• Title/Summary/Keyword: adsorption application

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APPLICATION OF RERFLUOROPOLYMETHYLISOPROPYLETHER TO HAND CARE CREAM USING ABSORPTION AND DISPERSION

  • Ahn, Baek-Sun;Sliin, Dong-Ug;Jo, Pan-Gu;Kim, Sang-Je;Lim, Ho-Soon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.75-81
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    • 1997
  • It has been used that fluorinated compounds could be applied to cosmetic products. It is that fluorinated conpounds are hydrophobicity and lipophobicity. These fluorinated compounds are reported to form a highly protective and effective film against most aggressive chemical and physical agents. PerfluropolymethyoisopropylEther has homophobicity and are colorless, odorless, tasteless and non-greasy. In this we made a success to formulate the new type of hand care cream using PFPE. PFPE are suitable thickness and chemical inertness to skin. The reason that we select PFPE for this investigation. We developed the new type hand care cream by adsorption and dispersion of PFPE. There are very stable dispersion and highly moisture diffusion control. And these characteristics were verified by actual consumer test.

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Application of Perfluoropolymethlisopropyl Ether to Long Wearing Lipstick

  • Sang-Je Kim;Don
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.152-160
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    • 1997
  • It has been used that fluorinated compounds could be applied to Make-up products. It is that fluorinated compounds are hydrophobicity, lipophobicity and homophobicity. These fluorinated compounds are reported to form a highly protective and effective film against most aggressive chemical and physical agents. In this study we maed a success to formulate the new type of lipstic using perfluoropolymethylisopropylether with low molecular weight which is long wearing and comfortable to use. This PPIE was adsorbed more than 90% in this experiment and formed the well-balanced gel networks even if the selected PPIE is 100% volatile at room temperature. On the basis of the adsorption of PPIE, we developed the new type lipstick, which was highly-lip feeling and had long wearing and non coloration. And these characteristics were verified by actual consumer test.

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Reuse of Spent FCC Catalyst for Removing Trace Olefins from Aromatics

  • Pu, Xin;Luan, Jin-Ning;Shi, Li
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2642-2646
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    • 2012
  • Pretreatment of spent FCC catalyst and its application in remove trace olefins in aromatics were investigated in this research. The most effective pretreatment route of spent FCC catalyst was calcining at $700^{\circ}C$ for 1 h, washing with 5% oxalic acid solution in ultrasonic reactor and dried. Treated spent FCC catalyst was modified with metal halides, then to prepare catalyst to remove trace olefins in aromatics. X-ray diffraction, Pyridine-FTIR, $N_2$ adsorption-desorption and inductively coupled plasma optical emission spectrometer (ICP-OES) were used to investigate the pretreatment process. The result showed that the performance of the treated spent FCC catalyst was much greater than that of the spent FCC catalyst, which indicted the possibility and improvement of this research.

Application of Modified Stokes Expression to Model the Behavior of Expanded Beds with Feed Streams Containing E. coli Homogenates

  • Chae, Young-Rea;Yoon, Yeo-Joon;Ryu, Keun-Garp
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.9 no.4
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    • pp.323-325
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    • 2004
  • To model the behavior of expanded beds with aqueous feed streams containing different amounts of glycerol, we previously developed a modified Stokes expression that correlates the terminal settling velocity of a particle of a solution with the properties of the particle (particle diameter and density) and the solution (density and viscosity). Two empirical parameters, the effective diameter of the poly-disperse resins for protein adsorption and an exponent of non-unity for $(\rho_{P}-\rho)/\mu$ term, are introduced in the modified Stokes expression. We applied the same type of the modified Stokes expression in combination with the Richardson-Zaki correlation to the published results [1], and found that the expansions of the beds with feed streams containing different amounts of E. coli homogenates can also be successfully described.

Nano-scale Au nanopaticles Pattern and Application by Using NSOM Lithography (근접상 주사 현미경(NSOM)을 이용한 금(Au)나노입자의 패터닝과 기술응용)

  • Huh K.S.;Chang W.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1539-1542
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    • 2005
  • Self-assembled monolayers (SAMs) formed by the adsorption of alkanethiols, $HS(CH_2)_nX$, where X is an organic functional group, onto gold surfaces have attracted widespread interest as templates for the fabrication of molecular and biomolecular microstructures. Previously photopatterning has been thought of as being restricted to the micron scale, because of the wellknown diffraction limit. So, we have explored a novel approach to nanofabrication by utilizing a femtosecond laser coupled to a near-field scanning optical microscope (NSOM).

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Synthesis of Al-SBA-1 molecular sieve and its application in synthesis reaction of Coumarins (Al-SBA-1 분자체의 합성과 Coumarins합성반응에 축매특성 연구)

  • Peng, Mei Mei;Hemalatha, Pushparaj;Ganesh, Mani;Jang, Hyun-Tae;Cha, Wang-Seog
    • Proceedings of the KAIS Fall Conference
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    • 2012.05a
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    • pp.431-435
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    • 2012
  • Aluminum containing mesoporous molecular sieves Al-SBA-1 ($n_{Si}/n_{Al}$= 2, 5, 10, 15) was synthesized with a one-step method, and the catalyst was characterized with powder X-ray diffraction (XRD), nitrogen adsorption-desorption, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). Finally, we studied the catalytic activities of Al-SBA-1 molecular sieves in Pechmann reaction of 3-methoxyphenol and Ethyl acetoacetate to get 7-methoxy-4-methyl coumarin. Four parameters reaction temperature, time, catalyst weight and reactants ratio were optimized.

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A Study on Toluene Removal of VOC and Characteristics of Material Using Biofilter (Bio필터를 이용한 VOC 가스 중 Toluene 제거율과 필터특성 연구)

  • 강신묵;하상안
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.88-94
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    • 1998
  • This study was investigated the application of biofiltration using cometabolic process to remediate gaseous toluene that are highly recalcitrant to adsorption, absorption and biodegradation. The investigation was conducted using specially built steel columns packed with granular activated carbon for removal of toluene and G.A.C was also coated with Pseudomonas putida microorganisms by addition of KH$_{2}$PO$_{4}$. The biofilter unit was operated in the condition of dry and 27.5% moisture content at gas loading rate of 12.5 l/min. Gaseous toluene taken from tedlar bag was analyzed by the use of G.C. equipped with F.I.D. detector. The removal efficiency of gaseous toluene was 85% at average inlet concentration of 970 ppm during dry operating condition. For gaseous toluene, 91% removal efficient was obtained at the filter material with moisture content and 97% removal efficiency was obtained with Pseudomonas putida microorganisms at gas loading rate of 12.5 l/min.

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Application of Polymer Brush to Enzyme-Multilayered Porous Hollow-Fiber Membrane

  • Kawakita Hidetaka;Uezu Kazuya;Tsuneda Satoshi;Saito Kyoichi;Tamada Masao;Sugo Takanobu
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.11a
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    • pp.142-145
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    • 2004
  • Anion-exchange porous hollow-fiber membranes with a thickness of about 1.2 mm and a pore size of about $0.30{\mu}m$ were used as a supporting matrix to immobilize cycloisomaltooligosaccharide glucanotransferase (CITase). CITase was immobilized to the membrane via anion-exchange adsorption and by subsequent enzymatic cross-linking with transglutaminase, the amount of which ranged from 3 to 110 mg per g of the membrane. The degree of enzyme multilayer binding was equivalent to 0.3 to 9.8. Dextran, as the substrate, was converted into seven- to nine-glucose-membered cycloisomaltooligosaccharides (CI-7, -8, and -9) at a maxi mum yield of $28\%$ in weight at a space velocity of 10 per hour during the permeation of $2.0(w/w)\%$ dextran solution across the CITase-immobilized porous hollow-fiber membrane.

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Fabrication of Hollow Metal Microcapsules with Mesoporous Shell Structure: Application as Efficient Catalysts Recyclable by Simple Magnetic Separation

  • Jang, Da-Young;Jang, Hyung-Gyu;Kim, Gye-Ryung;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3274-3280
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    • 2011
  • Monodispersed porous NiO and $Co_3O_4$ microcapsules with a hollow core were synthesized using SBA-16 silica sol and PS as a hard template. The porous hollow microcapsules were characterized by XRD, TEM and $N_2$ adsorption/desorption analysis. After $H_2$ reduction of metal oxide microspheres, they were conducted as an active catalyst in the reduction of chiral butylronitrile and cyanobenzene. The mesoporous metals having a hollow structure showed a higher activity than a nonporous metal powder and an impregnated metal on the carbon support.

A Formation of Hole Pattern on Ti Electrode by Lift-off and Its Application to TCO-less Dye-sensitized Solar Cells (Ti 전극의 Lift-off 공정을 이용한 홀 패턴 형성과 TCO-less 염료감응형 태양전지의 응용)

  • Jung, Haeng-Yun;Ki, Hyun-Chul;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.3
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    • pp.175-179
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    • 2015
  • In this study, we propose Ti hole pattern structure on the transparent conductive oxide (TCO) less dye-sensitized solar cells (DSSCs) using the lift-off process to improve the low light transmittance and low efficiency caused by opaque Ti electrode. The formation of Ti hole patterns make it possible to move the dye adsorption and electrolyte. The DSSCs with Ti hole patterns showed a higher photoelectric conversion efficiency (PCE) than those with general structure by 11.1%. As a result, The Ti hole pattern structure can be improved to increase the light absorption of the dyes and PCE of the TCO-less DSSCs is also increased.