• Title/Summary/Keyword: acidic condition

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Enzymatic saccharification of autohydrolyzed industrial hemp (Cannabis sativa L.) lignocellulosic biomass (자기가수분해 처리가 산업용 대마 목부 바이오매스의 효소 당화에 미치는 영향)

  • Shin, Soo-Jeong;Yu, Ju-Hyun;Lee, Soo-Min;Cho, Nam-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.74-76
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    • 2008
  • Autohydrolysis at different temperature levels was applied as industrial hemp pretreatment technique for glucose generation. Main structural components removed by autohydrolysis was xylan, which is more sensitive in acidic hydrolysis condition than cellulose or lignin. Higher temperature reaction conditions promoted more biomass components (xylan) removal than lower temperature, which led to better respond to enzymatic saccharification of residual biomass after autohydrolysis. With $185^{\circ}C$ and 60 min, saccharification degree was 53.0% of cellulose in hemp woody core biomass.

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FT-IR Study of Dopant-wool Interactions During PPy Deposition

  • Varesano Alessio;Aluigi Annalisa;Tonin Claudio;Ferrero Franco
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.105-111
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    • 2006
  • Coating the fibre surface by in situ oxidative chemical polymerisation of polypyrrole (using $FeCl_3$ as oxidant) is a readily industrial applicable way to give electrical properties to wool with good ageing stability [1], although pre-treatments are required to avoid damage of the cuticle surface due to the acidic condition of the process. FT-IR and EDX analysis reveal that organic sulphonates and sulphates, used as dopants, are absorbed by wool, while chlorine ions are preferably embedded on the polypyrrole layer. The resulting electrical conductivity seems mainly due to the presence of chlorine as counter-ion of polypyrrole; nevertheless, the presence of arylsulphonate in the polymerisation bath increases the electrical conductivity of the coating layer.

Characterization of Xylanase of Cladosporium cladosporioides H1 Isolated from Janggyeong Panjeon in Haeinsa Temple

  • Hong, Jin-Young;Kim, Young-Hee;Jung, Mi-Hwa;Jo, Chang-Wook;Choi, Jung-Eun
    • Mycobiology
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    • v.39 no.4
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    • pp.306-309
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    • 2011
  • Cladosporium cladosporioides H1 was found to be the most abundant microbe in Janggyeong Panjeon. C. cladosporioides H1 produced a 20 kDa xylanase, which was generally stable below $60^{\circ}C$ and had specialized activity in an acidic condition. Our results may lead to the development of a strategy for preservation of organic cultural heritage environments.

Sulphamic Acid: an Efficient Catalyst for the Synthesis of α-HydroxyPhosphonates Using Ultrasound Irradiation (술팜산: 초음파 조사를 이용한 α-히드록시 인산염 합성의 효과적인 촉매)

  • Sadaphal, Sandip A.;Sonar, Swapnil S.;Pokalwar, Rajkumar U.;Shitole, Nanasaheb V.;Shingare, Murlidhar S.
    • Journal of the Korean Chemical Society
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    • v.53 no.5
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    • pp.536-541
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    • 2009
  • Sulphamic acid has been exploited as a cost-effective catalyst and green alternative for conventional acidic materials to synthesize $\alpha$-hydroxy phosphonates under solvent-free condition. The reaction carried out using ultrasound irradiation with better yields and shorter reaction time.

1-Butyl-3-Methyl Imidazolium Hydrogen Sulphate Promoted One-Pot Three-Component Synthesis of Amidoalkyl Naphthols

  • Sapkal, Suryakant B.;Shelke, Kiran F.;Madje, Balaji R.;Shingate, Bapurao B.;Shingare, Murlidhar S.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2887-2889
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    • 2009
  • An efficient and easy method for one-pot three-component synthesis of amidoalkyl naphthols by the condensation of aromatic/heteroaromatic/aliphatic aldehydes, 2-naphthol and amides or urea under thermal condition at $60^{\circ}C$ in the presence of acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulphate ([bmim]$HSO_4$) has been described.

Effect of Impact Energy on the Impact-Wear Properties of High Manganese Steels in Acidic Corrosive Conditions

  • Wang, Kai;Du, Xiao-Dong;Wu, Kai;Youn, Kuk-Tae;Lee, Chan Gyu;Koo, Bon Heun
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.362-369
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    • 2008
  • The impact abrasion behavior of high manganese steel is investigated under three kinds of impact energy in acid hematite ore slurry by using a modified MLD-10 impact abrasion tester. Through the SEM observation of the worn surface and the optical metallographic analysis of the cross-sectional samples, the corrosive impact abrasion mechanisms of the steel under different impact energies are studied. In acid-hematite slurry, the variations of impact energies would result in synchronous transformation of the impact abrasion properties and mechanisms of the high manganese steel in the corrosive condition, as led different corrosive impact abrasion mechanism under different impact energies.

Conversion of Penicillin to Cephalosporin. The Iodination of Thiazoline-azetidinone in the Presence of Water (페니실린에서 세파로스포린으로의 전환. 물 존재하에서 티아졸린-아제티디논의 요오드화 반응)

  • Choe, In Yeong;Jeong, Gyu Hyeon;Lee, Yun Yeong;Gu, Yang Mo
    • Journal of the Korean Chemical Society
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    • v.34 no.1
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    • pp.102-107
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    • 1990
  • The reaction of thiazoline-azetidinone (7) with $I_2$ in $CH_2Cl_2-H_2O$ gave directly 3-iodo-3-methylcepham (4). A phase transfer catalyst considerably increased the reaction rate. Similar to the hydrolysis of thiazoline-azetidinone (7) under a weak acidic condition, thiazole (10) was given as major product in the treatment with 0.1 eq. of iodine. The difference between cyclization reaction and hydrolysis could be explained in terms of solvents, the amount of iodine and the nature of thiazoline-azetidinones (7).

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Efficiency Prediction of the Particle Removal Efficiency of Multi Inner Stage(MIS) Cyclone by Computational Fluid Dynamics(CFD) Analysis and Experimental Verification (CFD 해석을 이용한 Multi Inner Stage Cyclone 내부의 미세입자제거 효율 예측 및 실험적 검증)

  • Kim, Hye-Min;Kwon, Sung-An;Lee, Sang-Jun
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2012.07a
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    • pp.243-246
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    • 2012
  • A new multi inner stage(MIS) cyclone was designed to remove the acidic gas and minute particles of harmful materials produced from electronic industry. To characterize gas flow in MIS cyclone, pressure and velocity distribution were calculated by means of computational fluid dynamics(CFD) commercial program. Also, the flow locus of particles and particle removal efficiency were analyzed by Lagrangian method. When outlet pressure condition was -1,000 Pa, the efficiency was the best in this study. Based on the CFD simulation result, the pressure loss and destruction removal efficiency was measured through MIS cyclone experiment.

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Decomposition of Ethylene Glycol by Catalytic Wet Air Oxidation (촉매습식산화에 의한 Ethylene Glycol의 분해)

  • 안상준;최장승;이동근
    • Textile Coloration and Finishing
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    • v.13 no.4
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    • pp.264-271
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    • 2001
  • Catalytic wet oxidation of ethylene glycol as refractory compound was studied in a batch slurry reactor using lwt% $Pt/A1_2O_3$, lwt% $Pt/TiO_2,\;Mn/CeO_2$(1:1) and 5wt% $Mn/Al_2O_3$. Experiments were conducted to investigate theeffects of temperature, initial ethylene glycol concentration, catalyst dosage and PH on the ethylene glycol decomposition. When compared with the uncatalyzed reaction, the use of catalysts could increase the rate of ethylene glycol decomposition. The lwt% $Pt/A1_2O_3$ catalyst was preferable to the other catalysts for the destructive oxidation of ethylene glycol. The reaction rate was first order with respect to initial concentration of ethylene glycol. In acidic condition the removal efficiency of ethylene glycol was good, but there was a significant leaching of platinum. Small amount of acetic acid, oxalic acid, masonic acid and formic acid as intermediates were detected during catalytic wet air oxidation of ethylene glycol.

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Chemical Characteristics of Ozone Treated Aspen Wood Meal (오존 처리에 의한 이태리포플러 목분의 화학적 성상 변화)

  • Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.29-35
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    • 2011
  • Since the role of lignin in the wood cell wall is to keep integrity and structure rigidity of lignocellulosic substrate, lignin of the cell wall has to be destroyed before enzymatic hydrolysis of wood polysaccharides. The aspen wood meals were delignified with ozone in acidic condition. The chemical characteristics of wood meal were investigated. The 60% of lignin and almost zero % of polysaccharides in aspen wood meal was degraded with 10min. ozone treatment. The phenolic hydroxyl groups of lignin in ozonated wood meal were increased with ozonation time. The sugar composition of ozonated wood meal showed that the hemicellulose was more susceptible to ozonation than cellulose. The yield of aldehyde was increased in some degree with 10min. ozone treatment and decreased with longer ozone treatment.