• Title/Summary/Keyword: advanced thermal analysis

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Pyrolysis kinetics and microstructure of thermal conversion products on toluene soluble component from two kinds of modified pitch

  • Zhu, Yaming;Zhao, Xuefei;Gao, Lijuan;Cheng, Junxia
    • Carbon letters
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    • v.28
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    • pp.38-46
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    • 2018
  • Modified pitch A (MPA) and modified pitch B (MPB) were prepared by oxidative polymerization and thermal polycondensation reaction with refined pitch as the raw material, respectively. The toluene soluble components (TS-1 and TS-2) were obtained by solvent extraction from MPA and MPB, separately. The Flynn-Wall-Ozawa method and Kissinger-Akahira-Sunose method were used to calculate the pyrolysis activation energy of TS. The Satava-Sestak method was used to investigate the pyrolysis kinetic parameters of TS. Moreover, the optical microstructure of the thermal conversion products (TS-1-P and TS-2-P) by calcination shows that TS-1-P has more contents of mosaic structure and lower contents of fine fiber structure than TS-2-P. The research result obtained by a combination of X-ray diffraction and the curve-fitting method revealed that the ratios of ordered carbon crystallite (Ig) in TS-1-P and TS-2-P were 0.3793 and 0.4417, respectively. The distributions of carbon crystallite on TS-1-P and TS-2-P were calculated by Raman spectrum and curve-fitting analysis. They show that the thermal conversion product of TS-2 has a better graphite crystallite structure than TS-1.

Evaluation of Quality of Ginger Oleoresin by Thermal Analysis (열분석에 의한 생강엑기스의 품질평가)

  • Shin, Ae-Ja
    • Korean Journal of Food Science and Technology
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    • v.22 no.3
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    • pp.229-233
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    • 1990
  • The thermal analysis method has been proposed for the evaluation of the relative qualities of different ginger oleoresin samples and discussed to demonstrate its simple applicability. TGA measurement to compare characteristics of ginger oleoresins give more sensitive indication on the thermal decomposition than that of DSC. The results show that the quality of oleoresin obtained from sliced sun dried ginger is better than that from hot air dried whole ginger.

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Synthesis and Thermal Analysis of Mullite Whiskers in Al(OH)3-SiO2-AIF3 System (Al(OH)3-SiO2-AIF3계에서 뮬라이트 휘스커 합성과 열분석)

  • Lee Hong-rim;Lee Young-Woo;Lee Jung-Won;Kang Jong-Bong
    • Korean Journal of Materials Research
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    • v.15 no.10
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    • pp.644-651
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    • 2005
  • The thermal analysis of $Al(OH)_3-SiO_2-AIF_3$ system was done. The thermal behaviors of components and the effect of moisture on the formation of mullite were investigated via TG-DTA and XRD analysis. The mixture of $Al(OH)_3,\;SiO_2,\;AIF_3$showed two endothermic peaks with drastic weight loss and one exothermic peak. Fluorotopaz was formed at $800^{\circ}C$ and turned into mullite completely at $1100^{\circ}C$. But the mixture $Al_2O_3$ of or dehydrated $Al(OH)_3$ and $SiO_2$ could not form mullite even at $1200^{\circ}C$ in which the crystalline phases were $\alpha-Al_2O_3$ ana cristobalite. It was found that the synthesized mullite was aciculate shaped single crystalline whisker.

Frequency Tracking Error Analysis of LQG Based Vector Tracking Loop for Robust Signal Tracking

  • Park, Minhuck;Kee, Changdon
    • Journal of Positioning, Navigation, and Timing
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    • v.9 no.3
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    • pp.207-214
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    • 2020
  • In this paper, we implement linear-quadratic-Gaussian based vector tracking loop (LQG-VTL) instead of conventional extended Kalman filter based vector tracking loop (EKF-VTL). The LQG-VTL can improve the performance compared to the EKF-VTL by generating optimal control input at a specific performance index. Performance analysis is conducted through two factors, frequency thermal noise and frequency dynamic stress error, which determine total frequency tracking error. We derive the thermal noise and the dynamic stress error formula in the LQG-VTL. From frequency tracking error analysis, we can determine control gain matrix in the LQG controller and show that the frequency tracking error of the LQG-VTL is lower than that of the EKF-VTL in all C/N0 ranges. The simulation results show that the LQG-VTL improves performance by 30% in Doppler tracking, so the LQG-VTL can extend pre-integration time longer and track weaker signals than the EKF-VTL. Therefore, the LQG-VTL algorithm is more robust than the EKF-VTL in weak signal environments.

Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) - (PET 말단에 대한 인계난연제의 라디칼계 부가반응 (1) - 비스페놀에이비스다이페닐포스페이트의 반응 -)

  • Kim, Min-Kwan;Ghim, Han-Do
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.33-38
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    • 2012
  • In this study, to increase flame retardation of poly(ethylene terephthalate) (PET) in burning, bisphenol A bis(diphenyl phosphate) (BDP), a well known flame retardant containing phosphorous, was reacted on end groups of PET by radical pathway. End-capping mechanism of PET with BDP was suggested and confirmed by spectroscopic and thermal analysis. From 400 MHz $^{31}P$ solid state FT-NMR spectrum of end-capped PET (PET-BDP), phosphorus spectra peak in BDP was found at ca. -20 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. $600cm^{-1}$ in FT-IR spectrums of PET-BDP. These results showed that BDP can be chemically added on end groups of PET by our method. Thermal characteristics of pure PET (pPET) and PET-BDP were measured and evaluated by TGA analysis. There was not significant changes in thermal characteristics of PET-BDP compared to that of pPET.

Development and validation of multiphysics PWR core simulator KANT

  • Taesuk Oh;Yunseok Jeong;Husam Khalefih;Yonghee Kim
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2230-2245
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    • 2023
  • KANT (KAIST Advanced Nuclear Tachygraphy) is a PWR core simulator recently developed at Korea Advance Institute of Science and Technology, which solves three-dimensional steady-state and transient multigroup neutron diffusion equations under Cartesian geometries alongside the incorporation of thermal-hydraulics feedback effect for multi-physics calculation. It utilizes the standard Nodal Expansion Method (NEM) accelerated with various Coarse Mesh Finite Difference (CMFD) methods for neutronics calculation. For thermal-hydraulics (TH) calculation, a single-phase flow model and a one-dimensional cylindrical fuel rod heat conduction model are employed. The time-dependent neutronics and TH calculations are numerically solved through an implicit Euler scheme, where a detailed coupling strategy is presented in this paper alongside a description of nodal equivalence, macroscopic depletion, and pin power reconstruction. For validation of the steady, transient, and depletion calculation with pin power reconstruction capacity of KANT, solutions for various benchmark problems are presented. The IAEA 3-D PWR and 4-group KOEBERG problems were considered for the steady-state reactor benchmark problem. For transient calculations, LMW (Lagenbuch, Maurer and Werner) LWR and NEACRP 3-D PWR benchmarks were solved, where the latter problem includes thermal-hydraulics feedback. For macroscopic depletion with pin power reconstruction, a small PWR problem modified with KAIST benchmark model was solved. For validation of the multi-physics analysis capability of KANT concerning large-sized PWRs, the BEAVRS Cycle1 benchmark has been considered. It was found that KANT solutions are accurate and consistent compared to other published works.

Development and Performance Validation of Thermal Control Subsystem for Earth Observation Small Satellite Flight Model (지구관측 소형위성 비행모델의 열제어계 개발 및 성능 검증)

  • Chang, Jin-Soo;Jeong, Yun-Hwang;Kim, Byung-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.36 no.12
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    • pp.1222-1228
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    • 2008
  • A small satellite, DubaiSat-1 FM(Flight Model), which is based on SI-200 standard bus platform and scheduled to be launched in 2008, is being developed by Satrec Initiative and EIAST(Emirates Institution for Advanced Science and Technology). The TCS(Thermal Control Subsystem) of DubaiSat-1 FM has been designed to mainly utilize passive thermal control in order to minimize power consumption, but the active control method using heaters has been applied to some critical parts. Also, thermal analysis has been performed for DubaiSat-1's mission orbit using a thermal analysis model. The thermal design is modified and optimized to satisfy the design temperature requirements for all parts according to the analysis result. The thermal control performance of DubaiSat-1 FM is verified by thermal vacuum space simulation, consisting of thermal cycling and thermal balance test. Also, to validate the thermal modeling of DubaiSat-1 FM, comparison of test results with analysis has been performed and model calibration has been completed.

Modelling of bonded and unbonded post-tensioned concrete flat slabs under flexural and thermal loading

  • Mohammed, Abbas H.;Taysi, Nildem
    • Structural Engineering and Mechanics
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    • v.62 no.5
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    • pp.595-606
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    • 2017
  • During their life span, post-tensioned concrete structures may be exposed to thermal loads. Therefore, there has been a growing interest in research on the advanced analysis and design of post-tensioned concrete slabs subjected to thermal loads. This paper investigates the structural behaviour of post-tensioned one-way spanning concrete slabs. A nonlinear finite element model for the analysis of post- tensioned unbonded and bonded concrete slabs at elevated temperatures was developed. The interface between the tendon and surrounding concrete was also modelled, allowing the tendon to retain its profile shape during the deformation of the slab. The load-deflection behaviour, load-force behaviour in the tendon, and the failure modes are presented. The numerical analysis was conducted by the finite element ANSYS software and was carried out on two different one-way concrete slabs chosen from literature. A parametric study was conducted to investigate the effect of several selected parameters on the overall behavior of post-tensioned one-way concrete slab. These parameters include the effect of tendon bonding, the effect of thermal loading and the effect of tendon profile. Comparison between uniform thermal loading and nonuniform thermal loading showed that restrained post tensioned slab with bottom surface hotter has smaller failure load capacity.

Use of Modern Non­destructive Techniques in High Temperature Degradation of Material and Coatings

  • Lee, C.K.;Sohn, Y.H.
    • International Journal of Korean Welding Society
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    • v.3 no.2
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    • pp.29-39
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    • 2003
  • The durability and reliability of thermal barrier coatings (TBCs) play an important role in the service reliability, availability and maintainability (RAM) of hot­section components in advanced turbine engines for aero and utility applications. Photostimulated luminescence spectroscopy (PSLS) and electrochemical impedance spectroscopy (EIS) are being concurrently developed as complimentary non­destructive evaluation (NDE) techniques for quality control and life­remain assessment of TBCs. This paper overviews the governing principles and applications of the luminescence and the impedance examined in the light of residual stress, phase constituents and resistance (or capacitance) in TBC constituents including the thermally grown oxide (TGO) scale. Results from NDE by PSLS and EIS are discussed and related to the microstructural development during high temperature thermal cycling, examined by using a variety of microscopic techniques including focused ion beam (FIB) in­situ lift­out (INLO), transmission and scanning transmission electron microscopy (TEM and STEM).

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Simplified welding distortion analysis for fillet welding using composite shell elements

  • Kim, Mingyu;Kang, Minseok;Chung, Hyun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.7 no.3
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    • pp.452-465
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    • 2015
  • This paper presents the simplified welding distortion analysis method to predict the welding deformation of both plate and stiffener in fillet welds. Currently, the methods based on equivalent thermal strain like Strain as Direct Boundary (SDB) has been widely used due to effective prediction of welding deformation. Regarding the fillet welding, however, those methods cannot represent deformation of both members at once since the temperature degree of freedom is shared at the intersection nodes in both members. In this paper, we propose new approach to simulate deformation of both members. The method can simulate fillet weld deformations by employing composite shell element and using different thermal expansion coefficients according to thickness direction with fixed temperature at intersection nodes. For verification purpose, we compare of result from experiments, 3D thermo elastic plastic analysis, SDB method and proposed method. Compared of experiments results, the proposed method can effectively predict welding deformation for fillet welds.