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Effects of Mo on the Passive Films Formed on Ni-(15, 30)Cr-5Mo Alloys in pH 8.5 Buffer Solution

  • Jang, Hee-Jin;Kwon, Hyuk-Sang
    • Journal of the Korean Electrochemical Society
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    • v.12 no.3
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    • pp.258-262
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    • 2009
  • The composition and semiconducting properties of the passive films formed on Ni- (15, 30)Cr-5Mo alloys in pH 8.5 buffer solution were examined. The depth concentration profile of passive films formed on Ni-(15, 30)Cr-5Mo in pH 8.5 buffer solution showed that Mo enhances the enrichment of Cr. The Mott-Schottky plot for the passive film on Ni-(15, 30)Cr- 5Mo closely resembled that for the film on Cr, whereas those for the less Cr-enriched film on Mo-free alloys showed similar behavior to that for the film on Ni. The acceptor density was reduced by increasing Cr content in Ni-(15, 30)Cr-(0, 5)Mo alloys, but addition of Mo considerably increased the acceptor density.

Simulation of laser zone texturing of Ni-P disk substrates by PLIC method (PLIC 방법을 사용한 Ni-P 디스크의 레이저 존 텍스처링 모사)

  • Kim, Heon-Joon;Ha, Eung-Ji;Kim, Woo-Seung
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.255-260
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    • 2000
  • Laser zone texture technology is widely used to enhance the tribological performance of high areal density media. This work investigates the transient process of melting and microscale surface deformation upon pulsed laser heating of Ni-P hard disk substrates by PLIC(Piecewise Linear Interface Calculation) method. The present results are compared with both the experimental and the Donor-Acceptor method results. It is found that the results from PLIC method are better than those of Donor-Acceptor method and they are in good agreements with the experimental results.

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Diffusion Kinetics of Si in GaAs and Related Defect Chemistry (GaAs에서의 Si의 확산기구와 그에 관련된 격자 결함 화학)

  • Lee, Gyeong-Ho
    • ETRI Journal
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    • v.11 no.4
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    • pp.75-83
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    • 1989
  • The diffusion mechanism of Si in GaAs was investigated using different diffusion sources based on the Si-Ga-As ternary phase equilibria. The Si profiles are measured with secondary ion mass spectrometry and differ significantly for sources taken from the different phase fields in the ternary phase diagram. Neutral As vacancy diffusion is proposed for acceptor Si diffusion anneals using a Ga - Si - GaAs source. Donor Si diffusion using As - rich sources and a Si -GaAs tie line source shows concentration dependent diffusion behavior. Concentration dependent diffusion coefficients of donor Si for As - rich source diffusion were found to be related to net ionized donor concentration and showed three regimes of different behavior: saturation regime, intermediate regime,and intrinsic regime. Ga vacancies are proposed to be responsible for donor Si diffusionin GaAs: $Si_Ga^+V_Ga^-$ (donor Si -acceptor Gavacancy) complex for the extrinsic regime and neutral $V_G$a, for the intrinsic regime.The Si - GaAs tie line source resulted in two branch profiles, intermediate between the As - rich and the Ga - rich source diffusion cases.

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First Hyperpolarizabilities of Heteroaromatic Stilbene Derivatives

  • Cho, Bong-Rae;Lee, Sang-Hae;Yosep Min;Kang, Tae-Im;Jeon, Seung-Joon
    • Journal of Photoscience
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    • v.8 no.2
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    • pp.79-82
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    • 2001
  • 2-(p-Diethylaminostyryl)pyrrole (I) and 2-[5-diethylaminothienyl]vinyl]pyrrole (II) derivatives with systematic variation of the acceptors have been synthesized and their first hyperpolarizabilities were measured. The $\beta$ values increased systematically as the aromatic resonance energy decreased. Moreover, the value of $\beta$ for the former increased gradually as the acceptor strength increased. The opposite trend observed in the latter series of compounds has been attributed to the distorted structure caused by the steric hindrance between the N-methyl group and the acceptor moiety.

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A Batch Study on BTEX and MTBE Biodegradation by Denitrifiers under Aerobic and Anaerobic Conditions

  • 오인석;이시진;장순웅
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.467-470
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    • 2003
  • Leaking underground storage tanks are a major source of groundwater contamination by petroleum hydrocarbons. Aerobic bioremediation has been highly effective in the remediation of many fuel releases. However, Bioremediation of aromatic hydrocarbons in groundwater and sediments is ofen limited by the inability to provide sufficient oxygen to the contaminated zones due to the low water solubility of oxygen. Nitrate can also serve as an electron acceptor and results in anaerobic biodegradation of organic compounds via the processes of nitrate reduction and denitrification. Because nitrate is less expensive and more soluble than oxygen. it may be more economical to restore fuel-contaminated aquifers using nitrate rather than oxygen. And denitrifying bacteria are commonly found in the subsurface and in association with contaminated aquifer materials. These studies have shown that BTEX and MTBE can be degraded by the nitrate-amended microcosms under aerobic and anaerobic conditons. Biodegradation of the toluene and ethylbenzne compounds occurred very quickly under denitrifying conditions. MTBE, benzene and p-xylene were recalcitrant under denitrifying conditions in this study, But finally Biodegradaton was observed for all of the test compounds.

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Design of Half-Wavelength Low-PASS Filter using EBG Structure (EBG 구조를 이용한 반파장 저역통과 여파기 설계)

  • Kang, Myung-Soo;Kim, Young-Tae;Park, Jun-Seok
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2003.11a
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    • pp.376-379
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    • 2003
  • In this raper, proposed easy half-wavelength LPF and acceptor structure in actuality manufacture using EBG (Electromagnatic Bandgap) structure for application of micro-strip circuit. Because conventional half-wavelength LPF and acceptor is narrow line-width of High impedance, actuality manufacture is difficult. Width that in proposed structure narrow microstrip line of High impedance EBG structure use and has equal impedance embodied to wide microstrip line. Also, it is seen that actuality manufacture is available applying to half-wavelength LPF that have cut-off Frequency of 3GHz.

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Vapor Phase Epitaxial Growth and Properties of GaN (GaN의 기상성장과 특성)

  • 김선태;문동찬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.72-75
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    • 1996
  • A hydride vapor phase epitaxy (HVPE) method is performed to prepare the GaN thin films on c-plane sapphire substrate. The full-width at half maximum of double crystal X-ray rocking curves from 20$\mu\textrm{m}$-thick GaN was 576 arcsecond. The photoluminescence spectrum measured 10 K shows the hallow bound exciton (I$_2$) line and weak donor-acceptor peak, however, there was not observed deep donor-acceptor pair recombination indicate the GaN crystals prepared in this study are of high purity and high crystalline quality. The GaN layer is n-type conducting with electron mobility of 72 $\textrm{cm}^2$/V$.$sec and with carrier concentration of 6 x 10$\^$18/cm/sup-3/.

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Preliminary Study of Bioremediation in Diesel Contaminated Soil (디젤 오염토양의 생물학적 복원에 관한 기초연구)

  • 김선영;권수열;이상훈
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.167-170
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    • 2000
  • The purpose of study is to evaluate the effects of physical parameters on diesel biodegradation in diesel contaminated soil. The parameters applied are concentration, temperature, moisture contents, electron acceptor(O$_2$). The results of this study showed that diesel were degraded faster at high temperature and moisture contents than at low temperature and moisture content. However concentration effect study indicates that diesel were more faster degraded at low concentration than at high concentration. The results of electron acceptor test showed concentration of oxygen did not affect the biodegradation rate of diesel in oxygen condition(10, 20%) of this study.

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탈질조건을 이용한 유류물질 생분해 기초연구

  • 오인석;장순웅;이시진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.368-371
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    • 2003
  • Leaking underground storage tanks are a major source of groundwater contamination by petroleum hydrocarbons. Bioremediation of aromatic hydrocarbons in groundwater and sediments is often limited by dissolved oxygen. Aerobic bioremediation has been highly effective in the remediation of many fuel releases, but Many aromatic hydrocarbons degrade very slowly under anaerobic conditions. Nitrate is a good alternative electron acceptor to oxygen and denitrifying bacteria are commonly found in the subsurface and in association with contaminated aquifer materials. Because nitrate is less expensive and more soluble than oxygen. it may be more economical to restore fuel-contaminated aquifers using nitrate rather than oxygen. This study show that biodegradation of BTEX and MTBE is enhanced by the nitrate-amended microcosms under aerobic/anaerobic conditons. Although aromatic hydrocarbons degrade very slowly under anaerobic conditions. Biodegradaton was observed for all of the test compounds.

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Charge Transfer between Graphene and a Strong Electron Acceptor, Tetrafluorotetracyanoquinodimethane (F4-TCNQ)

  • Lee, Ji-Eun;Kim, Seon-Ho;Gang, Seong-Gyu;Yang, Seong-Ik;Ryu, Sun-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.458-458
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    • 2011
  • Graphene, a single atomic layer of sp2-bonded carbon, shows substantial potential for various applications. Chemical manipulation of its electronic properties will be of great importance. In this study, we have investigated interaction between graphene and organic molecular layer of tetrafluorotetracyanoquinodimethane (F4-TCNQ), a strong electron acceptor. F4-TCNQ films of varying thickness were evaporated onto graphene mechanically exfoliated on SiO2/Si substrates. F4-TCNQ molecules increase the frequencies of Raman G and 2D bands of graphene while decreasing the linewidth of G band and 2D/G intensity ratio, which is consistent with increase of hole density in graphene. These results exemplify the possibility of chemical tuning of electronic properties of graphene.

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