• Title/Summary/Keyword: active alkali

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Study on the Quality Characteristics of High-strength Concrete Using LCD Industrial Waste (LCD 산업부산물을 이용한 고강도 콘크리트의 품질 특성에 관한 연구)

  • Kim, Dong-Jin;Park, Seung-Hee;Choi, Sung;Han, Yang-Su
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.650-657
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    • 2021
  • Alkali activators that stimulate mineral compounds are expensive materials, but in order to replace industrial products of high alkali in gredien ts, both product an d econ omic feasibility must be satisfied. In this study, alkali in dustrial waste(LW) from the LCD man ufacturin g process were used for the purpose of alkali active reaction of GGBFS for high stren gth concrete over 50MPa. Concrete mixed with LW had reduced workability, but it had the characteristic of increasing compressive strength. Analysis using ACI 209 Compressive Strength Model Equation was made to compare the changes in strength coefficients according to LW mixing. The durability test of concrete, such as Chloride Penetration Resistance and carbonation resistance, also showed excellent performance. In the Adiabatic temperature rise test results, the concrete mixed with LW had the effect of accelerating the initial hydration heat. However, the final Adiabatic temperature rise was not significantly affected by the mixing of LW.

Studies on the Anthelmintic constituents of Gelidium amansii. (우무가사리(Gelidium amansii)의 구충성분에 대하여(제 1 보))

  • 서석수;홍승철
    • YAKHAK HOEJI
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    • v.6 no.2
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    • pp.1-6
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    • 1962
  • Clinical tests revealed that the extracts of Gelidium amansii (Gelidiaceae) had a anthelmintic action and further examinations were made on the anthelmintic components of this seaweed. This anthelmintic principle is absorbed on alumina and eluted from it by alkali solution. The active principle is absorbed on activated carbon from aqueous extract and eluted from it by methanol and it is not adsorbed on Amberite IR-120(H-form). This anthelmintic effective fraction was prepared by the use of this properties. Action of the active principle of Gelidium amansii was examined pharmacologically. The active principle of Gelidium amansii was found to decrease the tensity, tonus and mobility of Eisenia foetida(Savigny) nerve muscles. The active principle of this effective fraction was submitted to paper chromatography and spots to ninhydrin were detected at Rf; 0.30-0.31(yellow), 0.26(violet), 0.2(violet), 0.14-0.13(violet), 0.9(orange) and 0.04(violet).

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Purification, Characterization and Chemical Modification of the Xylanase from Alkali-tolerant Bacillus sp. YA-14

  • Park, Young-Seo;Yum, Do-Young;Hahm, Byoung-Kwon;Bai, Dong-Hoon;Yu, Ju-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.4 no.1
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    • pp.41-48
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    • 1994
  • The xylanase from alkali-tolerant Bacillus sp. YA-14 was purified to homogeneity by CM-cellulose, Sephadex G-50, and hydroxyapatite column chromatographies. The molecular weight of the purified enzyme was estimated to be 20, 000 Da by sodium dodecyl sulfate-polyacrylamide gel electrophoresis. The purified enzyme slightly hydrolyzed carboxymethyl cellulose and Avicel, but did not hydrolyze soluble starch, dextran, pullulan, and ${\rho}-nitrophenyl-{\beta}$-D-xylopyranoside. The maximum degree of hydrolysis by enzyme for birchwood xylan and oat spelts xylan were 47 and 40%, respectively. The Michaelis constants for birchwood xylan and oat spelts xylan were calculated to be 3.03 mg/ml and 5.0 mg/ml, respectively. The activity of the xylanase was inhibited reversibly by $HgCl_2$, and showed competitive inhibition by N-bromosuccinimide, which probably indicates the involvement of tryptophan residue in the active center of the enzyme. The Xylanase was identified to be xylose-producing endo-type xylanase and did not show the enzymatic activities which cleave the branch point of the xylan structure.

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Mechanical and Dyeing Properties of Wool Fabric Treated with Papain (파파인 처리한 양모직물의 물성 및 염색성)

  • Sung, Jong-Mi;Kim, In-Young;Song, Wha-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.4
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    • pp.697-702
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    • 2010
  • This study researches the mechanical and dyeing properties of wool fabric treated with papain. In this study, shrinkage, water contact angle, alkali solubility, and the dyeability of wool fabric treated with papain at the optimal activity condition were measured to confirm the effect of papain treatment. The shrinkage and water contact angle of wool fabric treated with papain decreased more than the untreated wool; however, the alkali solubility and the dyeability increased. L-cysteine was more active than EDTA as an activator of papain.

Analysis of Chemical Components and Microstructure Characteristics of CBS Dust (CBS-Dust의 화학성분 및 미세구조 특성 분석)

  • Han, Jun-Hui;Lee, Young-Jun;Hyun, Seung-Yong;Lee, Dong-Joo;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.180-181
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    • 2019
  • In this study, in order to find new uses for CBS dust, the chemical components of CBS dust were analyzed and effectively proposed a method. Chemical analysis shows that CBS dust contains a large amount of alkali in addition to chloride therefore, if CBS dust is used for secondary concrete products that use high amounts of mixed materials without rebars, it will be found that it can be used effectively for enhancing strength by active alkali.

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Effective Electrolytic Water Generation Characteristics by Overlapped Multi-layer Electrode (중첩형 다단전극에 의한 효율적인 전해 이온수 발생 특성)

  • Shin, Dong-Hwa;Hwang, Deok-Hyun;Jung, Jae-Seung;Kim, Hyung-Pyo;Kim, Jin-Gyu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.30 no.3
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    • pp.59-64
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    • 2016
  • Applications of electrolytic ion water generated by the oxidation-reduction have gradually been expanded due to their strong sterilizing power and a surface active force. We demonstrate the effect of the multi-layer type electrode for effective ion water generation. The multi-layer type electrode has ability to generate stronger acid and alkali water by increase of the electrode reactive area. Also power consumption efficiency enhances because the electrodes disposed in middle position of the reactive cell raise the usage rate by overlapped effect as an electrolysis electrode.

Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives (첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究))

  • Lim, Kie-Pyo;Shin, Dong-Sho
    • Journal of the Korean Wood Science and Technology
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    • v.7 no.2
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    • pp.3-30
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    • 1979
  • Larch ($\underline{Larix}$ $\underline{leptolepis}$ GORDON), one of the major afforestation species in Korea in view of its growing stock and rate of growth, is not favored as a raw material for pulp due to its low yield of pulp and difficulties with bleaching arising from the high content of extractives in wood, and the high heartwood ratio and the active phenolics, respectively. The purpose of this study is to investigate the characteristics of firstly pulping with various additives of cellulose protector for the yield of pulp, and secondly bleaching with oxygen for chlotination-alkali extraction of five stage-sequence to reduce chlorine compounds in bleaching effluents. The kraft cooking liquor for five age groups of larchwood was 18 percent active alkali with 25 percent sulfidity and 5 : 1 liquor-to-wood ratio, and each soda liquor for sap-and heart-wood of the 15-year-old larchwood was 18 percent alkali having one of the following cellulose protectors as the additive; magnesium sulfate ($MgSO_4$, 2.5%), zinc sulfate ($ZnSO_4$, 2.5%), aluminium sulfate ($Al_2(SO_4)_3$, 2.5%), potasium iodide (KI, 2.5%), hydroquinone (HQ, 2.5%), anthraquinone (AQ, 0.1%) and ethylene diamine (EDA, 2.5%). Then each anthraquinone-soda liquor for the determination of suitable cooking condition was the active alkali level of 15, 17 and 19 percent with 1.0, 0.5 and 0.1 percent anthraquinone, respectively. The cooking procedure for the pulps was scheduled to heat to 170$^{\circ}C$ in 90 minutes and to cook 90 minutes at the maximum temperature. The anthraquinone-soda pulps from both heartwood and sapwood of 15-year-old larchwood prepared with 0.5 percent anthraquinone and 18 percent active alkali were bleached in a four-stage sequency of OCED. (O: oxygen bleaching, D: chlorine dioxide bleaching and E: alkali extraction). In the first stage oxygen in atmospheric pressure was applied to a 30 percent consistency of pulp with 0.1 percent magnesium oxide (MgO) and 3, 6, and 9 percent sodium hydroxide on oven dry base, and the bleached results were compared pulps bleached under the conventional CEDED (C: chlorination). The results in the study were summarized as follows: 1. The screened yield of larch kraft pulp did not differ from particular ages to age group, but heartwood ratio, basic density, fiber length and water-extractives contents of wood and the tear factor of the pulp increased with increasing the tree age. The total yield of the pulp decreased. 2. The yield of soda pulp with various chemicals for cellulose protection of the 15-year-old larchwood increased slightly more than that of pure soda pulp and was slightly lower than that of kraft pulp. The influence of cellulose protectors was similar to the yield of pulps from both sapwood and heartwood. The effective protectors among seven additives were KI, $MgSO_4$ and AQ, for which the yields of screened pulp was as high as that of kraft pulp. Considering the additive level of protector, the AQ was the most effective in improving the yield and the quality of pulp. 3. When the amount of AQ increased in soda cooking, the yield and the quality of the pulp increased but rejects in total yield increased with decreasing the amount of active alkali from 19 to 15 percent. The best proportion of the AQ seemed to be 0.5 percent at 17 percent active alkali in anthraquinone-soda pulping. 4. On the bleaching of the AQ-soda pulp at 30 percent consistency with oxygen of atomospheric pressure in the first stage of the ODED sequence, the more caustic soda added, the brighter bleached pulp was obtained, but more lignin-selective bleaching reagent in proportion to the oxygen was necessary to maintain the increased yield with the addition of anthraquinone. 5. In conclusion, the suitable pulping condition for larchwood to improve the yield and quality of the chemical pulp to the level for kraft pulp from conventional process seemed to be. A) the selection of young larchwood to prevent decreasing in yield and quality due to the accumulation extractives in old wood, B) the application of 0.5 percent anthraquinone to the conventional soda cooking of 18 percent active alkali, and followed, C) the bleaching of oxygen in atmospheric pressure on high consistency (30%) with 0.1 percent magnesium oxide in the first stage of the ODED sequence to reduce the content of chlorine compounds in effluent.

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Influence of Drying Methods on Measurement of Hydration Degree of Hydraulic Inorganic Materials: 2) Alkali-activated slag (수경성 무기재료의 수화도 측정에 대한 건조방법의 영향: 2) 알칼리 활성 슬래그)

  • Lee, Hyo Kyong;Song, Keum-Il;Song, Jinkyu;Kim, Hyeong-Ki
    • Resources Recycling
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    • v.27 no.1
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    • pp.106-117
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    • 2018
  • The present study was carried out to find a suitable drying method for the determination of non-evaporable water in hydraulic inorganic materials. In Part 1 of the paper, the case ordinary Portland cement was discussed and, in this Part 2, the case of alkali active slag (AAS) was investigated. Various drying methods including vacuum and oven drying, and an ignition, were used for the AAS system having different w/b, types and amounts of alkali activators. It was found that a combination of the vacuum and oven drying was a suitable drying method for the AAS case. Although a part of the crystallized water in hydration products was decomposed, but the free and adsorbed water could be completely evaporated and the deviation of the results was small.

Chemical Composition and Alkaline Pulping of a Stem of Red Pepper (Capsium annuum L.) (고추 줄기의 화학 조성분 및 알칼리 펄프화)

  • Kim, Chul Hyun;Kim, Young Yook;Park, Soung Bae;Eom, Tae Jin
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.2
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    • pp.26-32
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    • 2004
  • Chemical compositions and chemical structure of lignin and alkali cooking condition and fiber length of red pepper were investigated and compared to those of woods. The chemical compositions of red pepper were higher component of extraction than that of wood. The contents of carbon and hydrogen of Klason lignin in red pepper were similar to that of pine and birch wood. On the other hand, the contents of oxygen and nitrogen of Klason lignin in the red pepper were higher than that of wood. The result of nitrobenzene oxidation shows that Klason lignin of red pepper was similar to lignin of softwood. The best alkali cooking condition of red pepper was 0.2%-anthraquinone, active alkali of 20% and liquor ratio of 1:7. The fiber length of red pepper was about 0.47 mm. Therefore, the red pepper fiber will be able to use special purpose of short fiber.