• Journal of the Korean Ceramic Society
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• v.40 no.7
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• pp.683-689
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• 2003

The cylindrical ${\gamma}$-alumina pellets were prepared using amorphous alumina and pore generating agent. Its were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH, Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and HNO$_3$, and Fe(NO$_3$)$_3$.9$H_2O$ and HNO$_3$. The pellets thus were hydrothermally treated at 20$0^{\circ}C$ for 3 h in autoclave, and were investigated morphologies and changes of crystal pore characteristics, $N_2$ adsorption and desorption isotherms, active sites and mechanical strength etc. According to the preparation method, acicular platelet pseudo-boehmite crystals of 0.1~0.3 ${\mu}{\textrm}{m}$ size were transformed into acicular pseudo-boehmite cristals of 0.5~2 ${\mu}{\textrm}{m}$ size having the same crystal structure. When ${\gamma}$-alumina pellets were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and then were hydrothermally treated, pore volume between 100 $\AA$ and 1000 $\AA$ was increased from 0.34 ㏄/g to 0.86 ㏄/g, and the gap of $N_2$ adsorption and desorption hysteresis loop was decreased due to increasement of pore size. New active site that could adsorb the C-H functional group was created on the catalist. Also, mechanical strength of catalyst was increased from 1.06 ㎫ to 1.36 ㎫.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.9
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• pp.5743-5747
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• 2015

In this study, Fe-based bulk amorphous alloy powder manufactured using gas atomization fabrication was used for laser welding. the fracture behavior of welding layer were analyzed. Tensile test results show that the destruction occurred immediately after the elastic deformation, After plastic deformation of the substrate, the destruction occurred. The actual maximum tensile strength of the welding layer and the substrate are 959.9MPa and 220.4MPa. welding layer were each $485.5{\pm}21$ and $197.4{\pm}14$ to the substrate and the actual microhardness, The welding layer has very high hardness. The welding layer showed a very weak fine acicular structure. The base material was shown in the micro structure appear a coarse grain. SEM observations of the fracture after the tensile test. Fracture morphology of the base metal and the welding layer showed ductile fracture and brittle fracture, respectively.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.1398-1401
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• 2005

The nano/microstructure, the aging response (in T5 heat treatment), and the mechanical/tribological properties of the eutectic regions in squeeze-cast A356 alloy were investigated using nano/micro-indentation and mechanical scratching, combined wit optical microscopy and atomic force microscope(AFM). Most eutectic Si crystals in the A356 alloy showed a modified morphology as fine-fibers. The loading curve for the eutectic region was more irregular than that of the primary Al region due to the presence of various particles of varying strength. In addition, the eutectic region showed lower pile-up and higher elastic recovery than the primary Al region. The aging responses of the eutectic regions in the squeeze-cast A356 alloys aged at $150^{\circ}C$ for different times(0, 2, 4, 8, 10, 16, 24, 36 and 72 h) were investigated. As the aging time increased, acicular Si particles in the eutectic regions gradually came to a fine structure. Both Vickers hardness ($H_V$) and indentation ($H_{IT}$) test results showed almost the same trend of aging curves, and the peak was obtained at the same aging time of 10 h. A remarkable size-dependence of the tests was found. The friction coefficient for the eutectic region was lower than that for the primary Al region.

• Proceedings of the KWS Conference
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• 2010.05a
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• pp.30-30
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• 2010

고강도강의 용접성은 저온균열 저항성으로 대변되는데, TMCP강과 HSLA강 등이 개발되면서 고강도강의 저온균열저항성이 크게 향상되어 무예열 용접성이 확보되었다. 그러나 용접재료 측면에서는 그에 상응하는 재료의 개발이 지연되어 강재 개발로 인한 우수한 성능을 충분히 발휘하지 못하고 있으며 용접부의 건전성 문제가 심각하게 인식되고 있다. 이로 인해 고강도강에 적용시킬 수 있는 무예열 용접재료의 필요성이 대두되어 개발이 진행되고 있으며 상용화를 앞두고 있다. 이러한 용접재료의 개발단계에서 합금설계는 가장 중요한 항목으로 합금 조성에 따라 용착금속의 강도 및 인성에 상당한 변화를 가져오기 때문이다. 합금원소 중 Al은 강재의 탈산을 돕기 때문에 가능한 많은 양의 첨가를 요구하지만 적정량 이상을 초과하게 되면 오히려 용착금속의 저온인성 특성에 부정적인 영향을 미치게 된다. 본 연구에서는 고강도 GMA 용착금속의 Al함량을 단계적으로 변화시켜 용착금속 내 최적의 Al의 함량을 찾고자 하였다. 또한 높은 비용 및 많은 시간을 필요로 하는 와이어로드를 제작하지 않고도 Al함량을 조절 할 수 있는 방법을 고안하고자 하였다. 실험의 모재는 HSLA-100강을 사용하였으며 용접재료는 ER120S-G급의 GMA용접 재료를 사용하였다. 모재 성분과의 희석을 방지하기 위해 V-Groove 가공 후 6패스 Buttering 용접을 실시하였고, 다시 Buttering용접부에 V-Groove 가공을 하여 최종 용접을 실시하였다. 이 때 Al함량을 조절하기 위해 최종 용접 개선부 밑면에 홈을 판 후 Al fiber(직경 0.3mm)를 깔고 용접(입열량 20kJ/cm)하여 Al함유량을 총 3가지(0.003~0.04% Al)로 제어하였다. 용접 후 각각의 시편에 대해 미세조직, 충격시험, O/N분석, 성분분석 등의 시험을 수행하여 저온인성과의 상관관계를 알아보았다.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.47-47
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• 2009

용착금속의 미세조직은 크게 Acicular ferrite(AF), Ferrite with aligned second phase(FS), Primary ferrite(=Grain boundary Ferrite) 등으로 나눌 수 있다. 이 중 침상형 페라이트(AF)는 인성과 강도를 동시에 증가시킬 수 있으므로 이를 다량 확보하는 것이 용접산업의 관건이다. 본 연구에서는 침상형 페라이트 발생에 기여한다고 알려진 Ti 함량을 용착금속에서 단계적으로 조절하여 나타나는 미세조직과 특성변화를 관찰하였다. 모재는 HSB-600을 사용하였으며 용접재료는 ER100S-G급의 Ti가 함유되어 있는 것(A)과 미함유된 것(B)을 사용하였다. 모재 성분의 희석을 방지하기 위해 V-Groove 가공 후 Buttering 용접을 실시하였다. 중앙에 가공된 V-그루브에 이들 재료를 적절히 조합하고 용접(입열량 20kJ/cm)하여 Ti함유량을 총 4가지(0.002~0.025% Ti)로 제어하였다. 용접 후 각각의 시편에 대해 미세조직, 충격시험, O/N분석, 성분분석 등의 시험을 진행하였다. 미세조직 관찰결과 Ti함량이 증가할수록 AF는 증가하고 FS는 감소함을 확인할 수 있었으며 충격시험결과 Ti가 많이 함유된 시편일수록 더 낮은 연성취성 천이온도(DBTT)를 나타내었다. EDS와 SEM으로 관찰한 결과 Ti함량 증가에 따라 비금속개재물의 크기는 작아지고 밀도는 높아지는 것을 확인할 수 있었으며 개재물 내에서의 Ti함량도 더 많아지는 것을 확인 할 수 있었다.

• Journal of the Korean Ceramic Society
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• v.40 no.8
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• pp.758-764
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• 2003

The cylindrical ${\gamma}$-alumina pellets were prepared by forming, hydration, drying and calcination after mixing amorphous alumina and pore generating agent with water. Concentration of Fe(NO$_3$)$_3$ㆍ9$H_2O$ that was catalyst precursor was fixed and made mixing solution that changed concentration of $CH_3$COOH in range of 2.5~20%, and here ${\gamma}$-alumina pellets were immerged and were hydrothermaly treated for 3 h at $200^{\circ}C$. And then we investigated creation and change of crystal, pore characteristics, $N_2$ adsorption and desorption isotherms, changes of acid site and mechanical strengths etc. According to the concentration of $CH_3$COOH, the crystals grew to acicular shape of 0.5~2${\mu}m$ length, and crystal structure showed the pseudo-boehmite structure. When hydrothermaly treated in 10% $CH_3$COOH solution, pore volume between 100~1000 $\AA$ was highest by 0.86 cc/g, and width of hysteresis curved line due to $N_2$ adsorption/desorption appeared as was smallest. When concentration of $CH_3$COOH was in range of 5~15%, new C-H functional groups were formed. Mechanical strength of pellets was highest by 1.35 MPa when $CH_3$COOH concentration was 2.5%.

• Journal of the Mineralogical Society of Korea
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• v.1 no.2
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• pp.83-93
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• 1988

Amethysts in Eonyang Granite of Woolju-Kun, Kyungnam Province are frequently parallelly grown on top of preexisting smoky quartz crystallized on milky and colorless quartz crystals, which, as a whole, resemble "mushroom" in outer appearance. Fluid inclusions in the amethysts may be grouped into (1) gaseous inclusions (G>L), (2) liquid inclusions (L>G), (3) $L_{CO_2}$-bearing inclusions (L+G+$L_{CO_2}$), (4) halite-bearing inclusions (L+G+halite), (5) multiphase inclusions (L+G+halite+sylvite${\pm}$opaque mineral). In addition, euhedral K-feldspars and acicular hematite crystals are included in colorless-milky quartz and deep purple-red quartz, respectively. Filling temperatures of each type of fluid inclusions were measured as follows: $320{\sim}560^{\circ}C$ for gaseous inclusions; $100{\sim}290^{\circ}C$ for liquid inclusions; $200{\sim}310^{\circ}C$ for $L_{CO_2}$-bearing inclusions; $300{\sim}430^{\circ}C$ for halite-bearing inclusions; and $370{\sim}430^{\circ}C$ for polyphase inclusions. The finished-gem amethysts from Eonyang may be distinguished from Brazilian amethysts by the difference in filling degree of gaseous inclusions by the presence of hematite aciculae, and of $L_{CO_2}$-bearing inclusions, and also by the absence of Zebra-striation structure. They may also be differentiated from synthetic amethysts by presence of straight color banding, solid inclusions, and $L_{CO_2}$-bearing inclusions which are not found in synthetic materials.

• Journal of the Korean Geographical Society
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• v.41 no.3 s.114
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• pp.331-345
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• 2006

This study deals with geomorphological process of the sand dune landform including the distribution and surface environments, characteristics of sediments, origins and moving processes in lower reach and mouth delta of Duman River, Northeast Korea and China. The methodology of the study includes image analysis of Landsat TM(1992.10) and ETM(2000.9) and Spot(2005.4) for analysis of land cover, 2 times field survey for recognition of landform and acquisition of sediments raw data materials, and grain analysis and exoscopy about raw data materials. The geomorphic elements from satellite image analysis are composed of the delta, sand spit, active and stable dune, sand bar and riparian vegetated zone. Results of the grain analysis indicate the sediments originated from marine coastal zone than riverine one. This means that present sand dune not so much reflect present climatic and geomorphic environments. Result of the exoscopy analysis show that ratio of quartz, which is comparatively resistant to environment, is highest as $65{\sim}83%$ out of sediments. But the surface of the $30{\sim}40%$ of mineral grains was coated by yellow-colored stained materials, due to chemical weathering. Some grains show rough skin, looking as acicular, network structure and etching pits, affected by physical and chemical weathering.