• Title/Summary/Keyword: acrylic modified

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Surface modification of Poly-(dimethylsiioxane) using polyelectrolYte multilayers and its characterization (다층의 고분자 전해질을 이용한 Poly-(dimetnylsiloxane)의 표면 개질 및 특성)

  • Shim, Hyun-Woo;Lee, Chang-Hee;Lee, Ji-Hye;Hwang, Taek-Sung;Lee, Chang-Soo
    • KSBB Journal
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    • v.23 no.3
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    • pp.263-270
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    • 2008
  • A poly-(dimethylsiloxane) (PDMS) surface modified by the successive deposition of the polyelectrolytes, poly-(allylamine hydrochloride) (PAH), poly-(diallyldimethylammoniumchloride) (PDAC), poly-(4-ammonium styrenesulfonic acid) (PSS), and poly-(acrylic acid) (PAA), was presented for the application of selective cell immobilization. It is formed via electrostatic attraction between adjacent layers of opposite charge. The modified PDMS surface was examined using static contact angle measurements and fourier transform infrared (FT-IR) spectrophotometer. The wettability of the PDMS surface could be easily controlled and functionalized to be biocompatible through regulation of layer numbers. The modified PDMS surface provides appropriate environment for adhesion to cells, which is essential technology for cell patterning with high yield and viability in the patterning process. This method is reproducible, convenient, and rapid. It could be applied to the fabrication of biological sensing, patterning, microelectronics devices, screening system, and study of cell-surface interaction.

Adhesion Behavior of Chondrocyte and Osteoblast on Surface-Modified Biodegradable PLLA Films and Scaffolds (표면개질된 생분해성 PLLA 필름 및 지지체의 연골세포와 조골세포 점착거동)

  • Choi, Ji-Yeon;Jung, Hyun-Jung;Park, Bang-Ju;Joung, Yoon-Ki;Park, Kwi-Deok;Han, Dong-Keun
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.357-363
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    • 2012
  • Surface-modified poly(L-lactic acid) (PLLA) films and scaffolds were treated with plasma discharge in oxygen gas and subsequently subjected to $in$ $situ$ grafting of acrylic acid (AA) in order to increase the cell compatibility. The surface of AA-grafted PLLA was converted to hydroxyapatite (HA)-deposited PLLA in stimulated body fluid (SBF). After the samples were immersed in phosphate-buffered saline (PBS), fetal bovine serum (FBS), normal saline, or cell medium, the water contact angles were significantly reduced on the surface of HA-deposited PLLA. Chondrocyte and osteoblast showed a higher attachment and cell proliferation on HA-deposited surfaces and in particular, it was confirmed that chondrocyte was considerably influenced by HA. However, osteoblast showed better cell proliferation on the surfaces immersed in FBS, cell medium or HA-deposited surface. In addition, the cell proliferation in 3D scaffolds was much higher than that on film type, irrespective of chondrocyte and osteoblast. Therefore, such surface-modified PLLAs are expected to be useful as organic-inorganic hybrid scaffolds in the regeneration of cartilage and bone.

Effect of Saliva Contamination Stage and Different Decontamination Procedures on Bonding Strength of Resin-Modified Glass Ionomer (레진강화형 글라스아이오노머의 초기 결합력과 타액오염 제거의 상관관계)

  • Go, Hanho;Park, Howon;Lee, Juhyun;Seo, Hyunwoo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.46 no.2
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    • pp.158-164
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    • 2019
  • The purpose of this study was to compare the bond strength of resin-modified glass ionomer (RMGI) to dentin with saliva contamination at different stages and using different decontamination procedures. Extracted human permanent molars were embedded onto acrylic resin with the dentin surface exposed. Group I was a control group that was conditioned with polyacrylic acid (PAA). Groups II and III were contaminated with saliva before PAA conditioning and Groups IV, V, and VI were contaminated with saliva after PAA conditioning. After saliva contamination, Groups II and IV were dried, Groups III and V were rinsed and dried, and Group VI was additionally conditioned with PAA. After surface treatment, the dentin specimens were filled with RMGI. Group I showed significantly higher bond strength than the other groups. Group VI showed a significantly higher bond strength than the other saliva contaminated groups. However, there were no significant differences in the failure mode between the different groups. Saliva contamination impaired the bond strength of RMGI to dentin, regardless of when the saliva contamination occurred. Decontamination with washing and drying could not improve the shear bond strength of RMGIC. When saliva contamination occurred after PAA conditioning, additional PAA conditioning improved the shear bond strength.

Effects of Surface Modification of the Membrane in the Ultrafiltration of Waste Water

  • Cho Dong Lyun;Kim Sung-Hyun;Huh Yang Il;Kim Doman;Cho Sung Yong;Kim Byung-Hoon
    • Macromolecular Research
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    • v.12 no.6
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    • pp.553-558
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    • 2004
  • An ultrafiltration membrane (polyethersulfone, PM 10) was surface-modified by treating it with low-tem­perature plasmas of oxygen, acrylic acid (AA), acetylene, diaminocyolohexane (DACH), and hexamethyldisiloxane (HMDSO). The effects that these modifications have on the filtration efficiency of a membrane in waste water treat­ment were investigated. The oxygen, AA, and DACH plasma-treated membranes became more hydrophilic. The water contact angles ranged from < $10^{\circ}\;to\;55^{\circ}$ depending on the type of plasma and the treatment conditions. The oxygen plasma-treated membranes displayed a higher initial flux $(312-429\%),$ but lower rejection $(6-91\%),$ than did an untreated membrane. The AA plasma-treated membranes displayed lower or higher initial flux $(42-156\%),$ depending upon the treatment conditions, but higher rejection $(224-295\%)$ in all cases. The DACH plasma-treated membranes displayed lower initial flux. All of them, especially the AA plasma-treated membrane, displayed improved fouling resistance with either a slower or no flux decline. Acetylene and HMDSO plasma-treated membranes became more hydrophobic and displayed both lower initial flux and lower fouling resistance.

C-activator treatment for distalization of maxillary molars in Class II anterior deep bite malocclusion (C-activator를 이용한 성장기 II급 부정교합환자의 구치부 원심이동 치험례)

  • Kim, Seong-Hun;Chung, Kyu-Rhim;Kook, Yoon-Ah
    • The korean journal of orthodontics
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    • v.34 no.3 s.104
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    • pp.269-277
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    • 2004
  • A modified removable appliance for molar distalization called C-activator was used in a 10-year old male patient with a Class II anterior deep bite malocclusion with upper arch discrepancy. The treatment plan involved correcting the Class ll relationship, distalizing both upper first molars, and regaining space for the erupting canines. The C-activator, which was used for 6 months, consisted of a labial framework formed from .036-in stainless steel wire and an acrylic monobloc. Both the closed helices of the labial framework were compressed for reactivation during the C-activator treatment period. C-activator mechanics simultaneously achieved distalization of the upper first molars into their proper positions and repositioning of the mandible. After 21 months of treatment, the correct oberbite and overjet was obtained and contributed to an Improvement in facial balance. The treatment results were stable 6 months after debonding. Fabrication and placement of the new appliance and clinical procedures are detailed, and the treatment sequence and results of this case are presented as follows.

Effects of abutment diameter, luting agent type, and re-cementation on the retention of implant-supported CAD/CAM metal copings over short abutments

  • Safari, Sina;Ghavam, Fereshteh Hosseini;Amini, Parviz;Yaghmaei, Kaveh
    • The Journal of Advanced Prosthodontics
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    • v.10 no.1
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    • pp.1-7
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    • 2018
  • PURPOSE. The aim of this study was to evaluate the effects of abutment diameter, cement type, and re-cementation on the retention of implant-supported CAD/CAM metal copings over short abutments. MATERIALS AND METHODS. Sixty abutments with two different diameters, the height of which was reduced to 3 mm, were vertically mounted in acrylic resin blocks with matching implant analogues. The specimens were divided into 2 diameter groups: 4.5 mm and 5.5 mm (n=30). For each abutment a CAD/CAM metal coping was manufactured, with an occlusal loop. Each group was sub-divided into 3 sub-groups (n=10). In each subgroup, a different cement type was used: resin-modified glass-ionomer, resin cement and zinc-oxide-eugenol. After incubation and thermocycling, the removal force was measured using a universal testing machine at a cross-head speed of 0.5 mm/min. In zinc-oxide-eugenol group, after removal of the coping, the cement remnants were completely cleaned and the copings were re-cemented with resin cement and re-tested. Two-way ANOVA, post hoc Tukey tests, and paired t-test were used to analyze data (${\alpha}=.05$). RESULTS. The highest pulling force was registered in the resin cement group (414.8 N), followed by the re-cementation group (380.5 N). Increasing the diameter improved the retention significantly (P=.006). The difference in retention between the cemented and recemented copings was not statistically significant (P=.40). CONCLUSION. Resin cement provided retention almost twice as strong as that of the RMGI. Increasing the abutment diameter improved retention significantly. Re-cementation with resin cement did not exhibit any difference from the initial cementation with resin cement.

Development of a Set of an Experimental Equipment of Westerly Wave for High School (고등학교에 적합한 편서풍 파동 실험장치 개발)

  • Lee, Soon-Hwan;Park, Gwang-Soon;Kim, Hee-Soo
    • Journal of the Korean earth science society
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    • v.27 no.2
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    • pp.177-187
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    • 2006
  • Due to a lack of reproducibility and visibility of the conventional equipment for westerly wave simulation, it is difficult to have indoor experiments at high school that show the stream of Hadley cell. A modified improvement of the old one improves the problem. The side wall and bottom of the new equipment is made by copper and acrylic resin, respectively, in order to clarify the difference between the water temperature inside and outside of the water tank. The equipment also has a high quality digital record for generating exact analysis of the results. And we also carried out several experiments that relate theoretical and experimental aspection of westerly wave. Temperature Detected Sheet (TDS) in flow visualization unit provides not only visual information of liquid flow, but also clear understanding of the relation between upper and lower wind flow structure. And the liquid stream simulated in indoor experiment using proposed equipment is commensurate with westerly wave in real atmosphere. The efficiency of educational properties of the proposed equipment is verified indirectly by Likert Scales survey of high school teachers.

Preparation and Properties of Poly(organosiloxane) Rubber Nanocomposite Containing Ultrafine Nickel Ferrite Powder (Nickel Ferrite 함유 Poly(organosiloxane) Rubber Nanocomposite의 제조와 특성)

  • Kang Doo Whan;Lee Kweon Soo
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.156-160
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    • 2005
  • $\alpha,\omega-Vinyl$ poly (dimethyl-methylphenyl) siloxane prepolymer (VPMPS ) was prepared by the equilibrium polymerization of octamethylcyclotetrasiloxane $(D_4)$, 1,3,5-trimethyl-1,3,5-triphenylcyclotrisiloxane $(D_3^{Me,Ph)$, and 1,1,3,3-tetramethyl-1,3-divinyldisiloxane (MVS). And also, of $\alpha,\omega-hydrogen$ poly(dimethyl-methyl)siloxane prepolymer (HPDMS) as end blocker was prepared from octamethylcyclotetrasiloxane $(D_4)$, 1,3,5-trimethylcyclotrisiloxane $(D_3^:Me,H})$, and 1,1,3,3-tetramethyldisiloxane (MS). Nickel ferrite nanoparticles having spinel magnetic material was prepared by the sol-gel method using PAA as a chelating agent. Poly(organosiloxane) rubber nanocomposite containing silica and nickel ferrite ultrafine powder modified with 1,3-divinyltetramethyldisilazane (VMS) was prepared by compounding VPMPS, HPDMS, and catalyst in high speed dissolver. The mechanical properties, heat dissipating away characteristics, and volume resistivities for POX-30 and POX-50 were measured.

A Study on the Minimization of Spatial Error in 3-Demensional Neuronavigator (3차원 영상지원 뇌수술장비의 공간오차 최소화에 관한 연구)

  • 이동준;다영신;이정교
    • Progress in Medical Physics
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    • v.8 no.2
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    • pp.19-26
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    • 1997
  • 3-dimensional Neuronavigator, Viewing Wand(ISG Technologies, Toronto, Cannda) is the surgery aid equipment for real time image (CT or MRI) guided surgery. The assurance of spatial accuracy of this system is important for clinical application. In this study, we have designed the acrylic brain phantom and measured the spatial error with that phantom. The phantom has designed to have capability to simulate image guided surgery. The phantom has 22 vertical rods whose diameters are 5mm and each rods has different length. CT scans were performed by 2.0mm slice and reconstructed for 3-Dimensional analysis. End point of rods can be obtained using reconstructed 3- Dimensional images and they are compared to actual position data. Average deviation was less than 2mm for various situations. Spatial error of Viewing Wand is acceptable in the clinical points of view, while cosmetics of the software needs to be modified to more user friend. Better accuracy can be expected when we apply the mixed fiducial fit registration and surface fit registration method. And even better results can be obtained if registration points distributed even and symetric around the target.

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The Use of a Porcine Cancellous Bone Graft for Arthrodesis of Bilateral Antebrachiocarpal Luxation in a Dog (양측 전완앞발목관절 탈구의 관절고정술을 위한 돼지뼈 해면골이식의 적용)

  • Heo, Su-Young;Lee, Ki-Chang;Kim, Nam-Soo
    • Journal of Veterinary Clinics
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    • v.29 no.3
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    • pp.259-262
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    • 2012
  • A seven-year-old Yorkshire terrier 2.1 kg was admitted with a 2 months history of sever bilateral forelimb lameness and joint instability. Examination and radiographs revealed caudal luxation of bilateral antebrachiocarpal joint. Luxation of bilateral antebrachiocarpal (ABC) joint in a toy breed dog was treated with pancarpal arthrodesis. Modified external skeletal fixator (ESF) (type IIb) with polymethylmethacrylate (PMMA) was utilized in this case. Porcine cancellous bone graft (PCBG) was inserted to fill the joint space in carpus. The clinical and radiographic assessments of joint after the surgical procedure proved that PCBG can be used a promising alternative to Autogenous cancellous bone graft (ACBG).