• Journal of Environmental Science International
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• 제23권11호
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• pp.1821-1826
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• 2014

The adsorption characteristics of the methylene blue (MB) were studied using three activated carbons such as ACA and ACB with similar specific surface area (1,185 and $1,105m^2/g$), and ACC with relatively high specific surface area ($1,760m^2/g$). The surface chemical properties of these activated carbons were investigated by X-ray photoelectron spectroscopy (XPS). The results indicated that ACA had more functional groups (with phenol, carbonyl, and carboxyl etc.) than ACB (with carbonyl and carboxyl) and ACC (with carboxyl). The isotherm data were fitted well by Langmuir isotherm model. The adsorption capacities of ACA, ACB, and ACC for MB were 454.7 mg/g, 337.7 mg/g, and 414.0 mg/g, respectively. As phenol and carboxyl content of the surface on activated carbon increased, MB adsorption capacity was increased. Although ACA had a smaller specific surface area than ACC, the content of phenol and carboxyl group was abundant, so MB adsorption capacity was found to be higher than ACC.

• The Transactions of The Korean Institute of Electrical Engineers
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• 제59권1호
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• pp.102-107
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• 2010

Dye-sensitized solar cell (DSC) has been expected to be an alternative to the conventional silicon solar cell due to simple manufacturing process and low fabrication casts. In order to improve productivity of DSC, we attempted to optimize the required time of the adsorption process. According to the change in the adsorption time from 1 to 24h, We analyzed the output characteristics and the change of internal impedance. As a result, The outputs of DSC were continuously increased until 12h of the adsorption time and remained the same after that. Also, We reconfirmed this result that 12h was optimum adsorption by the analysis of the electrochemical impedance spectroscope because the internal impedance was similar to the output.

• Journal of Environmental Science International
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• 제15권4호
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• pp.341-347
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• 2006

Adsorption characteristics of benzene by zeolite were investigated using irradiating microwave. Experimental apparatus was applied to a U-type fix-bed column equipped with microwave system. Zeolite, itself, seems to be inappropriated to remove benzene because of a hygroscopic property, Microwave irradiation to zeolite, however, brings about decreasing $H_{2}O$ adsorption and increasing benzene adsorption. This causes that the dipole material such as $H_{2}O$ was vibrated and heated by irradiation of microwave and desorbed from zeolite. And then, benzene starts to be absorbed by zeolite. In this study, the results showed that the selective adsorption of benzene was occurred by the microwave irradiation and the adsorption capacity of benzene was increased by increasing microwave energy. As a results, it was found that the zeolite could be used to adsorb benzene with microwave and this method make it feasible simultaneously to adsorb and desorb benzene.

• Journal of Environmental Science International
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• 제21권6호
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• pp.705-711
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• 2012

Adsorption experiment of carbon dioxide was performed on MCM41 silica with a 30 wt.% EDA(ethylenediamine) loading at different $CO_2$ inlet concentration and various adsorption temperature. The surface characteristics of $CO_2$ capturing agent were carried out using BET analysis, X-ray diffraction and FT-IR. The results of BET showed 781 $m^2/g$ for MCM41 and 464 $m^2/g$ for EDA/MCM41. X-ray diffraction results reveled typical hexagonal pore system. The higher sorption capacity of EDA/MCM41 was about 80 $mg_{CO2}/g_{sorbent}$ with 50% $CO_2$ inlet concentration and 303 K adsorption temperature. The isosteric heat of adsorption in 303-353 K ranged from -25.47 to -28.24 KJ/mole for EDA/MCM41, which indicates $CO_2$-EDA/MCM41 interaction with exothermic adsorption process. Finally, the performance of EDA/MCM41 in 10 consecutive sorption-desorption runs was a stable with only a minor drop in its sorption capacity.

• Carbon letters
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• 제6권2호
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• pp.89-95
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• 2005

Crushed peach stone shells were impregnated with $H_3PO_4$ of increasing concentrations (30-70%) followed by heat treatment at 773 K for 3 h. Produced carbons (ACs) were characterized by $N_2$ adsorption at 77 K using the BET-equation and the ${\alpha}$-method. High surface area microporous ACs were obtained, with enhanced internal pore volume, as function of % $H_3PO_4$. Adsorption isotherms from aqueous solution were determined for methylene blue (MB) and p-nitrophenol (PNP), as representatives for dye and phenolics pollutant molecules. Application of the Langmuir model proved the high limiting capacity towards both solute molecules, MB was uptaken in increasing amounts as function of $H_3PO_4$ concentration and generated porosity. High removal of PNP was almost the same irrespective of porosity characteristics. Competitive adsorption of $H_2O$ molecules on the hydrophilic carbon surface seems to partially reduce the available area to the PNP molecules. Application of the pseudo-second order law described well the fast adsorption (${\leq}$ 120 min) at two initial dye concentrations.

• Carbon letters
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• 제16권1호
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• pp.45-50
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• 2015

High crystallinity coke-based activated carbon (hc-AC) is prepared using a potassium hydroxide solution to adsorb carbon dioxide ($CO_2$). The $CO_2$ adsorption characteristics of the prepared hc-AC are investigated at different temperatures. The X-ray diffraction patterns indicate that pitch-based cokes prepared under high temperature and pressure have a high crystal structure. The textural properties of hc-AC indicate that it consists mainly of slit-like pores. Compared to other textural forms of AC that have higher pore volumes, this slit-pore-shaped hc-AC exhibits higher $CO_2$ adsorption due to the similar shape between its pores and $CO_2$ molecules. Additionally, in these high-crystallinity cokes, the main factor affecting $CO_2$ adsorption at lower temperature is the pore structure, whereas the presence of oxygen functional groups on the surface has a greater impact on $CO_2$ adsorption at higher temperature.

• Carbon letters
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• 제4권1호
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• pp.31-35
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• 2003

The specific adsorption behaviors of activated carbons (ACs) treated with 30 wt% $H_3PO_4$ or NaOH were investigated in the removals of NO or $NH_3$. The acid and base values were determined by Boehm's titration method. And, the surface properties of ACs were studied by FT-IR and XPS analyses. Also, $N_2/77K$ adsorption isotherm characteristics, including the specific surface area and micropore volume were studied by BET and t-plot methods, respectively. From the adsorption tests of NO and $NH_3$, it was revealed in the case of acidic treatment on ACs that the $NH_3$ removal was more effective due to the increase of acidic functional groups in carbon surfaces. Also, the NO removal was increased, in the case of basic treatment, due to the improvement of basic functional groups, in spite of significant decreases of BET's specific surface area and total pore volume. It was found that the adsorption capacity of ACs was not only determined by the textural characteristics but also correlated with the surface functional groups in the acid-base intermolecular interactions.

• Journal of Korean Society on Water Environment
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• 제27권4호
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• pp.486-490
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• 2011

As(V) adsorption on aluminum oxide powder which was recycled from industrial wastes containing aluminum hydroxide was evaluated. Aluminum oxide powder in this study was prepared by calcinating aluminum hydroxide wastes at$550^{\circ}C$. Spectroscopic analysis indicated that the aluminum hydroxide wastes were changed to aluminum oxide by calcination. Arsenic adsorption isotherm was conducted with variation of ionic strength and multiple-ion systems using Ca(II) and Cu(II). As(V) removal showed typical anionic adsorption characteristics that the removal efficiency decreased with increasing pH in single As(V) system as well as in binary and ternary system. More than 80% of As(V) at an initial concentration of $5{\times}10^{-5}$ M was removed from aluminum oxide powder in As(V) single system. The effect of ionic strength on As(V) adsorption was negligible, which indicated the strong bonding between aluminum oxide powder and As(V). The removal efficiency of As(V) was higher in a binary system with Cu(II) than in a binary system with Ca(II).

• Journal of Korean Society of Environmental Engineers
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• 제33권9호
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• pp.686-691
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• 2011

The $CO_2$ adsorption and characteristics of mesoporous silica MCM-41 impregnated by MEA (Monoethanolamine) were examined in this study. The adsorbents were characterized by XRD (X-ray powder diffraction), FT-IR (Fourier transform infrared spectroscopy), $N_2$ adsorption-desorption isotherms. $CO_2$ adsorption measurements were carried out using a GC-TCD unit using 15% $CO_2$ gas. The $CO_2$ adsorption capacity of MCM-41 increased by MEA contents to 10~40 wt%, otherwise MEA content of 50 wt% was decreased $CO_2$ adsorption capacity. The amines tended to deform at MCM-41 surface if too many amines were provided. Therefore $CO_2$ adsorption capacity can be decreased. The results of this study suggest it is important to control content of MEA in MCM-41 for adsorption of $CO_2$.

• Applied Chemistry for Engineering
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• 제29권4호
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• pp.388-394
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• 2018

The removal of 2,4-dichlorophenol (2,4-dichlorophenol, 2,4-DCP) in aqueous solution was studied using the magnetic activated carbon (MAC) prepared from waste citrus peel. The adsorption characteristics of 2,4-DCP by MAC were investigated by varying the contact time, MAC dose, solution temperature, pH and 2,4-DCP concentration. The isothermal adsorption data were well explained by the Langmuir isotherm model equation and the maximum adsorption capacity calculated from the Langmuir isotherm equation was 312.5 mg/g. The adsorption kinetic data were well described by the pseudo-second-order reaction equation. The intraparticle diffusion model data indicated that both the film and intraparticle diffusion occur simultaneously during the adsorption process. The thermodynamic parameters of ${\Delta}H^o$ and ${\Delta}G^o$ have positive and negative values, respectively, indicating that the adsorption of 2,4-DCP by MAC is a spontaneous endothermic reaction. After the adsorption experiment was completed, the used MAC could be easily separated by an external magnet.