• Title/Summary/Keyword: absorption mechanism

Search Result 552, Processing Time 0.03 seconds

Study on Photochromism for Transition Metal Compounds by Using the Optieal Waveguide (광 도파관을 이용한 전이금속 화합물의 광색성연구)

  • SeeWooLee
    • Journal of the Korean Graphic Arts Communication Society
    • /
    • v.10 no.1
    • /
    • pp.1-13
    • /
    • 1992
  • The recent results concerning the synthesis and application of spiroxazine dyes have been summerized., The absorption bands of usual spiroxazine dyes are changed from colorless to colored from by irradiation of ultraviolet ray. This mechanism is derived from the cleavage of oxazine ring. Such properties are dependent on its chemical structure and surrounded matrix of spiroxazine dyes. the chemical structure of this dye is similar to the well known spriopyran. But spiroxazine dyes have noticed recently, because of excellent high light-sensitivity and superior fatigue-resistant property. This dye are already applied as photochromic lens, cloths and UV light checker.

  • PDF

Recent progress in silicon photocatalyst (실리콘 광 촉매 연구동향)

  • Lee, Min Woo;Shim, Woo Young
    • Ceramist
    • /
    • v.23 no.2
    • /
    • pp.178-183
    • /
    • 2020
  • Solar energy conversion is now actively researching because of pollution. Especially silicon photocatalyst has big potential, because of wide absorption range. But low quantum yield of silicon photocatalyst can't be used for commercialization. This paper summarize mechanism of silicon photocatalyst. In addition, properties and current states of photo catalyst using nanomaterials of silicon are also introduced.

Noise Evaluation and Measures of Cooling Tower at Apartment (아파트 냉각탑의 소음 평가 및 대책)

  • Lee, Kyu-Bae
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 2004.11a
    • /
    • pp.1020-1023
    • /
    • 2004
  • Recently, Cooling tower are used the necessary element in a residential area and living space on the viewpoint of indoor temperature control. The purpose of this study is to assistance the comfortable environment and economical measures of noise transmission mechanism on tile cooling tower. The results show that noise evaluation interact the main factor of distance reduction and diffraction reduction. Noise criterion apply to the NC level and equivalent transmission loss about already the design of noise reduction.

  • PDF

Expanding Thermal Plasma CVD of Silicon Thin Films and Nano-Crystals: Fundamental Studies and Applications

  • Sanden, Richard Van De
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.08a
    • /
    • pp.78-78
    • /
    • 2012
  • In this presentation I will review the expanding thermal plasma chemical vapour deposition (ETP-CVD) technology, a deposition technology capable of reaching ultrahigh deposition rates. High rate deposition of a-Si:H, ${\mu}c$-Si:H, a-SiNx:H and silicon nanocrystals will be discussed and their various applications, mainly for photovoltaic applications demonstrated. An important aspect over the years has been the fundamental investigation of the growth mechanism of these films. The various in situ (plasma) and thin film diagnostics, such as Langmuir probes, retarding field analyzer, (appearance potential) mass spectrometry and cavity ring absorption spectroscopy, spectroscopic ellipsometry to name a few, which were successfully applied to measure radical and ion density, their temperature and kinetic energy and their reactivity with the growth surface. The insights gained in the growth mechanism provided routes to novel applications of the ETP-CVD technology, such as the ultrahigh high growth rate of silicon nanorystals and surface passivation of c-Si surfaces.

  • PDF

Deterioration Mechanism of Paper according to Sizing and Beating(I)-Influences of Sizing- (사이징과 고해에 따른 종이의 열화기구(제1보)- 사이징의 영향 -)

  • 김봉용
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.30 no.2
    • /
    • pp.24-29
    • /
    • 1998
  • This study was carried out in order to elucidate the deterioration mechanism of paper according to various sizing chemicals. No additive paper and four kinds of papers containing rosin-alum, alum only, alkylketene dimer(AKD)-cation polymer and cation polymer only were treated by UV light to study changes of water-resistant, optical and mechanical properties from the view points of natural deterioration of paper. Since rosin chemicals have UV absorption at the relatively long wavelength region, rosins are degraded to form hydrophilic groups such as carboxylic acid from their double bonds by UV treatments. These phenomena caused the decreasing of sizing degree and wetting time in case of rosin-sized paper, while the UV treatments brought about the slight increase of wetting time in rosin-free papers such as no additive, alum and kymene only paper owing to the auto-sizing effect. Optical properties were primarily influenced by sizing chemicals. Rosin-sized paper showed lower brightness after UV and near UV treatment because of its UV instability.

  • PDF

Antidiabetic Activity and Mechanisms of Acarbose in $KKA^{y}$ Mice

  • Kim, Young-Lim;Chung, Sung-Hyun
    • The Korean Journal of Physiology and Pharmacology
    • /
    • v.5 no.2
    • /
    • pp.183-188
    • /
    • 2001
  • To elucidate antidiabetic effect and mechanism(s) of acarbose in a polygenic spontaneous hyperglycemic and hyperinsulinemic diabetic animal model, $KKA^y$ mice, acarbose was administered orally for 4 weeks and effects on body weight, plasma glucose and insulin levels, genetic expressions of intestinal sucrase-isomaltase (SI), sodium-glucose cotransporter (sGLT1) and glucose transporter in quadriceps muscle (GLUT4) were examined in this study. Although no differences in body weight were detected between control and acarbose-treated groups, plasma glucose level in acarbose-treated group was markedly reduced as compared to the control. In the mechanism study, acarbose downregulated the SI and SGLT1 gene expressions, and upregulated the GLUT4 mRNA and protein expressions when compared to the control group. In conclusion, the data obtained strongly implicate that acarbose can prevent the hyperglycemia in $KKA^y$ mice possibly through blocking intestinal glucose absorption by downregulations of SI and sGLT1 mRNA expressions, and upregulation of skeletal muscle GLUT4 mRNA and protein expressions.

  • PDF

Reaction Mechanism on the Synthesis of $SrTiO_3$ by Direct Wet Process ($SrTiO_3$ 습식 직접 합성 반응기구에 관한 연구)

  • 이경희;이병하;김대웅
    • Journal of the Korean Ceramic Society
    • /
    • v.23 no.6
    • /
    • pp.45-51
    • /
    • 1986
  • $SrTiO_3$ reaction mechanism formed from $TiCl_4$ and $SrCl_2$ solution by direct-wet-process was studied. Through this study it is identified that crystalline $SrTiO_3$ is formed above pH 13.8 amorphous $SrTiO_3$ above pH7 and crystallization temperature of amorphous $SrTiO_3$ is at 37$0^{\circ}C$. the final products are composed of 60% crystalline $SrTiO_3$ and 40% amorphous $SrTiO_3$ The amorphous $SrTiO_3$ is identified with the IR absorption spectrum of Sr-Ti-O by FT-IR spectrometer. Under pH 7 gelationus metatitanate (H2TiO3) is formed from TiCl4 but above pH7 the activity by the formation of metatitnic acid ion $[TiO_3]^{2-}$ is so high that $SrTiO_3$is formed more easily through the reaction with $Sr^{2+}$.

  • PDF

Kinetic Study on Absorption of Carbonyl Sulfide in Aqueous Monoethanolamine

  • Park, Moon-Ki;Moon, Yung-Soo;Suh, Dong-Soo
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • v.4 no.3
    • /
    • pp.195-200
    • /
    • 2000
  • The kinetics of the reaction between carbonyl sulfide and aqueous monoethanolamine were studied over a range of temperature (298-348 K) and amine concentrations using a wetted-sphere absorber. The key physicochemical properties used to interpret the data included the solubility and diffusivity of the COS in the aqueous amine solution. The experimental data were interpreted using a zwitterion mechanism, which produced an Arrhenius plot with third-order kinetic rate constants. The fit of these data was $K_3$=$1.32\times10(sup)10exp(\frac{-6136}{T}}$

  • PDF

Preparation of Highly Visible-Light Photocatalytic Active N-Doped TiO2 Microcuboids

  • Zhao, Kang;Wu, Zhiming;Tang, Rong;Jiang, Yadong
    • Journal of the Korean Chemical Society
    • /
    • v.57 no.4
    • /
    • pp.489-492
    • /
    • 2013
  • N-doped $TiO_2$ microcuboids were successfully prepared by a simple one-pot hydrothermal method. The samples were characterized by X-ray diffraction, scanning electron microscopy, diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. It was found that the N-doped $TiO_2$ microcuboids enhanced absorption in the visible light region, and exhibited higher activity for photocatalytic degradation of model dyes. Based on the experimental results, a visible light induced photocatalytic mechanism was proposed for N-doped anatase $TiO_2$ microcuboids.

Effect of Polyoxyethylene Alkyl Esters on Permeation Enhancement and Impedance of Skin

  • Kim, Hee-Sun;Oh, Seaung-Youl
    • Biomolecules & Therapeutics
    • /
    • v.19 no.1
    • /
    • pp.109-117
    • /
    • 2011
  • In this work, we have investigated the effect of polyoxyethylene alkyl ester nonionic surfactants on percutaneous permeation enhancement of a model drug, ketoprofen. We also investigated the mechanism involved in the enhancement using impedance and solubility measurement. Three groups of nonionic surfactants with different ethylene oxide content were studied. The permeation results showed that all surfactants enhanced the percutaneous absorption, irrespective of the molecular weight. The permeation results from PEG-45 monostearate (PEGMS45) were rather unexpected. Impedance and solubility results indicate that the mechanism involved in the enhancement of permeation by PEG-10 monooleate (PEGMO10) and PEGMS45 is rather different. The results from PEGMS45 suggest that it could be a potential candidate as a skin penetration enhancer with high molecular weight, which may poses less skin irritation and systemic side effect than the smaller surfactant molecules. Overall, this work provided some useful information on percutaneous transport enhancement and the mechanistic insights involved in skin permeation for these nonionic surfactants.