• Title/Summary/Keyword: absorption spectra

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The chemical effects of milking machine detergents on the rubber composition of the newly-developed teat cup liners (착유기 세척제가 신개발 젖소 유두컵 라이너용 고무조성물 재질에 미치는 화학적 영향)

  • Lee, Jeong-Chi
    • Korean Journal of Veterinary Service
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    • v.41 no.2
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    • pp.125-131
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    • 2018
  • This study investigated the effects of the alkaline detergent and acid rinse used for cleaning milking machines on the rubber composition of the newly-developed teat cup liners. The samples prepared for use in the clean-in-place process were analyzed by ultraviolet spectrophotometer, ion chromatography and liquid chromatography. In the absorption spectrum of the first sample solution, the form of absorbance or absorption peak was largely different, compared to the absorption spectrum of alkaline detergent alone, but in the absorption spectra of the second and third sample solutions, the absorbance decreased, which was similar to the absorption spectrum in the pure acid detergent. In the ion chromatogram, two main peaks only, which might be shown by the pure alkaline detergent alone, were measured. In the liquid chromatograms, however, new peaks were observed in addition to the two main peaks caused by the pure alkaline detergent alone, which suggested that various molecular materials were created or eluted from the liner by the reaction with the alkaline detergent, but when washed with the acid detergent, any ion species were not produced. Therefore, we propose that an acid rinse should be applied, after cleaning the milking machine with the alkaline detergent.

Electrochemical Study on Rhodamine 6G-Indole Based Dye for HOMO and LUMO Energy Levels

  • Kim, Hyungjoo;Lee, Do-Hyun;Son, Young-A
    • Textile Coloration and Finishing
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    • v.25 no.1
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    • pp.7-12
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    • 2013
  • The energy levels are very important to investigate properties of organic dye materials. These values of energy levels can be calculated and compared with absorption spectra, cyclic voltammetric measurement and computer simulative calculation. In this study, absorption and emission changes were observed by complexation between rhodamine 6G based dye and mercury. This is related to spirolactam ring system of rhodamine 6G based dye. According to structural change of this dye, HOMO and LUMO energy levels were investigated and determined by their values with different approaches.

졸-겔법에 의한 CdS 분산$SiO_2$ Glass 박막의 비선형광학특성

  • 문종수;강종봉;김경문
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1353-1364
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    • 1996
  • Recently semiconductor doped glasses have attracted attention as nonlinear optical materials because of their large third order nonlinear optical properties. The transparent and homogeneous CdS-doped SiO2 glass thin films were obtained by the dip=coating process of the sol-gel method. Thin films were consisted of glasses containing CdS microcrystallites which were formed by dissolved Cd2+ and S2- ions in a SiO2 matrix solutions. A subsequent thermal treatment of this samples led the formation of colloidal agglomerates and finally of microcrystallites. The size of CdS microcrystallites was about 4 to 15 nm after thermal treatments at various heating conditions. From the optical absorption spectra of the CdS-doped SiO2 glass films it was found that the absorption edge was blue-shifted compared with that of the bulk CdS crystal(~2, 4 eV) and that the amount of energy shift was inversely proportional to the crystal size. And the band gap energy increased with the decrease in crystallite size indicating that the quantum size effects occured.

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Optical Properties of $In_2S_3$ and $In_2S_3:Co^{2+}$ single crystal ($In_2S_3$$In_2S_3:Co^{2+}$ 단결정의 광학적 특성에 관한 연구)

  • Oh, Seok-Kyun;Park, Kwang-Ho;Hyun, Seung-Cheol;Jeong, Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.156-156
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    • 2008
  • Single crystal of $In_2S_3$ and $In_2S_3:Co^{2+}$ were grown successfully with a good quality by the CTR(Chemical Transport Reaction)method. XRD analysis showed that the grown In2S3 and $In_2S_3:Co^{2+}$ single crystals were cubic structure. The optical absorption spectra of $In_2S_3:Co^{2+}$ single crystal showed impurity absorption peaks due to cobalt impurity. These impurity absorption pesks were assigned to the ligand transition between the split energy levels of $Co^{2+}$ ions with $T_d$ symmetry of these semiconductor host lattice.

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Deterioration Mechanism of Paper According to Sizing and Beating (II) -Influences of Beating- (사이징과 고해에 따른 종이의 열화기구(제2보) -고해의 영향-)

  • 김봉용
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.2
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    • pp.58-63
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    • 1999
  • Three kinds of papers were prepared from different beating degree of pulps. Physical and optical properties were examined to elucidate the deterioration mechanism of paper according to beating degrees. Changes of double folds, elongation, water retention value, DP, K/S value and visible, UV region light absorption spectra of those papers treated by UV light were studied. Double folds and brightness were decreased more rapidly by UV treatment with increasing of beating degree. The light absorption rates of pulps in visible and UV region were also increased with change of beating level. The formation of new hydrogen bonds and higher light absorption rate of pulps according to beating induced to absorb and interact with much UV light. These phenomena maybe brought about to accelerate paper deteriortion by UV treatment both optical and physical properties.

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New red light-emitting copolymer based on polyfluorene

  • Cho, Nam-Sung;Hwang, Do-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.721-723
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    • 2002
  • We report a new red light emitting fluorene-based copolymer, poly{9,9-bis(2'-ethylhexyl)fluorene-2,7-diyl-co-2, 5-bis(2-thienyl-1-cyanovinyl}-1-(2'-ethylhexyloxy)-4methoxybenzene-5",5'''-diyl} (PFTCVB). The synthesized copolymers showed the absorption maxima at about 380 nm and the absorption between 425 and 600 nm increased as the fraction of the thiophene-containing monomer (BTCVB) increased. In PL, the emission maxima of the copolymers were red-shifted as the fraction of BTCVB increased, despite the similar absorption characteristics were shown in the UV-visible spectra. The copolymer containing 15 mol% of BTCVB showed a maximum PL and EL emission at 620 and 630 nm.

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Synthesis of Super Hydrophobic Orange Dyes Having Maximum Absorption at 450-500nm for Pure Polyolefin Fibers (450-500nm의 최대흡수를 가지는 순수 폴리올레핀 소재용 초소수성 오렌지 염료의 합성)

  • Kim, Taekyeong;Ryu, Myeonghwa
    • Textile Coloration and Finishing
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    • v.26 no.3
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    • pp.165-172
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    • 2014
  • Novel super hydrophobic orange dyes having maximum absorption band at 450-500nm were synthesized to dye polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers, using 4-alkylanilines and ${\beta}$-naphthol. Their absorption spectra at visible range showed almost the same, which meant that the alkyl substituents introduced to chromophore did not affect on color appearance of the dyes. Considering both color strength and wash fastness, the decyl-substituted dye was determined as the optimum one practically. From the dyeing results at various conditions, the optimum dyeing was $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing 4-5 for both fibers. Light fastness was also acceptable giving rating 3-4 for polypropylene fibers and rating 3 for ultra high molecular weight polyethylene fibers.

Anthraquinone and Indole based Chemosensor for Fluoride Anions Detection

  • Son, Young-A;Kim, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.26 no.1
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    • pp.1-6
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    • 2014
  • We have designed and synthesized the colorimetric chemosensor through the reactions of 1,2-anthraquinone and indol-3-carboxaldehyde. Due to its well conjugated D-${\pi}$-A system and the existence of NH-fragment in indole moiety, we expected that the chemosensor can detect target anions with NH-fragment in indole part of the structure. In this regard, UV-Vis absorption spectra were measured to investigate sensing properties of the probe toward different anions in DMSO. This chemosensor shows to detect fluoride anions with absorption change in intensity. These properties are mainly related to the deprotonation effect. ICT system in this molecule was also observed by the computational approach using Material Studio 4.3 package.

A study on the electrical and magnetic properties of Viologen-TCNQ(2:2) LB films (Viologen-TCNQ(2:2) LB막의 전기 및 자기적 특성에 관한 연구)

  • 이용수;신동명;김태완;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.195-198
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    • 1996
  • In conducting systems based on LB films, TCNQ derivatives have been extensively studied as electron acceptor molecules. We have investigated the optical, electrical, and magnetic properties of Viologen-(TCNQ ̄)$_2$LB films. In UV/visible absorption measurements, we have observed TCNQ ̄ peak at 380 nm and dimer peak at 620 nm. The electron spin resonance measurements infer that Viologen-(TCNQ ̄)$_2$LB film exhibits anisotropic properly. In other words, the LB film shows angular dependence. Iodine doping affects the degree of charge transfer and the conductivity of the films. The UV/visible absorption spectra of the LB film doped with I$_2$show peaks at near 400~430 nm and there is no dimer absorption peak. The in-plane electrical conductivity of the undoped film is approximately 4.2$\times$10$^{-6}$ S/cm.

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Improved spectral line measurements of the SDSS galaxy spectra

  • Oh, Kyu-Seok;Sarzi, Marc;Yi, Suk-Young
    • Bulletin of the Korean Space Science Society
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    • 2009.10a
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    • pp.35.1-35.1
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    • 2009
  • We have established a database of galaxy spectral line strengths for the SDSS database using an improved line measuring method. Our work includes the entire SDSS DR7 galaxies within redshift of 0.2. The absorption line strengths measured by the SDSS pipeline are seriously contaminated by emission filling. Our code, GANDALF (gas and absorption line fitting code) performs more accurate measurements by effectively separating emission lines from absorption lines. A significant improvement has also been made on the velocity dispersion measurement, more notably in late-type galaxies. We have also identified a number of broad line region galaxies which were misclassified as normal galaxies by the SDSS pipeline. We developed an effective method measuring their line strengths. The database will be provided with new parameters that are indicative of the line strength measurement quality. In addition, we made galaxy templates for the Hubble sequence. The database will be useful for many fields of galaxy studies including star formation and AGN activities.

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