, Yinsheng;Lee, Han-Sang;Bae, Si-Yeon;Kim, Doo-Soo
    • KEPCO Journal on Electric Power and Energy
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    • v.4 no.1
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    • pp.25-31
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    • 2018
  • A boiler system transforms water to pressured supercritical steam which drives the running of the turbine to rotate in the generator to produce electricity in power plants. Materials for building the tube system face challenges from high temperature creep damage, thermal fatigue/expansion, fireside and steam corrosion, etc. A database on the creep resistance strength and steam oxidation of the materials is important to the long-term reliable operation of the boiler system. Generally, the ferritic steels, i.e., grade 1, grade 2, grade 9, and X20, are extensively used as the superheater (SH) and reheater (RH) in supercritical (SC) and ultra supercritcal (USC) power plants. Currently, advanced austenitic steel, such as TP347H (FG), Super304H and HR3C, are beginning to replace the traditional ferritic steels as they allow an increase in steam temperature to meet the demands for increased plant efficiency. The purpose of this paper is to provide the state-of-the-art knowledge on boiler tube materials, including the strengthening, metallurgy, property/microstructural degradation, oxidation, and oxidation property improvement and then describe the modern microstructural characterization methods to assess and control the properties of these alloys. The paper covers the limited experience and experiment results with the alloys and presents important information on microstructural strengthening, degradation, and oxidation mechanisms.

Fabrication and characterization of Mn-Si thermoelectric materials by mechanical alloying (MA법에 의한 Mn-Si계 초미세 열전재료의 제조 및 평가)

  • Lee, Chung-Hyo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.6
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    • pp.246-252
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    • 2011
  • The semiconducting $MnSi_{1.73}$ compound has been recognized as a thermoelectric material with excellent oxidation resistance and stable characteristics at elevated temperature. In the present work, we applied mechanical alloying (MA) technique to produce $MnSi_{1.73}$ compound using a mixture of elemental manganese and silicon powders. The mechanical alloying was carried out using a Fritsch P-5 planetary mill under Ar gas atmosphere. The MA powders were characterized by the X-ray diffraction with Cu-$K{\alpha}$ radiation, thermal analysis and scanning electron microscopy. Due to the observed larger loss of Si relative to Mn during mechanical alloying of $MnSi_{1.73}$, the starting composition of a mixture Mn-Si was modified to $MnSi_{1.83}$ and then $MnSi_{1.88}$. The single $MnSi_{1.73}$ phase has been obtained by mechanical alloying of $MnSi_{1.88}$ mixture powders for 200 hours. It is also found that the grain size of $MnSi_{1.73}$ compound powders analyzed by Hall plot method is reduced to 40 nm after 200 hours of milling.