• Title/Summary/Keyword: acid-resistance

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Multiple Polyamide Fiber Reinforced Shotcrete for Railway Tunnel Structure (철도 터널 구조물 시공을 위한 다발형 폴리아미드섬유 보강 숏크리트)

  • Jeon, Joong-Kyu;Chung, Jae-Min;Yoon, Ji-Hyun;Jeon, Chan-Ki
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.1214-1219
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    • 2011
  • Fiber reinforced shotcrete began to be used in tunnel constructions because it facilitates and expedites the construction process, and improves reinforcement properties. As one of the most widely used forms of shotcrete used in tunneling, steel fiber reinforced shotcrete offers excellent strength and ductility and allows quick reinforcement. However, steel fibers tend to lump together in cement matrix, and low levels of water and acid resistance cause corrosion in steel fiber, resulting in cracks and delamination. In particular, rebound and backlash of steel fiber is significantly increased during steel fiber reinforced shotcrete construction, compromising the flexural toughness and quality of shotcrete. In order to resolve the problems associated with steel fiber reinforced shotcrete and improve the application, durability, and cost-effectiveness of shotcrete, this paper proposes methods for manufacturing and constructing tunnels with multiple polyamide fiber reinforced shotcrete. We performed experiments to evaluate the performance of the proposed shotcrete, and the experimental results indicate that the multiple polyamide fiber reinforced shotcrete proposed in this paper offers outstanding performance that meets various construction design criteria.

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Evaluation of Long-Term Performance of Concrete Blended with Industrial Waste(Oyster Shell) (산업폐기물(굴패각)을 혼입한 콘크리트의 장기성능 평가)

  • 김학모;양은익;이성태;정용일;최중철
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.227-232
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    • 2002
  • To evaluate the practical application of oyster shells as construction materials, an experimental study was performed. More specifically, the long-term mechanical properties and durability of concrete blended with oyster shells were investigated. Test results indicate that long-term strength of concrete blended with 10% oyster shells is almost identical to that of normal concrete. However, the long-term strength of concrete blended with 20% oyster shells Is appreciably lower than that of normal concrete. 1'hereby, concrete with higher oyster shell has the possibility giving a bad influence on the concrete long-term strength. Elastic modulus of concrete blended with crushed oyster shells decreases as the blending mixture ratio increases. Namely, the modulus is reduced by approximately 10∼15% when oyster shells are blended up to 20% replacing the fine aggregate. The drying shrinkage strain increases as the blending ratio increases. In addition, the existing model code of drying shrinkage does not coincide with the test results of this study. An adequate prediction equation needs to be developed. The utilization of oyster shells as the fine aggregate in concrete has an insignificant effect on freezing and thawing resistance, carbonation and sulfuric acid attack of concrete recycling. However, water permeability is considerably improved.

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Synthesis of Co(II), Ni(II) and Cu(II) Complexes from Schiff base Ligand and Reactivity Studies with Thermosetting Epoxy Resin

  • Lakshmi, B.;Shivananda, K.N.;Prakash, Gouda Avaji;Rama, Krishna Reddy K.;Mahendra, K.N.
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1613-1619
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    • 2011
  • A hybrid thermosetting maleimido epoxy compound 4-(N-maleimidophenyl) glycidylether (N-MPGE) containing Co(II), Ni(II) and Cu(II) ions was prepared by curing N-MPGE and tetradentate Schiff base Co(II), Ni(II) and Cu(II) complexes. The curing polymerization reaction of N-MPGE with metal complexes as curing agents was studied. The cured samples were studied for thermal stability, chemical (acid/alkali/solvent) and water absorption resistance and homogeneity of the cured systems. The tetradentate Schiff base, 3-[(Z)-2-piperazin-1-yl-ethylimino]-1,3-dihydro indol-2-one was synthesized by the condensation of Isatin (Indole-2, 3-dione) with 1-(2-aminoethyl)piperazine (AEP). Its complexes with Co(II), Ni(II) and Cu(II) have been synthesized and characterized by microanalysis, conductivity, Uv-Visible, FT-IR, TGA and magnetic susceptibility measurements. The spectral data revealed that the ligand acts as a neutral tetradentate Schiff base and coordinating through the azomethine nitrogen, two piperazine nitrogen atoms and carbonyl oxygen.

Impact of transgenic AFPCHI (Cucumis melo L. Silver Light) fungal resistance melon on soil microbial communities and enzyme activities

  • Bezirganoglu, Ismail;Uysal, Pinar
    • Journal of Plant Biotechnology
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    • v.44 no.2
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    • pp.156-163
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    • 2017
  • A greenhouse experiment was conducted for evaluation of ecological effects of transgenic melon plants in the rhizospheric soil in terms of soil properties, enzyme activities and microbial communities. Organic matter content of soil under transgenic melon plants was significantly higher than that of soil with non-transgenic melon plants. Significant variations were observed in organic matter, total P and K in soil cultivation with transgenic melon plants. There were also significant variations in the total numbers of colony forming units of fungi, actinomycetes and bacteria between soils treated with transgenic and non-transgenic melon plants. Transgenic and non-transgenic melon significantly enhanced several enzymes activities including urease, acid phosphatase, alkalin phosphatase, arysulphtase, ${\beta}$ glucosidase, dehydrogenase, protease and catalase. Soil polyphenoloxidase activity of $T_1$ transgenic melon was lower than that of $T_0$ transgenic melon and a non-melon plant during the same period. The first generation transgenic melon plants ($T_0$) showed significantly greater (p<0.05) effect on the activitiy of arylsulfatase, which increased from $2.540{\times}10^6CFU\;g^{-1}$ (control) to $19.860{\times}10^6CFU\;g^{-1}$ ($T_0$). These results clearly indicated that transgenic melon might change microbial communities, enzyme activities and soil chemical properties.

Effect of centrifugation on the structure and properties of silk sericin

  • Park, Chun Jin;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.33 no.2
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    • pp.144-148
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    • 2016
  • Recently, silk sericin has been studied extensively for biomedical and cosmetic applications because of its unique properties, including UV resistance and wound healing ability. For use in applications, sericin is fabricated in various forms including films and gels. However, the mechanical properties of sericin are too weak. In this basic study on improving the mechanical properties of sericin, a silk sericin aqueous solution was separated into two layers by centrifugation. The solution viscosity, molecular conformation, and mechanical properties of each separation layer of the sericin were examined. Sericin from the lower layer had a higher solution viscosity and film mechanical properties (strength and strain) than that from the upper layer, implying that sericin from the lower layer had a higher molecular weight than that from the upper layer. The molecular conformation of the sericin films varied depending on the casting solvent. In aqueous solution, the sericin film from the lower layer showed a ${\beta}$-sheet conformation, whereas that from the upper layer displayed a random coil conformation. All the sericin films showed a highly ${\beta}$-sheet-crystallized state when cast in formic acid, regardless of the separation layer.

Strength and Durability of Mortar Made with Plastics Bag Waste (MPBW)

  • Ghernouti, Youcef;Rabehi, Bahia
    • International Journal of Concrete Structures and Materials
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    • v.6 no.3
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    • pp.145-153
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    • 2012
  • The aim of this study is to explore the possibility of re-cycling a waste material that is now produced in large quantities, while achieving an improvement of the mechanical properties and durability of the mortar. This study examines the mechanical properties and the durability parameters of mortars incorporating plastics bag wastes (PBW) as fine aggregate by substitution of a variable percentage of sand (10, 20, 30 and 40 %). The influence of the PBW on the, compressive and flexural strength, drying shrinkage, fire resistance, sulfuric acid attack and chloride diffusion coefficient of the different mortars, has been investigated and analyzed in comparison to the control mortar. The results showed that the use of PBW enabled to reduce by 18-23 % the compressive strength of mortars containing 10 and 20 % of waste respectively, which remains always close to the reference mortar (made without waste). The replacement of sand by PBW in mortar slows down the penetration of chloride ions, improves the behavior of mortars in acidic medium and improves the sensitivity to cracking. The results of this investigation consolidate the idea of the use of PBW in the field of construction.

The Korean Traditional Anti-obesity drug Gyeongshingangjeehwan Stimulates $AMPK{\alpha}$ Activation in Skeletal Muscle of OLETF Rats

  • Shin, Soon-Shik;Yoon, Mi-Chung
    • Biomedical Science Letters
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    • v.17 no.4
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    • pp.273-281
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    • 2011
  • Our previous study demonstrated that the Korean traditional medicine Gyeongshingangjeehwan (GGEx) inhibits obesity and insulin resistance in obese type 2 diabetic Otsuka Long-Evans Tokushima Fatty (OLETF) rats. We investigated whether GGEx may affect AMP-activated protein kinase ${\alpha}$ ($AMPK{\alpha}$) since $AMPK{\alpha}$ activation is known to stimulate fatty acid oxidation in skeletal muscle of obese rodents. After OLETF rats were treated with GGEx, we studied the effects of GGEx on $AMPK{\alpha}$ and acetyl-CoA carboxylase (ACC) phosphorylation, and the expression of $AMPK{\alpha}$, $PPAR{\alpha}$, and $PPAR{\alpha}$ target genes. The effects of GGEx on mRNA expression of the above genes were also measured in C2C12 skeletal muscle cells. Administration of GGEx to OLETF rats for 8 weeks increased phosphorylation of $AMPK{\alpha}$ and ACC in skeletal muscle. GGEx also elevated skeletal muscle mRNA levels of $AMPK{\alpha}1$ and $AMPK{\alpha}2$ as well as $PPAR{\alpha}$ and its target genes. Consistent with the in vivo data, similar activation of genes was observed in GGEx-treated C2C12 cells. These results suggest that GGEx stimulates skeletal muscle $AMPK{\alpha}$ and $PPAR{\alpha}$ activation, leading to alleviation of obesity and related disorders.

Studies on Salmonella isolated from chicks (초생추 유래 Salmonella속균의 생물학적 특성)

  • Oh, Gang-hee;Choi, Won-pil
    • Korean Journal of Veterinary Research
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    • v.34 no.3
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    • pp.501-510
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    • 1994
  • This paper deals with the distribution, reservoir and mode of spread of infection on 6 hatcheries in Taegu, Kyungpook and 5 broiler farms in Kyungpook during the period from June 1991 to June 1992. Isolated Salmonella were examined for serotypes, biotyping of Salmonella(S) typhimurtum, antibiotic susceptibility and some biochemical characteristics. Forty two Salmonella strains were isolated from 42(2.7% of 1,577 caecal samples of chicks, and their serotypes were S typhimurium 10, S typhimurium var Copenhagen 5, S infantis 4, S thompson 3, and untypable 20. The isolation rate of Salmonella varied from 0 to 5.1% in 6 hatcheries and that of Salmonella from 5 broiler farms was 10. 5%. Biotypes of 10 S typhimurium and 5 S typhimurium var Copenhagen strains isolated from chicks of hatcheries and broiler farms were biotype 2(86.6%), 8(6.7%), and 10a(6.7%), and 26i(6.7%) according to Duguid's scheme. Antibiotic susceptibility test of Salmonella isolated were performed by agar dilution method, using 9 antibiotics as follows: ampicillin(Am), chloramphenicol(Cm), gentamicin(Gm), kanamycin(Km), nalidixic acid(Na), rifampicin(Rf), streptomycin(Sm), sulfadimethoxine(Su), and tetracycline(Tc), All the strains were sensitive to RF. But 8 strans(23.8%) were resistant to one or more drugs and the most common resistance patterns of transferred R plasmids were SmSuGm and SmSu. Among 42 isolates, one had transferable citrate utilizing plasmid. S typhimurium and S typhimurium var copenhagen strains were resistant to killing by 90% normal guinea pig serum.

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Effect of MWCNTs/PSf support layer on the performance of polyamide reverse osmosis membrane (탄소나노튜브가 첨가된 폴리술폰 지지체가 폴리아미드 역삼투막의 성능에 미치는 영향)

  • Min, Choong-Sik;Kim, Seung-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.2
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    • pp.127-137
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    • 2020
  • In this study, a MWCNT(multi-wall carbon nanotube) was added to polysulfone(PSf) support layer to improve flux of TFC(thin film composite) RO(reverse osmosis) membrane. Two different kinds of MWCNT were used. Surfaces of some MWCNTs were modified hydrophilically through acid treatment, while those of other MWCNTs were modified through heat treatment to maintain their hydrophobicity. MWCNT/PSf support layer was prepared by adding PSf to the NMP mixed solvent containing 0.1 wt% MWCNTs using a phase inversion method. The surface porosity of the MWCNT/PSf support increased by 42~46% while its surface pore size being maintained. The TFC RO membrane made of MWCNT/PSf support layer showed a 20% flux increase while its salt rejection characteristics is sustained. In addition, the MWCNT/PSf support layer has better mechanical stability than the PSf support layer, there resulting in an increased resistance of flux reduction due to physical pressure.

Selection of Environmental Friendly Organic Agricultural Materials for Controlling Ginseng Gray Mold (인삼 잿빛곰팡이병의 친환경방제를 위한 유기농업자재 선발)

  • Kim, Woo Sik;Kim, Jong Seong;Park, Jee Sung;Ahn, In;Park, Kyung Hoon;Kim, Ki Hong
    • Korean Journal of Medicinal Crop Science
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    • v.23 no.6
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    • pp.473-479
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    • 2015
  • Background : To control ginseng gray mold, farmers have mainly used inorganic chemical based fungicides. The recent emergence of fungicide resistance has reduced the effectiveness of such control methods. Such pesticides also carry additional problems, such as diffuse pollution. Methods and Results : Six treatments of organic agricultural materials were tested for control of ginseng gray mold, CAPW (Chrysophanic acid + Phytoncide + Wood vinegar), EmEWV (Emodin + Ethanol + Wood vinegar), CEWV (Curcumin + Eugenol + Wood vinegar), Bacillus subtilis, soybean oil and sulfur. The control effect for gray mold by a single application of the agrochemical fungicide industrial Fenhexamid wettable powder (WP) was 84.4%. The control effect by CAPW, EmEWV and CEWV varied between 52.7 - 64.9%. The control effect by B. subtilis, soybean oil, and sulfur were 32.9 - 59.2%. Conclusions : In the field tests, CAPW showed the highest control effects when used before, and at first stage of disease incidence, against ginseng gray mold.