• Journal of ILASS-Korea
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• v.25 no.4
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• pp.196-203
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• 2020

Nowadays, urea SCR technology is considered as the most effective NOx reduction technology of diesel engine. However, low NOx conversion efficiency under low temperature conditions is one of its problems to be solved. This is because injection of UWS (Urea Water Solution) is impossible under such a low temperature condition due to the problem of insufficient of urea decomposition and urea deposits. In several previous studies, it has been reported that appropriate control of the amount of ammonia adsorbed on SCR catalyst can improve the NOx conversion efficiency under low temperature conditions. In this study, we tried to find out how much the NOx conversion efficiency increases with respect to the amount of ammonia adsorbed on the catalyst, and what the temperature conditions that the ammonia slip occurs. This study shows the results of 8 times repeated WHTC test with a diesel engine, in which UWS was injected with NH3/NOx mole ratio of '1'. Through this study, it was found that 13% of the NOx conversion efficiency of WHTC increased while the θ (ammonia adsorption rate) increased from "0%" to "22%". In addition, it is found that in cases of high θ value, the significant improvement of NOx conversion efficiency at low temperatures presented during the beginning period of WHTC and at high temperature and transient conditions presented during last part of WHTC test. The NH3 slip occurring condition was 250℃ of catalyst temperature and 10% of θ, and the amount of NH3 slip increased as the temperature and θ are increased.

• Proceedings of the Korean Society of Potoscience Conference
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• spring
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• pp.92-93
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• 1999

• Vacuum Magazine
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• v.1 no.1
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• pp.11-16
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• 2014

A variety of metal vacuum systems displays the celebrated 1/t pressure, namely, power-law dependence on time t, with the exponent close to unity, as to the origin of which there has been long-standing controversy. Here we propose a chemisorption model for water adsorbates, based on the argument for 2D fermion behavior of water adsorbed on a metal surface, and obtain analytically the power-law behavior of pressure with an exponent unity. Further, the model predicts that the pressure should depend on the temperature T according to $T^{1.5}$, which is indeed confirmed by our experiment.

• Journal of Korean Society on Water Environment
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• v.23 no.3
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• pp.314-318
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• 2007

The feasibility of the employment of waste oyster shell as an adsorbent for fluoride ion has been tested by considering the effect ionic condition on the adsorption of fluoride ion on oyster shell. The adsorption capacity of oyster shell for fluoride ion was found not to be significantly influenced by the ionic strength of aqueous environment. The existence of complexing agent such as nitrilotriacetic acid in wastewater decreased the adsorbed amount of fluoride ion by forming a stable complex of $CaT^-$ and the adsorption reaction of fluoride ion on oyster shell was examined to be endothermic. The coexisting heavy metal ionic adsorbate in wastewater hindered the adsorption of fluoride ion, however, its adsorbed amount was increased as the particulate size of adsorbent was decreased. Finally, a serial adsorption column test has been conducted for a practical application of adsorption process and the breakthrough of the column adsorption was observed in 22 hours under the experimental condition.

• Journal of Korean Society on Water Environment
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• v.22 no.4
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• pp.626-631
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• 2006

The adsorption features of copper ion have been investigated by taking the barley residue which occurring from the beer production process as an adsorbent. Under the experimental conditions, adsorption equilibrium of copper ion was attained within 30 minutes after the adsorption started and the adsorption reaction was observed to be first order. As the temperature increased, the adsorbed amount of copper ion at equilibrium was also increased, which indicated that the adsorption reaction was endothermic. Based on the experimental results which obtained by varying the temperatures, several thermodynamic parameters for copper adsorption reaction were estimated. Regarding the electrokinetic behavior of barley residue, its electrokinetic potential was observed to be positive below pH 5 and turned into negative above this pH. In the pH range from 1.5 to 4, copper adsorption was found to be increased, which was well explained by the electrokinetic behavior of barley residue in the pH range. When nitrilotriacetic acid, which is a complexing agent, was coexisted with copper ion, equilibrium adsorption of copper ion was decreased and this was presumed to be due to the formation of metal complex. In addition, the adsorbed amount of copper ion was examined to be increased when $KNO_3$ was coexisted, however, it approached a saturated value above a certain concentration of $KNO_3$.

• Journal of Microbiology and Biotechnology
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• v.17 no.9
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• pp.1527-1532
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• 2007

Lysine produced during microbial fermentation is usually recovered by an ion-exchange process, in which lysine is first converted to the cationic form (by lowering the pH to less than 2.0 with sulfuric acid) and then fed to a cationexchange column containing an exchanger that has a sulfone group with a weak counterion such as NH;. Ammonia water with a pH above 11 is then supplied to the column to displace the purified lysine from the column and allow its recovery. To enhance the adsorption capacity and for a possible reduction in chemical consumption, monovalent lysine fed at pH 4 was investigated in comparison with conventional divalent lysine fed at pH 1.5. The adsorption capacity increased by more than 70% on a mass basis using pH 4 feeding compared with pH 1.5 feeding. Lysine adsorbed at pH 4 started to elute earlier than that adsorbed at pH 1.5 when ammonia water was used as the eluant solution, and the extent of early elution became more notable at lower concentrations of ammonia. Moreover, the elution of monovalent lysine fed at pH 4 displayed a stiffer front boundary and higher peak concentration. However, when the ammonium concentration was greater than 2.0 N, complete saturation of the bed was delayed during adsorption and the percent recovery yield from elution was lowered., both drawbacks that were considered inevitable features originating from the increased adsorption of monovalent lysine.

• Restorative Dentistry and Endodontics
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• v.18 no.2
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• pp.423-430
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• 1993

The purpose of this study was to investigate the effect of ferric and ferric ions contained in phosphoric acid solution as a pretreatment solution on bonding of MMA/TBBO resin to dentin. Each of 1 % and 3 % ferric chloride. cupric chloride. cupric sulfate. and cupric nitrate was mixed into 10% phosphoric acid solution and pretreated dentin surface of bovine anterior teeth for 30 seconds followed- by water rinse and dry. Tensile bond strength was determined after bonding of pretreated dentin with MMA/TBBO resin by use of brush-on ;technique and storing for 24 hours in 3it distilled water. The amount of cupric ions adsorbed on pretreated dentin surface was detected by Wave-Dispersion X-ray microanalyzer for different groups of each pretreatment solution containing cupric salts. The pretreatment with cupric ions contained in 10% phosphoric acid solution was effective to increase bonding strength of MMA/TBBO resin to dentin but not in case of ferric ions. The pretreatment with 3 % cupric chloride and cupric nitrate both enhanced significant increase in bonding strength compared to the control group of 10% phosphoric acid solution(p<0.05). Cupric ions measured in pretreated dentin surface was higher in 3 % cupric chloride group than in 1% cupric chloride group, but couldn't find distinct relationship from the results of this experiment between the amount of adsorbed cupric ions according to the kind of cupric salts and the bonding strength value.

• Membrane and Water Treatment
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• v.12 no.1
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• pp.37-41
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• 2021

This paper presents the multiscale calculation results of the very fast volume transport in micro/nano cylindrical tubes with the wall slippage. There simultaneously occurs the adsorbed layer flow and the intermediate continuum fluid flow which are respectively on different scales. The modeled fluid is water and the tube wall is somewhat hydrophobic. The calculation shows that the power loss on the tube no more than 1.0 Watt/m can generate the wall slippage even if the fluid-tube wall interfacial shear strength is 1 MPa; The power loss on the scale 104 Watt/m produces the volume flow rate through the tube more than one hundred times higher than the classical hydrodynamic theory calculation even if the fluid-tube wall interfacial shear strength is 1 MPa. When the wall slippage occurs, the volume flow rate through the tube is in direct proportion to the power loss on the tube but in inverse proportion to the fluid-tube wall interfacial shear strength. For low interfacial shear strengths such as no more than 1 kPa, the transport in the tube appears very fast with the magnitude more than 4 orders higher than the classical calculation if the power loss on the tube is on the scale 104 Watt/m.

• Advances in nano research
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• v.10 no.3
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• pp.295-312
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• 2021

A new ionic liquid functionalized magnetic silica nanoparticle was synthesized and characterized and tested as an adsorbent. The adsorbent was used for magnetic solid phase extraction on ICP-MS method. Simultaneous determination of precious metal Au has been addressed. The method is simple and fast and has been applied to standard water and surface water analysis. A new method for separation/analysis of trace precious metal Au by Magnetron Solid Phase Extraction (MSPE) combined with ICP-MS. The element to be tested is rapidly adsorbed on CoFe2O4@SiO2@[BMIM]PF6 composite nano-adsorbent and eluted with thiourea. The method has a preconcentration factor of 9.5-fold. This method has been successfully applied to the determination of gold in actual water samples. Hydrophobic Ionic Liquids (ILs) 1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6) coated CoFe2O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (CoFe2O4@SiO2@ILs) and establish a new method of MSPE coupled with inductively coupled plasma mass spectrometry for separation/analysis of trace gold. The results showed that trace gold was adsorbed rapidly by CoFe2O4@SiO2@[BMIM]PF6 and eluanted by thiourea. Under the optimal conditions, preconcentration factor of the proposed method was 9.5-fold. The linear range, detection limit, correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.01~1000.00 ng·mL-1, 0.001 ng·mL-1, 0.9990 and 3.4% (n = 11, c = 4.5 ng·mL-1). The CoFe2O4@SiO2 nanoparticles could be used repeatedly for 8 times. This proposed method has been successfully applied to the determination of trace gold in water samples.

• Journal of the Korea Institute of Building Construction
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• v.13 no.6
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• pp.594-601
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• 2013

One of the important problems associated with building demolition is the dust generated during the work. The only way to reduce the demolition dust is to use a dust net during water spraying. However, it is difficult to supply the necessary amount of water to remove demolition dust, thus making it difficult to apply this method on a demolition site. This work attempted to find an alternative approach to dust removal by incorporating surfactant and high range AE water reducer in the water being sprayed. Through the experiment, it was found that the addition of surfactant did not contribute to the removal of demolition dust. However, the use of high range AE water reducer showed better performance than spraying plain water, indicating that some amount of demolition dust had been adsorbed on the high range AE water reducer.