• Title/Summary/Keyword: acid dissolution

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A Study on the Dissolution of Aluminum Hydroxide with Mineral and Organic Acid (Aluminum Hydroxide의 유무기산(有無機酸)에 의한 용해특성(溶解特性) 연구(硏究))

  • Lee, Hwa-Young
    • Resources Recycling
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    • v.18 no.2
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    • pp.56-61
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    • 2009
  • The dissolution of domestic aluminum hydroxide of 99.7% purity has been performed with mineral and organic acid prior to the synthesis of aluminum compounds from aluminum solution. Mean particle size of aluminum hydroxide used in the work was $14.4{\mu}m$, $22.9{\mu}m$ and $62.3{\mu}m$, respectively and the effect of reaction temperature, concentration of acid and reaction time on the dissolution of aluminum hydroxide has been examined. As a result, the dissolution of aluminum hydroxide was increased with the concentration of HCl and more than 70% dissolution was obtained with 5 mole/l HCl at $70^{\circ}C$ for reaction time of 4 hr. As far as the dissolution of aluminum hydroxide with sulfuric acid was concerned, it was found that the optimum concentration of sulfuric acid was about 6 mole/l for the effective dissolution of aluminum hydroxide. When oxalic acid was used for the dissolution of aluminum hydroxide, nearly complete dissolution could be obtained by the dissolution for 16 hr with 1.0 mole/l oxalic acid at $90^{\circ}C$.

Effect of Surfactants on Dissolution Rate of Mefenamic Acid Capsules (메페남산 캅셀의 용출에 미치는 계면활성제의 영향)

  • Jun, Young-Bin;Kim, Seung-In;Kim, Young-Il
    • Journal of Pharmaceutical Investigation
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    • v.20 no.3
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    • pp.121-127
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    • 1990
  • Mefenamic acid has been widely used clinically as an anti-inflammatory analgesic. It has poor solubility in water $(41\;{\mu}g/ml)$ and there is the difficulty of dissolution in the mefenamic acid capsules. A study was made to investigate the effect of various surfactants on the dissolution of mefenamic acid capsules. The surfactants used were sodium lauryl sulfate (SLS), Pluronic F-68, F-77, and F-127. Mefenamic acid capsule containing surfactant showed significantly improved dissolution characteristics. The dissolution rate was fast in the order of SLS > F-77 > F-68 > F-127 in mefenamic acid capsules containing 0.2 w/w % surfactant. SLS was selected for further study on the bioavailability in rabbits. The area under the plasma concentration-time curve $(AUC_{0-24})$ of mefenamic acid capsule containing SLS was higher than one of mefenamic acid capsule not containing surfactant.

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Improvement of Dissolution Rate of Mefenamic Acid by Roll Mixing with Sodium Lauryl Sulfate (라우릴황산나트륨과의 Roll 혼합에 의한 메페남산의 용출성 개선)

  • Park, Seong-Yeon;Seo, Seong-Hoon
    • Journal of Pharmaceutical Investigation
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    • v.22 no.4
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    • pp.307-315
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    • 1992
  • Dissolution rate of practically insoluble mefenamic acid was improved by roll mixing with sodium lauryl sulfate (SLS) or polyvinylpyrrolidone (PVP). The dissolution rate of the drug roll mixtures with SLS was superior to that of roll mixtures with PVP. The maximal dissolution rate was found in the roll mixtures system with SLS content of 60%. The dissolution rate of mefenamic acid roll mixtures with SLS content of 60% reached to the maximum value after 10 min of roll mixing. The transport of roll mixtures with SLS across rat jejunum was studied by the perfusion method using everted rat jejunum in vitro. The absorption rate of roll mixtures was superior to that of mefanamic acid.

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The Effect on Copper Dissolution from Copper Cookware by Acid Condiments (구리냄비의 구리용출에 미치는 산성조미료의 영향)

  • ;;;;南出隆久
    • Journal of the East Asian Society of Dietary Life
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    • v.10 no.3
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    • pp.239-244
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    • 2000
  • Effects of acetic acid, malic acid and citric acid on copper dissolution from new and used copper saucepans at different concentrations (0, 0.02. 0.04, 0.1 0.2, 0.4, 1.0, 2.0, 4.0%), different boiling times (0,10, 20. 30, 40, 50, 60mins.), and different temperatures (5, 20, 40, 60, 80, 10$0^{\circ}C$ ) were investigated. As acetic acid concentration increases, copper content increases. Copper dissolution concentration from copper saucepans at boiling in malic acid increases more than in acetic acid or citric acid. At above 6$0^{\circ}C$, as the temperature increases, the concentration of copper dissolved from copper saucepans also increases. As boiling time increases, the concentration of copper dissolved from copper saucepans also increases. In addition, through repeated use, the concentration of copper increases as well. And copper concentration dissolves in large amounts from used saucepans rather than new saucepans. The dissolution of copper with distilled water by repeated use does not dissolve at all. 1% acetic acid dissolves in large quantities.

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Dissolution of North Korean Magnesite by using Hydrochloric Acid

  • Baek, Ui-Hyun;Park, Hyungkyu;Lee, Jin-Young;Kang, Jungshin
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.711-717
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    • 2017
  • A fundamental study was conducted on the dissolution of North Korean magnesite using hydrochloric acid to understand the dissolution behavior of the magnesium and impurities. The influence of the acid concentration, particle size of the magnesite, reaction temperature, and pulp density on the dissolution of magnesium, iron, calcium, aluminum, and silicon dioxide was studied. The experimental results showed that 98.5% of magnesium, 86.9% of iron, 87.3% of calcium, 23.6% of aluminum, and 20.4% of silicon dioxide were dissolved when magnesite particle sizes within the range of $75{\sim}105{\mu}m$ were reacted using 3 M HCl solution under 6% pulp density at 363 K for 3 h. The residues that remained after the dissolution were silicon dioxide, talc, and clinochlore.

A clean technology development using the iron(Fe) dissolution reaction with hydrogen peroxide (과산화수소를 이용한 철(Fe)선 용해반응에 따른 청정기술 개발에 관한 연구)

  • 김재우
    • Journal of environmental and Sanitary engineering
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    • v.16 no.4
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    • pp.62-68
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    • 2001
  • The advantages of hydrogen peroxide dissolution method were no discharge of noxious matter when dissolution of iron wire which used as the center supporter, reactions occur in room temperature and easy to recover dissolved iron. This study was aimed at gathering the basic data of iron wire dissolution- recovery process and proposes the reaction condition of iron wire dissolution- recovery process rind the factors influencing those reactions. The results were as follows : 1 . Hydrogen peroxide dissolution method used hydrochloric acid as the catalyst. 1. In the dissolution of iron wire(1.668 g), the condition of reaction was E1702(30 ml), HCI(20 ml) and $H_2O$(200 ml) ; time of the reaction was 18 min. P.W.(Piece weight) was 7.75 mg, and C.R. was $2.34{\;}{\Omega}$ 2. In the dissolution of iron wire(1.529 g), the condition of reaction was H7O2(30 ml), HCI(20 ml) and $H_2O$(200 ml), time of the reaction was 21 min., P.W.(Piece weight) was 7.73 mg, and C.R. was $2.35{\;}{\Omega}$. Hydrogen peroxide dissolution method used sulfuric acid as the catalyst. 1. In the dissolution of iron wire(0.834 g), the condition of reaction was $H_2O$(65 ml), $H_2SO_4$(5 ml) and 1702(5 ml) ; time of the reaction was 5 min.30 sec, P.W.(Piece weight) was 7.74 mg, and C.R. was $2.33{\;}{\Omega}$ 2. In the dissolution of iron wire(1.112 g), the condition of reaction was $H_2O$(65 ml), $H_2SO_4$(5 ml) and $H_2O_2$(5 ml) ; time of the reaction was 4 min.30 sec, P.W.(Piece weight) was 7.75 mg, and C.R. was $2.33{\;}{\Omega}$. Hydrogen peroxide dissolution method used hydrochloric acid and sulfuric acid as the catalyst confirmed a clean technology, because there were not occurred a pollutant discharged in the existing method.

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Effects of Limestone on the Dissolution of Phosphate from Sediments under Anaerobic Condition (혐기성 퇴적물에서 석회석이 인산염용해에 미치는 영향)

  • Kim, Hag Seong;Park, Juhyun
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.81-86
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    • 2007
  • This paper describes a study on the role of limestone which might affect the dissolution of phosphates when phosphate containing sediments are put under anaerobic conditions. A small quantity of calcium hydroxy-apatite, alone or mixed with limestone powder, was put in contact with aqueous solution of acetic acid or carbonic acid, and variations of phosphate concentration were determined time dependantly. The results showed that the concentration was remarkably low in the presence of limestone, signifying that the coexistence of limestone suppresses the dissolution of phosphate by organic acid and/or carbonic acid. Separate experiments conducted by developing an anaerobic condition, after mixing lake sediments with dried leaves and limestone, showed that the existence of limestone suppressed the dissolution of phosphate. These results show that the application of limestone might be a useful measure to prevent deterioration of water quality originated from eutrophication by inhibiting the internal loading of P in eutrophic water-bodies.

Removal of Uranium from U-bearing Lime-Precipitate using dissolution and precipitation methods (우라늄 함유 석회침전물의 용해 및 침전에 의한 U 제거)

  • Lee, Eil-Hee;Lee, Keun-Young;Chung, Dong-Yong;Kim, Kwang-Wook;Lee, Kune-Woo;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.2
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    • pp.77-85
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    • 2012
  • This study was carried out to remove (/recover) the uranium from the Uranium-bearing Lime Precipitate (ULP). An oxidative dissolution of ULP with carbonate-acidified precipitation and a dissolution of ULP with nitric acid-hydrogen peroxide precipitation were discussed, respectively. In point of view the dissolution of uranium in ULP, nitric acid dissolution which could dissolved more than 98% of uranium was more effective than carbonate dissolution. However, in this case, uranium was dissolved together with a large amount of impurities such as Al, Ca, Fe, Mg, Si, etc. and some impurities were also co-precipitated with uranium during a hydrogen peroxide precipitation. On the other hand, in the case of carbonate dissolution-acidified precipitation, U was dissolved less than 90%. Therefore, it was less effective than nitric acid dissolution for the volume reduction of radioactive solid waste. However, it was very effective to recover the pure uranium, because impurities were hardly dissolved and hardly co-precipitated with uranium.

토양 제염에 있어서 magnetite 용해 거동 연구

  • 원휘준;김민길;김계남;박진호;오원진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.393-396
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    • 2003
  • Soil contains the several kinds of metal oxides. Magnetite in soil may contribute the generation of secondary waste during the decontamination of soil by citric acid. Dissolution of magnetite powders by citric acid was investigated in the pH range between 2.0 and 5.0. The dissolution behaviour of magnetite was well described by the equation, A[1 - $e^{-B(x-c)}$]. The parameters of the equation were optimized by the iteration method, and the physical meaning of each parameter was explained. Concentration of each of the dissociated chemical species of citric acid was calculated using the ionization constants. The dissolution reaction was explained by the concentration of the dissociated chemical species of citric acid.d.

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Anti-gelling Effect of Poly(methacrylic acid, methyl methacrylate) on Cefuroxime Axetil Composition

  • Shim, Ji-Yeon;Wang, Hun-Sik;Kwon, Min-Chang;Park, Jun-Sang
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.237.1-237.1
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    • 2003
  • Cefuroxime axetil, a broad spectrum antibiotic, has been known to form a gelatinous mass in contact with aqueous media, which could lead to poor dissolution. Therefore, this study was conducted for removing the gelling phenomenon and thereby obtaining a favorable dissolution profile. We have found that the addition of poly (methacrylic acid, methyl methacrylate) could not only inhibit the tendency of cefuroxime axetil to form a gel but also showed the good dissolution profile compared to the formula without poly (methacrylic acid, methyl methacrylate). (omitted)

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