• Title/Summary/Keyword: addition silicone

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Properties of Silicone Rubber According to the Addition of Different Particle Size of ATH (ATH 의 입도에 따른 실리콘 고무의 특성)

  • Park, Hyo-Yul;Kang, Dong-Pil;Ahn, Myeong-Sang;Kim, Dae-Whan;Lee, Hoo-Bum;Oh, Se-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.216-219
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    • 2002
  • Much quantity of anti-tracking agent, ATH is added to the silicone rubber for the protection of silicone rubber against surface discharge. Hydrophobicity recovery properties of silicone rubber could be different by the content, surface treatment state and particle size of ATH. Because hydrophobicity of silicone rubber is depend much on the surface state of ATH. In this paper, the properties of silicone rubber is investigated according to the addition of different particle size of ATH to the silicone rubber. Hydrophobicity recovery properties and arc resistance of silicone rubber were investigated according to the addition of different particle size of ATH. Hydrophobicity recovery properties of silicone rubber were evaluated by the measurement of contact angle.

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Blends of Silicone Rubber and Liquid Crystalline Polymer

  • Shivakumar E.;Das C. K.;Pandey K. N.;Alam S.;N.Mathur G.
    • Macromolecular Research
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    • v.13 no.2
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    • pp.81-87
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    • 2005
  • Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared by the melt mixing technique. Mechanical, XRD, thermal and dynamic mechanical investigations are reported for the pure silicone rubber and blends. The mechanical properties, viz. the tensile strength, tear strength and elongation at break, of the silicone rubber decreased with the addition of LCP. The SEM study on the tensile fractured surface of the blends revealed that they had a two phase structure, and that the failure was mainly due to fiber pull out, which suggests that the VMQ and LCP are incompatible in all of the proportions examined in this study. However, the FTIR study shows that there was a partial interaction between the VMQ and LCP, but which may not be sufficient to grip the fibrils under the applied load. In the XRD analysis, it was observed that the crystalline structure of the silicone rubber deteriorated in the presence of LCP. The DMA study suggested that the storage modulus of the silicone rubber was improved with the addition of LCP, due to the high modulus of the LCP phase. The thermal stability of the silicone rubber was greatly reduced by the addition of LCP, due to the latter having a thermal stability lower than that of silicone rubber.

A simple and effective method for addition silicone impression disinfection

  • Azevedo, Maria Joao;Correia, Ines;Portela, Ana;Sampaio-Maia, Benedita
    • The Journal of Advanced Prosthodontics
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    • v.11 no.3
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    • pp.155-161
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    • 2019
  • PURPOSE. Although dental impression disinfection is determinant to reduce the cross-infection risk, some studies have shown that, in real practice, the disinfection procedures vary considerably. Thus, the aim of this study was to evaluate the antimicrobial effectiveness and the impact on the dimensional stability of addition silicone' impressions of water wash and the most clinically used disinfection solutions: 3% hydrogen peroxide, commercial disinfectant MD520 (Durr) and 1% and 5.25% sodium hypochlorite. MATERIALS AND METHODS. For this investigation, dental impressions were taken on 16 volunteer dental students. The antimicrobial effectiveness of each procedure was evaluated by pour plate method. The dimensional stability was evaluated using a standardized stainless-steel model, according to ANSI/ADA nº19 specification. RESULTS. The study results showed that water wash does not alter the dimensional stability of addition silicone impressions but doesn't reduce the microbial load of the material (P>.05). On the other hand, addition silicone disinfection by immersion with 3% hydrogen peroxide, MD520 (Durr), or sodium hypochlorite at 1% and 5.25% does not alter the dimensional stability significantly but reduces > 99.9% of the microbial load of the impressions (P<.001). CONCLUSION. Addition silicone impressions should always be disinfected after water wash in order to reduce effectively the cross-infection risk. All disinfectants tested showed high antimicrobial efficiency without significant changes in three-dimensional shape of impressions. Hydrogen peroxide and sodium hypochlorite are of particular importance because are easily accessible in dental setting. The less explored hydrogen peroxide could be a valuable alternative for silicone impressions disinfection.

Preparation and characterization of poly(dimethylsiloxane) foam prepared by hydrogen condensation reaction (수소 축합 반응에 의한 폴리디메틸실록산 미세 발포체의 제조 및 물성분석 연구)

  • Lee, Soo;Moon, Sung Jin
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.802-812
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    • 2016
  • Silicone foam is very useful as flame resistant material for many industrial areas such as high performance gasketing, thermal shielding, vibration mounts, and press pads. A silicone foam was prepared through simultaneous crosslinking and foaming by hydrogen condensation reaction of a vinyl-containing polysiloxane (V-silicone) and a hydroxyl-containing polysiloxane (OH-silicone) with hydride containing polysiloxane (H-silicone) in the presence of platinum catalyst and imorganic filler at room temperature. This is more convenient process for silicone foam manufacturing than the conventional separated crosslinking and foaming systems. Funtionalized silicones we used in this experiment were consisted with a V-silicone containing 1,0 meq/g of vinyl groups and a viscosity of 20 Pa-s, an OH-silicone with 0.4 meq/g of hydroxyl groups and a viscosity from 50 Pa-s, and an H-silicone containing 7.5 meq/g of hydride groups and a viscosity of 0.06 Pa.s. The effects of compositions of functionalized silicones and additives, such as catalyst and filler on the structure and mechanical properties of silicone foam were studied. 0.5 wt% of Pt catalyst was enough to accelerate the foaming rate of silicone resins. The addition of OH-silicone with lower viscosity accelerates the initial foaming rate and decreases the foam density, but the addition of V-silicone with lower viscosity reduces the tensile strength as well as the elongation. The final foam density, tensile strength, and elogation of silicone foam prepared under the SF-3 condition increase maximum to $0.58g/cm^3$, $3,51kg_f/cm^2$, and 176 %, repectively. We found out the filler alumina also played an important role to improve the mechanical properties of silicone foams in our foaming system.

Effects of Hydroxy Silicone Oil on Insulation Properties of Silicone Rubber(1) (Hydroxy Silicone Oil이 실리콘 고무의 절연특성에 미치는 영향(1))

  • 강동필;박효열;안명상;이웅재;이후범;오세호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.11
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    • pp.1001-1007
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    • 2003
  • The silicone fluids have been generally used as processing agent in silicone rubber(SIR) compounding. The addition of hydroxy silicone (HS) fluids to SIR for insulator housing material is required to meet the good electrical performance and the good processability. In this study, SIR with HS fluids was evaluated to investigate how the kinds of them affect insulation properties. The contact angle of the virgin sample of 40-HS SIR was low and its recovery rate was also slow. The recovery rate of 50-HS SIR was the highest being decreased with the viscosity increase of HS fluids. The tracking resistances and the corona aging resistance of 70-HS SIR and 1,040-HS SIR were excellent Tracking resistance depended largely on heat resistance of silicone fluids. But arc resistance didn't depend merely on the kind of silicone fluids.

Effect of Silicone Oil on Properties of Cooking Oils for Pork Cutlet Frying (돼지고기 튀김조리시(調理時) Silicone oil 첨가(添加)가 튀김기름의 성질(性質)에 미치는 영향(影響))

  • Yun, Sook-Ja;Yum, Cho-Ae
    • Korean Journal of Food Science and Technology
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    • v.19 no.6
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    • pp.556-560
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    • 1987
  • In this study, silicone oil was added into soybean oil in order to investigate its effect on acid value (AV), carbonyl value (COV), TBA value, fatty acid composition and color intensity of soybean oil during frying at $170^{\circ}C$. It was found that the AV, COV and TBA value were significantly decreased as the concentration of silicone oil increased from 0 to 5 ppm in soybean oil after frying for 7 hours. The color intensity was also decreased by 26% of color of 7 hours-heated soybean oil without silicone oil addition. Little changes in fatty arid composition was measured between the samples after 7 hours frying. From the overall result of this study, addition of silicone oil by 1 ppm was recommended for effective reduction of rancidity development of soybean oil ing frying.

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The Change of the Cyclic Aging Characteristics under Salt-fog/Heating on Silicone Rubber by ATH Additions (ATH 첨가에 의한 실리콘 고무의 염무/열 반복열화 특성 변화)

  • Lee, Chung;Kim, Ki-Yup;Kim, Gyu-Baek;Ryu, Boo-Hyung
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.58-63
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    • 2005
  • In this research, silicone rubber with additions of inorganic filler, alumina trihydrate$(Al(OH)_3\;:\;ATH)$, was aged acceleratedly and cyclically by the salt-fog and heating. The optimum amount of ATH addition to silicone rubber have been investigated by measurements of leakage current in the change of electrical properties and tensile strength, %elongation in mechanical properties and FT-IR, TG, SEM in the change of the chemical properties. With regard to un-aged silicone rubber, as the ATH addition amount increases, conductive path formation time was shortened in the electrical properties and tensile strength was increased, %elongation was decreased. In case of identical ATH addition amount, as cyclic aging increases, surface resistivity, tensile strength and %elongation were decreased. Considering the cyclic aging, the most effective amount of ATH addition was about 90phr.

DIMENSIONAL STABILITY AND WETTABILITY OF RUBBER IMPRESSION MATERIALS (고무 인상재의 크기 안정성 및 친수성에 관한 연구)

  • Kang Choong-Hee;Vang Mong-Sook
    • The Journal of Korean Academy of Prosthodontics
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    • v.30 no.2
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    • pp.233-245
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    • 1992
  • The purpose of this study was to evaluate the demensioal stability and wettability of several rubber impression materials. Impressions were made from a metal master die machined to stimulate five full veneer crown preparations symmetrically placed in an arch form. Cast from impressions were measured about ; 1) intrapreparation distance 2) lower base diameter 3) length. For comparing materials were formed against a smooth surface. The advancing contact angle of a saturated aqueous solution of $CaSO_4$ on the impression materials was measured after 1 minute. Mean contact angle were calculated and results were analyzed. Results were as follows : 1. As the intrapreparation distance, hydrophilic addition-cured silicone had the smallest change and condensation-cured silicone had the largest one. 2. As the lower base diameter, traditional addition-cured silicone had the smallest change and polyether had the largest one. 3. As the height, traditional addition-cured silicone had the smallest change and polyether had the largest one. 4. As the contact angle, polyether had the smallest change and condensation-cured silicone had the largest one.

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The Effects of Silicone oil in Deep Fat Frying Process (튀김과정에서의 Silicone oil의 효과에 관한 연구)

  • 원미량
    • Journal of the Korean Home Economics Association
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    • v.19 no.2
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    • pp.213-221
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    • 1981
  • This theiss deals with the effects of addition of silicone oil to the polymerization and oxidation of frying oil in the practical deep fat frying process. The measurement of frying oil stability was carried out under various silicone oil content and compared with controlled frying process. In controlled frying process A.V., C.O.V., TBA, and contents of petroleumether insoluble fatty acids were increased as time was increased. It means thermal oxidized polymerization and hydrolysis of frying oil was occurred. When silicone oil was added to frying oil, it's thermal stability was better than that of the controlled oil and the degree of thermal stability was changed according to the contents of silicone oil. We obtained the highest degree of thermal stability when silicone oil was added 1ppm.

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Effect of latex gloves on polymerization inhibition of addition silicone impression materials (라텍스 글러브가 시판되는 3종류 부가중합형 실리콘 인상재의 중합에 미치는 영향)

  • Kim, Soo-Hwa
    • Journal of Korean society of Dental Hygiene
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    • v.9 no.3
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    • pp.369-379
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    • 2009
  • This study investigated the polymerization inhibition effect of latex gloves on addition silicone impression material. Three different kinds of addition silicone impression materials and a natural latex gloves were used in this study. The results were as follows. 1. Compared to the control group, all of those three kinds of impression materials took longer curing time in order of unwashed, alcohol and washed group, on the other hand, degloving group had shorter curing time than control group(p<0.05). 2. By the type of impression materials, there was no significant difference observed between Exafine and Twinz in ungloved group, Exafine and Imprint II in unwashed group, and Exafine and Twinz in degloving group(p>0.05). 3. The degree of polymerization at 6 minutes after mixing impression materials was evaluated by dividing its range into score 1 to 5. All of the impression materials got score 5 in control group and degloving group, which implies perfect polymerization. In unwashed group, most of them appeared to be score 2 while score 3 were most frequently observed in alcohol group and score 4 in washed group. Thus each group showed differences in the degree of polymerization(p<0.05).

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