• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.216-219
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• 2002

Much quantity of anti-tracking agent, ATH is added to the silicone rubber for the protection of silicone rubber against surface discharge. Hydrophobicity recovery properties of silicone rubber could be different by the content, surface treatment state and particle size of ATH. Because hydrophobicity of silicone rubber is depend much on the surface state of ATH. In this paper, the properties of silicone rubber is investigated according to the addition of different particle size of ATH to the silicone rubber. Hydrophobicity recovery properties and arc resistance of silicone rubber were investigated according to the addition of different particle size of ATH. Hydrophobicity recovery properties of silicone rubber were evaluated by the measurement of contact angle.

• Macromolecular Research
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• 제13권2호
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• pp.81-87
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• 2005

Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared by the melt mixing technique. Mechanical, XRD, thermal and dynamic mechanical investigations are reported for the pure silicone rubber and blends. The mechanical properties, viz. the tensile strength, tear strength and elongation at break, of the silicone rubber decreased with the addition of LCP. The SEM study on the tensile fractured surface of the blends revealed that they had a two phase structure, and that the failure was mainly due to fiber pull out, which suggests that the VMQ and LCP are incompatible in all of the proportions examined in this study. However, the FTIR study shows that there was a partial interaction between the VMQ and LCP, but which may not be sufficient to grip the fibrils under the applied load. In the XRD analysis, it was observed that the crystalline structure of the silicone rubber deteriorated in the presence of LCP. The DMA study suggested that the storage modulus of the silicone rubber was improved with the addition of LCP, due to the high modulus of the LCP phase. The thermal stability of the silicone rubber was greatly reduced by the addition of LCP, due to the latter having a thermal stability lower than that of silicone rubber.

• The Journal of Advanced Prosthodontics
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• 제11권3호
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• pp.155-161
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• 2019

PURPOSE. Although dental impression disinfection is determinant to reduce the cross-infection risk, some studies have shown that, in real practice, the disinfection procedures vary considerably. Thus, the aim of this study was to evaluate the antimicrobial effectiveness and the impact on the dimensional stability of addition silicone' impressions of water wash and the most clinically used disinfection solutions: 3% hydrogen peroxide, commercial disinfectant MD520 (Durr) and 1% and 5.25% sodium hypochlorite. MATERIALS AND METHODS. For this investigation, dental impressions were taken on 16 volunteer dental students. The antimicrobial effectiveness of each procedure was evaluated by pour plate method. The dimensional stability was evaluated using a standardized stainless-steel model, according to ANSI/ADA nº19 specification. RESULTS. The study results showed that water wash does not alter the dimensional stability of addition silicone impressions but doesn't reduce the microbial load of the material (P>.05). On the other hand, addition silicone disinfection by immersion with 3% hydrogen peroxide, MD520 (Durr), or sodium hypochlorite at 1% and 5.25% does not alter the dimensional stability significantly but reduces > 99.9% of the microbial load of the impressions (P<.001). CONCLUSION. Addition silicone impressions should always be disinfected after water wash in order to reduce effectively the cross-infection risk. All disinfectants tested showed high antimicrobial efficiency without significant changes in three-dimensional shape of impressions. Hydrogen peroxide and sodium hypochlorite are of particular importance because are easily accessible in dental setting. The less explored hydrogen peroxide could be a valuable alternative for silicone impressions disinfection.

• 한국응용과학기술학회지
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• 제33권4호
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• pp.802-812
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• 2016

실리콘 폼은 고성능 가스켓, 열 차폐, 진동 마운트 및 Enter 키 패드로 많은 산업 분야에서 난연성 소재로서 매우 유용하다. 실리콘 발포체는 실온에서 백금 촉매 및 무기필러 존재하에서 비닐기를 함유한 폴리실록산 (V-silicone) 및 수산기를 함유한 폴리실록산 (OH-silicone)과 하이드라이드를 함유한 폴리실록산 (H-silicone)의 수소와의 수소축합반응의해 가교와 발포를 동시에 일으켜 제조하였다. 이러한 방법은 종래의 발포와 경화를 각각 실시한 공정보다 매우 편리한 방법이다. 이 실험에 사용 된 기능성 실리콘수지들은 1.0 meq/g의 vinyl기를 가진 점도 20 Pa-s의 V-silicone과 0.4 meq/g의 수산기를 가진 점도 50 Pa-s의 OH-silicone 및 7.5 meq/g의 하이드라이드기를 함유한 점도 0.06 Pa.s.의 H-silicone으로 구성되어 있다. 본 연구에서는 실리콘의 종류 및 함량, 촉매, 충전제 등의 변화에 따른 실리콘수지 발포체의 구조 및 기계적 특성에 미치는 영향을 연구하였다. 백금 촉매는 실리콘 수지에 대하여 0.5 wt%이면 충분하였다. 낮은 점도의 OH-silicone의 첨가는 초기 발포 속도를 높이며 발포체 밀도는 감소시키지만, 낮은 점도의 V-silicone의 첨가는, 인장 강도뿐만 아니라 신율도 감소시킨다. SF-3 조건에서 얻은 실리콘수지 발포체의 밀도, 인장강도 및 신율을 각각 $0.58g/cm^3$, $3.51kg_f/cm^2$ 및 176 %를 얻을 수 있었다. 본 발포 시스템에서의 알루미나 충전재 역시 실리콘수지 발포체의 기계적 특성을 향상시키는 중요한 역할을 하였다.

• 한국전기전자재료학회논문지
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• 제16권11호
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• pp.1001-1007
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• 2003

The silicone fluids have been generally used as processing agent in silicone rubber(SIR) compounding. The addition of hydroxy silicone (HS) fluids to SIR for insulator housing material is required to meet the good electrical performance and the good processability. In this study, SIR with HS fluids was evaluated to investigate how the kinds of them affect insulation properties. The contact angle of the virgin sample of 40-HS SIR was low and its recovery rate was also slow. The recovery rate of 50-HS SIR was the highest being decreased with the viscosity increase of HS fluids. The tracking resistances and the corona aging resistance of 70-HS SIR and 1,040-HS SIR were excellent Tracking resistance depended largely on heat resistance of silicone fluids. But arc resistance didn't depend merely on the kind of silicone fluids.

• 한국식품과학회지
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• 제19권6호
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• pp.556-560
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• 1987

최근 우리의 식생활에 튀김기름의 이용도가 급격히 증가되고 앞으로 더 가속화 될것이 예상됨에 따라 본 연구에서는 튀김조리시 튀김기름의 질저하를 방지하기 위하여 Pork cutlet을 대두유로 튀김하는 과정에서 대두유에 silicone oil을 0, 0.5, 1, 2 및 5 ppm을 첨가한 후 $170^{\circ}C$에서 가열시간에 따라 산가(AV), 카보닐가(COV), TBA가, color intensity, 지방산조성의 변화 등을 측정하였다. 산가는 pork cutlet 튀김 7시간후에 무첨가유와 비교해보면 silicone oil 1ppm 첨가유가 약12%의 산화억제 효과를 나타내어 가장 높은 효과를 보였다. 카본닐가는 7시간을 시점으로 silicone oil 1ppm첨가유가 무첨가유에 비하여 5%의 산화억제효과를 나타내어 가장효과가 높았고 TBA가도 1ppm 첨가유가 약 25%의 억제효과로 1ppm이 가장 산화억제 유효첨가량임을 알수 있었다. 착색도는 7시간을 시점으로 무첨가유와 비교해 보면 Silicone oil 1ppm첨가유가 26%의 착색억제 효과를 나타내어 가장 억제효과가 큰것을 알수 있었다. 지방산 조성은 7시간 튀김후 Silicone oil무첨가유(無添加油)와 silicone oil을 각각 첨가한 대두유 사이에는 큰 변화가 없었다.

• 한국안전학회지
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• 제20권3호
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• pp.58-63
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• 2005

In this research, silicone rubber with additions of inorganic filler, alumina trihydrate$(Al(OH)_3\;:\;ATH)$, was aged acceleratedly and cyclically by the salt-fog and heating. The optimum amount of ATH addition to silicone rubber have been investigated by measurements of leakage current in the change of electrical properties and tensile strength, %elongation in mechanical properties and FT-IR, TG, SEM in the change of the chemical properties. With regard to un-aged silicone rubber, as the ATH addition amount increases, conductive path formation time was shortened in the electrical properties and tensile strength was increased, %elongation was decreased. In case of identical ATH addition amount, as cyclic aging increases, surface resistivity, tensile strength and %elongation were decreased. Considering the cyclic aging, the most effective amount of ATH addition was about 90phr.

• 대한치과보철학회지
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• 제30권2호
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• pp.233-245
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• 1992

The purpose of this study was to evaluate the demensioal stability and wettability of several rubber impression materials. Impressions were made from a metal master die machined to stimulate five full veneer crown preparations symmetrically placed in an arch form. Cast from impressions were measured about ; 1) intrapreparation distance 2) lower base diameter 3) length. For comparing materials were formed against a smooth surface. The advancing contact angle of a saturated aqueous solution of $CaSO_4$ on the impression materials was measured after 1 minute. Mean contact angle were calculated and results were analyzed. Results were as follows : 1. As the intrapreparation distance, hydrophilic addition-cured silicone had the smallest change and condensation-cured silicone had the largest one. 2. As the lower base diameter, traditional addition-cured silicone had the smallest change and polyether had the largest one. 3. As the height, traditional addition-cured silicone had the smallest change and polyether had the largest one. 4. As the contact angle, polyether had the smallest change and condensation-cured silicone had the largest one.

• 대한가정학회지
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• 제19권2호
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• pp.213-221
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• 1981

This theiss deals with the effects of addition of silicone oil to the polymerization and oxidation of frying oil in the practical deep fat frying process. The measurement of frying oil stability was carried out under various silicone oil content and compared with controlled frying process. In controlled frying process A.V., C.O.V., TBA, and contents of petroleumether insoluble fatty acids were increased as time was increased. It means thermal oxidized polymerization and hydrolysis of frying oil was occurred. When silicone oil was added to frying oil, it's thermal stability was better than that of the controlled oil and the degree of thermal stability was changed according to the contents of silicone oil. We obtained the highest degree of thermal stability when silicone oil was added 1ppm.

• 한국치위생학회지
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• 제9권3호
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• pp.369-379
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• 2009

This study investigated the polymerization inhibition effect of latex gloves on addition silicone impression material. Three different kinds of addition silicone impression materials and a natural latex gloves were used in this study. The results were as follows. 1. Compared to the control group, all of those three kinds of impression materials took longer curing time in order of unwashed, alcohol and washed group, on the other hand, degloving group had shorter curing time than control group(p<0.05). 2. By the type of impression materials, there was no significant difference observed between Exafine and Twinz in ungloved group, Exafine and Imprint II in unwashed group, and Exafine and Twinz in degloving group(p>0.05). 3. The degree of polymerization at 6 minutes after mixing impression materials was evaluated by dividing its range into score 1 to 5. All of the impression materials got score 5 in control group and degloving group, which implies perfect polymerization. In unwashed group, most of them appeared to be score 2 while score 3 were most frequently observed in alcohol group and score 4 in washed group. Thus each group showed differences in the degree of polymerization(p<0.05).