• 대한기계학회논문집A
• /
• 제33권4호
• /
• pp.425-429
• /
• 2009

The protection for copper tarnish was developed by surface treatment method and volatile corrosion inhibiting (VCI) technology. The performance of surface treatment and VCI material is also examined in simulated test environment. Benzotriazole (BTAH) solution that contained molybdate showed best performance than others. Usage of VCI materials with surface treatment was more effective. The protection film foamed on the surface of copper was investigated by auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). Molybdate does not participate in the formation of the protective film but promotes the passivation effect. This facilitates the stabilization of the cuprous oxide film, and strengthens the adsorption of BTAH.

• Bulletin of the Korean Chemical Society
• /
• 제32권12호
• /
• pp.4239-4243
• /
• 2011

Biocompatible hydrogels from 2-hydroxyethyl methacrylate (HEMA) monomer containing various amount of alginate in the presence and absence of hydrophilic methacrylic acid (MAA) were synthesized in order for biomedical application. The antimicrobial effect and interaction with proteins for hydrogels were investigated in this study. MAA was introduced because it was expected to increase the amount of water content in the polymer which is an important factor for biocompatibility, and alginate was expected to enhance the antimicrobial activity. The antimicrobial effect against S. aureus and E. coli increased for all hydrogels as the amount of alginate and MAA contained. Presence of MAA further enhances the antimicrobial effect. Amount of adsorption of bovine serum albumin (BSA) increased with increasing concentration of alginate whether MAA was present or not. Contrarily, the amount of lysozyme was not affected with increasing alginate concentration in the absence of MAA, while it decreased in the presence of MAA.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
• /
• pp.195-198
• /
• 2004

This study applied EK method to remediate contaminated soil by heavy metal(Pb), tried to increase the efficiency of remediation using zeolite as enhanced EK remediation method to overcome the limit of traditional EK remediation method. Adsorption tests on Pb were conducted to apply the EK extraction and test conditions which contained the electrode reversal, operating time were established. After tests, lead-ions were transported into the specific position of zeolite by EK phenomena, then the immobilization of lead-ions at zeolite was developed. Based on these tests, the efficiency of remediation is different with its test conditions. In addition, the efficiency of remediation was improved dramatically by adding zeolite without electrode reversal and satisfied TCLP regulation of EPA in USA through the whole sample range. Finally, absorption and immobilization capacity of zeolite were proved its excellence and confirmed the possibility of application as enhanced EK remediation method.

• 한국생물공학회:학술대회논문집
• /
• 한국생물공학회 2002년도 생물공학의 동향 (X)
• /
• pp.423-426
• /
• 2002

A novel process for $H_2S$ gas treatment has been introduced, based on the combined action of a chemical absorption step and a biological step involving the biocatalytic activity of the bacterium Thiobacillus ferrooxidans. The aim of this study is the development of a process for $H_2S$ elimination from gas streams based on that chemical/biological method. The immobilized biomass reactor/chemical adsorption system is suitable for application of the removal of $H_2S$. A double stage reactor was used for the experimental work. The removal efficiencies of over 99% were observed in the range of inlet $H_2S$ concentration from 200 to 1,000ppm. The novel process showed the stable elimination efficiencies of over 95% under the retention time range from 20 to 40sec at the 1,000ppm of $H_2S$ inlet concentration.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1999년도 추계학술대회 논문집 학회본부 A
• /
• pp.442-445
• /
• 1999

In this work, to detect of hydrogen in DI water in the generator area of nuclear power plants was fabricated Pd/Pt gate MISFET sensor using Pd membrane. $H_2$ permeation through Pd accounts for external mass transfer, surface adsorption and desorption, transitions to and from the bulk metal, and diffusion within the metal. The identification of pinholes in the generator area of plant is an important safety consideration, as hydrogen build-up gives rise to explosion. For this type of application the sensor needs to be isolated in DI water, accordingly, a Pd membrane was used to separate the DI water. The hydrogen in the DI water was then absorbed on the Pd thin film and diffused into the oil through the thin film. The Pd/Pt gate MISFET sensor, encapsulated by oil, will thereby detect permeated hydrogen.

• 한국염색가공학회지
• /
• 제7권2호
• /
• pp.63-69
• /
• 1995

To improve the blood compatibility of chitosan membranes, 2-(methacryloyloxy)-ethyl-2-(trimethylammonium)ethyl phosphate(MTP), which is a methacrylate with phospholipid polar groups, was grafted on the surface of chitosan membranes and the biocompatibility of MTP-grafted chitosan membranes was investigated. The permeation coefficient gradually decreased with increasing in molecular weights of biocomponents below 10$^{4}$, and drastically decreased above 10$^{4}$. This result corresponds with the permeability of solutes in case of hemodialysis membranes. The MTP-grafted chitosan membranes displayed less blood cell adhesion than the chitosan membranes. This may due to the formation of biomembrane4ike surface by adsorption and arrangement of phospholipid molecules from serum onto the MTP copolymer surface.

• 대한핵의학회지
• /
• 제7권1호
• /
• pp.51-54
• /
• 1973

The use of ion-exchange resins for the treatment of radioactive wastes has many advantages, but thes eare rather expensive as compared with the Korean vermiculite. The Korean vermiculite has slightly different chemical constituents from the ones produced in other countries, and its physical properties might be applicable to the management of radioactive waste, in a small nuclear installation. The decontaminating effect of Korean vermiculite for the low-level radioactive liquid was investigated. $^{106}Ru,\;^{90}Sr,\;and\;^{137}Cs$ were utilized for the experiments. The removal rates by Korean vermiculite were calculated for $^{106}Ru,\;^{90}Sr\;and\;^{137}Cs$ and the removal rates increased as the weight of vermiculite in the exchange column increased. The decontaminating constants, $K_d$ of the Korean vermiculite for $^{106}Ru,\;^{90}Sr\;and\;^{137}Cs$ were 2.7, 69.3 and 263ml/g respectively. Through the results of experiments, the application of Korean vermiculite column to the treatment of low-level radioactive waste is quite feasible.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 추계학술대회 논문집
• /
• pp.627-627
• /
• 2009

In this work, the activated carbons (ACs) with high porosity were synthesized from pitch by KOH chemical activation. The structure and surface properties of ACs were characterized by means of elemental analysis, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy(XPS). And, the influence of the KOH-to-pitch ratio on the porosity of the ACs was investigated using the nitrogen adsorption isotherms at 77 K and a scanning electron microscopy (SEM). As a result, pitch could be successfully converted into ACs with well-developed micro and mesopores. The specific surface areas and pore volumes were increased with an increase of the KOH-to-pitch ratio. Furthermore, it was found that the addition of KOH led to the transformation of the micropores to the meso- and macropores. In the application to electric double layer capacitors (EDLC), the pitch-based ACs showed a higher capacitance per weight and per volume, and an excellent electrochemical stability in the high voltage region.

• KSBB Journal
• /
• 제29권1호
• /
• pp.9-21
• /
• 2014

One of the most abundant microalgaes, diatom is characterized by its unique cell wall structures composed of nano-patterned silica. Due to its highly ordered porosity, these silica frustules, which are found as sediments called diatomite, were used as a cheap adsorption material for water purification. Recently, new emerging nanotechnology compels many researchers to have interest in such diatom's unique properties (eg, nano-scale mesoporosity, photo luminescence, light transparency, etc.) as biogenic inorganic materials as well as the biomass resource (conventional usage of microalgae). In this review, we will focus on the current knowledge about the diatoms research and the possibility of its applications.

• 한국결정학회:학술대회논문집
• /
• 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
• /
• pp.50-50
• /
• 2002

물리흡착은 기체와 표면간의 상호작용이 반데르발스 힘에 의한 흡착현상으로 평형상태에서 물리적인 조건 변화만으로 흡착과 탈착이 가능하다. 이러한 흡착측정 데이터는 흡착 시스템에 대한 다양한 정보를 제공해주게 된다. 기체와 표면간의 상호작용 포텐셜, 흡착된 물질의 물리적 상태, 흡착막의 두께, 흡착구조, 흡착량 등이 결정될 수 있다. 이러한 정보는 흡착 및 탈착 등온곡선의 분석을 통하여 사용된 흡착제의 비표면적 및 기공의 기하학적 구조에 대한 것도 유추할 수 있게 한다. 본 실험실에서는 흡착량을 직접 측정하는 체적식 흡착측정 방법, 흡착량을 간접적으로 측정하는 광 및 관련 흡착시스템 및 수정진동자를 이용한 박막에서의 흡착측정 방법들을 소개하며 기공표준화에 적용하고자 한다.