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Real-time Evolution of Poly (3-hexylthiophene) type-II Phase in P3HT:PCBM Blend thin films

  • Lee, Hyeon-Hwi;Lee, Si-U;Geum, Hui-Seong;Kim, Han-Seong;Kim, Je-Han;Lee, Dong-Ryeol;Kim, Hyo-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.168.2-168.2
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    • 2015
  • We observed the temperature-dependent evolution and behavior of P3HT type-II phase during a real time annealing process from a cryo-cooled low temperature in the absence and presence of an Al electrode. A poly (3-hexylthiophene) (P3HT) Type-II phase in the P3HT:PCBM films started to form near at $-10^{\circ}C$, regardless of Al layer presence. In the absence of an Al layer, type-II phase was extinct at $30^{\circ}C$. However, the extinction temperature was extended to $50^{\circ}C$ in the presence of the Al layer. Simultaneously, combined with the type-II phase, a 1:3 ordered P3HT type-II (1/3,0,0) super-lattice peak evolved. These type-II domains tended to be formed near the Al electrode layer with higher aligned status than host P3HT crystals.

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A Survey Study of Nursing Diagnosis Use in Clinical Practice (간호진단의 임상적용 활성화를 위한 기초조사 연구)

  • 최영희;이향련;김혜숙;김소선;박광옥
    • Journal of Korean Academy of Nursing
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    • v.26 no.4
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    • pp.930-945
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    • 1996
  • The purpose of this study was to identify the degree to which nursing diagnoses accepted by NANDA are used and to identify problems in application of nursing diagnoses in clinical practice. With the expanding potential for computerization of nursing diagnosis, the survey also included data on the present status of hospital computerization and willingness to use computerized nursing diagnoses. The data collection was done from July 1 to August 3, 1996 using structured questionnaires. The questionnaires were mailed to 1,126 head nurses working in 44 hospitals with on occupacy of over 500 beds located in Korea, of these, 883 were returned from 40 hospitals. Among the 883 questionnaires, 867 were used for the analysis. The results of the analysis are as follows 1. Among 109 nursing diagnoses, pain, constipation, diarrhea, hyperthermia, high risk for infection, sleep pattern disturbance, and anxiety, chronic pain, altered urinary elimination, and altered nutrition : less than body requirements were the ten most frequently used diagnoses. 2. The primary problem in the use of nursing diagnoses was lack of time and personnel. Others were lack of knowledge and motivation, absence of protocols and absence of the appropriate methods to apply nursing diagnoses. 3. Among the 40 hospitals, 27 hospitals used a computerized system and expressed willingness to utilize the computerized system of nursing diagnoses that is planned for the future.

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Evaluation of the Genetic Toxicity of Synthetic Chemicals (IV) - in vitro Chromosomal Aberration Assay with 18 Chemicals in Chinese Hamster Lung Cells -

  • Ryu, Jae-Chun;Kim, Kyung-Ran;Kim, Youn-Jung
    • Environmental Mutagens and Carcinogens
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    • v.22 no.3
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    • pp.149-156
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    • 2002
  • The detection of many synthetic chemicals used in industry that may pose a genetic hazard in our environment is of great concern at present. Since these substances are not limited to the original products, and enter the environment, they have become widespread environmental pollutants, thus leading to a variety of chemicals that possibly threaten the public health. In this respect, to regulate and to evaluate the chemical hazard will be important to environment and human health. The clastogenicity of 18 synthetic chemicals was evaluated in Chinese hamster lung fibroblast cells in vitro. 4-Chloro-3,5-dimethyl phenol (CAS No. 88-04-0) induced chromosomal aberrations with significance at the concentration of 15.7 $\mu\textrm{g}$/$m\ell$ both in the presence and absence of metabolic activation system. Phenoxybenzene (CAS No. 101-84-8) which is one of the most cytotoxic chemical among 18 chemicals tested revealed no clastogenicity in the range of 0.11-0.43 $\mu\textrm{g}$/$m\ell$ both in the presence and absence of metabolic activation system. From the results of chromosomal aberration assay with 18 synthetic chemicals in Chinese hamster lung cells in vitro, 4-chloro-3,5-dimethyl phenol (CAS No. 88-04-0) revealed weak positive clastogenic results in this study.

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Statistical Model-Based Voice Activity Detection Using Spatial Cues for Dual-Channel Noisy Speech Recognition (이중채널 잡음음성인식을 위한 공간정보를 이용한 통계모델 기반 음성구간 검출)

  • Shin, Min-Hwa;Park, Ji-Hun;Kim, Hong-Kook;Lee, Yeon-Woo;Lee, Seong-Ro
    • Phonetics and Speech Sciences
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    • v.2 no.3
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    • pp.141-148
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    • 2010
  • In this paper, voice activity detection (VAD) for dual-channel noisy speech recognition is proposed in which spatial cues are employed. In the proposed method, a probability model for speech presence/absence is constructed using spatial cues obtained from dual-channel input signal, and a speech activity interval is detected through this probability model. In particular, spatial cues are composed of interaural time differences and interaural level differences of dual-channel speech signals, and the probability model for speech presence/absence is based on a Gaussian kernel density. In order to evaluate the performance of the proposed VAD method, speech recognition is performed for speech segments that only include speech intervals detected by the proposed VAD method. The performance of the proposed method is compared with those of several methods such as an SNR-based method, a direction of arrival (DOA) based method, and a phase vector based method. It is shown from the speech recognition experiments that the proposed method outperforms conventional methods by providing relative word error rates reductions of 11.68%, 41.92%, and 10.15% compared with SNR-based, DOA-based, and phase vector based method, respectively.

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A Persistent Left Superior Vena Cava Draining into Left Atrium Associated with ASD, Absence of the Coronary Sinus Ostium and PDA Report of One Case (관상정맥동불형성, 좌상공정맥좌심방환류, 동맥관개존을 동반한 심방중격결손의 체험예)

  • 조중구
    • Journal of Chest Surgery
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    • v.15 no.2
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    • pp.243-249
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    • 1982
  • A persistent left superior vena cava draining into the left atrium associated with atresia of the coronary sinus-ostium, ASD, and PDA is a rare congenital anomaly. The patient was a 4 year-old female whose complaints were frequent URI and exertional dyspnea. The congenital heart anomaly was suspected at 2 months of her age. Chest films showed cardiomegaly [C-T ratio, 75%]. EKG, Echocardiography, cardiac catheterization and angiocardiography were performed. Open heart surgery was done under impression of LV-RA shunt, bilateral superior vena cavae, and ASD. At the time of operation, huge LA and RA, inferior vena caval defect of a secundum type ASD [1.5 x 3cm in diameter], absence of innominate vein, atresia of the coronary sinus-ostium, and persistent LSVC draining into LA were noted. Direct suture closure of ASD and ligation of LSVC were done. The patient`s postoperative course was somewhat eventful: systolic murmur at apex remained. Four months after the operation, congestive heart failure attacked a few times. PDA that was overlooked at the time of open heart surgery was detected through postoperative cardiac catheterization in.4 months later. Emergent operation for closure of PDA was performed on the day of recatheterization. After that, patient`s heart failure was easily controlled without any notable problem.

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SENSITIZED PHOTOINITIATING SYSTEM USED IN PHOTOPOLYMER FILMS

  • Liu, A.D;Trifunac, A.D;Krongauz, V.V.
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.20-24
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    • 1998
  • Photploymer films are widely used in printing and electronic industries, and their usage is expanding to encompass holography, data storage and data processing, optical waveguides and compact disks, etc. One of widely used photoplymerization initiator, 20chloro-hexaarylbiimidazole (o-Cl-HABI), is studied by laser flash photolysis in dichloromethane solution in the absence and presence of the visible light photosensitizing dye, 2, 5-bis[(2, 3, 6, 7 -tetrahydro- 1H, 5H -benzo [i, j,] quinolizin -1-yl) methylene]-cyclopenta-none, (JAW). In the presence of JAW, an increase in triarylimidazolyl radicals L.formation is observed in relative to the absence of JAW. The mechanism of this photosensitizing dissociation is concluded as the dissociation of the o-Cl-HABI radical anion formed by the electron transfer from excited singlet state of JAW to o-Cl-HABI. The observed formation of L.radicals exhibits a linear dependence on o-Cl-HABI concentration. The rate constant of electron transfer obtained from this dependence is equal to (1.0$\pm$0.2) x $10^9 M^{-1}s^{-1}$. No reaction between the excited triplet state of JAW and o-Cl-HABI is found.

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THE INFLUENCE OF THE PRESENCE AND IMPACTED STATE OF MANDIBULAR THIRD MOLARS ON THE INCIDENCE OF MANDIBULAR CONDYLE FRACTURE (하악 제 3 대구치유무 및 매복정도가 하악과두 골절에 미치는 영향)

  • Oh, Jae-Kyung;Cha, Du-Won;Kim, Chin-Soo
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.28 no.6
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    • pp.565-569
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    • 2006
  • The purpose of this study was to assess the influence of the presence and impacted state of the mandibular third molars on the incidence of mandibular condyle fracture. A retrospective study was designed for patients presenting to the Department of Oral and Maxillofacial Surgery, Kyungpook National University Hospital and Tae-gu Fatima Hospital for treatment of mandibular fractures from January 2003 to January 2006. The independent variables in this study were the presence, degree of impaction of third molars, and the outcome variables were the incidence of mandibular condyle fractures. Hospital charts and panoramic radiographs were used to determine and classify these variables. The demographic data included age, sex, mechanisms of injuries and number of mandibular condyle fractures. The study sample comprised 136 mandibular condyle fractures in 105 patients. Result of this study demonstrated a statistically significant difference in ipsilateral condyle fractures and mandibular third molar absence(P=0.032) and bilateral condyle fractures without another fracture and mandibular third molar absence(P=0.028).

The Effects on Clothing Weight in the Health State of the Kindergartners (착의량이 유아건강에 미치는 영향)

  • Lee Won-Ja;Choi Jeong-wha
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.1 s.29
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    • pp.13-33
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    • 1989
  • The purpose of this study is to obtain the effects on clothing weight in the health state of the kindergartners. So 1 divided 140 kindergartners into 3 groups. A not trained of light wearing in the control group, B the semi-experimetnal group, C the experimental group. In the field surveys conducted their monthly clothing weight and anthropometric measurements, physique index (obesity index) and motor-ability and rate of cold contraction and of absence, Cornell Medical index from Jun, 1986 to Feb, 1987 in Seoul. 1) The experimental group was even less clothing than the control group in clothing weight during the training period. 2) All the experimental group droped conspicuosly the rate of cold contraction and absence during this period. 3) After this training, the experimental group was better than semi-experimental group and control group in motor-ability especially in standing broad jump, flexibility and tennis ball throw, 25 meter dash. 4) But, 1 could not find the different of anthropometric-measurements, physique-index about this train.

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THE IMPORTANCE OF BICARBONATE-BUFFER ON CARDIAC FUNCTION: Contractility, Membrane Potentials and ATP Content of Isolated Atria in the Absence of External Buffers (심장기능(心臟機能)에 미치는 Bicarbonate-Buffer의 중요성(重要性) : Buffer 제거(除去)에 의(依)한 유리심방(遊離心房)의 수축성(收縮性), 막전위(膜電位) 및 ATP 함량(含量)의 변동(變動))

  • Ko, Kye-Chang;Han, Dae-Sup;Jung, Jee-Chang
    • The Korean Journal of Pharmacology
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    • v.8 no.2
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    • pp.63-69
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    • 1972
  • The effects of omission of buffers from Krebs-Ringer medium on contractile activity, membrane potentials and ATP content of electrically stimulated isolated rat atria were investigated. 1) Contractile status: A rapid and marked depression of the contractile activity of atria occurred when buffer-free medium was substituted for the normal Krebs-Ringer medium. 2) Electrical status: The omission of buffers from medium did not alter the resting or action potential magnitudes of atria. However, the action potential duration was on initial increase followed by a decrease in the buffer-free medium. 3) ATP concentration: The omission of buffers from medium resulted in a marked decrease in the ATP levels of atria. It has been also found in the present study that bicarbonate buffer plays an important role for the maintenance of the contractility and ATP levels of the heart. The contractile depression by the omission of buffers was not directly associated with electrical alterations in resting or action potentials of the heart. In the absence of bicarbonate-buffer, glucose no longer plays to maintain the contractile activity and the ATP levels of rat atria.

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Poland Syndrome - A Case Report- (Poland 증후군 - 1예 보고 -)

  • Jeong, Soon-Taek;Moon, Dong-Kyu;Sung, Chang-Meen;Park, Hyung-Bin
    • Clinics in Shoulder and Elbow
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    • v.13 no.1
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    • pp.123-126
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    • 2010
  • Purpose: Poland syndrome is rare disease which is characterized by absence of unilateral pertoralis major muscle accompanied by ipsilateral syndactyly or brachydactyly, which was described first by Alfred Poland in 1841. Materials and Methods: We performed the physical examination, laboratory test and radiologic evaluation to 18 year old male, who complaint asymmetry of right anterior chest. Results: We diagnosed the Poland syndrome due to absence of right pectoralis major muscle and brachydactyly of right hand. Conclusion: Current authors report a patient who had hypopalsia of pectoralis muscles, which needed differential diagnosis with pectoralis major rupture.