• Journal of the Korean Chemical Society
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• v.65 no.1
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• pp.37-47
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• 2021

In this study, the model cognition level of high school science-gifted students about the two types of acid-base models taught in secondary schools was analyzed. In order to find out the model cognition level of students, 12 items were developed based on the acid-base reaction and the dissociation reaction of acids and bases. The subjects of the study were 95 students of two science-gifted schools. As a result of the questionnaire analysis, model cognition levels were analyzed 6 levels in the context of consistency, inconsistency, and unexplainable scope of the two models. In the acid-base reaction item, the largest percentage of students cognized only understanding of the two models. In the acid-base dissociation reaction item, they understood the two models and perceived the 'Known Ignorance' that cognizes the limitations of one model. However, there was only one student who perceived the limitations of both models and all of the 'Unknown Ignorance' that the model could not explain. Through this, we argued that there is a need for educational efforts to raise the model cognition level of science-gifted students.

• Journal of the Korean Chemical Society
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• v.63 no.1
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• pp.56-65
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• 2019

This study investigated the perceptions of the relationship among the three acid-base models of chemistry teachers. In addition, we examined how the perception of the relationship between models affected on the interpretation of concepts in each model. To investigate teachers' perceptions and interpretations, a questionnaire and interviews were conducted for 24 chemistry teachers. As results, most of the chemistry teachers recognized the three models as cumulative extension relationships. The perceptions were related to the contents of textbooks. The perception of the relationship of these models influenced on interpretations of the models' acid-base concept. In this study, we suggested that science teachers need to be aware of diverse models' roles.

• Journal of the Korean Chemical Society
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• v.64 no.5
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• pp.267-276
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• 2020

This study analyzed the level of chemistry teachers' cognition related to two types of acid-base models taught in secondary schools. For the purpose, a questionnaire was developed to identify teachers' cognitions based on previous studies that analyzed the 'Ignorance' of each model. The questionnaire consisted of two items, one related to acid and base reactions and one related to acid and base dissociation, which suggested inconsistencies between the two models. The subjects were 15 chemistry teachers, and as a result, teachers' cognitions were analyzed at four levels. The four levels are: if they don't know the two models, if they only understand one model, if they understand the two models, and perceived the 'Ignorance' of one model, and if they understand the two models and perceived the 'Ignorance' of the two models. The largest proportion of teachers understood the two models and perceived the 'Ignorance' of one model. However, the proportion of understanding the two models and perceiving the 'Ignorance' of the two models was very small. Through this, we argued that efforts to increase the level of chemistry teachers' cognition of the model and 'Ignorance' were necessary.

• Journal of Korean Society of Forest Science
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• v.90 no.1
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• pp.133-138
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• 2001

Increased base cation loss and Al mobilization, a consequence of soil acid neutralization responses, are common in air polluted areas showing forest decline. The prediction models of acid neutralization responses were developed by using indicators of soil acidification level(pH, and base saturation) in order to assess the forest soil sensitivity to acidification. The soil acidification level was greatest in Namsan followed by Kanghwa, Ulsan, and Hongcheon, being contrary to regional total $ANC_H$ pattern through soil columns leached with additional acid ($16.7mmol_c\;H^+/kg$), Both base exchange and Al dissolution were main acid neutralization processes in all study regions. There were low base exchange and high Al dissolution in the regions of the low total $ANC_H$. The $ANC_M$ by sulfate adsorption was greatest in Hongcheon compared with other regions even though the AN rate was very low as 6.4%. Coefficients of adjusted determination of simple and multiple regression models between soil acidification level indicators and the acid neutralization responses were more than 0.52(p<0.04) and 0.89(p<0.01), respectively. The result suggests that soil pH and base saturation are available indicators for predicting the acid neutralization responses. These prediction models could be used as an useful method to measure forest soil sensitivity to acidification.

• Journal of the Korean Chemical Society
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• v.64 no.1
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• pp.30-37
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• 2020

The purpose of this study was to identify the problems faced by students in sub-microscopic representation of acid-base reactions. Herein, we selected 30 students of 12^th grade science classes, who had studied various acid-base models. In order to investigate the sub-microscopic representation ability of the students, we developed nine items related to various contexts, such as one type of solute and solvent, two types of solutes and solvent, cases with water as solvent or with nonaqueous solvents. For all items, we consistently observed lack of concept of chemical change. In context of aqueous and nonaqueous solutions, the frequency of lack of concept of chemical bonding was high if ammonia was the solute or solvent. Moreover, the frequency of lack of concept related to the degree of electrolytic dissociation was high. Therefore, chemistry teachers should understand that students' ability to sub-microscopic representation of acid-base reactions can be enhanced by analyzing the difficulties faced by the students in solving diverse acid-base problems.

• Journal of the Korean Chemical Society
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• v.64 no.1
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• pp.19-29
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• 2020

We analyzed the representations of acid-base models in 4 kinds of Chemistry I and 4 kinds of Chemistry II textbooks of the 2009 revised curriculum, and 9 kinds of Chemistry I textbooks and 6 kinds of chemistry II textbooks of the 2015 revised curriculum in this study. The problems of the textbook were divided into the problems of definitions and the representations of the logical thinking. As a result of the study, the lack of the concept of chemical equilibrium had a problem with the representation of reversible reactions in the definition of the Brønsted-Lowry model in the Chemistry I textbooks of 2009 revised curriculum, it also appeared to persist in Chemistry I textbooks of 2015 revised curriculum which contains the concept of chemical equilibrium. The representations of logical thinking were related to particle kinds of conservation logic, combinational logic, particle number conservation logic, and proportion logic. There were few problems related to representation of logical thinking in Chemistry I textbook in 2009 revision curriculum, but more problems of representations related to logics are presented in Chemistry I textbooks in 2015 revision curriculum. Therefore, as the curriculum is revised, the representations of chemistry textbooks related to acid and base models need to be changed in a way that can help students' understanding.

• Carbon letters
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• v.6 no.3
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• pp.141-147
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• 2005

The carbon sample "O", phosphoric acid-activated carbon "OP", zinc chloride-activated carbon "OZ", and two steam activated carbons "OS" and "OS2" with different burn-off of 25% and 58% respectively, were prepared from olive stones. The textural properties were determined from the results of nitrogen adsorption at 77 K and by analyzing these results through the application of different adsorption models. The chemistry of the carbon surfaces was determined from the base neutralization capacities, acid neutralization capacity and surface pH. The sorption of $Pb^{2+}$ ions on to the carbons prepared was followed under dynamic and equilibrium conditions. The differences between the values of the textural parameters were attributed to the inapplicability of some adsorption models and to the heterogeneity of the microporous carbons. The sorption of $Pb^{2+}$ ions is favored on carbon and activated carbons. However, chemically activated carbons are more effective compared with steam-activated ones. The sorption of $Pb^{2+}$ ions were related to the chemistry of the surface rather than to the textural properties.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.3 no.2
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• pp.146-155
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• 2002

Surface complexation models employ mass law equations to describe the reaction of surface functional groups with ions in the solution and also Gouy-Chapman theory to consider the electrostatic effects in the surface reactions. In current surface complexation models, however, the coulombic factors used are not wholly consistent with the Gouy-Chapman model of the surface. This study was to provide the derivation of the coulombic term usually employed and then a revised coulombic term completely consistent with Gouy-Chapman Theory. The electrical potential energy. zF${\psi}$, in current surface complexation models is not consistent with the Gouy-Chapman theory with the potential gradient close to the charged surface but with the Donnan model with the uniform potential. Even though the new coulombic factor yielded lower surface potential, it provided worse fits for acid-base titration data of the goethite suspensions.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.3
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• pp.205-211
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• 2005

Water-soluble polyethyleneimine (PE) derivatives containing nucleic acid bases and hydrophilic amino acids such as homoserine (Hse) and serine were prepared by the activated ester method as nucleic acid models. From spectroscopic measurements, the polymers were found to interact with DNA accompanied by an induction of conformational change. Hypochromicity in UV spectra indicated that a stable polymer complex was formed between poly (A) with PEI­Hse-Ura by complementary hydrogen bonding with equimolar nucleic base units (adenine:uracil=1:1). The induced conformation of DNA by the interaction with the polymer containing uracil and homoserine (PEI-Hse-Ura) was concluded to be a super triple helical structure. The formation of the polymer complex, DNA: PEI-Hse-Ura, was found to be affected by the presence of metal ions such as $Ca^{2+}\;and\;Cu^{2+}$.

• Preventive Nutrition and Food Science
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• v.21 no.2
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• pp.104-109
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• 2016

In the current study, we investigated the longitudinal association between dietary acid load and the risk of insulin resistance (IR) in the Tehranian adult population. This longitudinal study was conducted on 925 participants, aged 22~80 years old, in the framework of the third (2006~2008) and fourth (2009~2011) phases of the Tehran Lipid and Glucose Study. At baseline, the dietary intake of subjects was assessed using a validated semi-quantitative food frequency questionnaire, and the potential renal acid load (PRAL) and net endogenous acid production (NEAP) scores were calculated at baseline. Fasting serum insulin and glucose were measured at baseline and again after a 3-year of follow-up; IR was defined according to optimal cut-off values. Multiple logistic regression models were used to estimate the risk of IR according to the PRAL and NEAP quartile categories. Mean age and body mass index of the participants were 40.3 years old of $26.4kg/m^2$, respectively. Mean PRAL and NEAP scores were -11.2 and 35.6 mEq/d, respectively. After adjustment for potential confounders, compared to the lowest quartile of PRAL and NEAP, the highest quartile was accompanied with increased risk of IR [odds ratio (OR)=2.81, 95% confidence interval (CI)=1.32~5.97 and OR=2.18, 95% CI=1.03~4.61, respectively]. Our findings suggest that higher acidic dietary acid-base load, defined by higher PRAL and NEAP scores, may be a risk factor for the development of IR and related metabolic disorders.