• Title/Summary/Keyword: adsorption ability

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Adsorption Treatment of Petroleum Oil on Aqueous Phase (수용액중에 함유된 석유화합물들의 흡착처리에 관한 연구)

  • Lee, T.H.;Son, B.C.;Lee, S.B.;Kim, l.H.
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.1-5
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    • 1992
  • The adsorption amount of petroleum oil on XAD-4, XAD-7 and replacement adsorbents as rice bran, rice straw and sawdust were studied by using batch method measured in the optimum adsorption condition. The adsorption capacity of rice bran and rice straw of petroleum oil were excellent as well as adsorption ability about 50% of XAD resins and adsorption capacity of their replacement adsorbents were increased with optimum condition that pyrolysis time was 30 min. at $200^{\circ}C$. Adsorption ability of sawdust was very weak on the 30% MeOH aqueous medium but adsorption ability was range of about 50% of XAD resin's adsorption capacity on the 0.5M NaCl aqueous medium. Adsorption ability of rice bran and rice straw showed the same adsorption capacity even if difference external structure. Therefore, showing that rice bran and rice straw were have to good adsorption ability as replacement adsorbent for XAD resins.

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Study on the Adsorption of Heavy Metal Ions by Biomaterials (생물질재료에 의한 중금속 흡착에 관한 연구)

  • 정석희;김상규;이민규
    • Journal of Environmental Science International
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    • v.2 no.4
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    • pp.357-365
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    • 1993
  • This study was conducted for the efficient utilization of biomaterials such as starch residue, tangerine skin, and green tea residue, which are agricultral by-products discarded in Cheju Province annually, as adsorbents and biomaterials were examined for their removal ability of heavy metal ions in waste water by batch adsorption experiments. The removal efficiency of biomaterials for heavy metal ions was above 80-90% and almost similar to activated carbon and the adsorption ability of those treated with 포르말린 was improved in the green tea residue only for $Pb^{2+}$, $Cu^{2+}$, and $Zn^{2+}$. In the conditions of pH, the removal efficiency of heavy metal ions was high in the range of 5-7. In the solutions which heavy metal ions were mixed, the removal efficiency was similar at $Ag^+$, $Pb^{+2}$ and reduced to about 10% at the other ions, as compared with the solutions they were not mixed. Adsorption isotherm of biomaterials was generally obeyed to Freundlich formular than Langmuir formular and Freundlich constant, 1/n were obtained in the range of 0.1-0.5.

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An Investigation for the Adsorption of Heavy Metal Ions by Polyamine Organic Adsorbent from the Aqueous Solution - The Influence of Molecular Weight and Degree of Deacetylation of Chitosan - (수용액 중에서 Polyamine계 유기응집제를 이용한 중금속 이온의 흡착 - 키토산의 분자량과 탈아세틸화도 -)

  • Park, Young-Mi;Jeon, Dong-Won
    • Fashion & Textile Research Journal
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    • v.8 no.4
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    • pp.458-464
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    • 2006
  • The adsorption ability of heavy metal ions from the aqueous solution by chitosan, which it is well known natural biopolymer, has been investigated. The fundamental study in this research is focusing on the physicochemical adsorption utilizing the chitosan as a organic chelating adsorbent, adsorb especially heavy metal ions from the waste liquid solution. The adsorption ability of the chitosan between metal ions, having different characteristics with Mw of 188,600, 297,200, and 504,200 g/mol and degree of deacetylation (DD) of 86.92% and 100% were investigated targeting on the $Ni^{2+}$, $Co^{2+}$, $Zn^{2+}$, and $Pb^{2+}$ ions, respectively. The uptake of heavy metal ions with chitosan was performed by atomic absorption flame emission spectrophotometer (AAS) as conducted residual metal ions. It was found that chitosan has an strong adsorption capacity for some metals under certain conditions. Chitosan, which have 100% degree of deacetylation showed high adsorption recovery ratio and have an affinity for all kinds of heavy metals. In contrast, the molecular weight of chitosan was not completely affected on metal ion adsorption.

Effects of Plasma on the Surface of Protein Chip Plates (단백질 칩 기판의 플라즈마 효과)

  • Hyun, J.W.;Kim, N.Y.
    • Journal of the Korean Vacuum Society
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    • v.17 no.6
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    • pp.549-554
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    • 2008
  • Nickel Chloride coated protein chip plates were developed by using a spin coating method after $H_2$ plasma treatment. The adsorption ability of histidine tagged protein was investigated at various times of plasma treatment. The properties of the nickel chloride and protein on the surface of the slides were assayed using particle size analysis and the extent of the protein adsorption was determined by using a bio imaging analyzer system. The results show that the ability of protein adsorption decreased as increasing the time of $H_2$ plasma treatment. The mechanism on the ability of protein adsorption at the plate surface is discussed on results and discussions. The results also suggest that the surface stabilization of protein chip plates treated by plasma technology may be applicable in biosensor markets.

Adsorption of Hg(I), Pb(II), and U(VI) ions using from Fruits of Schizandra Chinensis (오미자를 이용한 Hg(I), Pb(II), U(VI) 이온들의 흡착)

  • Kim, Kwan-Chun;Kim, Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.22 no.1 s.63
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    • pp.29-35
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    • 2007
  • This study was examined adsorption ability of heavy metal Hg(I), Pb(II), and U(Vl) ion use of fruit from schizandra chinensis, The fruits of schizandra chinensis sample used breaking into fragments $50{\sim}100$ mesh. The sample solution was mixed fruits of schizandra chinensis and heavy metal ion. Each heavy metal ion of into solution was quantum analysis with ICP-AES. As the result, each condition of maxium adsorption ability of heavy metal ion was high in the range of pH 5-7, adsorption time was about 15 minutes, and the optimum temperature was $100^{\circ}C$. The heavy metal ion was increased adsorption in order of increasing concentration and in ethanol solution better than in aqueous solution.

Dye Adsorption Ability of Chitin in Reactive Dyebath (반응염료염액에서의 키틴의 염료흡착성능)

  • 유혜자;김정희;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.2
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    • pp.349-354
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    • 2002
  • In order to decolorize the reactive dye wastewater, we investigated the dye-adsorption ability of chitin, which was natural polymer obtained from shrimp shell. Chitin particle(less than 250 ${\mu}{\textrm}{m}$n) was prepared from shrimp shells in the processes of decalcification in aqueous hydrochloric acid solution and deproteination in aqueous sodium hydroxide solution. The particle size of chitin was controlled to less than 250 ${\mu}{\textrm}{m}$. Three tripes of the reactive dyes-C.I. Reactive Red 120, C.I. Reactive red 241 and C.I. Reactive Black 5-were used. Dye adsorption ability of chitin was investigated by dipping the particle in the dyebaths of concentration of 0.0l%, 0.03% and 0.05% for various periods of time(1,3,5, 10,20,40,80,160minutes). The influence of addition of salt(Na$_2$SO$_4$) and alkali to the dyebaths on dye-absorption was also investigated. We obtained the following results fur the dye-absolution ability of chitin in the dyebaths of three types of reactive dyes. 1) The amount of dye uptake by chitin was increased by addition of salt to the dyebaths. 2) As the concentration of alkali became higher than 3g/I, the amount of dye uptake by chitin was increased. Chitin showed good dye-adsorption ability, when the alkali concentration was high. 3) Chitin showed equal dye uptake in the three types of dyebaths when the dye concentration was 0.0l%. Over 90% of dyestuffs was adsorbed from the dyebaths in ten minutes. When the dye concentration was higher, better adsorption ability was showed in a dye bath of Reactive black 5 than in the others. When the dye concentration was 0.03%, 90% of Reactive red 120 and Reactive red 241 was adsorbed in 40 minutes and the same of Reactive black 5 in 10 minutes. When the dye concentration was 0.05%, 9()% of Reactive red 120 was adsorbed in 80 minutes, and Reactive black 5 in to minutes.

Effect of Solvent on the Surface of Protein Chip Plate (단백질 칩 기판의 표면에 미치는 용매 효과)

  • 현준원;윤미영;안상민;노승정;허영덕;박헌용;송예신;피재호;김경례
    • Journal of the Korean institute of surface engineering
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    • v.37 no.2
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    • pp.76-79
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    • 2004
  • Nickel chloride coated protein chip plate was developed by using a spin coating method. The ability of histidine tagged protein adsorption was investigated at various solvents. The surface of plate has a large aggregated nickel complex with high density in water. However, the surface of plate has a very small size of aggregated nickel complex with low density in isopropanol. The ability of protein adsorption decreased as increasing the size of alkyl chain in various alcohol solvents. The mechanism on the ability of protein adsorption at the plate surface is discussed.

A study on elemental mercury adsorption behaviors of nanoporous carbons with carbon dioxide activation

  • Bae, Kyong-Min;Park, Soo-Jin
    • Carbon letters
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    • v.15 no.4
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    • pp.295-298
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    • 2014
  • In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs' pore structures and total pore volumes were analyzed by reference to $N_2$/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on their specific surface area and micropore fraction.

Lubricating Mechanism Analyzed from Wear Characteristics of Polyolester Base Oils Haying different Branch Shapes(II) (서로 다른 모양의 가지사슬을 갖는 폴리올에스터 오일의 마모특성으로부터 해석된 윤활작용 메커니즘(II))

  • 한두희;마사부미마스꼬
    • Tribology and Lubricants
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    • v.17 no.3
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    • pp.171-178
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    • 2001
  • In order to elucidate the lubricating mechanism of polyolester base oils [POEs], the wear characteristics of 27 kinds of polyolester base oils including mixed POEs were investigated. Their wear results were discussed in terms of the effect of molecular structure on wear performance and compared with those of mineral oil. In addition, the adsorption ability of POEs to reduced iron and their hydrolysis rates were measured and the effect of their molecular structures on the adsorptivity and hydrolysis rate of POEs was discussed, respectively. Finally, the lubricating mechanism anlyzed from these results of wear characteristics, adsorptivity and hydrolysis rate was proposed. That is to say, POEs are firstly adsorbed to friction surface and decomposed by hydrolysis or thermal degradation. Fatty acids obtained by degradation of POEs form adsorption film on friction surface. The larger become cohesive ability among fatty acid molecules in the adsorption film, the better gets the wear performance of POEs.

Chloride Penetration Properties of Portland Cement Mortar Substituted with Anion Exchange Resin Powder (음이온교환수지 분말이 치환된 포틀랜드 시멘트 모르타르의 염소이온 침투 특성)

  • Lee, Yun-Su;Lim, Seung-Min;Park, Jang-Hyun;Jung, Do-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.1
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    • pp.1-9
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    • 2020
  • Chloride ion, which penetrates into the cement composites from the outside, generally diffuses by the concentration gradient. Chloride ions are adsorbed by the chemical reaction with cement hydrates. Recent studies have shown that anion exchange resin (AER) powder can effectively adsorb the chloride ion in the cement composites, and thus, the cement composites containing AER have a high chloride adsorption capacity and a good resistance for chloride penetration. In this study, the chloride adsorption ability of the AER powder was investigated under the conditions of distilled water and calcium hydroxide saturated solution to determine if the AER powder is less effective to increase the chloride adsorption ability after grinding process. The chloride adsorption ability of AER powder was compared with the previous research about the chloride adsorption of AER bead. In addition, the compressive strength, chloride diffusion coefficient (using NT Build 492 method), and the chloride profile of cement mortar substituted with AER powder were investigated. There was no decrease in the chloride adsorption capacity of AER powder but increase in the kinetic property for chloride adsorption after the grinding process. The AER powder could absorb the chloride ion in the mortar quickly, and showed better chloride ion adsorption ability than the cement hydrates.