• 천문학회보
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• 제36권2호
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• pp.62.2-62.2
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• 2011

The correlation between black hole mass and stellar velocity dispersion provides an important clue on the black hole growth and galaxy evolution. In the case of AGN, however, it is extremely difficult to measure stellar velocity dispersions in the optical since AGN continuum dilutes stellar absorption features. In contrast, stellar velocity dispersions of active galaxies can be measured in the near-IR, where AGN-to-star flux ratio is much smaller. Expecting that more stellar velocity dispersion measurements will be available using future near-IR facilities, it is crucial to test whether the stellar velocity dispersions measured from the near-IR spectra are consistent with those measured from the optical spectra. For a sample of 35 nearby galaxies, for which optical stellar velocity dispersion measurements and dynamical black hole masses are available, we obtained high quality H-band spectra, using the TripleSpec at the Palomar 5-m Telescope, in order to calibrate the stellar velocity dispersions and define the $M_{BH}-sigma_*$ relation in the near-IR. Based on the spatially resolved kinematics, we correct for the rotation component and determine the luminosity-weighted stellar velocity dispersion of the spheroid component in each galaxy. In this presentation, we will show the comparison between optical and near-IR stellar velocity dispersion measurements and define the $M_{BH}-sigma_*$ relation based on uniformly measured stellar velocity dispersion in the near-IR.

• Journal of Information Display
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• 제5권4호
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• pp.12-17
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• 2004

A series of statistical random copolymers of dioctylfluorene (DOF) and 3,4-ethylenedioxythiophene (EDOT) were synthesized by Ni (0) mediated polymerization and their light-emitting properties were compared with poly (9,9-di-n-octylfluorene) (PDOF). The synthesized polymers were characterized using UV-vis spectroscopy, TGA, photoluminescence (PL) & electroluminescence (EL) spectroscopy and by conducting molecular weight studies. The resulting polymers were found to be thermally stable and readily soluble in organic solvents. The UV-visible absorption and PL emission spectra of the copolymers were gradually red-shifted as the fraction of EDOT in copolymers increased. Light-emitting devices were fabricated in an ITO (indium-tin oxide)/PEDOT/polymer/Ca/Al configuration. Interestingly, the EL spectra of these devices were similar to the PL spectra of the corresponding polymer film. However, the EL devices constructed from the copolymer showed more than 10 times higher efficiency level than the devices constructed from the PDOF homopolymer. This higher efficiency is possibly the result of better charge carrier balance in the copolymer systems due to the lower HOMO levels of the copolymers in comparison to that of PDOF homopolymer.

• Bulletin of the Korean Chemical Society
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• 제24권8호
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• pp.1075-1080
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• 2003

We have investigated femtosecond coherent vibrational motions of Zn(II)-5,15-diphenylporphyrin in toluene using chirp-controlled ultrashort pulses. The oscillatory features superimposed on the temporal profiles of the pump-probe transient absorption signal are affected by the chirping and energy of excitation pulses. Using chirp- and excitation energy-controlled femtosecond pulses, we are able to obtain information on the structural changes between the electronic ground and excited states based on a comparative analysis of the Fouriertransformed frequency-domain spectra retrieved from the oscillatory components with the ground state resonance Raman spectra and normal mode calculations.

• 대한화학회지
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• 제44권3호
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• pp.194-199
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• 2000

The chemical behavior for Mo(0) and W(0) complexes, [M(CO)$_2$(PPh$_3$)$_4$] (M=Mo and W),has been investigated by UV-vis spectroscopic, magnetic, and electrochemical methods. Three absorption bands are observed in the UV-spectra. The crystal-field-splitti ng energy, spin-pairing energy, and bond strengths were deduced from the spectra. The metal d electrons in both complexes seemed to be delocalized in low-spin state.Metal ligand correlation appeared to strongly depend on bond strengths and diamagnetic properties. In electrochemical processes, both complexes exhibit an irreversible reduction wave.

• 한국염색가공학회지
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• 제13권3호
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• pp.165-171
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• 2001

In this study, UV/vis. spectra of color solution extracted from onion shell and dyeing properties of polyamide fibers such as wool, silk, and nylon were investigated. Also, the effect of mordanting on wash fastness and light fastness was Investigated. The amount of colors extracted was increased with extracting temperature and time. The wavelength of maximum absorption of onion shell extract corresponds to flavonol peak and quercetin peak. Also, spectra of color solution were shifted to longer wavelength at higher pH values. It appeared that the optimum condition of the dyeing of wool, nylon, and silk fabrics with onion shell extract was $60^\circ{C}$ , 30min, and pH 4.0 of dyed bath. Surface colors of the dyed fabrics were different according to the used mordants: Al and Cr mordanted fabrics were dyed in yellowish colors, Cu mordanted fabric in greenish color, Sn mordanted fabric in orange color, and Fe mordanted fabric in khaki color. The mordanting was effective at improving wash fastness and light fastness.

• Journal of Photoscience
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• 제1권1호
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• pp.25-29
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• 1994

Diffuse reflectance and emission spectra of 7-hydroxyquinoline intercalated in the supercage of X and Y zeolites are compared with the absorption and emission spectra of aqueous 7-hydroxyquinoline solutions at various pH to understand protropic and photophysical properties of 7-hydroxyquinoline in zeolite microenvironments. Predominance of zwitterionic spedes with significant existences of the other three protropic equilibrium species, normal, protonated and deprotonated species in zeolite samples indicates that the major fraction of the molecules interact with strong acid and base sites of zeolite at an adsorbed position. Observed zeolite pHs of near neutrality are established by a near balance in numbers of many strong acid and base sites rather than by'small numbers or weakness of acid and base sites. Excitations of nonzwitterionic species such as deprotonated species also give prevailing zwitterionic fluorescence, indicating that excited and ground proton transfer cycles of protropic species can be triggered by photons in organized zeolite media as well as in water.

• Journal of Photoscience
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• 제7권3호
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• pp.97-101
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• 2000

The 77 K emission and excitation spectra, and 298 K infrared and absorption spectra of mer-[CrCl(en)(dpt)]ZnCl$_4$(en=1,2-diaminoethane; dpt=1,5,9-triazanonane) have been measured. Ligand field electronic transitions due to spin-allowed and spin-forbidden are assigned. The zero-phonon line in the excitation spectrum splits into two components by 151$cm^{-1}$ /, and large$^2$E$^{g}$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the en and dpt ligands have a strong $\delta$-donor character, but chloride ligand has weak $\delta$-and $\pi$-donor properties toward chromium(III) ion.

• 한국분말재료학회지
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• 제20권5호
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• pp.371-375
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• 2013

ZnO nanoparticles in the size range from 5 to 15 nm were prepared by zinc-lithium-acetate system. The morphologies and structures of ZnO were characterized by TEM, XRD and FT-IR spectra. UV-visible results shows that the absorption of ZnO nanoparticles is blue shifted with decrease in particles size. Furthermore, photoluminescence spectra of the ZnO nanoparticles were also investigated. The ZnO nanoparticles have strong visible-emission intensity and their intensities depend upon size of ZnO nanoparticles.

• 천문학회지
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• 제29권spc1호
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• pp.35-38
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• 1996

Much of our knowledge about the formation and evolution of high-redshift galaxies has come from studying the absorption signatures they impress on the spectra of background QSOs. The damped Lyman $\alpha$ (DLA) systems, in particular, have proved to be valuable probes of the metallicity and dust at redshifts z $\~$2-3 in what are the likely progenitors of galaxies like our own. At z $\~$ 2 we find that the typical metallicity of the universe was 1/15 solar. In addition, we find clear evidence for the existence of trace amounts of interstellar dust in DLA galaxies and show that this is consistent with recent high resolution spectra of DLAs with the Keck telescope, despite claims to the contrary.

• 한국광학회:학술대회논문집
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• 한국광학회 2000년도 제11회 정기총회 및 00년 동계학술발표회 논문집
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• pp.258-259
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• 2000

Quantum Well Disordering (QWD) has drawn a considerable attention in recent years$^{(1-3)}$ due to its wide applicability to optoelectronic devices. QWD allows modification of the shape of QW in selected regions, hence it modifies the subband energies in conduction and valance bands$^{(4)}$ . This leads to changes in optical properties such as band gap, absorption coefficient and refractive index. Thus such disordering in selected areas enables monolithic integration of various optoelectronic devices such as lasers, EA/EO modulators, waveguides and optical amplifiers. In this paper, we investigate the quantum well disordering effects on photoluminescence spectra by using experimental measurements and theoretical analysis$^{(5)}$ . (omitted)