• Title/Summary/Keyword: acidic and alkaline solutions

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Weibull Statistical Analysis on the Mechanical Properties of SiC by Immersion in Acidic and Alkaline Solutions (산 및 알칼리 용액에 부식된 SiC의 기계적 특성에 대한 와이블 통계 해석)

  • Ahn, Seok-Hwan;Jeong, Sang-Cheol;Nam, Ki-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.9
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    • pp.767-773
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    • 2016
  • A Weibull statistical analysis of the mechanical properties of SiC ceramics was carried out by immersion in acidic and alkaline solutions. The heat treatment was carried out at 1373 K. The corrosion of SiC was carried out in acidic and alkaline solutions under KSL1607. The bending strength of corroded crack-healed specimens decreased 47% and 70% compared to those of uncorroded specimens in acidic and alkaline solutions, respectively. The corrosion of SiC ceramics is faster in alkaline solution than in acid solution. The scale and shape parameters were evaluated for the as-received and corroded materials, respectively. The shape parameter of the as-received material corroded in acidic and alkaline solutions was significantly more apparent in the acidic solution. Further, the heat-treated material was large in acidic solution but small in alkaline solution. The shape parameters of the as-received and heat-treated materials were smaller in both acidic and alkaline solutions.

The Adhesion of Abrasive Particle during Poly-Si, TEOS and SiN CMP (Poly-Si, TEOS, SiN 막질의 CMP 공정 중의 연마입자 오염 특성 평가.)

  • Kim, Jin-Young;Hong, Yi-Kwan;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.561-562
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    • 2006
  • The purpose of this study was to investigate the root cause of adhesion of silica and ceria particles during Poly-Si, TEOS, and SiN CMP process, respectively. The zeta-potentials of abrasive particles and wafers were observed negative surface charges in the alkaline solutions. SAC and STI patterned wafers have intermediate values of their composition surface's zeta potentials. The theoretical interaction force and adhesion force of silica and ceria particle were calculated in solution with acidic, neutral and alkaline pH. A stronger attractive force was calculated for silica and ceria particles on wafers in acidic solutions than in alkaline solutions. The theoretical interaction forces of the SAC and STI patterned wafers have intermediate values of their constitution wafer's values. The adhesion forces is observed lower values in alkaline solutions than in acidic solutions. And the ceria particle has lower adhesion than that of the silica particle.

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On the Micellization of ${\alpha}$-Amino Capric Acid (${\alpha}$-아미노카프르산의 Micelle 형성을 위한 한계농도에 관하여)

  • Ryu, Ji-Yong;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.10 no.4
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    • pp.161-165
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    • 1966
  • The critical concentrations of ${\alpha}$-amino capric acid for micelle formation have been determined by the surface tension measurements in both acidic and alkaline solutions, and also by the dye titration using Rhodamine B in alkaline solutions. The critical micelle concentrations obtained by the two methods show the good agreements within experimental errors. Since ${\alpha}$-amino acid is an ampholyte, it may aggregate to form the micelles in both more acidic and basic media than its isoelectric point. It is found that the basic media are rather preferable for the micelle formation than the acidic media. The effect of gegen ions upon the critical concentration for micelle formation in alkaline media is similar to that expected from the salt effect on the CMC (Critical Micelle Concentration).

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Scanning Tunneling Microscopy (STM)/Atomic Force Microscopy(AFM) Studies of Silicon Surfaces Treated in Alkaline Solutions of Interest to Semiconductor Processing

  • Park, Jin-Goo
    • Journal of the Korean institute of surface engineering
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    • v.28 no.1
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    • pp.55-63
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    • 1995
  • Alkaline solutions such as $NH_4$OH, choline and TMAH (($CH_3$)$_4$NOH) have been introduced in semiconductor wet processing of silicon wafers to control ionic and particulate impurities following etching in acidic solutions. These chemicals usually mixed with hydrogen peroxide and/or surfactants to control the etch rate of silicon. The highest etch rate was observed in $NH_4$OH solutions at a pH in alkaline solutions. It indicates that the etch rate depends on the content of $OH^{-}$ as well as cations of alkaline solutions. STM/AFM techniques were used to characterize the effect of alkaline solutions on silicon surface roughness. In SC1 (mixture of $NH_4$OH : $H_2$$O_2$ : $H_2$O) solutions, the reduction of the ammonium hydroxide proportion from 1 to 0.1 decreased the surface roughness ($R_{rms}$) from 6.4 to $0.8\AA$. The addition of $H_2$$O_2$ and surfactants to choline and TMAH reduced the values of $R_{p-v}$ and $R_{rms}$ significantly. $H_2$$_O2$ and surfactants added in alkaline solutions passivate bare silicon surfaces by the oxidation and adsorption, respectively. The passivation of surfaces in alkaline solutions resulted in lower etch rate of silicon thereby provided smoother surfaces.s.ces.s.

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Antimicrobial and Other Properties of a New Stabilized Alkaline Glutaraldehyde Disinfectant/Sterilizer (병원에서 사용하는 수술도구 살균제, glutaraldehyde 용액의 살균 효과에 관하여)

  • 궁리환
    • YAKHAK HOEJI
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    • v.31 no.4
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    • pp.236-251
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    • 1987
  • The chemistry, antimicrobial properties, organic soil resistance, toxicity, corrosivity and chemical stability of stabilized alkaline 2%, glutaraldehyde solution(SGS) are discussed. SGS retains the maximum antimicrobial activity of alkaline glutaraldehyde solutions and the chemical stability here to fore observed only with acidic glutaraldehyde solutions. These improvements, along with the inherent resistance of glutaradehyde to neutralization by organic soil, allow SGS to be continuously used for 14 days in situations of high dilution, or 28 days in situations of low dilution.

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Chemical Changes of Dissolved Sulfur Dioxide In Vitro (In Vitro에서 $SO_2$ 수용액의 화학적 변화)

  • Lee, Mie-Soon;Lee, Su-Rae
    • Applied Biological Chemistry
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    • v.19 no.1
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    • pp.51-56
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    • 1976
  • Chemical changes of dissolved $SO_2$ were followed in vitro system. Varying concentrations of sulfite solution reached similar Eh values 20 hours after preparation. No further increase of Eh values occurred in acidic solutions. Eh values were more greatly increased in neutral solutions than in alkaline solutions, and slightly higher in light than in dark. The decrease of measurable $SO_2$ content tended to be greater with increasing concentrations of sulfite, on exposure to light, and at higher pH values. A larger amount of hydrogen atoms was produced with higher concentrations of $SO_2$ and in neutral to alkaline solutions than in acidic solutions.

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Effect of pH and Concentration on Electrochemical Corrosion Behavior of Aluminum Al-7075 T6 Alloy in NaCl Aqueous Environment

  • Raza, Syed Abbas;Karim, Muhammad Ramzan Abdul;Shehbaz, Tauheed;Taimoor, Aqeel Ahmad;Ali, Rashid;Khan, Muhammad Imran
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.213-226
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    • 2022
  • In the present study, the corrosion behavior of aluminum Al-7075 tempered (T-6 condition) alloy was evaluated by immersion testing and electrochemical testing in 1.75% and 3.5% NaCl environment at acidic, neutral and basic pH. The data obtained by both immersion tests and electrochemical corrosion tests (potentiodynamic polarization and electrochemical impedance spectroscopy tests) present that the corrosion rate of the alloy specimens is minimum for the pH=7 condition of the solution due to the formation of dense and well adherent thin protective oxide layer. Whereas the solutions with acidic and alkaline pH cause shift in the corrosion behavior of aluminum alloy to more active domains aggravated by the constant flux of acidic and alkaline ions (Cl- and OH-) in the media which anodically dissolve the Al matrix in comparison to precipitated intermetallic phases (cathodic in nature) formed due to T6 treatment. Consequently, the pitting behavior of the alloy, as observed by cyclic polarization tests, shifts to more active regions when pH of the solutions changes from neutral to alkaline environment due to localized dissolution of the matrix in alkaline environment that ingress by diffusion through the pores in the oxide film. Microscopic analysis also strengthens the results obtained by immersion corrosion testing and electrochemical corrosion testing as the study examines the corrosion behavior of this alloy under a systematic evaluation in marine environment.

Separation and purification of elements from alkaline and carbonate nuclear waste solutions

  • Alexander V. Boyarintsev ;Sergei I. Stepanov ;Galina V. Kostikova ;Valeriy I. Zhilov;Alfiya M. Safiulina ;Aslan Yu Tsivadze
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.391-407
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    • 2023
  • This article provides a survey of wet (aqueous) methods for recovery, separation, and purification of uranium from fission products in carbonate solutions during the reprocessing of spent nuclear fuel and methods for removal of radionuclides from alkaline radioactive waste. The main methods such as selective direct precipitation, ion exchange, and solvent extraction are considered. These methods were compared and evaluated for reprocessing of spent nuclear fuel in carbonate media according to novel alternative non-acidic methods and for treatment processes of alkaline radioactive waste.

Surface Texturing and Anti-Reflection Coating of Multi-crystalline Silicon Solar Cell (다결정 실리콘 태양전지의 표면 텍스쳐링 및 반사방지막의 영향)

  • Jun, Seong-Uk;Lim, Kyung-Muk;Choi, Sock-Hwan;Hong, Yung-Myung;Cho, Kyung-Mox
    • Journal of the Korean institute of surface engineering
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    • v.40 no.3
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    • pp.138-143
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    • 2007
  • The effects of texturing and anti-reflection coating on the reflection properties of multi-crystalline silicon solar cell have been investigated. The chemical solutions of alkaline and acidic etching solutions were used for texturing at the surface of multi-crystalline Si wafer. Experiments were performed with various temperature and time conditions in order to determine the optimized etching condition. Alkaline etching solution was found inadequate to the texturing of multi-crystalline Si due to its high reflectance of about 25%. The reflectance of Si wafer texturing with acidic etching solution showed a very low reflectance about 10%, which was attributed to the formation of homogeneous. Also, deposition of ITO anti-reflection coating reduced the reflectance of multi-crystalline si etched with acidic solution($HF+HNO_3$) to 2.6%.

A Study on the Dyeing of Polyester Fiber in Alkaline Dyebath ―Dyeing Properties of Disperse dyes According to variation of pH values― (폴리에스테르섬유의 알칼리욕염색에 관한 연구 -pH변화에 따른 분산염료의 염색성을 중심으로-)

  • Sung, Woo Kyung;Ryu, Ki Hyo;Park, Soo Min;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.34-42
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    • 1996
  • This Study was made to investigate alkaline dyeing systems for a new dyeing applicable polyester fibers. Disperse dyes for dyeing of polyester fibers were C.I. Red 60, Blue 56 and Yellow 54 as three primary colors of E type which used widely on the scene. Dyeing properties of dispers dyes on the polyester fibers are discussed according to variation of pH values for application of alkaline dyeing method compared with to ordinary acidic dyebath. Alkaline pH of the dyebath was controlled to pH 9 and 10.5 with buffer solutions using each hydrochloride and disodiumtetraborate, disodiumtetraborate and sodium hydroxide to promote the reproducibility of dyeing. Dyeing properties of dispers dyes on the polyester fibers by alkaline dyeing method compared with to ordinary acidic dyebath were discussed by estimation of color, wash-fastness, bleeding and migration of dyed polyester fabric.

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