• Title/Summary/Keyword: addition-chain

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Manufacturing Data Aggregation System Design for Applying Supply Chain Optimization Technology (공급망 최적화 기술 적용을 위한 제조 데이터 수집 시스템)

  • Hwang, Jae-Yong;Shin, Seong-Yoon;Kang, Sun-Kyoung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.25 no.11
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    • pp.1525-1530
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    • 2021
  • By applying AI-based efficient inventory management and logistics optimization technology using the smart factory's production plan and manufacturing data, the company's productivity improvement and customer satisfaction can be expected to increase. In this paper, we proposed a system that collects data from the factory's production process, stores it in the cloud, and uses the manufacturing data stored there to apply AI-based supply chain optimization technology later. While the existing system supported approximately 10 to 20 data types, the proposed system is designed and developed to support more than 100 data types. In addition, in the case of the collection cycle, data can be collected 1-2 times per second, and data collection in TB units is possible. Therefore This system is designed to be applied to the existing factory of past in addition to the smart factory.

Solution Properties of Polyglycerol Alkyl Ether Nonionic Surfactant (폴리글리세롤을 친수성기로한 비이온성 계면활성제의 용액성)

  • Yun, Y.K.;Nam, K.D.;Kang, T.J.
    • Journal of the Korean Applied Science and Technology
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    • v.9 no.2
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    • pp.107-117
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    • 1992
  • The synthesis and solution properties of polyglycerol alkyl ether($R_{12}Gn$) are described. The phase behavior, surface tension, cloud point and HLB value of polyglycerol dodecyl ether in aqueous solution and in mixed solution of surfactant /water /oil have been investigated and compared with values of polyoxyethylene dodecyl ether. The surface tension showed that $R_{12}Gn$ have sufficiently low values of surface tension and cmc to serve as useful polyoxyethylene alkyl ether. The mesophases appearing in the $R_{12}Gn$ systems were more stable in a high temperature range than the mesophases of polyoxyethylene alkyl ether systems. The cloud point and HLB data indicated that addition of one glycerol group was equivalent to the addition of three oxyethylene group units, as far as the hydrophilic property was concerned. The phase diagrams of the polyglycerol alkyl ether /dodecane /water systems showed that the solubilizing and emulsifying powers of $R_{12}Gn$ were greater than those of polyoxyethylene alkyl ether. It is concluded that the polyglycerol chain can be even more useful as hydrophilic group of nonionic surfactants than the polyoxyethylene chain.

Soy Isoflavones Do Not Alter the Effects of Fructooligosaccharide on the Intestinal Ecosystem of Colon-Cancer Model Rats

  • Sung, Hye-Young;Lim, Young-Jee;Choi, Young-Sun
    • Food Science and Biotechnology
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    • v.15 no.6
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    • pp.931-936
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    • 2006
  • This study sought to investigate any additive or interactive effects that soy isoflavones may have on the ecosystem of the gut, which is influenced by fructooligosaccharide (FOS) in colon-cancer model rats. Male Sprague-Dawley rats treated with 1,2-dimethylhydrazine were given experimental diets containing 0, 3, 6, or 9% FOS with or without 0.1% soy isoflavone for 12 weeks. In addition to the effects of FOS dosage on the gut ecosystem, dietary supplementation with soy isoflavone reduced the number of colonic aberrant crypts (ACs). The fecal weight, fecal pH, and gut transit time significantly decreased in a dose-dependent manner in rats fed FOS and the fecal concentration of bifidobacteria was higher in rats fed FOS than in control rats. The fecal output of total short-chain fatty acids, acetate, and propionate was significantly increased by the presence of FOS and was negatively correlated with the number of ACs, whereas the fecal output of butyrate showed no significant correlation with FOS dosage. The addition of soy isoflavone to the diet did not result in any significant differences in gut ecosystem parameters. Therefore, we conclude that the suppressive effect of soy isoflavone on ACs was not associated with the intestinal ecosystem, which was significantly altered by the dosage of FOS.

Effect of Manganese Promotion on Al-Pillared Montmorillonite Supported Cobalt Nanoparticles for Fischer-Tropsch Synthesis

  • Ahmad, N.;Hussain, S.T.;Muhammad, B.;Ali, N.;Abbas, S.M.;Khan, Y.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3005-3012
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    • 2013
  • The effect of Mn-promotion on high surface area Al-pillared montmorillonite (AlMMT) supported Co nanoparticles prepared by hydrothermal method have been investigated. A series of different weight% Mn-promoted Co nanoparticles were prepared and characterized by XRD, TPR, TGA, BET and SEM techniques. An increase in the surface area of MMT is observed with Al-pillaring. Fischer-Tropsch catalytic activity of the as prepared catalysts was studied in a fixed bed micro reactor at $225^{\circ}C$, $H_2/CO$ = 2 and at 1 atm pressure. The data showed that by the addition of Mn the selectivity of $C_1$ dropped drastically while that of $C_2-C_{12}$ hydrocarbons increased significantly over all the Mn-promoted Co/AlMMT catalysts. The $C_{13}-C_{20}$ hydrocarbons remained almost same for all the catalysts while the selectivity of $C_{21+}$ long chain hydrocarbons decreased considerably with the addition of Mn. The catalyst with 3.5%Mn showed lowest $C_{21+}$ and highest $C_2-C_{12}$ hydrocarbons selectivity due to cracking of long chain hydrocarbons over acidic sites of MMT.

Amphiphilic Norbornene-Based Diblock Copolymers Containing Polyhedral Oligomeric Silsesquioxane Prepared by Living Ring Opening Metathesis Polymerization

  • Park, Su-Dong;Xu, Wentao;Chung, Chan-Hong;Kwon, Young-Hwan
    • Macromolecular Research
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    • v.16 no.2
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    • pp.155-162
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    • 2008
  • We report the successful synthesis of poly(NBECOOH-b-NBEPOSS) copolymers, taking advantage of the sequential, living ring opening metathesis polymerization of NBETMS and NBEPOSS using the $RuCl_2(=CHPh)(PCY_3)_2$/$CH_2Cl_2$/$20^{\circ}C$ system, followed by the hydrolysis of trimethylsilyl groups in poly(NBETMS-b-NBEPOSS) copolymers. The living behavior of ROMP of NBETMS was first investigated using two diagnostic plots, a first order kinetic plot and a $\bar{M}_n$ vs. conversion plot. The plots confirmed that no termination and chain transfer reaction had occurred during polymerization. Poly(NBECOOH-b-NBEPOSS) copolymers were prepared using the sequential monomer addition of NBEPOSS to living poly(NBETMS) chain ends, followed by the hydrolysis of trimethylsilyl groups in the poly(NBETMS-b-NBEPOSS) copolymers. The high structural integrity of poly(NBE-COOH-b-NBEPOSS) copolymers was confirmed by $^1H$-NMR, $^{13}C$-NMR spcctroscopy and GPC.

A DFT Study for the Reaction Pathway(s) of Polycyclic Aromatic Hydrocarbons I: Phenanthrene Degradation with two OH Radicals (다고리 방향족 탄화수소의 반응 경로에 대한 DFT 연구 I: 2개의 OH 라디칼에 의한 페난트렌의 분해 반응)

  • Lee, Min-Joo;Lee, Byung-Dae
    • Journal of the Korean Chemical Society
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    • v.65 no.1
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    • pp.9-14
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    • 2021
  • In this study, the DFT calculation was performed using the B3LYP/6-31G(d,p) basis sets for the reaction process in which phenanthrene decomposes due to the chain reaction of two OH radicals on phenanthrene in the gaseous state of 298 K at 1 atm. As a result of the calculation, even when two OH radicals act on phenanthrene in a chain, the reaction for producing phenanthren-9-ol is predicted to be more advantageous than the reaction for producing phenanthren-1-ol. On the other hand, it was predicted that the OH addition process at room temperature would be advantageous for the priority of the OH addition and H abstraction process.

Understanding Consumer Perceptions of Luxury Vintage Fashion

  • Tungyun Liu;Sijun Sung;Heeju Chae
    • Asia-Pacific Journal of Business
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    • v.14 no.1
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    • pp.41-57
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    • 2023
  • Purpose - The purpose of this study is to research how the different types of experiences affect consumer's recognition in terms of luxury vintage fashion products, and what kinds of value consumer can achieve. Design/methodology/approach - The study is based on the means-end chain (MEC) approach for an in-depth understanding of consumers' recognition systems through conducting the laddering interview technique. Above all, the research conducted a pilot test to gain attributes of consumer experiences about luxury vintage fashion products from Korean and Taiwanese. Findings - It is found that not only by actual purchase, experience without purchasing also can lead to consumers' self-fulfilment and self-accomplishment, which filled the lack of relevant literature in the luxury vintage industry. In addition, the study sorted out the channels that consumers approach LVF products, which provide a classification reference for future research related to the luxury vintage consumer. Research implications or originality - As consumers can gain a lot kind of value through LVF products, luxury brands can attract consumers by using vintage as a market strategy. For luxury marketers, by running LVF shopping mall online or opening LVF stores, not only allow consumers' attach with LVF products but also can further lead to the purchase behaviors. In addition, consumers who are interested in LVF are those who are aware of the authenticity, uniqueness, and rarity of the brand. Due the fact, these consumers may be interested in the topic of sustainability.

The Roles of Knowledge Sources in and out of the Value Chain on Radical and Incremental Innovation : Moderating Effects of Knowledge Sources on the R&D Investment-Innovation Relationship (가치사슬 내부 및 외부의 지식원천이 급진적 혁신 및 점진적 혁신에 미치는 영향 : 지식원천들의 연구개발투자-혁신성과 관계에 대한 조절효과)

  • Kim, KonShik
    • Journal of Korea Technology Innovation Society
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    • v.21 no.1
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    • pp.454-490
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    • 2018
  • This paper examined the nonlinear relationships between external knowledge sources and the innovation performance of SMEs (small and medium-sized enterprises). Using 3,218 firm-year panel data in South Korea, this study found that increasing the number of external knowledge channels out of the value chain increases radical innovation. Meanwhile, increasing the number of external knowledge channels within the value chain increases the incremental innovation. Further, the external sources of knowledge both out of and in the value chain had inverted U-shaped relationships on radical and incremental innovation respectively. This finding implies that a mechanism of diminishing returns works in the relationship between the external sources of knowledge and innovation. The study also identified the synergistic effects between the external sources of knowledge out of the value chain and within the value chain, and confirmed that the synergistic effects strengthen the linear mechanism between the external sources of knowledge and innovation. In addition, this study found that the sources of knowledge both out of and within the value chain positively moderate the relationships between R&D investment and radical innovation of SMEs.

Investigation of Gas Transport Properties of Polymeric Membranes having Different Chain Lengths Via Molecular Dynamics (MD) (분자동역학을 이용한 고분자 주쇄의 길이 변화에 따른 기체 투과 성능 연구)

  • Kang, Hoseong;Park, Chi Hoon
    • Membrane Journal
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    • v.28 no.1
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    • pp.67-74
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    • 2018
  • In the molecular dynamics study of polymeric membranes, it is very important to select the proper length of the polymer main chain because it requires a large number of constituent atoms and a long time to simulate the permeation behavior. In this study, we tried to investigate how the correlation between polymer main chain length and permeation behavior appears in actual molecular dynamics simulation results. Molecular dynamics were performed using the widely known commercial polymer Kapton(R) polyimide structure and the gas permeation behavior was simulated. The movement of the polymer main chain was not related to its length and the short main chain length did not act more actively. In addition, unlike the prediction that the end group of the polymer main chain is relatively easy to move, there are many cases where the atoms located at the middle of the polymer main chains have a higher movement than the atoms located at the end groups. Finally, permeabilities of the gas molecules was not affected by the length of the main chain and the end groups of the polymer, which indicates that the end effect should be carefully mentioned and followed by the verification process.

Study on Characteristics of PLA/PBAT Composite Film with Various Chain Extenders (고분자 사슬연장제를 이용한 폴리유산 / 폴리부틸렌 아디페이트테레프탈레이트 복합필름의 제조 및 특성 분석)

  • Kim, Sun-jong;Cho, Hyun-seung;Lee, Jae-hwan;You, Myung-je;Um, Yoo-Jun;Park, Su-il
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.2
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    • pp.61-66
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    • 2017
  • Poly lactic acid(PLA) and poly butylene adipate-co-terephthalate(PBAT) film was prepared using a twin extruder. PLA (25%) and PBAT (75%) were mixed with various ratio of chain extenders, such as $Joncryl^{(R)}$ and hexamethylene diisocyanate(HDI) to improve the mechanical and thermal properties of produced bio composite films. Tensile strengths of films were steadily increased with increasing ratio of chain extender. The tensile strength of control films was about 25 MPa, and the tensile strength of films with combined chain extenders was above 40 MPa. The films with $Joncryl^{(R)}$ resulted in improved tensile strength, while the film with HDI alone showed improved percent elongation at break. By adding chain extenders into PLA/PBAT resin, the cold crystallization temperature (Tcc) and decomposition temperature (Td) of the produced bio composite films increased. It revealed that the addition of two types of chain extenders was efficient way to get PLA/PBAT film with improved strength and elongation.