• Title/Summary/Keyword: accelerated corrosion

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Study on Design Change of a Pipe Affected by Liquid Droplet Impingement Erosion (액적충돌침식 영향 배관의 설계변경에 관한 연구)

  • Hwang, Kyeong-Mo;Lee, Chan-Gyu;Bhang, Keug-Jin;Yim, Young-Sig
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.10
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    • pp.1097-1103
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    • 2011
  • Liquid droplet impingement erosion (LDIE) is caused by the impact of high-velocity droplets entrained in steam or air on metal. The degradation caused by the LDIE has been experienced in steam turbine internals and high-velocity airplane components (particularly canopies). Recently, LDIE has also been observed in the pipelines of nuclear plants. LDIE among the pipelines occurs when two-phase steam experiences a high pressure drop (e.g., across an orifice in a line to the condenser). In 2011, a nuclear power plant in Korea experienced a steam leak caused by LDIE in a pipe through which a two-phase fluid was flowing. This paper describes a study on the design change of a pipe affected by LDIE in order to mitigate the damage. The design change has been reviewed in terms of fluid dynamics by using the FLUENT code.

Evaluation of Liquid Droplet Impingement Erosion through Prediction Model and Experiment (예측모델 및 실험을 통한 액적충돌침식 손상 평가)

  • Yun, Hun;Hwang, Kyeong-Mo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.10
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    • pp.1105-1110
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    • 2011
  • Flow-accelerated corrosion (FAC) is a well-known phenomenon that may occur in piping and components. Most nuclear power plants have carbon-steel-pipe wall-thinning management programs in place to control FAC. However, various other erosion mechanisms may also occur in carbon-steel piping. The most common forms of erosion encountered (cavitation, flashing, Liquid Droplet Impingement Erosion (LDIE), and Solid Particle Erosion (SPE)), have caused wall thinning, leaks, and ruptures, and have resulted in unplanned shutdowns in utilities. In particular, the damage caused by LDIE is difficult to predict, and there has been no effort to protect piping from erosive damage. This paper presents an evaluation method for LDIE. It also includes the calculation results from prediction models, a review of the experimental results, and a comparison between the UT data in the damaged components and the results of the calculations and experiments.

Limit Loads for Circular Wall-Thinned Feeder Pipes Subjected to Bending and Internal Pressure. (원형 감육이 발생한 중수로 피더관의 한계하중 평가)

  • Je, Jin-Ho;Lee, Kuk-Hee;Chung, Ha-Joo;Kim, Jong-Sung;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.11
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    • pp.1675-1680
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    • 2010
  • Flow Accelerated Corrosion (FAC) occurring during in-service conditions results in localized wall-thinning in the feeder pipes of CANDU. The wall-thinning of the feeder pipes is the main degradation mechanisms affecting the integrity of piping systems. In this paper, we assess the integrity of wall-thinned feeder pipes by limit load analysis. The limit loads for wall-thinning feeder pipes subjected to in-plane bending and internal pressure were determined on the basis of finte element limit analyses. The limit loads are determined from the results of limit analyses of elasticperfectly-plastic materials using the large geometry change. Closed-form approximations of limit load solutions for wall-thinning feeder pipes subjected to in-plane bending and pressure are proposed.

Evaluation of Material Characteristics of Suspension-Type Porcelain Insulators for 154 KV Power Transmission Lines

  • Choi, In-Hyuk;Park, Joon-Young;Kim, Tae-gyun;Yoon, Yong-Beum;Yi, Junsin
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.4
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    • pp.207-210
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    • 2017
  • The suspension arrangement of insulators provides flexibility and assists in power transmission in transmission lines. The performance of the insulator string is strongly influenced by the environmental conditions to which it is exposed, its shape and the inherent material properties of suspension-type insulators. The suspension-type insulators are mostly made from glass, porcelain and ceramic material due to their high resistivity. Irregularity in charge distribution throughout the porcelain insulator may lead to accelerated aging and electrical breakdown. A very high and steep lightning impulse voltage may also cause breakdown of suspension-type insulators. We investigated various material characteristics such as alumina addition, surface morphology, x-ray diffraction pattern and relative density of suspension porcelain insulators manufactured in 1989 (36,000 lbs.), 1995 (36,000 lbs.) and 2001 (36,000 lbs.) by the KRI Company for use in 154 kV high power transmission lines. We compared the material characteristics of these porcelain insulators with that of the top-of-the-line porcelain insulators (36,000 lbs.) manufactured by the NGK Company in 2000. These suspension-type porcelain insulators were exposed to arc and flashover tests to examine their electrical and mechanical strength. It was noted that alumina addition (17 wt.%) for K-2001 was one of the major contributors to the enhancement of the performance of the porcelain insulators and to their ability to withstand very high current generation during the arc test. The porcelain insulators manufactured during 2001 also showed the highest relative density of 95.8% as compared to the other insulators manufactured in 1989 and 1995 respectively 94.2% and 91.5%. We also discuss reports of various failure modes of suspension-type porcelain insulators.

Relationship between Chloride Diffusivity and the Fundamental Properties of Concrete (염소이온의 확산계수와 콘크리트의 기초물성과의 관계)

  • Choi, Doo-Sun;Choi, Jae-Jin
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.15-20
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    • 2009
  • Marine concrete structure is exposed to salt injury and deteriorated by steel corrosion due to chloride ions diffusion. It, therefore, is very important to estimate the chloride diffusivity in concrete. In this paper the compressive strength and permeable pore volume of concrete are measured and the diffusion coefficient and penetration depth of chloride ions in concrete were investigated to estimate the chloride diffusivity efficiently. To correlate these results each other, regression analysis was done. The results showed a good linear relation between chloride diffusivity and the fundamental properties of concrete and the chloride diffusivity of concrete with water-cement ratios of $40%{\sim}60%$ were about $2.5{\sim}6.6{\times}10^{-12}m^2/s$.

Effects of the Changes in Flow Pattern on Convective Heat Transfer in the Vicinity of Pipe Elbow (유동형태 변화가 배관 곡관부 대류열전달에 미치는 영향)

  • Song, Seung-Hyun;Yoo, Hoseon
    • Plant Journal
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    • v.15 no.1
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    • pp.25-30
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    • 2019
  • In this study, by varying flow patterns, which is one of the hydraulic factors of FAC, a strategy to reduce pipe wall thinning by mass transfer has been investigated. A similarity between heat transfer and mass transfer was verified via theoretical analysis, and local convective heat transfer coefficients were analyzed using a commercial numerical analysis program. When ribs were installed inside and outside of the internal surface in the straight section of the pipe, the maximum local heat transfer coefficient was shown to decrease substantially by up to 24.9% compared to the basic flow depending on the position and shape of ribs. If a guide vein was inserted in the pipe elbow, the maximum local heat transfer coefficient decreased by up to 26.7% compared to the basic flow depending on the internal surface area of the pipe by the guide vein.

A Study on the Effect of Metallic Fillers and Plastic for Ionic Migration (이온마이그레이션에 대한 플라스틱과 금속첨가제의 영향 연구)

  • Jeon, Sang Soo;Kim, Ji Jung;Lee, Ho Seung
    • Journal of Auto-vehicle Safety Association
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    • v.13 no.2
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    • pp.30-34
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    • 2021
  • Electrical failures and reliability problems of electronic components by ionic migration between adjacent device terminals have become an issue in automotive electronics. Especially unlike galvanic corrosion, ionic migration is occurred at high temperature and high humidity under applied electric field condition. Until now, although extensive studies of the ionic migrations dealing with PCBs, electrodes, and solders were reported, there is no study on the effect of insulation polymers and metallic fillers for ionic migration. In this research, therefore, ionic migration induced by the types and contents of polymers and metallic fillers, and variety conditions of temperature, humidity, and applied voltage was studied in detail. Ester and amide types of liquid crystal polymer (LCP) and poly (phthalamide) (PPA) were used as base polymers, respectively and compounded with the metallic fillers of Copper iodide (CuI), Zinc stearate (Zn-st), or Calcium stearate (Ca-st) in various compositions. The compounding polymers were fabricated in IPC-B-24 of SIR test coupon according to ISO 9455-17 with Cu electrodes for ionic migration test. While there is no change in LCP-based samples, ionic migration in PPA compounding sample with a high water absorption property was accelerated in the presence of 0.25 wt% or above of CuI at the environmental conditions of 85℃, 85% RH and 48V. The dendritic short-circuit growth of Cu caused by ionic migration between the electrodes on the surface of compounded polymers was systematically observed and analyzed by using optical microscopy and SEM (EDX).

Reflow Behavior and Board Level BGA Solder Joint Properties of Epoxy Curable No-clean SAC305 Solder Paste (에폭시 경화형 무세정 SAC305 솔더 페이스트의 리플로우 공정성과 보드레벨 BGA 솔더 접합부 특성)

  • Choi, Han;Lee, So-Jeong;Ko, Yong-Ho;Bang, Jung-Hwan;Kim, Jun-Ki
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.1
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    • pp.69-74
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    • 2015
  • With difficulties during the cleaning of reflow flux residues due to the decrease of the part size and interconnection pitch in the advanced electronic devices, the need for the no-clean solder paste is increasing. In this study, an epoxy curable solder paste was made with SAC305 solder powder and the curable flux of which the main ingredient is epoxy resin and its reflow solderability, flux residue corrosivity and solder joint mechanical properties was investigated with comparison to the commercial rosin type solder paste. The fillet shape of the cured product around the reflowed solder joint revealed that the curing reaction occurred following the fluxing reaction and solder joint formation. The copper plate solderability test result also revealed that the wettability of the epoxy curable solder paste was comparable to those of the commercial rosin type solder pastes. In the highly accelerated temperature and humidity test, the cured product residue of the curable solder paste showed no corrosion of copper plate. From FT-IR analysis, it was considered to be resulted from the formation of tight bond through epoxy curing reaction. Ball shear, ball pull and die shear tests revealed that the adhesive bonding was formed with the solder surface and the increase of die shear strength of about 15~40% was achieved. It was considered that the epoxy curable solder paste could contribute to the improvement of the package reliability as well as the removal of the flux residue cleaning process.

Comparison of Catalyst Support Degradation of PEMFC Electrocatalysts Pt/C and PtCo/C (PEMFC 전극촉매 Pt/C와 PtCo/C의 촉매 지지체 열화비교)

  • Sohyeong Oh;Yoohan Han;Minchul Chung;Donggeun Yoo;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.341-347
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    • 2023
  • In PEMFC, PtCo/C alloy catalysts are widely used because of good performance and durability. However, few studies have been reported on the durability of carbon supports of PtCo/C evaluated at high voltages (1.0~1.5 V). In this study, the durability of PtCo/C catalysts and Pt/C catalysts were compared after applying the accelerated degradation protocol of catalyst support. After repeating the 1.0↔1.5V voltage change cycles, the mass activity, electrochemical surface area (ECSA), electric double layer capacitance (DLC), Pt dissolution and the particle growth were analyzed. After 2,000 cycles of voltage change, the current density per catalyst mass at 0.9V decreased by more than 1.5 times compared to the Pt/C catalyst. This result was because the degradation rate of the carbon support of the PtCo/C catalyst was higher than that of the Pt/C catalyst. The Pt/C catalyst showed more than 1.5 times higher ECSA reduction than the PtCo/C catalyst, but the corrosion of the carbon support of the Pt/C catalyst was small, resulting in a small decrease in I-V performance. In order to improve the high voltage durability of the PtCo/C catalyst, it was shown that improving the durability of the carbon support is essential.

Influence of Water-Cement Ratios and Curing Conditions on the Diffusion Characteristics of Chloride Ion in Concrete (콘크리트의 염소이온 확산특성에 미치는 물-시멘트비 및 양생조건의 영향)

  • Bae, Su-Ho;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.753-759
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. Of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-cement (W/C) ratio, age, curing conditions, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of W/C ratio and curing conditions on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. In the test, the voltages passing through the diffusion cell were measured by accelerated test method using potential difference, and then with the consideration of IR drop ratio the diffusion coefficient of chloride ion for concrete with different W/C ratios were estimated by Andrade's model. Furthermore, under different curing conditions formulas for the estimation of the diffusion coefficient of chloride ion have been proposed by the regression analysis considering the effect of W/C ratio and age.