• Title/Summary/Keyword: advanced thermal analysis

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A Study on The Resilient Modulus of Coal Ash (석탄회(石炭灰)의 MR특성(特性)에 관한 연구(硏究))

  • Chun, Byung Sik;Oh, Min Yeoul;Kwon, Hyung Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.3
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    • pp.215-220
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    • 1992
  • The rational methods of pavement design and analysis using the resilient modulus have been increasingly adopted by major advanced countries and many researches concerning the resilient characteristics of pavement materials as well as developement of reliable testing method have been actively performed. Accordingly, fundamental researches on the resilient modulus characteristics of domestic subgrade soils are very important. With want of aggregate due to the national constuction projects, it is siginificant to examine on the utilization of coal ash as pavement materials. The purpose of this study is to examine resilient modulus characteristics and to evaluate the relationship between MR and CBR by AASHTO testing method. The materials for this investigation are Coal Ash (Fly Ash, Bottom Ash) from 5 thermal-power-plants and 4 decomposed-granite-soils from central regions of Korea.

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Copolymerization of 2-Hydroxyethyl Methacrylate with Functional Silane Monomers (2-히드록시에틸 메타크릴레이트와 기능성 사이레인 단량체와의 공중합에 관한 연구)

  • Sung, Yong-Kiel;Lee, Chang-Gyu;Jung, Il-Nam
    • Journal of Biomedical Engineering Research
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    • v.8 no.1
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    • pp.29-40
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    • 1987
  • 2-Hydroxyethyl methacrylate(HEMA) was copolymerized with allyltrimethylsilane- (ATMS) and allylt.imethoxysilane(ATMOS) at 70。C in N, N'dimethylformamide- (DMV) using $\alpha$ , $\alpha$'-azobisisobutyronitrile(AIBN). The compositions of unreacted monomers were determined by gas chromatographic analysis. The monomer reactivity ratios were determined by Fireman-Ross, Helen-Tiidus and intersection methods. The average values are as follows : $$r_1(HEMA) : 6.62 $\pm$ 0.07, r_2(ATMS) : 0.07 $\pm$ 0.01 for HEMA-ATMS system.$$ $$r_l(HEMA) : 4.09 $\pm$ 0.14, r_2(ATMOS) : 0.06 $\pm$ 0.01 for HEMA-ATMOS toys tem.$$ The lower rl(HEMA) In the HEMA-ATMOS system as compared to HEMA ATMS system may be contributed to higher relative reactivity of ATMOS toward the poly(HEMA) radical. The compositions of synthesized copolymers were determined from silicon con tents estimated gravimetrically. The thermal stabilities of the copolymers were investigated by thermogravimetry(TG). The enthalpic changes associated with the endothermic transition were evaluated by differential scanning calorimetry(DSC). The swelling properties of the copolymers in water were also investigated.

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Microstructure and Properties of Fully Aliphatic Polyimide/Mesoporous Silica Hybrid Composites

  • Mathewst, Anu Stella;Jung, Yu-In;Lee, Tae-Sung;Park, Sung-Soo;Kim, Il;Ha, Chang-Sik;Selvaraj, M.;Han, Mi-Jeong
    • Macromolecular Research
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    • v.17 no.9
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    • pp.638-645
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    • 2009
  • We report the effect of the amount of the mesoporous material, SBA-15, on the basic traits of fully aliphatic polyimides (API). For this purpose, water soluble, fully aliphatic poly(amic acid) triethyl amine salts ($PAA_{(s)}$) were prepared and mixed with various amounts of SBA-15. Fully aliphatic polyimide hybrid composites containing the SBA 15-type mesoporous silica were synthesized successfully from bicyclo [2.2.2] oct-7-ene-2,3,5,6-tetracarboxylic dianhydride and alicyclic diamine, 4,4'-methylene bis(2-methylcyclohexylamine). The structure of the hybrid composites was confirmed by IR spectroscopic analysis. Scanning electron microscopy revealed the morphology of the compounds. The hybrid composites exhibited good thermal stability, reasonable transparency, and a low dielectric constant.

A Study of Environment & Bullet-Proof Capability Test Method for KLTV's Transparent Armour (한국형 전술차량 방탄유리 환경 및 방호력 시험 적용 기법 연구)

  • Park, Jinwon;Park, Youngchan;Kim, Seonjin
    • Journal of the Korea Institute of Military Science and Technology
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    • v.21 no.1
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    • pp.69-73
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    • 2018
  • Korean-peacekeeper's transparent armors in Iraq showed delamination, cracking and clouding a decade ago. And there were also similar deterioration recurrences in KLTV during the operational test a few years ago. Also, the differences between operational capability & lab Bullet-proof test condition, and insufficiency of military protection spec resulted in incomplete bullet-proof results. Moreover, although so many ground weapon systems have been developed, there were not secure test & evaluation codes to verify transparent armoured glasses equal to advanced-overseas products. So in this study, first, environmental test codes were established that all tests should be carried out as the application of only one specimen with newly adopted thermal shock test instead of completing each test with different one. Second, protection standards were integrated through the analysis of global developed country's specifications and reinforced as adding to the real mock-up condition if vehicle's glasses are smaller than standard specimen. Hereby, by applying to test-codes which including actual operational & vehicular conditions, the gap between development test and operational environment was minimized.

Analysis of Two Phase Natural Circulation Flow in the Reactor Cavity under External Vessel Cooling (원자로용기 외벽냉각시 원자로공동에서 이상유동 자연순환 해석)

  • Park, Rae-Joon;Ha, Kwang-Soon;Kim, Sang-Baik;Kim, Hee-Dong
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2141-2145
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    • 2004
  • As part of study on thermal hydraulic behavior in the reactor cavity under external vessel cooling in the APR (Advanced Power Reactor) 1400, one dimensional two phase flow of steady state in the reactor cavity have been analyzed to investigate a coolant circulation mass flow rate in the annulus region between the reactor vessel and the insulation material using the RELAP5/MOD3 computer code. The RELAP5/MOD3 results have shown that a two phase natural circulation flow of 300 - 600 kg/s is generated in the annulus region between the reactor vessel and the insulation material when the external vessel cooling has been applied in the APR 1400. An increase in the heat flux of the inner vessel leads to an increase of the coolant mass flow rate. An increase in the coolant outlet area leads to an increase in the coolant circulation mass flow rate, but the coolant inlet area does not effective on the coolant circulation mass flow rate. The change of the lower coolant outlet to a lower position affects the coolant circulation mass flow rate, but the variation trend is not consistent.

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Analysis of the Influence of Post-Combustion $CO_2$ Capture on the Performance of Fossil Power Plants (후처리를 이용한 $CO_2$ 포집이 화력 발전설비 성능에 미치는 영향 해석)

  • Tak, Sang-Hyun;Kim, Tong-Seop;Chang, Young-Soo;Lee, Dae-Young;Kim, Min-Sung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.8
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    • pp.545-552
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    • 2010
  • Research and development efforts to reduce $CO_2$ emission are in progress to cope with global warming. $CO_2$ emission from fossil fuel fired power plants is a major greenhouse gas source and the post-combustion $CO_2$ capture is considered as a short or medium term option to reduce $CO_2$ emissions. In this study, the application of the post-combustion $CO_2$ capture system, which is based on chemical absorption and stripping processes, to typical fossil fuel fired power plants was investigated. A coal fired plant and a natural gas fired combined cycle plant were selected. Performance of the MEA-based $CO_2$ capture system combined with power plants was analyzed and overall plant performance including the energy consumption of the $CO_2$ capture process was investigated.

Thermal Decomposition Kinetics of Copolymers Derived from p-dioxanone, L-lactide and Poly(ethylene glycol)

  • Bhattarai Narayan;Khil Myung Seob;Oh Seung Jin;Kim Hak Yong;Kim Kwan Woo
    • Fibers and Polymers
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    • v.5 no.4
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    • pp.289-296
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    • 2004
  • The kinetic parameters, including the activation energy E, the reaction order n, and the pre-exponential factor Z, of the degradation of the copolymers based on the poly(L-lactide) (PLLA) or poly(p-dioxanone-co-L-lactide) (PDO/PLLA) and diol-terminated poly(ethylene glycol) (PEG) segments have been evaluated by the single heating methods of Friedman and Freeman-Carroll. The experimental results showed that copolymers exhibited two degradation steps under nitrogen that can be ascribed to PLLA or PDO/PLLA and PEG segments, respectively. However, copolymers exhibited almost single degradation step in air. Although the values of initial decomposition temperature were scattered, copolymers showed the lower maximum weight loss rate and degradation-activation energy in air than in nitrogen whereas the higher value of temperature at the maximum rate of weight loss was observed in air.

Electrospun Calcium Metaphosphate Nanofibers: I. Fabrication

  • Kim, Ye-Na;Lee, Deuk-Yong;Lee, Myung-Hyun;Lee, Se-Jong
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.144-147
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    • 2007
  • Calcium metaphosphate (CMP) nanofibers with a diameter of ${\sim}600nm$ were prepared using electrospun CMP/polyvinylpyrrolidone (PVP) fibers through a process of drying for 5 h in air followed by annealing for 1 h at $650^{\circ}C$ in a vacuum. The viscosity of the CMP/PVP precursor containing 0.15 g/ml of PVP was 76 cP. Thermal analysis results revealed that the fibers were crystallized at $569^{\circ}C$. The crystal phase of the as-annealed fiber was determined to be ${\delta}-CMP\;({\delta}-Ca(PO_3)_2)$. However, the morphology of the fibers changed from smooth and uniform (as-spun fibers) to linked-particle characteristics with a tubular form most likely due to the decomposition of the inner PVP matrix. It is expected that this large amount of available surface area has the potential to provide unusually high bioactivity and fast responses in clinical hard tissue applications.

Thermodynamic analysis on the chemical vapor deposition process of Ta-C-H-Cl system

  • Kim, Hyun-Mi;Shim, Kwang Bo;Lee, Jung-Min;Lee, Hyung-Ik;Choi, Kyoon
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.519-524
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    • 2018
  • Carbon/carbon composites (C/C) have been widely studied in the aerospace field because of their excellent thermal shock resistance and specific strength at high temperature. However, they have the problems that is easily oxidized and deteriorated under atmospheric environment. In order to overcome these shortcomings, the CVD coating of ultra-high-temperature ceramics to C/C has become an important technical issue. In this study, thermodynamic calculations were performed to TaC CVD coating on C/C by FactSage 6.2 program. The Ta-C phase diagrams were constructed with the results of thermodynamic calculations in the Ta-C-H-Cl system. Based on the Ta-C phase diagram, the experimental conditions were designed to confirm the deposition of various phases such as TaC single phase, TaC + C and $TaC+Ta_2C$ by varying the composition of Ta/C ratio. The deposited films were found to be in good agreement with the predicted phases.

Atmospheric Oxidation of Fe-16Cr-6Ni-6Mn-1.7Mo Stainless Steel between 700 and 900℃ (Fe-16Cr-6Ni-6Mn-1.7Mo 스테인리스 합금의 700~900℃에서의 대기중 산화)

  • Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.153-160
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    • 2011
  • The AISI 216L stainless steel with a composition of Fe-16Cr-6Ni-6Mn-1.7Mo (wt.%) was oxidized at $700{\sim}900^{\circ}C$ in air for 100 h. At $700^{\circ}C$, a thin $Mn_{1.5}Cr_{1.5}O_4$ oxide layer with a thickness of $0.4{\mu}m$ formed. At $800^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $FeCr_2O_4$ oxide layer with a total thickness of $30{\mu}m$ formed. The non-adherent scale formed at $800^{\circ}C$ was susceptible to cracking. At $900^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $Mn_{1.5}Cr_{1.5}O_4$ oxide layer formed, whose total thickness was $10{\sim}15{\mu}m$. The scales formed at $900^{\circ}C$ were non-adherent and susceptible to cracking. 216 L stainless steel oxidized faster than 316 L stainless steel, owing to the increment of the Mn content and the decrement of Ni content.