• 제목/요약/키워드: activation parameter

검색결과 199건 처리시간 0.025초

셀룰로오스의 열분해 반응속도론 (Kinetics on the Thermal Decomposition of Cellulose)

  • 최승찬;박영수
    • 한국연초학회지
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    • 제5권2호
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    • pp.55-62
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    • 1983
  • Cellulose의 열분해 반응에 대한 Kinetic Parameter를 구하기 위하여 Thermogravimetry(TG)와 Differential Scanning Calorimetry(DSC)를 이용하는 네가지 비등온법을 고찰하였다. 그 결과 DSC에 의한 가열속도법과 TG에 의한 근사법이 가장 간편하였고Kinetic Parameters의 신뢰도도 매우 높았다. Cellulose 열분해 반응에서 반응차수는 1/2차였고 활성화에너지는 42kca1/mo1로 나타났다.

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$Cul-Cu_2S-Cu_2O-MoO_3$계 유리의 전기전도 및 유전환화와의 상관 (Correlation between Electrical Conduction and Dielectric Relaxation in the Glass System $Cul-Cu_2S-Cu_2O-MoO_3$)

  • 이재형;임기조
    • 대한전기학회논문지
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    • 제43권7호
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    • pp.1152-1157
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    • 1994
  • The glasses were prpared in the system CuI-CuS12TS-CuS12TO-MoOS13T by rapid quenching technique. These glasses have high ionic conductivities at 2$0^{\circ}C$ in the range of 10S0-1T[S/m], and the conductivities increase with increasing CuI and CuS12TS content. The value of activation energy for dielectric relaxation is nearly identical with that for conductivity. The cole-Cole parameter $\beta$ for representation of the distribution of dielectric relaxation times varies the range from 0.92 to 0.96. This parameter has a weak dependence on the composition of glass, and is independent of temperature. The correlation factors P for the glasses shows from 1.1 to 1.7.

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Prompt Fission Neutron Spectra in Supercritical Accidents (Influence on the Fission Spectrum-averaged cross-sections of Some Threshold Activation Reactions)

  • Ro, Seung-Gy;Jun, Jae-Shik
    • Nuclear Engineering and Technology
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    • 제7권2호
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    • pp.119-126
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    • 1975
  • 핵임계 사고시에 방출되는 즉발중성자 스펙트럼을 두개의 스펙트럼 매개변수를 갖는 일반화된 Cranberg 식으로 표시할 수 있다고 가정한 다음, 이들 매개변수를 변화시키면서 몇개의 발단 방사화검출체에 대한 평균핵반응단면적의 변화를 고속전자계산기로 계산하였다. 평균핵반응 단면적은 스펙트럼 변화에 따라 민감하게 변화하는데 발단 방사화 에너지가 높을수록 그 변화정도가 심한것 같았다.

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Gas detonation cell width prediction model based on support vector regression

  • Yu, Jiyang;Hou, Bingxu;Lelyakin, Alexander;Xu, Zhanjie;Jordan, Thomas
    • Nuclear Engineering and Technology
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    • 제49권7호
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    • pp.1423-1430
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    • 2017
  • Detonation cell width is an important parameter in hydrogen explosion assessments. The experimental data on gas detonation are statistically analyzed to establish a universal method to numerically predict detonation cell widths. It is commonly understood that detonation cell width, ${\lambda}$, is highly correlated with the characteristic reaction zone width, ${\delta}$. Classical parametric regression methods were widely applied in earlier research to build an explicit semiempirical correlation for the ratio of ${\lambda}/{\delta}$. The obtained correlations formulate the dependency of the ratio ${\lambda}/{\delta}$ on a dimensionless effective chemical activation energy and a dimensionless temperature of the gas mixture. In this paper, support vector regression (SVR), which is based on nonparametric machine learning, is applied to achieve functions with better fitness to experimental data and more accurate predictions. Furthermore, a third parameter, dimensionless pressure, is considered as an additional independent variable. It is found that three-parameter SVR can significantly improve the performance of the fitting function. Meanwhile, SVR also provides better adaptability and the model functions can be easily renewed when experimental database is updated or new regression parameters are considered.

Thrust Force Estimation using Flexible Neural Networks

  • Kim, Myeong-Hee;Shigeyasu Kawaji;Masaki Arao
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2001년도 ICCAS
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    • pp.47.1-47
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    • 2001
  • The drilling process has a great importance for the production technology due to its widerspread use in the manufacturing industry. In order to enhance a maximum production rate and prevent the drill from the damage, it is important to monitor and control the drilling system. Thrust force and cutting torque are the main output variables in the design of drilling control systems. In this paper, an alternative estimation method of thrust force by using flexible neural networks is proposed. Flexible neural network uses the sigmoid activation function with adjustable parameter in order to enhance the approximation accuracy ...

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$^{99m}Tc-HMPAO$ 뇌 SPECT에서 시각자극에 의한 국소 뇌 혈류변화의 정량적 검증 (Quantitative Evaluation of Regional Cerebral Blood Flow by Visual Stimulation in $^{99m}Tc-HMPAO$ Brain SPECT)

  • 주라형;서태석;곽철은;최보영;이형구;정용안;김성훈;정수교
    • 대한핵의학회지
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    • 제36권3호
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    • pp.166-176
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    • 2002
  • 목적: 이 연구의 목적은 시각 활성 자극에 의한 뇌 활성영역을 확인하고 국소 뇌 혈류량을 정량적으로 분석하는데 그 목적이 있다. $^8F-fluoro-2-deoxy\;glucose\;(FDG)\;PET$$^{15}O-water\;PET$에서 시각 자극을 가하는 동안 시각피질에서의 기전이 확인되었으며 PET에 비해 적은 비용으로 널리 사용되고 있는 $^{99m}Tc-HMPAO$ Brain SPECT를 이용하여 시각자극을 주었을 때 대뇌 후두엽의 일차시각피질과 시각 연합 피질에서의 국소 뇌 혈류 변화율을 정량적으로 분석하고자 하였다. 대상 및 방법: 오른손을 주로 사용하는 25세에서 33세의 나이 분포를 갖는 남자 3, 여자 3명(평균나이 26.7세)의 정상인을 대상으로 $^{99m}Tc-HMPAO$ Brain SPECT (925 MBq)를 시행하였고 8 Hz의 발광다이오드를 이용하여 $4{\sim}5$분 동안 시각활성 자극을 주었을 때와 대조군으로 자극을 가하지 않은 비 활성상태에서의 경우로 나누어 스캔하고 해부학적 기준정보를 제공하기 위해 MR 영상과 융합하였으며 관심영역을 설정하여 혈류량을 정량적으로 분석하였다. 결과: 정량적인 분석을 위해 대뇌의 전체 용적과 계수율을 계산하고 관심 영역을 설정하여 관심영역에 대한 복셀 당 평균 계수율을 측정하여 각 대상의 시각 활성자극을 가한 영상에서 정상 상태의 영상을 픽셀 당 픽셀로 감산하여 통계적 파라미터를 이용한 뇌 지도를 구성하였으며 뇌 활성이 Brodmann 영역의 시각피질(Ba 17)과 시각연합피질(Ba 18,19)에서 활성화되어 있음을 Talairach 좌표를 통해 확인하였고 regional index를 계산하여 국소 뇌혈류 변화율을 측정하였다. 결론: $^{99m}Tc-HMPAO$ Brain SPECT에서 8 Hz의 발광 다이오드로 시각 자극을 주었을 때 후두엽의 일차 시각피질과 시각 연합 피질에서 뇌 활성화를 확인하였고 통계적 파라미터를 이용한 SPM99에서 뇌 지도를 작성하여 시각자극에 의한 활성영역을 Talairach 좌표와 Brodmann 분류에 의해 확인하여 T1 강조 MR 영상에 융합하였다. 후두엽의 일차시각피질에서 시각 활성자극에 의해 국소 뇌 혈류량이 $32.50{\pm}5.67%$ 증가하고 있음을 정량적으로 분석하였다.

Computational Study on Unsteady Mechanism of Spinning Detonations

  • Matsuo, Akiko;Sugiyama, Yuta
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.367-373
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    • 2008
  • Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

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Computational Study on Unsteady Mechanism of Spinning Detonations

  • Matsuo, Akiko;Sugiyama, Yuta
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년 추계학술대회논문집
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    • pp.367-373
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    • 2008
  • Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

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구름방울 활성화 과정 모수화 방법에 따른 구름 형성의 민감도 실험 (Sensitivity Test of the Parameterization Methods of Cloud Droplet Activation Process in Model Simulation of Cloud Formation)

  • 김아현;염성수;장동영
    • 대기
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    • 제28권2호
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    • pp.211-222
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    • 2018
  • Cloud droplet activation process is well described by $K{\ddot{o}}hler$ theory and several parameterizations based on $K{\ddot{o}}hler$ theory are used in a wide range of models to represent this process. Here, we test the two different method of calculating the solute effect in the $K{\ddot{o}}hler$ equation, i.e., osmotic coefficient method (OSM) and ${\kappa}-K{\ddot{o}}hler$ method (KK). To do that, each method is implemented in the cloud droplet activation parameterization module of WRF-CHEM (Weather Research and Forecasting model coupled with Chemistry) model. It is assumed that aerosols are composed of five major components (i.e., sulfate, organic matter, black carbon, mineral dust, and sea salt). Both methods calculate similar representative hygroscopicity parameter values of 0.2~0.3 over the land, and 0.6~0.7 over the ocean, which are close to estimated values in previous studies. Simulated precipitation, and meteorological variables (i.e., specific heat and temperature) show good agreement with reanalysis. Spatial patterns of precipitation and liquid water path from model results and satellite data show similarity in general, but on regional scale spatial patterns and intensity show some discrepancy. However, meteorological variables, precipitation, and liquid water path do not show significant differences between OSM and KK simulations. So we suggest that the relatively simple KK method can be a good alternative to the OSM method that requires various information of density, molecular weight and dissociation number of each individual species in calculating the solute effect.

전자 패키징에 사용되는 무연 솔더에 관한 열역학적 연구 (Thermodynamic Issues of Lead-Free Soldering in Electronic Packaging)

  • 정상원;김종훈;김현득;이혁모
    • 마이크로전자및패키징학회지
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    • 제10권3호
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    • pp.37-42
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    • 2003
  • 전자 패키징에 사용되는 솔더합금에 납을 함유됨으로써 인하여 야기되는 환경적 문제와 인체 유해성 때문에 Pb-Sn 합금계를 대체할 수 있는 새로운 무연 솔더 재료의 필요성이 대두되고 있다. 새로운 솔더합금의 개발에 있어서 솔더 조인트의 신뢰성이 가장 중요한 문제라고 할 수 있는데, 솔더 조인트의 신뢰성은 솔더와 기판 사이의 계면 반응 형태와 그 정도에 의해서 크게 영향을 받기 때문에 솔더와 기판 사이의 계면 현상에 관한 더 깊은 이해가 필요하게 된다 솔더링 동안 기판/솔더 계면에서 가장 먼저 생성되는 금속간 화합물의 상을 예측하기 위한 열역학적인 방법이 제안되었다. 계면 에너지와 석출 구동력의 함수로 표현되는 각각의 금속간 화합물에 대한 핵생성 활성화 에너지를 비교함으로써 활성화 에너지가 가장 낮은 금속간 화합물이 가장 먼저 생성된다고 예측하였다. 거기에 더해 에너지를 기반으로 한 계산을 통하여 솔더 조인트에서 금속간 화합물의 입자 형상을 설명하였다. 울퉁불퉁한 계면을 가진 금속간 화합물의 Jackson의 parameter 값은 2보다 작은 반면 평평한 입자의 경우 2보다 크게 된다.

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