• 제목/요약/키워드: a raman scattering

검색결과 226건 처리시간 0.028초

Investigation on HT-AlN Nucleation Layers and AlGaN Epifilms Inserting LT-AlN Nucleation Layer on C-Plane Sapphire Substrate

  • Wang, Dang-Hui;Xu, Tian-Han
    • Journal of the Optical Society of Korea
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    • 제20권1호
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    • pp.125-129
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    • 2016
  • In this study, we have investigated a high-temperature AlN nucleation layer and AlGaN epilayers on c-plane sapphire substrate by low-pressure metal-organic chemical vapor deposition (LP-MOCVD). High resolution X-ray diffraction (HRXRD), atomic force microscopy (AFM), scanning electron microscope (SEM) and Raman scattering measurements have been exploited to study the crystal quality, surface morphology, and residual strain of the HT-AlN nucleation layer. These analyses reveal that the insertion of an LT-AlN nucleation layer can improve the crystal quality, smooth the surface morphology of the HT-AlN nucleation layer and further reduce the threading dislocation density of AlGaN epifilms. The mechanism of inserting an LT-AlN nucleation layer to enhance the optical properties of HT-AlN nucleation layer and AlGaN epifilm are discussed from the viewpoint of driving force of reaction in this paper.

Optoelectronic Characteristics of Hydrogen and Oxygen Annealed Si-O Superlattice Diode

  • Seo, Yong-Jin
    • Transactions on Electrical and Electronic Materials
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    • 제2권2호
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    • pp.16-20
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    • 2001
  • Optoelectronic characteristics of the superlattice diode as a function of deposition temperature and annealing conditions have been studied. The multilayer nanocrystalline silicon/adsorbed oxygen (nc/Si/O) superlattice formed by molecular beam epitaxy (MBE) system. Experimental results showed that deposition temperature of 550$^{\circ}C$, followed by hydrogen annealing leads to best results, in terms of optical photoluminescence (PL) and electrical current-voltage (I-V) characteristics. Consequently, the experimental results of multilayer Si/O superlattic device showed the stable photoluminescence and good insulating behavior with high breakdown voltage. This is very useful promise for Si-based optoelectronic devices, and can be readily integrated with conventional silicon ULSI processing.

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Optical Characterization of Cubic and Pseudo-cubic Phase Perovskite Single Crystals Depending on Laser Irradiation Time

  • Byun, Hye Ryung;Jeong, Mun Seok
    • Applied Science and Convergence Technology
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    • 제27권2호
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    • pp.42-45
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    • 2018
  • Photovoltaic and optoelectronic devices based on hybrid metal halide perovskites ($MAPbX_3$; $MA=CH_3NH_3{^+}$, $X=Cl^-$, $Br^-$, or $I^-$) are rapidly improving in power conversion efficiency. Also, during recent years, perovskite single crystals have emerged as promising materials for high-efficiency photovoltaic and optoelectronic devices because of their low defect density. Here we show that the light soaking effect of mixed halide perovskite ($MAPbBr_{3-x}I_x$) single crystals can be explained using photoluminescence, time-resolved photoluminescence, and Raman scattering measurements. Unlike Br-based single crystal, Br/I mixed single crystal show a strong light soaking effect under laser irradiation condition that was related to the existence of multiple phases.

물리기상증착을 이용한 금속표면 나노구조제어 (Control of surface metal nanostructure with physical vapor deposition)

  • 정지혜;한민아;김현종;이호년
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2015년도 추계학술대회 논문집
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    • pp.251-251
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    • 2015
  • 최근 질병 조기진단에 대한 사회적 요구가 높아짐에 따라 이에 대한 기술에 관심이 집중되고 있다. 그 중 표면증강라만산란(surface enhanced Raman scattering(SERS))을 이용하여 인체 내 소량의 바이오마커를 검출하는 연구가 활발히 진행중이다. 본 연구에서는 바이오마커의 검지감도를 최대치로 증가시키기 위해 SERS 기판의 나노구조를 최적화 하였다. SERS 기판 표면의 나노구조, 크기, 형상, 밀도 등에 따라 검지감도가 변화되기 때문에 이를 제어하기 위해 증착공정 변수에 변화를 주어 표면의 나노구조를 형성하였다. 이를 분석하기 위해 SEM, XRD를 사용하였으며 최적화된 SERS 기판을 활용하여 Rhodamine 6G의 신호가 $1{\times}10^5$ 이상의 enhancing factor를 확인하였다.

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Multi-kilowatt Single-mode Ytterbium-doped Large-core Fiber Laser

  • Jeong, Yoon-Chan;Boyland, Alexander J.;Sahu, Jayanta K.;Chung, Seung-Hwan;Nilsson, Johan;Payne, David N.
    • Journal of the Optical Society of Korea
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    • 제13권4호
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    • pp.416-422
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    • 2009
  • We have demonstrated a highly efficient cladding-pumped ytterbium-doped fiber laser, generating $>$2.1 kW of continuous-wave output power at 1.1 μm with 74% slope efficiency with respect to launched pump power. The beam quality factor ($M^2$) was better than 1.2. The maximum output power was only limited by available pump power, showing no evidence of roll-over even at the highest output power. We present data on how the beam quality depends on the fiber parameter, based on our current and past fiber laser developments. We also discuss the ultimate power-capability of our fiber in terms of thermal management, Raman nonlinear scattering, and material damage, and estimate it to 10 kW.

루비듐 셀을 이용한 마이크로파 주파수 표준기 연구 (A Study of the Microwave Frequency Standard with Rubidium Cell)

  • 박상종;조혁;박종대;권택용;이호성
    • 한국광학회:학술대회논문집
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    • 한국광학회 2000년도 하계학술발표회
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    • pp.78-79
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    • 2000
  • 소형 루비듐 원자시계를 만들기 위해 원자에서의 CPT(coherent population trapping) 현상, 유도 라만 산란(SRS: Stimulated Raman Scattering), 루비듐 메이저 등 다양한 방법들이 소개되고 있다$^{(1, 3)}$ . 본 연구에서는 루비듐 원자 주파수 표준기를 위해 루비듐 셀을 이용한 마이크로파 주파수 표준기(즉, 원자시계)에 관한 연구를 수행하였다. 루비듐 셀을 이용한 원자시계는 가격이 저렴하고 부피가 작아 휴대용으로 적합하다. 따라서 정보통신 분야에서 동기 신호 발생기에 사용되는 등 다양한 응용분야를 갖고 있다. (중략)

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고효율 바이오물질 분리 및 농축을 위한 나노필터소자제작 (Fabrication of Nano-filter Device for High Efficient Separation and Concentration of Biomolecules)

  • 허윤석;최봉길;홍원희
    • Korean Chemical Engineering Research
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    • 제50권4호
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    • pp.738-742
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    • 2012
  • 본 연구에서는 알루미나 나노 템플레이트(anodic alumina oxide; AAO)를 이용하여 신속하면서도 효과적으로 나노입자 및 바이오물질을 분리, 농축할 수 있는 나노필터 소자를 개발하였다. 본 연구에서 사용한 나노필터 소자는 유체의 주입 및 흐름이 가능한 미세유체채널(microfluidic channel)을 PDMS에 패터닝하였다. 위아래로 형성된 PDMS 미세유체채널 사이로, 다양한 크기의 나노 다공을 형성하고 있는 AAO 막을 삽입하여 크기에 따른 나노입자 및 바이오 물질을 분리할 수 있었다. 위아래로 PDMS 유체채널과 AAO 분리막을 집적하고, 최종적으로 아크릴레이트 플락스틱(acrylic plastic)으로 전체 소자를 고정하여 나노필터유체소자를 제작하였다. 완성된 나노필터소자를 이용하여 나노입자의 농축효율 및 은나노입자가 뭉쳐져있는 필터존(filtration zone)으로부터 뎅기 바이러스(dengue virus)를 표면증강라만(surface enhanced Raman scattering)분석법에 의해 검출할 수 있었다.

Fabrication of shape-controlled Au nanoparticle arrays for SERS substrates

  • Shin, Seon Mi;Choi, Kyeong Woo;Ye, Seong Ji;Kim, Young Yun;Park, O Ok
    • Advances in materials Research
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    • 제3권3호
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    • pp.139-149
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    • 2014
  • Surface enhanced Raman Scattering (SERS) has attracted attention because the technique enables detection of various chemicals, even down to single molecular scale. Among the diverse candidates for SERS substrates, Au nanoparticles are considered promising due to their fine optical properties, chemical stability and ease of surface modification. Therefore, the fabrication and optical characterization of gold particles on solid supports is highly desirable. Such structures have potential as SERS substrates because the localized surface plasmon resonance of gold nanoparticles is very sensitive to combined molecules and environments. In addition, it is well-known that the properties of Au nanoparticles are strongly dependent on their shape. In this work, arrays of shape-controlled Au nanoparticles were fabricated to exploit their enhanced and reproducible optical properties. First, shape-controlled Au nanoparticles were prepared via seed mediated solution-phase synthesis, including spheres, octahedra, and rhombic dodecahedra. Then, these shape-controlled Au nanoparticles were arranged on a PDMS substrate, which was nanopatterned using soft lithography of poly styrene particles. The Au nanoparticles were selectively located in a pattern of hexagonal spheres. In addition, the shape-controlled Au nanoparticles were arranged in various sizes of PDMS nanopatterns, which can be easily controlled by manipulating the size of polystyrene particles. Finally, the optical properties of the fabricated Au nanoparticle arrays were characterized by measuring surface enhanced Raman spectra with 4-nitrobenezenethiol.

공생별 Z And의 선윤곽 분석 (An Analysis of the Symbiotic Star Z And Line Profile)

  • 이성재;형식;이강환
    • 한국지구과학회지
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    • 제33권7호
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    • pp.608-617
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    • 2012
  • 분해능이 ${\Delta}{\lambda}{\sim}-0.1{\AA}$인 고분산 분광기를 사용하여 공생별 Z Andromedae (And)의 분광자료를 연구하였다. 분광 관측은 (1) 2001년 8월 30일(위상 ${\Phi}$=0.77)과 2002년 8월 12일(위상 ${\Phi}$ =0.22)에 Lick 천문대의 Hamilton Echelle Spectrograph (HES)를 사용하여, 1800초와 3600초 노출의 고분산 자료를 얻었으며, (2) 2009년 10월 21일(위상 ${\Phi}$=0.70)에는 보현산 천문대의 Bohyunsan Echelle Spectrograph (BOES)를 사용하여 1200초 노출 시간의 고분산 자료를 얻었다. 약 $3600{\AA}-9500{\AA}$파장대의 HES와 BOES 관측 자료로 부터 HI, HeI, HeII에 대한 방출선을 선택하여 분석하였다. 이 선들의 선 윤곽 분석 작업을 통해 2개 또는 3개로 분리시키고, 위상별로 각 성분이 어떤 지역에서 형성되고, 백색왜성과 적색거성의 궤도 운동과 어떠한 관련이 있는지를 조사하였다. 라만 산란(Raman scattering)된 $H{\alpha}$선 선폭 및 HI, HeI, HeII의 위상별 변화를 보이는 방출선의 특성으로부터, 방출선들은 백색왜성 주위를 감싸는 강착원반과 이 원반 안의 두 라그랑지안(Lagrangian) 포인트 $L_1$$L_2$지역에서 주로 생성된 것으로 결론지었다. Z And는 활동성이 2009년과 2001년에 가장 활발했고, 2002년의 선 윤곽은 매우 복잡한 양상을 보임에도 불구하고, 활동성은 비교적 조용하였음을 암시하고 있다.

Highly catalysis Zinc MOF-loaded nanogold coupled with aptamer to assay trace carbendazim by SERS

  • Jinling Shi;Jingjing Li;Aihui Liang;Zhiliang Jiang
    • Advances in nano research
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    • 제14권4호
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    • pp.313-327
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    • 2023
  • Zinc metal organic framework (MOFZn)-loaded goad nanoparticles (AuNPs) sol (Au@MOFZn), which was characterized by TEM, Mapping, FTIR, XRD, and molecular spectrum, was prepared conveniently by solvothermal method. The results indicated that Au@MOFZn had a very strong catalytic effect with the nanoreaction of AuNPs formation between sodium oxalate (SO) and HAuCl4. AuNPs in the new indicator reaction had a strong resonance Rayleigh scattering (RRS) signal at 370 nm. The indicator AuNPs generated by this reaction, which had the most intense surface enhanced Raman scattering (SERS) peak at 1621 cm -1. The new SERS/RRS indicator reaction in combination with specific aptamer (Apt) to fabricate a sensitive and selective Au@MOFZn catalytic amplification-aptamer SERS/RRS assay platform for carbendazim (CBZ), with SERS/RRS linear range of 0.025-0.5 ng/mL. The detection limit was 0.02 ng/mL. Similarly, this assay platform has been also utilized to detect oxytetracycline (OTC) and profenofos (PF).