• 제목/요약/키워드: ac-conductivity

검색결과 183건 처리시간 0.034초

이온 전송 및 고주파 유전 흡수 (Ion Transport and High Frequency Dielectric Absorption)

  • 윤주호;최용성;황종선;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.379-380
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    • 2008
  • Molecular Dynamics (MD) simulations have been used to model the dynamics of the charge-compensating sodium ions in the non-stoichiometric hollandite Nax$(Ti_{8-x}Cr_x)O_{16}$. These interstitial ions reside in 'tunnels' in the crystal structure and move under the forces of both the ions making up the cage structure and the many body interactions of the other sodium ions in the tunnel. The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6\times10^{12}$ Hz that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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SnO$_2$가 첨가된 ZnO의 전기적성질 (Electrical Properties of TiO$_2$added ZnO)

  • 최우성;박춘배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.221-223
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    • 1995
  • The electrical conductivity of SnO$_2$added ZnO was investigated using the DC and AC methods. The electrical conductivity of SnO$_2$added ZnO was decreased with increasing the concentration of SnO$_2$. The cal쳐lated effective dielectric constants of 3 mol%, 5 mo1%, and 7 mol% are ~7, ~13, and ~120, respectively. The factor of the decrease for the electrical conductivity seems to be the increase of the resistance of grain decreasing the size of grain.

Grain Size Dependence of Ionic Conductivity of Polycrystalline Doped Ceria

  • Hong, Seong-Jae
    • The Korean Journal of Ceramics
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    • 제4권2호
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    • pp.122-127
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    • 1998
  • Conductivities of polycrystalline ceria doped with several rare earth oxides were measured by AC admittance and DC four probe method. The conductions were separated into grain and grain boundary contributions using the complex admittance technique as well as grain size dependence of conductivity. The grain size dependence of polycrystalline conductivity, which can be adequately described by the so-called brick layer model, appears to give a more reliable measure of the grain conductivity compared to the complex admittance method. Polycrystalline resistivity(1/conductivity) increases linearly with the reciprocal of grain size. The intercept of resistivity vs. inverse grain size plot gives a measure of the grain resistivity and the slope gives a measure of the grain boundary resistivity. It was also noted that errors involved in the analysis of experimental data may be different between the complex admittance method and the impedance method. A greater resolution of the spectra was found in the complex admittance method, insofar as the present work is concerned, suggesting that the commonly used equivalent circuit may require re-evaluation.

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아연-이온 하이브리드 슈퍼커패시터를 위한 보론 도핑된 활성탄의 제조 (Fabrication of Boron-Doped Activated Carbon for Zinc-Ion Hybrid Supercapacitors)

  • 이영근;장해남;안건형
    • 한국재료학회지
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    • 제30권9호
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    • pp.458-464
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    • 2020
  • Zinc-ion hybrid supercapacitors (ZICs) have recently been spotlighted as energy storage devices due to their high energy and high power densities. However, despite these merits, ZICs face many challenges related to their cathode materials, activated carbon (AC). AC as a cathode material has restrictive electrical conductivity, which leads to low capacity and lifetime at high current densities. To overcome this demerit, a novel boron (B) doped AC is suggested herein with improved electrical conductivity thanks to B-doping effect. Especially, in order to optimize B-doped AC, amounts of precursors are regulated. The optimized B-doped AC electrode shows a good charge-transfer process and superior electrochemical performance, including high specific capacity of 157.4 mAh g-1 at current density of 0.5 A g-1, high-rate performance with 66.6 mAh g-1 at a current density of 10 A g-1, and remarkable, ultrafast cycling stability (90.7 % after 10,000 cycles at a current density of 5 A g-1). The superior energy storage performance is attributed to the B-doping effect, which leads to an excellent charge-transfer process of the AC cathode. Thus, our strategy can provide a rational design for ultrafast cycling stability of next-generation supercapacitors in the near future.

강섬유 종류에 따른 시멘트 복합체의 전기전도도 측정에 대한 실험적 연구 (An Experimental Study on the Measurement of Electrical Conductivity of Cementitious Composites According to the Type of Steel Fiber)

  • 이예찬;김규용;남정수;이상규;서동균;유하민
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
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    • pp.191-192
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    • 2020
  • The purpose of this study is to measure the electrical conductivity of cementitious composites as an early step to obtain shielding performance by mixing various type of steel fiber into cementitious composites, the main building material of protection facility, to shield electromagnetic pulse (EMP) damage. Fiber such as conductors as amorphous metallic fiber, hooked steel fiber, and smooth steel fiber are mixed into cementitious composites to give electrical conductivity and measure the impedance of concrete using LCR meter. By doing this, the electrical conductivity of each type of steel fiber reinforced cementitious composites (FRCC) is compared.

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AC 전기습윤 중 전기수력학 유동의 메카니즘 (Mechanism of Electrohydrodynamic Flow in AC Electrowetting)

  • 이호림;고성희;윤성찬;강관형
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2648-2651
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    • 2008
  • In AC electrowetting, it has been reported that there is a flow inside droplets. The flow characteristics such as flow rate, direction and the pattern of streamline are altered according to the frequency range of applied voltage. However, the mechanism of the flow has not been explained yet. This work is concentrated on investigation of the flow mechanism when high-frequency voltage is applied to droplets. We propose that this phenomenon arises from the electro-thermal flow. A numerical analysis is performed for the needle-electrode-plane geometry in which the Coulombic force term is included in the Navier-Stokes equation. According to our analysis, electrical charge is generated due to conductivity gradient which is originated from the nonuniform Joule heating of fluid medium. The result of the analysis is compared with experimental result.

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Photon-induced surface conductivity measurement of MgO in an AC PDP

  • Ha, Chang-Hoon;Kim, Joong-Kyun;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.130-133
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    • 2006
  • In order to study the relationship between the discharge characteristics of an ac PDP and the surface conductivity of MgO thin film, the surface current across a ring shaped MgO film was measured by exposure to monochromatic vacuum ultraviolet from the synchrotron radiation source whose wavelength ranges from 60nm to 240nm $(5.5eV{\sim}25eV)$. The experimental results show that the surface current begins to increase rapidly at the photon energy of about 9 eV which might correspond to the valence band edge of MgO. The difference in the surface current level correlate well with the differences in the preparation method of MgO films and their respective discharge characteristics such as the firing, minimum sustain voltages, address voltage margin and address discharge delay time.

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TiO$_2$가 첨가된 SnO$_2$의 Impedance Spectroscopy에대한 연구 (Impedance Spectroscopy Study of TiO$_2$ added SnO$_2$)

  • 최우성;박춘배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.277-279
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    • 1996
  • A.C. and D.C. characteristic of TiO$_2$ added SnO$_2$ are investigated to study the electrical properties. The electrical inductivity increases as TiO$_2$content increase. The doer effect of TiO$_2$ is crucial role for the increase of electrical conductivity. The frequency-dependent ac inductivity increases with the increase of TiO$_2$ contents at low frequency region. However, at high frequency region, the difference of ac conductivity is very small. Impedance spectrums are consist of the one semicircle. Therefore, the sizes of semicircle decreases with increasing the TiO$_2$ contents.

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La0.7Sr0.3FeO3 세라믹스의 교류 전도특성 (Alternating - Current Electrical Properties of La0.7Sr0.3FeO3 Ceramics)

  • 정우환
    • 한국세라믹학회지
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    • 제44권11호
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    • pp.627-632
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    • 2007
  • We have studied the ac conductivity of insulating $La_{0.7}Sr_{0.3}FeO_3$ in the frequency range 20 Hz-l MHz and in the temperature range 80-300 K. We have analyzed experimental results in the frame works of the quantum-mechanical tunneling mechanism (QMT) and the hopping of barrier mechanism (HOB). We observed that small polaron QMT model is the most suitable mechanism for the low temperature ac conductivity of $La_{0.7}Sr_{0.3}FeO_3$.

전기전도도법을 이용한 우레아 농도 센서 개발 (Development of an Urea Sensor using Electric Conductivity Method)

  • 최병철;김계연;양주영;김화남
    • 동력기계공학회지
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    • 제15권2호
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    • pp.55-60
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    • 2011
  • The popularity of diesel engines is derived primarily from their higher thermal efficiency resulting from higher compression ratio. NOx removal from the diesel emissions is very important to meet stringent emission regulations. NOx emission from diesel engines is removed by an urea-SCR or an LNT system. The urea-SCR system needs the urea-solution supply system with concentration and level sensor. This study was carried out to develop a sensor for the measurement of urea-solution concentration by an electric conductivity method. Considering experimental parameters were the material of electrode, two kinds of electric power(AC or DC), the distance between two electrodes, and the length of electrode. It was found that the AC electric power was more useful to measure the urea-solution concentration compared to DC, because it prevented an ionization of the urea-solution. The silver rod coated with Pt is the most useful electrode, tendency of which is similar to Pt rod, and the cost is more economic. We could also find out the optimum distance between two electrodes and the length of electrode was 10mm and 3mm, respectively.