• Title/Summary/Keyword: advanced thermal analysis

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Estimation of Decay Heat Generated from Long-Term Management of Spent Fuel (장기관리 핵연료로부터 방출되는 붕괴열량 추정)

  • Park, J.W.;J.H.Whang;Chun, K.S.;Park, H.S.
    • Nuclear Engineering and Technology
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    • v.21 no.1
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    • pp.48-55
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    • 1989
  • In this study, simple functional forms which could predict decay heat are referred to and modified in order to analyse more easily long-term behavior of decay heat generated from domestic PWR and CANDU spent fuel. To reduce the difference between the predicted data by functional forms and ORIGEN 2 results and to predict the decay heat under the important parameter(s), sensitivity analysis is performed. By introducing the identified hey parameter, turnup, into the functional forms, the decay heat of spent fuels within a limited rangs of cooling time(3~500 years) becomes predictable for various turnup rates. The predicted decay heat of spent fuels with representative turnup rates such as 33, 37 and 40 GWD/MTU by the functional forms is in so good agreement with ORIGEN 2 results within $\pm$10% difference over the cooling time from 1 to 10$^{5}$ years that the functional forms presented here may be used for engineering purposes such as the thermal design and assessment of the facilities associated with spent fuel management.

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ANALYSIS OF THIN FILM POLYSILICON ON GLASS SYNTHESIZED BY MAGNETRON SPUTTERING

  • Min J. Jung;Yun M. Chung;Lee, Yong J.;Jeon G. Han
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.11a
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    • pp.68-68
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    • 2001
  • Thin films of polycrystalline silicon (poly-Si) is a promising material for use in large-area electronic devices. Especially, the poly-Si can be used in high resolution and integrated active-matrix liquid-crystal displays (AMLCDs) and active matrix organic light-emitting diodes (AMOLEDs) because of its high mobility compared to hydrogenated _amorphous silicon (a-Si:H). A number of techniques have been proposed during the past several years to achieve poly-Si on large-area glass substrate. However, the conventional method for fabrication of poly-Si could not apply for glass instead of wafer or quartz substrate. Because the conventional method, low pressure chemical vapor deposition (LPCVD) has a high deposition temperature ($600^{\circ}C-1000^{\circ}C$) and solid phase crystallization (SPC) has a high annealing temperature ($600^{\circ}C-700^{\circ}C$). And also these are required time-consuming processes, which are too long to prevent the thermal damage of corning glass such as bending and fracture. The deposition of silicon thin films on low-cost foreign substrates has recently become a major objective in the search for processes having energy consumption and reaching a better cost evaluation. Hence, combining inexpensive deposition techniques with the growth of crystalline silicon seems to be a straightforward way of ensuring reduced production costs of large-area electronic devices. We have deposited crystalline poly-Si thin films on soda -lime glass and SiOz glass substrate as deposited by PVD at low substrate temperature using high power, magnetron sputtering method. The epitaxial orientation, microstructual characteristics and surface properties of the films were analyzed by TEM, XRD, and AFM. For the electrical characterization of these films, its properties were obtained from the Hall effect measurement by the Van der Pauw measurement.

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Fabrication of Y2O3 doped ZrO2 Nanopowder by Reverse Micelle and Sol-Gel Processing

  • Kim, Hyun-Ju;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.21 no.10
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    • pp.568-572
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    • 2011
  • The preparation of $Y_2O_3$-doped $ZrO_2$ nanoparticles in Igepal CO-520/cyclohexane reverse micelle solutions is studied here. In this work, we synthesized nanosized $Y_2O_3$-doped $ZrO_2$ powders in a reverse micelle process using aqueous ammonia as the precipitant. In this way, a hydroxide precursor was obtained from nitrate solutions dispersed in the nanosized aqueous domains of a microemulsion consisting of cyclohexane as the oil phase, with poly (oxyethylene) nonylphenylether (Igepal CO-520) as the non-ionic surfactant. The synthesized and calcined powders were characterized by thermogravimetrydifferential thermal analysis (TGA-DTA), X-ray diffraction analysis (XRD) and transmission electron microscopy (TEM). The crystallite size was found to nearly identical with an increase in the water-to-surfactant (R) molar ratio. A FTIR analysis was carried to monitor the elimination of residual oil and surfactant phases from the microemulsion-derived precursor and the calcined powder. The average particle size and distribution of the synthesized $Y_2O_3$-doped $ZrO_2$ were below 5 nm and narrow, respectively. The TG-DTA analysis showed that the phase of the $Y_2O_3$-doped $ZrO_2$ nanoparticles changes from the monoclinic phase to the tetragonal phase at temperatures close to $530^{\circ}C$. The phase of the synthesized $Y_2O_3$-doped $ZrO_2$ when heated to $600^{\circ}C$ was tetragonal $ZrO_2$.

Photoluminescence properties of oxy-fluoride glass-ceramics of La2O3-CaF2-Al2O3-SiO2 system (La2O3-CaF2-Al2O3-SiO2 계 oxy-fluoride 결정화 유리의 광 발광 특성)

  • Ha, Taewan;Kang, Seunggu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.2
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    • pp.84-88
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    • 2021
  • The change of the photoluminescence properties of La2O3-CaF2-Al2O3-SiO2 glass-ceramics doped with rare earth material, that is used as laser and optical sensors, was analyzed according to heat treatment temperature. The heat treatment conditions for fabricating glass-ceramics were obtained through non-isothermal thermal analysis, and X-ray diffraction analysis was performed to determine the degree of crystal growth and kinds of crystal phases generated according to the heat treatment temperature. Using Scherrer's equation, it was predicted that crystals with a size of 25~40 nm would be generated inside the glass-ceramics. Photoluminescence (PL) analysis showed that the specimens heat-treated at 660℃ to 670℃ for 1 hour had the highest PL intensity. Also, from the CIE color coordinate analysis, all glass-ceramics specimens emitted red-orange light regardless of the heat treatment condition.

Time-Dependent Warpage Analysis for PCB Considering Viscoelastic Properties of Prepreg (Prepreg의 점탄성 특성을 고려한 PCB의 Time-Dependent Warpage 분석)

  • Chanhee Yang;Chang-Yeon Gu;Min Sang Ju;Junmo Kim;Dong Min Jang;Jae Seok Jang;Jin Woo Jang;Jung Kyu Kim;Taek-Soo Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.31 no.2
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    • pp.23-27
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    • 2024
  • In this study, the time-dependent warpage behavior caused by the viscoelastic properties of prepreg in a printed circuit board (PCB) was analyzed by finite element method (FEM). The accurate viscoelastic properties of the prepreg were measured by stress relaxation test, which were then incorporated into constructed warpage analysis model. When the PCB was subjected to repeated thermal cycles, the warpage of the PCB was restored to its initial state when only the elastic properties of the prepreg were considered, but when the viscoelastic properties were also considered, the warpage was not restored and permanent warpage change occurred. The warpage analysis for three different types of prepreg was conducted to compare their mechanical reliability, and the results showed that materials with elastic properties dominating over viscoelastic properties experienced less warpage, resulting in better mechanical reliability.

A Systems Engineering Approach for Uncertainty Analysis of a Station Blackout Scenario

  • de Sousa, J. Ricardo Tavares;Diab, Aya
    • Journal of the Korean Society of Systems Engineering
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    • v.15 no.1
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    • pp.51-59
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    • 2019
  • After Fukushima Dai-ichi NPP accident, the need for implementation of diverse and flexible coping strategies (FLEX) became evident. However, to ensure the effectiveness of the safety strategy, it is essential to quantify the uncertainties associated with the station blackout (SBO) scenario as well as the operator actions. In this paper, a systems engineering approach for uncertainty analysis (UA) of a SBO scenario in advanced pressurized water reactor is performed. MARS-KS is used as a best estimate thermal-hydraulic code and is loosely-coupled with Dakota software which is employed to develop the uncertainty quantification framework. Furthermore, the systems engineering approach is adopted to identify the requirements, functions and physical architecture, and to develop the verification and validation plan. For the preliminary analysis, 13 uncertainty parameters are propagated through the model to evaluate the stability and convergence of the framework. The developed framework will ultimately be used to quantify the aleatory and epistemic uncertainties associated with an extended SBO accident scenario and assess the coping capability of APR1400 and the effectiveness of the implemented FLEX strategies.

Quantum-chemical Investigation of Substituted s-Tetrazine Derivatives as Energetic Materials

  • Ghule, Vikas D.;Sarangapani, Radhakrishnan;Jadhav, Pandurang. M.;Tewari, Surya. P.
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.564-570
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    • 2012
  • s-Tetrazine is the essential candidate of many energetic compounds due to its high nitrogen content, enthalpy of formation and thermal stability. The present study explores the design of s-tetrazine derivatives in which different $-NO_2$, $-NH_2$ and $-N_3$ substituted azoles are attached to the tetrazine ring via C-N linkage. The density functional theory (DFT) is used to predict the geometries, heats of formation (HOFs) and other energetic properties. The predicted results show that azide group plays a very important role in increasing HOF values of the s-tetrazine derivatives. The densities for designed molecules were predicted by using the crystal packing calculations. The introduction of $-NO_2$ group improves the density as compared to $-N_3$, and $-NH_2$ groups and hence the detonation performance. Bond dissociation energy analysis and insensitivity correlations revealed that amino derivatives are better candidates considering insensitivity and stability.

Theoretical Study of Hydration of Zeolite NaA (제올라이트 NaA의 수화에 관한 이론적 연구)

  • Kyoung Tai No;Mu Shik Jhon
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.374-384
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    • 1979
  • Hydration scheme and hydration energy are determined in ${\alpha}$ cage of zeolite NaA. The selectivity between Na(1) and Na(2) is determined from energy calculation. The waters in ${\alpha}$ cage form a distorted dodecahedral cage. The average binding energies of water(1), water(2) and water(3) are -29.847, -25.344 and -15.888 kcal/mole respectively. The positions of oxygens of hydrated waters are in good agreement with the X-ray data. The heat of immersion curve is also obtained. This result is in good agreement with the differential heat of sorption curve obtained from differential thermal analysis. It is concluded that theoretical method provides considerable uses in the determination and understanding of the hydration and interaction energy of zeolites sorbate binding.

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Preliminary Analysis of Several Storm Events by using the ECT data onboard Van Allen Probes

  • Choi, Eunjin;Hwang, Junga;Kim, Hang-Pyo;Kim, Kyoung-Chan;Park, Young-Deuk;Min, Kyoung-Wook
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.95.2-95.2
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    • 2013
  • The Van Allen Probes were designed to study the Earth's radiation belts on various scales of space and time. The identical two spacecrafts going nearly eccentric orbits lap each other several times over the course of the mission and each probe carries five instrument suites to address the science objectives on the radiation belt. Since Van Allen Probes launched on August 30, 2012, the probes detecte several storm events up to now. To understand the particle acceleration and loss mechanism in the radiation belt, we first focus on the energetic electrons' dynamics detected by ECT (Energetic Particle, Composition, and Thermal Plasma Suite). ECT measures near-Earth space's radiation particles covering the full electron and ion spectra from ~ eV to 10's of MeV with sufficient energy resolution. In this paper, we present the preliminary results of the recent several storm events using electron data from ECT(MagEIS and REPT).

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A Review of Measuring Sensors for Reactor Vessel Internals Comprehensive Vibration Assessment Program in Advanced Power Reactor 1400 (APR1400 원자로 내부구조물 종합진동평가프로그램용 측정센서 검토)

  • Ko, Do-Young;Lee, Jae-Gon
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.21 no.1
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    • pp.47-55
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    • 2011
  • Reactor vessel internals comprehensive vibration assessment program(RVI CVAP) is one of the necessary tests to ensure the safety of nuclear power plants. RVI CVAP of U.S. nuclear regulatory commission regulatory guide 1.20(U.S. NRC R.G. 1.20) consists of the analysis, measurement and inspection. One of the core technologies of the measurement program for RVI CVAP is to select suitable sensors because the measurement is conducted during the critical path of the construction period of nuclear power plants. Therefore, we analyzed RVI thermal-hydraulic and structure design data of Palo Verde nuclear power plant(U.S.), Yonggwang nuclear power plant(Korea) and APR1400 and researched measuring sensors used in them; moreover, we investigated sensors used for measurement of RVI CVAP for the last 20 years throughout the world. Based on these results, we selected suitable measuring sensors for RVI CVAP in advanced power reactor 1400(APR1400).