• Title/Summary/Keyword: adsorption application

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Modified Graphene Oxide-Based Adsorbents Toward Hybrid Membranes for Organic Dye Removal Application

  • Thi Sinh, Vo;Khin Moe, Lwin;Sun, Choi;Kyunghoon, Kim
    • Composites Research
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    • v.35 no.6
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    • pp.402-411
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    • 2022
  • In this study, the channels-contained hybrid membranes have been fabricated through the incorporation of glass fibers and GO sheets (GO/glass fibers, GG), or a mixture of chitosan/GO (CS/GO/glass fibers, CGG), as hybrid membranes using in organic dye removal. The material properties are well investigated the terms in the morphological, chemical, crystal, and thermal characterizations for verifying interactions in their formed structure. These hybrid membranes have been fitted well in pseudo-second order and Langmuir models that are associated with chemical adsorption and a monolayer approach, respectively. The highest adsorption ability of methylene blue and methyl orange reached 59.40 mg/g and 229.07 mg/g (GG); and 287.47 mg/g and 252.91 mg/g (CGG), which is more enhanced than that of previous GO-based other adsorbents. Moreover, the dye separation on these membranes could be favorable to superb sealing and trapping dye molecules from water instead of only the dye connection occurring on their surface, regarding the physically sieving effect. The membranes can also be reused within two and three adsorbing-desorbing cycles on the GG and CGG ones, respectively. These membranes can become future adsorbents to be applied for wastewater treatment due to their structural features.

Response of the Application of Slow-release Potassium Fertilizer Using Natural Zeolite to Flue-cured Tobacco (Nicotiana tabacum L.) (천연(天然) Zeolite를 이용한 완효성(緩效性) K 비료(肥料)의 황색종(黃色種) 연초(煙草)에 대(對)한 시용효과(施用效果))

  • Lee, Dong-Hoon;Park, Soo-June;Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.3
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    • pp.215-220
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    • 1989
  • For development of slow releaseing K-fertilizer using natural zeolite, two kinds of K adsorbed zeolite were made by ion exchange reaction in $K^+$ saturated aqueous solution. K-Zeolite was prepared by removing the excess salt after K adsorption on zeolite, however, NW. K-Zeolite was prepared only by K adsorption reaction without removing the excess salt. The adsorbed K on zeolite was not easily released, but continuously and slowly released from the surface of zeolite. By the results of application for tobacco cultivation, the K contents in soil treated with K-Zeolite and NW. K-Zeolite were lower than that of control (20kg/10a) at the early growth stage, but were higher at the late growth stage. Therefore, the results suggest that K adsorbed zeolite could be applied as a slow-releasing K fertilizer.

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Selectivity and behaviour of EK-5439 in the soil as a candidate for rice herbicide (신규 제초제 후보 화합물 EK-5439의 선택성 및 토양 중 행동특성)

  • Hwang, I.T.;Hong, K.S.;Lee, B.H.;Kim, H.R.;Jeon, D.J.;Cho, K.Y.
    • The Korean Journal of Pesticide Science
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    • v.8 no.3
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    • pp.175-183
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    • 2004
  • The characteristics of the experimental compound EK-5439 [3-Chloro-2-[4-chloro-2-fluoro-5-(5-methyl-3-phenyl-4,5-dihydroisoxazol-5-yl-methoxy)-phenyl]-4,5,6,7-tetrahydro-2H-indazole] was investigated to characterize as a new herbicide to use in rice field. The selectivity between rice and barnyardgrass was very good when treated from 0 to 4 days after seeding under soil application. In the overflowing experiment, herbicidal efficacy of EK-5439 was stabilized 12 hrs after application. Vertical migrations in submerged paddy soil of EK-5439 and oxadiazon were equally observed below a soil depth of 1 cm under 5 cm/day leaching condition. Half-lives for herbicidal efficacy of EK-5439 and oxadiazon were 6.1, and 9.6 days, respectively, under submerged paddy condition. EK-5439 showed rapid adsorption to the soil clay, such as bentonite.

Effect of Compost and Gypsum Application on the Chemical Properties and Fertility Status of Saline-Sodic Soil

  • Sarwar, Ghulam;Ibrahim, Muhammad;Tahir, Mukkram Ali;Iftikhar, Yasir;Haider, Muhammad Sajjad;Noor-Us-Sabah, Noor-Us-Sabah;Han, Kyung-Hwa;Ha, Sang-Keun;Zhang, Yong-Seon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.3
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    • pp.510-516
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    • 2011
  • Salt-affected soils are present in Pakistan in significant quantity. This experiment was conducted to assess the effectiveness of compost for reclamation and compare its efficiency with gypsum. For this purpose, various combinations of compost and gypsum were used to evaluate their efficacy for reclamation. A saline-sodic field having $pH_s$ 8.90, $EC_e$ $5.94dS\;m^{-1}$ and SAR $34.5(mmol\;L^{-1})^{1/2}$, SP (saturation percentage) 42.29% and texture Sandy clay loam, gypsum requirement (GR) $8.75Mg\;ha^{-1}$ was selected for this study. The experiment comprised of seven treatments (control, gypsum alone, compost alone and different combinations of compost and gypsum based on soil gypsum requirements). Inorganic and organic amendments (gypsum and compost) were applied to a saline sodic soil. Rice and wheat crops were grown. Soil samples were collected from each treatment after the harvest of both crops and analyzed for chemical properties (electrical conductivity, soil reaction and sodium adsorption ratio) and fertility status (organic matter, available phosphorus and potassium contents) of soil. Results of this study revealed that compost and gypsum improved chemical properties (electrical conductivity, soil reaction and sodium adsorption ratio) of saline sodic soil to the desired levels. Similarly, all parameters of soil fertility like organic matter, available phosphorus and potassium contents were built up with the application of compost and gypsum.

Development and Application Trend of Bipolar Membrane for Electrodialysis (전기투석용 바이폴라막의 개발 및 응용동향)

  • Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.23 no.5
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    • pp.319-331
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    • 2013
  • Electrodialysis with bipolar membranes (EDBM) has recently gained increasing attention for the recovery and production of acids or bases from the corresponding salt solutions and other high value-added business like food processing and biochemical industry. EDBM possesses economical and environmental benefits and can complex with other process such as ion exchange process, extraction and adsorption. So this paper investigates a brief overview of development for bipolar membrane and EDBM with the practical application.

Review on Application Progress of Carbon-Based Catalysts in Environmental Governance

  • Zheng, Xizhe;Huang, Yuming;Du, Changming
    • Journal of the Korean Chemical Society
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    • v.66 no.4
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    • pp.269-277
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    • 2022
  • In recent years, carbon-based catalysts have become a research hotspot in environmental governance applications. Carbon-based catalysts have large surface areas, porous structures, multi-surface functional groups and excellent electron transfer capabilities, and can synergistically exhibit adsorption and catalytic performance. This article reviews the research progress of carbon-based catalysts in environmental governance, mainly including its application in wastewater treatment, exhaust gas purification and soil remediation. In view of the current difficulties in the research of carbon-based catalysts, the development prospects are proposed. We hope that this review will provide convenience for new entrants and researchers intending to employ carbon-based catalysts for the remediation of contaminated environment.

Particle-Based Framework for Efficiently Representation of the Physical Properties of Paint in Virtual Environment (가상환경에서 물감의 물리적 특성을 효율적으로 표현하는 입자 기반 프레임워크)

  • HyeongJun Yoo;Jong-Hyun Kim
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2023.01a
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    • pp.385-387
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    • 2023
  • 본 논문에서는 물감의 유체성, 확산성, 흡착성, 흡수성 및 응고성과 같은 물감의 물리적 특성을 활용하여 사실적인 페인트 시뮬레이션할 수 있는 입자 기반 프레임워크를 제안한다. 현실에서는 물감이 흐르고, 확산하는 것뿐만 아니라 흡착하거나 시간에 지남에 따라 응고되는 현상을 쉽게 관찰할 수 있다. 본 논문에서는 이런 현상을 사실적으로 표현하기 위하여 SPH(Smoothed-particle hydrodynamics) 방식을 시뮬레이션 하였으며 Isotropic kernel이 아닌 Anisotropic kernel을 사용하여 확산 과정을 표현하는 방식을 소개한다. 우리의 방법은 Fick's law를 바탕으로 물질 전달 방식을 이용한 확산 과정을 표현하였으며, 시간이 지남에 따라 굳어가는 응고성, 그리고 Van der waals 힘을 기반으로 한 흡착 과정을 동시적으로 표현하여 사실적인 페인트를 구현하였다.

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Experimental Assessment of Forest Soil Sensitivity to Acidification(II) - Application of Extractable Sulfate and Sulfate Adsorption Capacity - (산림토양(山林土壤)의 산성화(酸性化) 민감도(敏感度)에 대(對)한 실험적(實驗的) 평가(評價)(II) - 추출성(抽出性) 황산(黃酸)이온(SO42-) 함량(含量)과 황산(黃酸)이온 흡착능(吸着能)의 활용(活用) -)

  • Lee, Sung Woo;Kim, Young Kul;Lee, Choong Hwa;Byun, Jae Kyoung
    • Journal of Korean Society of Forest Science
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    • v.90 no.4
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    • pp.431-436
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    • 2001
  • The extractable sulfate content and sulfate adsorption capacity in soils of four Pinus densiflora stands were measured to assess the soil acidification sensitivity to acid deposition. The soluble sulfate content in organic horizon which reflects the previous deposition of sulfur oxides was much higher for Namsan and Ulsan than Kanghwa and Hongcheon. In mineral soils, however, the extractable sulfate content was the greatest for Ulsan followed by Kanghwa, Namsan and Hongcheon due to the interactive effect of previous deposition and soil adsorption of sulfate. Adsorption rates of specifically adsorbed sulfate(proportion of insoluble sulfate to total extractable sulfate) for Namsan, Kanghwa and Ulsan affected by acid deposition were 16.6%, 56.8% and 37.4%, respectively, so that the soil in Namsan had the highest acidification sensitivity to acid deposition. For sulfate adsorption isotherm($RE=mX_i-b$), the significantly positive correlations between added sulfate($X_i$) and adsorbed sulfate(RE) were found only in mineral soil(p<0.05) over all regions. The regression coefficient(m) that means soil sulfate adsorption capacity by 0-30cm depth was 0.16, 0.24, 0.25 and 0.32 in $mmol_c\;kg^{-1}$ for Namsan, Kanghwa, Ulsan and Hongcheon, respectively, indicating that soil acidification sensitivity is the highest for Namsan. The added sulfate($X_i$) that could make the adsorbed sulfate(RE) null was 3.81, 2.17, 4.96 and 0.65 in $mmol_c\;kg^{-1}$ for Namsan, Kanghwa, Ulsan and Hongcheon, respectively and the values of former three regions considerably exceeded the realistic sulfate deposition.

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Development of Clean Water Supplying System for Greenhouse Cultivation and Convenience Water (II) - Assessment of the FDA System through a Site Application - (시설용수 및 영농편의용수 공급시스템 개발 (II) - FDA 시스템 현장적용성 평가 -)

  • Lee, Kwang-Ya;Choi, Kyung-Sook
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.5
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    • pp.101-106
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    • 2009
  • The previous study developed the Filter-Disinfection-Adsorption (FDA) system to provide clean irrigation water for greenhouse cultivation as well as convenience water to farmers. In this study, the field examination was undertaken to assess performance of the FDA system. The field application was made in the suburb of Daegu, one of the large city in Korea. The study area located near by down-stream of Gum-Ho river is suffering low irrigation water quality problems with no water supply service facilities. Four water quality parameters including Suspended Solid (SS), Biological Oxygen Demand (BOD), coliform, and turbidity were selected to test the purification performance of FDA system. Also in order to improve the system, this study investigated the defects of using the FDA system through field monitoring. As results, it was found that this system can be used to supply good quality of irrigation water for greenhouse cultivation and also provide convenience water to farmers in the field areas of no water supply services.

Extent and persistence of dissolved oxygen enhancement using nanobubbles

  • Tekile, Andinet;Kim, Ilho;Lee, Jai-Yeop
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.427-435
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    • 2016
  • In this study, change in water-dissolved oxygen (DO) was analyzed under various synthetic water qualities and nanobubbles (NBs) application conditions, such as gas type, initial DO as well as water dissolved, suspended and organic matters contents. When oxygen, rather than air, was introduced into nitrogen-desorbed ultra-pure water, the stagnation time was significantly increased. It took ten days for DO concentration to drop back to saturation. The higher the initial DO concentration, the longer particles were observed above saturation due to particle stability improvement. The oxygen mass transfer rate of 0.0482 mg/L/min was found to reach a maximum at an electrolytic concentration of 0.75 g/L, beyond which the transfer rate decreased due to adsorption of negative ions of the electrolyte at the interface. High levels of turbidity caused by suspended solids have become a barrier to dissolution of NBs oxygen into the water solution, and thus affected the transfer performance. On the other hand, by applying NBs for just an hour, up to 7.2% degradation of glucose as representative organic matter was achieved. Thus, NBs technology would maintain a high DO extent for an extended duration, and thus can improve water quality provided that water chemistry is closely monitored during its application.