• Title/Summary/Keyword: accidents of hazardous materials

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Numerical Study on Atmospheric Dispersion and Fire Possibility in Toluene Leakage (톨루엔 누출 시 대기확산 및 화재가능성에 관한 수치해석 연구)

  • Ko, Jae Sun;Kim, Joo-Seok
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.1-10
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    • 2017
  • This study examined the risk of accidents when handling hazardous materials in hazardous materials storage facilities without safety facilities. In the case of illegal dangerous cargo containers, the burning rate is very fast in the case of fire, which leads to explosions, that are damaging and difficult to control. In addition, accidents that occur in flammable liquid hazardous materials are caused mostly by accidents that occur in the space due to leakage. Therefore, the variables that affect these accidents were derived and the influence of these variables was investigated. Numerical and computational fluid dynamics programs were used to obtain the following final results. First, when a flammable liquid leaks into a specific space, it is influenced by temperature and relative humidity until a certain concentration (lower limit of combustion) is reached. In the case of temperature, it was found that the reaching time was shorter than the flash point In addition, the effect of variables on pool fire accidents of leakage tanks is somewhat different, but the variables that have the largest influence are the wind speed. Therefore, it is expected that the results of this study will be used as basic data for similar numerical analysis and it will provide useful numerical information about the accidental leakage of hazardous materials under various research conditions.

A Study on the Safety Improvement of Mixed Acid Storage Facility through the Accident Investigation Applicated by RCA (혼산 저장설비 사고의 근본원인 분석을 통한 안전성 향상방안)

  • Kwon, Nam-Ho;Kim, Dong-Joon
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.47-54
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    • 2018
  • Mixed acid is very reactive and highly corrosive. it has been causing many accidents in a electronic industry, a steel industry, and a chemical industry. Therefore, it is required that the high safety level for the acid storage facilities. In this study, we investigated the accident causes for resent leak accidents with Root Cause Analysis (RCA). The root causes analysed by RCA were categorized as nine divisions by the their characteristics. Furthermore, each nine divisions causes was applied to the PDCA model which are using at OHSAS 18001. It is suggested that the nine division with the root causes can be the essential items for the development of the safety management manual. It is helpful to the safety improvement of the acid storage facility.

Discussions on the Disaster Management for NaTech based on the Foreign Case Studies (국외 NaTech 사례연구를 통한 재난관리 방안 고찰)

  • Yoo, Byungtae;Baek, Jong-bae;Ko, Jae-wook
    • Journal of the Korean Society of Safety
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    • v.31 no.1
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    • pp.111-117
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    • 2016
  • Natural disasters can cause major accidents in chemical facilities where they can lead to the release of hazardous materials which in turn can result in fires, explosions or toxic dispersion. Technological disasters triggered by natural disasters are referred to as NaTech(Natural Disaster Triggered Technological Disaster). These trends increase the probability of catastrophic future disasters and the potential for mass human exposure to hazardous materials released during disasters. In the present study, we proposed some methods for effective disaster management by conducting case study of major NaTech. First, establishing information sharing system of chemical accident for stakeholders and improving disaster manuals and standards of central and local government and co-operation support system. Second, activating information service of emergency planning and community right to know. Third, improving the integrated chemical accident database including NaTech accidents.

A Study for the Safety Regulation of Tank Car for the Hazardous Material - General Oil Tank Car (위험물 수송 탱크 차량의 국내외 안전기준 비교 연구-유류 차량 중심)

  • Kim, Jae-Hoon;Goo, Byung-Chun
    • Fire Science and Engineering
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    • v.22 no.4
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    • pp.70-75
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    • 2008
  • Recently, there are so many studies related safety of railway vehicle. But these studies are focused on the passenger car, metro system and high speed train. However, the leakage of hazardous materials may contaminate the environment and cause terrible damage to the ecology, even the human and properties. And so, Safety and security have been already established in many countries, currently they are investing lots of money on the development of technology to prevent accidents. Therefore it is necessary to make a systematic plan and develop safety specifications. In this study, we compared between domestic and international general oil tank car safety regulations for the hazardous materials, and prepare the basic for the making of systematic safety plans and safety regulations for the transport of hazardous materials by tank car.

A Quantitative Analysis on Human Errors in Shifting Hazardous Materials of Semiconductor Plants (반도체공장의 위험물 교체작업시 인적과오에 대한 정량적 분석)

  • 임현교
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.161-168
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    • 1997
  • Most plants producing semiconductors use a lot of chemicals, hazardous materials, and explosive gases. Though those materials are hazardous too much, some works still have to be done manually by human workers. However, according to a historical survey, more than half industrial accidents of those plants resulted from human errors or malfunctions. Thus, this research aimed 1) to diagnose shifting hazardous materials of semiconductor plants, 2) to estimate failure probability of human workers through human reliability analysis, and 3) to find out the tasks on which educational emphasis should be put. Through personal interview and visiting working spots, shifting tasks were analyzed, and modelled into a 24-step work, and after that, THERP and ETA was applied. During the shifting work, estimated human failure probability under the assumption of independency, 2.3004E-05, underestimated that probability 8. l008E-05 which could be calculated under the assumption of dependency. And this analysis showed that gas leakage from an old cylinder occupies 78.27% in the case of independent failures whereas gas leakage from a new cylinder occupies 75.06% in the case of dependent failures. So it was concluded that dependency assumption may gloss real situations. In addition, confirming gauge of regulators and closing valves turned out to be the most important tasks than purge tasks.

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Analysis on the Legal Control Levels and GHS Classification Information Status for Strongly Acidic Hazardous Materials (강산성 유해화학물질의 법적관리 수준 및 GHS 분류정보 제공 실태분석 연구)

  • Lee, Kwon Seob;Jo, Ji Hoon;Park, Jin Woo;Song, Se Wook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.4
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    • pp.384-392
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    • 2013
  • Objective: This study inspected incident cases, legal control levels, and GHS(Globally Harmonized System of Classification and Labeling of Chemicals) classification results of strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid, which have been responsible for many recent chemical accidents. As a result, it is deemed necessary for legal control levels of these strong acids to be revised and GHS classification be managed nation-wide. Methods: This study inspected incident cases and legal control levels for strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid. The study analyzed and compared chemical information status and GHS classification results. Results: There were 76 domestic incidents involving strongly acidic hazardous materials over the five years between 2007 and 2011. They include 37 leakage incidents(46.7%) within a workplace, 30 leakage incidents(39.5%) during transportation, and nine leakage incidents(13.8%) following an explosion. The strongly acidic materials in question are defined and controlled as toxic chemicals according to the classes of Substances Requiring Preparation for Accidents, Managed Hazardous Substance, Hazardous Chemical(corrosive) as set forth under the Enforcement Decree of the Toxic Chemicals Control Act and Rules on Occupational Safety and Health Standards of Occupational Safety and Health Act. Among them, nitric acid is solely controlled as a class 6 hazardous material, oxidizing liquid, under the Hazardous Chemicals Control Act. The classification results of the EU ECHA(European Chemicals Agency) CLP(Commission Regulation(EC) No. 790/2009 of 10 August 2009, for the purposes of its adaptation to technical and scientific progress, Regulation(EC) No 1272/2008 of the European Parliament and of the Council on classification, labeling and packaging of substances and mixtures) and NIER (National Institute of Environmental Research) are almost identical for the three chemicals, with the exception of sulfuric acid. Much of the classification information of NITE (National Institute of Technology and Evaluation) and KOSHA(Korea Occupational Safety and Health Agency, KOSHA) is the same. NIER provides 12(41.4%) out of 29 classifications, as does KOSHA.

A Study of Emergency Response for the Leakage Accident of Hazardous and Noxious Substances in a Port (항만에서의 위험·유해물질(HNS) 누출사고 대응에 관한 연구)

  • Woo, Young Jin;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.31 no.6
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    • pp.32-38
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    • 2016
  • In general, lots of containers including various dangerous materials are transported to the port located in big cities such as Busan where massive residents live. Thus, it's really important how to make the emergency response for the leak accidents of dangerous materials and evaluate the direct or indirect damages to adjacent areas. In this study, in order to make reasonable emergency plans, CA (Consequence Analysis) is employed after selecting a key hazardous and noxious material, hydrogen fluroide. This material accounts for the third largest portion of cargo volume among all dangerous materials and can cause a huge damage in case of leakages. As a case study, Busan North port is selected as a test port since the portion of dangerous materials is higher than that of other ports in Busan. It is assumed that 1 ton of hydrogen fluoride is spilled at Busan North port. CA is performed to assess the impact of this accident. Throughout CA, the ERPG-2 range of a leak accident can be evaluated and this result can be used for decision making tools for mitigating the impact of a leak accident. To mitigate the damage of this accident, suitable a protective equipment and resident evacuation procedures should be prepared. Finally, this study can provide a systematic approach to make the emergency plan for reducing economical and personal losses.

A Comparative Study on Risk Management Systems for Hazardous and Noxious Substances at Sea, in Korea and USA. (해상 위험.유해물질 위험관리제도의 비교연구 - 한국과 미국 중심으로 -)

  • 최종해
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.8 no.1
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    • pp.15-52
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    • 2002
  • According to International Maritime Organization. more than 50% of cargoes transported by sea today can be regarded as dangerous or hazardous ones, mainly consisting of chemical cargoes in bulk, likely solid or liquid and other materials, such as gases and products for and of the oil refinery industry. 46% of total cargoes handled in ports of Korea in 1999. is said to be dangerous cargoes. These dangerous and hazardous cargoes are quite within a high realms of possibility of accidents, likely to be grave disaster. This paper reviews current risk management system for the dangerous and hazardous cargoes sea-transportation, mainly focusing on the prevailing regal regimes in both USA and Korea. And it aims to suggest some points for advancing the existing Korean system.

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Mobile Robot-based Leak Detection and Tracking System for Advanced Response and Training to Hazardous Materials Incidents (화학물질 저장시설의 사고대응 및 훈련을 위한 로봇기반 누출감지 및 추적시스템)

  • Park, Myeongnam;Kim, Chang Won;Kim, Tae-Ok;Shin, Dongil
    • Journal of the Korean Institute of Gas
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    • v.23 no.2
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    • pp.17-27
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    • 2019
  • In recent years, dangerous materials and gas leak accidents have been frequently occurred. The hazardous materials storage facility accidents are not rapidly controlled when a leak is detected, unlike other chemical plants can be controled. Externally, the human has to approach and respond to the source of leaking directly. As a result, the human and material damage are likely to larger result in the process. The current approach has been passive response after ringing the alarm. In this study, the suggested tracking system of the leak resource is designed system to track the resource actively by utilizing the mobile sensor robot platform, which can be made easily through recent rapid development technology, is verified through prototype system. Thus, a suggested system should pave the way for minimizing the spread and damage of the accident based on the exact site situation of the initial leak and quick and early measures.

A Study on Prevention of Explosion Accidents (폭발재해 예방대책에 관한 소고)

  • Kim In Sung
    • Explosives and Blasting
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    • v.12 no.3
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    • pp.32-41
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    • 1994
  • The specific characters in recent Chemical processing and industrial plants are the handling of severe limit conditions such as high pressure, high and low temperature, high speed production and transportation plant automation and appearance of many new hazardous materials in numbers and quantity. The possibilities of these characters causing the accident and environmental pollution in industrial activities become very high. This paper describes the concrete policy In prevent the explosion accident out of the many accidents which are the safety of the safety engineering.

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