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Development of Real-time Oceanographic Information System for Long Line Hanging Aquaculture Farm and Temperature Variation in the Coastal Area of the East Sea (수하식 양식장용 실시간 해양환경 관측시스템 개발 및 동해 연안의 수온변동 특성)

  • Yang, Joon-Yong;Kim, Lim-Hak;Lee, Joon-Soo;Hwang, Jae-Dong;Suh, Young-Sang;Kim, Dae-Chul
    • Journal of Environmental Science International
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    • v.19 no.11
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    • pp.1397-1405
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    • 2010
  • Mass mortalities of cultivated organisms have occurred frequently in Korean coastal waters causing enormous losses to cultivating industry. The preventive measures require continuous observation of farm environment and real-time provision of data. However, line hanging aquaculture farm are generally located far from monitoring buoys and has limitations on installation of heavy equipments. Substituting battery pack for solar panels and miniaturizing size of buoy, newly developed system can be attached to long line hanging aquaculture farm. This system could deliver measured data to users in real-time and contribute to damage mitigation and prevention from mass mortalities as well as finding their causes. The system was installed off Gijang and Yeongdeck in Korea, measuring and transmitting seawater temperature at the sea surface every 30 minutes. Short term variation of seawater temperature, less than one day, in Gijang from June to July 2009 corresponded tidal period of about 12 hours and long term variation seemed to be caused by cold water southeast coast of Korea, particularly northeast of Gijang. Seawater temperature differences between Gijang station and the other station that is about 500 m away from Gijang station were $1^{\circ}C$ on average. This fact indicates that it is need to be pay attention to use substitute data even if it is close to the station. Daily range of seawater temperature, one of crucial information to aquaculture, can be obtained from this system because temperature were measured every 30 minutes. Averages of daily range of temperature off Gijang and Yeongdeok during each observation periods were about $2.9^{\circ}C$ and $4.7^{\circ}C$ respectively. Dominant period of seawater temperature variation off Yeongdeok was one day with the lowest peak at 5 a.m. and the highest one at 5 p.m. generally, resulting from solar radiation.

Synthesis of Self-doped Poly(PEGMA-co-BF3LiMA) Electrolytes and Effect of PEGMA Molecular Weight on Ionic Conductivities (자기-도핑형 poly(PEGMA-co-BF3LiMA) 전해질의 합성과 이온전도도에 대한 PEGMA분자량의 영향)

  • Kim, Kyung-Chan;Ryu, Sang-Woog
    • Journal of the Korean Electrochemical Society
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    • v.15 no.4
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    • pp.230-235
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    • 2012
  • Polymer electrolytes consisted of $BF_3LiMA$ and 300 (PEGMA300) or 1100 (PEGMA1100) g $mol^{-1}$ of PEGMA were prepared and the electrochemical properties were characterized. Interestingly, the AC-impedance measurement shows $1.22{\times}10^{-5}S\;cm^{-1}$ of room temperature ionic conductivity from PEGMA1100 based solid polymer electrolytes while $8.54{\times}10^{-7}S\;cm^{-1}$ was observed in PEGMA300 based liquid polymer electrolytes. The more suitable coordination between lithium ion and ethylene oxide (EO) unit might be the reason of higher ionic conductivity which can be possible in PEGMA1100 based electrolytes since it has 23 EO units in monomer. The lithium ion transference number was found to be 0.6 due to the side reactions between $BF_3$ and lithium metal expecially for longer time but 0.9 was observed within 3000 seconds of measuring time which is strong evidence of a single-ion conductor.

Synthesis and Electrochemical Characterization of Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine Composite as Polymer Cathode Material (Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine 복합체 고분자 양극재료의 합성과 전기화학적 특성)

  • Oh, Ji-Woo;Ryu, Kwang-Sun
    • Journal of the Korean Electrochemical Society
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    • v.15 no.4
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    • pp.222-229
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    • 2012
  • We studied the electrochemical phenomena and increase of capacity according to the polymer composite electrode of two different polymeric materials with different the voltage range and capacity. Polyaniline (PANI) with relatively high voltage and small capacity and poly [1,2] bis-thio[1,8]-naphthylidine (PTND) with slightly low voltage and large capacity were used as polymer composite electrode materials. After PTND was synthesized, PANI was synthesized on the surface of PTND. The synthesis and the fine structure were analyzed by FT-IR, XPS, FE-SEM, and FE-TEM. Charge/discharge capacity and cyclic voltammetry measurements were carried out for the electrochemical performance as a polymer cathode active material for lithium secondary batteries. The discharge capacities of PANI/PTND after 1,5, and 10 cycles at 1.3~4.0 V voltage range and room temperature 167 mAh/g, 90 mAh/g, and 81 mAh/g. When we compared with PANI (80, 67, and 62 mAh/g), the discharge capacity after 10 cycles was improved about 30%. After 50 cycles, the discharge capacity of PANI/PTND was 67 mAh/g.

Synthesis of Mg2Ni by mechanical alloying and its electrochemical characteristics for Ni-MH secondary battery (Ni-MH 2차 전지용 Mg2Ni의 기계적 합금화법에 의한 제조 및 전기화학적 특성)

  • Moon, Hong-Gi;Choi, Seung-Jun;Kim, Dae-Hwan;Park, Choong-Nyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.4
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    • pp.225-232
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    • 1999
  • The $Mg_2Ni$ hydrogen storage alloys which have much higher theoretical discharge capacity than $AB_5$ and $AB_2$ type alloys were synthesized by mechanical alloying with some additives and subjected to the electrochemical measurements. Two different processes were employed to the synthesis of $Mg_2Ni$ alloys with using the high energy ball mill SPEX 8000. One was only ball milling, 12 hrs, the Mg and Ni powders for 12 hrs with additives such as $AB_5$, Ni, Co and Cu powders. In the other process the Mg and Ni powders were ball milled for 1 hr first and then heat treated at $300{\sim}400^{\circ}C$ for 1 hr to get $Mg_2Ni$ alloy, and finally the $Mg_2Ni$ alloy powders were ball milled with the additives for 12 hrs. The alloy powders prepared were compacted at room temperature under $7.64tons/cm^2$ into disk type electrodes for the electrochemical measurements. The experimntal results showed that the electrodes prepared with the heat treated alloy powders had a higher discharge capacities than those without heat treatment. The addition of Ni caused an increase of the discharge capacity and the addition of Co improved the cycling characteristics. The electrode prepared by ball milling of $Mg_2Ni$ and 10wt% Ni powders has showed the highest discharge capacity, 546mAh/g.alloy, which was 55% of the theoretical capacity.

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A High-Efficiency, Robust Temperature/voltage Variation, Triple-mode DC-DC Converter (고효율, Temperature/voltage 변화에 둔감한 Triple-mode CMOS DC-DC Converter)

  • Lim, Ji-Hoon;Ha, Jong-Chan;Kim, Sang-Kook;Wee, Jae-Kyung
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.6
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    • pp.1-9
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    • 2008
  • This paper suggests the triple-mode CMOS DC-DC converter that has temperature/voltage variation compensation techniques. The proposed triple-mode CMOS DC-DC converter is used to generate constant or variable voltages of 0.6-2.2V within battery source range of 3.3-5.5V. Also, it supports triple modes, which include Pulse Width Modulator (PWM) mode, Pulse Frequency Modulator (PFM) mode and Low Drop-Out (LDO) mode. Moreover, it uses 1MHz low-power CMOS ring oscillator that will compensate malfunction of chip in temperature/voltage variation condition. The proposed triple-mode CMOS DC-DC converter, which generates output voltages of 0.6-2.2V with an input voltage sources of 3.3-5.5V, exhibits the maximum output ripple voltage of below 10mV at PWM mode, 15mV at PFM mode and 4mV at LDO mode. And the proposed converter has maximum efficiency of 93% at PWM mode. Even at $-25{\sim}80^{\circ}C$ temperature variations, it has kept the output voltage level within 0.8% at PWM/PFM/LDO modes. For the verification of proposed triple-mode CMOS DC-DC converter, the simulations are carried out with $0.35{\mu}m$ CMOS technology and chip test is carried out.

THE DEVELOPMENT OF INDWELLING WIRELESS PH TELEMETRY OF INTRAORAL ACIDITY (구강 내 산도의 생체 내 측정을 위한 wireless pH telemetry의 개발)

  • Kim, Hyung-Jun;Kim, Jae-Moon;Jeong, Tae-Sung;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.35 no.1
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    • pp.1-10
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    • 2008
  • The purpose of this study was to develop the wireless pH telemetry lasting longer than 24 hours in the mouth to overcome the limits of conventional wire telemetry previously used for salivary and plaque pH measurement, and to assess its effectiveness. We developed a wireless pH telemeter which can measure and store the pH profile data during more than 24 hours. It was composed of intraoral part; pH sensor of antimony electrode, battery and microprocessor for data storage, and extraoral part; control/data receiver and data analyzing software which was newly made for this device. After inspecting wireless electrode for accurate measurement, it was attached to the removable intraoral appliance and delivered to the volunteer who was told to wear except brushing time, retrieved after 24 hours and finally the pH profile data was extracted and analyzed. When compared with conventional wire telemetry, this device showed similar results and induced less discomfort to examinees. The data showed pH changes at same time when examinees ate various scheduled foods and beverages. With this method it became possible to accurately measure pH changes within mouth for long time in accordance with individual's lifestyle, definitely reducing the discomfort inflicted to the examinees' life.

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Electrochemical Properties of Ionic Liquid Composite Poly(ethylene oxide)(PEO) Solid Polymer Electrolyte (이온성 액체 복합 Poly(ethylene oxide)(PEO) 고체 고분자 전해질의 전기화학적 특성)

  • Park, Ji-Hyun;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.101-106
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    • 2016
  • In this study, we prepared an ionic liquid composite solid polymer electrolyte (PEO-LiTFSI-$Pyr_{14}TFSI$) with poly(ethylen oxide), lithium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide by blending-cross linking process. Although the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte displayed a small peak at 4.4 V, it had high electrochemical oxidation stability up to 5.7 V. Ionic conductivity of the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte increased with increasing temperature from $10^{-6}S\;cm^{-1}$ at $30^{\circ}C$ to $10^{-4}S\;cm^{-1}$ at $70^{\circ}C$. To investigate the electrochemical properties, the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte assembled with $LiFePO_4$ cathode and Li-metal anode. At 0.1 C-rate, the cell delivered $40mAh\;g^{-1}$ for $30^{\circ}C$, $69.8mAh\;g^{-1}$ for $40^{\circ}C$ and $113mAh\;g^{-1}$ for $50^{\circ}C$, respectively. The PEO-LiTFSI-$Pyr_{14}TFSI$ solid polymer electrolyte exhibited good charge-discharge performance in Li/SPE/$LiFePO_4$ cells at $50^{\circ}C$.

A study on realtime Job Scheduling for Portable Devices (포터블 기기의 실시간 처리를 위한 Job Scheduling에 관한 연구)

  • 장석우;박인규
    • Proceedings of the IEEK Conference
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    • 1999.11a
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    • pp.989-992
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    • 1999
  • Battery로 작동되고, 소형인 제품들도 다양한 기능은 물론이고, 다양한 입출력 장치를 갖추고, 실시간으로 처리하는 시스템이 많이 요구되고 있는 실정이며, 점차 더욱 더 요구될 것으로 전망된다. 더욱이 포터블 기기는 일반적으로 MCU의 내부에 제한된 ROM type 메모리를 내장하게 되면, 데이터 메모리로 SRAM 및 flash memory를 갗추고 있다. 따라서 이러한 제한된 하드웨어 환경하에서 많은 기능을 수행해야 하는 경우가 많다. 여러 기능을 시간적인 간격으로 배분하거나, 기능 자체를 서로 배분하면서, 서로 융합하는 등의 여러 가지 기능을 수행하려다보면, 당연히 메인 소프트웨어 구조가 복잡해지며 대부분 어셈블리나 C와 같은 linear한 구조를 가지는 language로 개발되기 때문에 효과적인 프로그램 구조를 세우기는 쉽지 않다. 본 논문에서는 이를 위해 좀더 규격화된 방법을 제시하고자 한다. 보다 구체적인 구조를 연구할 목적으로 다양한 테스크를 수행하여야 하는 시스템이면서 프로세서가 필요한 포터블 기기의 한 응용 제품인 MP3 Player 에서 요구되는 job scheduling을 연구한다. 필요한 작업의 종류는 가장 부하가 많이 걸리는 압축된 MP3 file을 다시 복원시켜주는 codec 부분과 일정 시간 간격을 가지고 수행하여야 하는 외부 키보드 입력과 실시간으로 시간을 계산하는 타이머 기능, 그리고 LCD에 시간의 변화를 표시하여 주어야한다. 이와같이 수시로 작업이 발생하지만 시간 점유율이 중간 정도인 LCD 컨트롤과 메모리 컨트롤 등이다. 프로세서의 속도를 최소한으로 줄이면서 스케줄링에 의해 시간 문제를 해결하는 방법을 제시하도록 한다. 이는 기초과학 수준이 높은 북방권 국가들의 과학자들이 주로 활용되고 있다는 점에서도 잘 알 수 있으며 우리의 과학기술 약점을 보완하는 원천으로써 외국인 연구 인력이 대안이 되고 있음을 시사한다. 본 연구에서는 한국 연구 조직에서 일하는 외국인 연구자들의 동기 및 성과에 영향을 미치는 많은 요인들을 확인할 수 있었다. 상관관계, 분산분석, 회귀분석 등을 통해 활용 성과에 미치는 영향 요인들을 도출하였다. 설문 분석을 통하여 동기 및 성과 사이에는 강한 상관관계가 존재하는 것을 확인할 수 있었으며 이는 전통적인 동기 이론들과 부합한다. 대부분의 변수가 동기 및 성과에 동시에 영향을 미치는 것으로 조사되었으며 그중에서도 조직 협력 문화, 외국인 연구자의 의사소통 및 협력성, 외국인 연구자의 연구 능력 관련 변수들 및 연구 프로젝트의 기술수명주기, 외국인 연구자의 기존 기술지식의 흡수 등이 가장 중요한 변수로 나타났다. 이는 우리가 주로 중국 및 러시아 과학자들을 활용하여 상업화하는 외국인 연구인력 활용 패턴과도 일치하는 결과이다. 즉 우호적인 조직문화를 가지고 있는 연구 조직에서, 이미 과학기술 지식을 많이 가지고 있고 연구 능력도 높은 외국인 과학기술자를, 한국에서 기술이 태동 또는 성장하고 있는 연구 분야에서 활용하는 것이 가장 성과가 좋다는 사실을 확인시켜 주고 있다. 국내에서 최초로 수행된 본 연구는 외국인 연구 인력의 활용 성과가 매우 높으며, 우리의 과학기술혁신시스템을 보완하는 유효한 수단으로써 외국인 연구 인력이 중요한 대안이 될 수 있음을 발견하였다. 외국인 연구 인력을 잘 활용하기 위하여 문제점 및 개선방안을 활용 환경, 연구 인력이 중요한 대안이 될 수

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Structural and Electrochemical Properties of Li2Mn0.5Fe0.5SiO4/C Cathode Nanocomposite

  • Chung, Young-Min;Yu, Seung-Ho;Song, Min-Seob;Kim, Sung-Soo;Cho, Won-Il
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4205-4209
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    • 2011
  • The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ silicate was prepared by blending of $Li_2MnSiO_4$ and $Li_2FeSiO_4$ precursors with same molar ratio. The one of the silicates of $Li_2FeSiO_4$ is known as high capacitive up to ~330 mAh/g due to 2 mole electron exchange, and the other of $Li_2FeSiO_4$ has identical structure with $Li_2MnSiO_4$ and shows stable cycle with less capacity of ~170 mAh/g. The major drawback of silicate family is low electronic conductivity (3 orders of magnitude lower than $LiFePO_4$). To overcome this disadvantage, carbon composite of the silicate compound was prepared by sucrose mixing with silicate precursors and heat-treated in reducing atmosphere. The crystal structure and physical morphology of $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ was investigated by X-ray diffraction, scanning electron microscopy, and high resolution transmission electron microscopy. The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$/C nanocomposite has a maximum discharge capacity of 200 mAh/g, and 63% of its discharge capacity is retained after the tenth cycles. We have realized that more than 1 mole of electrons are exchanged in $Li_2Mn_{0.5}Fe_{0.5}SiO_4$. We have observed that $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ is unstable structure upon first delithiation with structural collapse. High temperature cell performance result shows high capacity of discharge capacity (244 mAh/g) but it had poor capacity retention (50%) due to the accelerated structural degradation and related reaction.

Dual-band RFID Tag Antenna Applicable for RF Power Harvester System (RF 에너지 충전 시스템 기능을 위한 이중대역 RFID 태그 안테나)

  • Mun, Byeonggwi;Rhee, Changyong;Kim, Jae-Sik;Cha, Junghoon;Lee, Byungje
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.12 no.5
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    • pp.46-51
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    • 2013
  • In this paper, a dual-band antenna is proposed for the RF power harvester system as well as RFID tag. The proposed antenna operates as the passive and active RFID tag antenna in the UHF and microwave band, respectively. In addition, to charge the battery of an active RFID tag in the microwave band, it harvest the RF signal for tagging from the passive RFID tag antenna in the UHF band. The proposed antenna operates in the UHF band (917~923.5 MHz) and microwave band (2.4~2.45 GHz). In order to obtain the dual-band operation, the dipole structure and meander parasitic elements are proposed as the ${\lambda}/2$ and $1{\lambda}$ dipole antenna, respectively. The radiating dipole structure in the microwave band acts as the coupled feed for the meander parasitic elements in the UHF band. The impedance bandwidth (VSWR < 2) of the proposed antenna covers 917~923.5 MHz (UHF band) and 2.4~2.45 GHz (Microwave band). Measured total efficiencies are over 45 % in the UHF band and over 70 % in the microwave band. Peak gains are over 0.18 dBi and 2.8 dBi in the UHF and microwave band with an omni-directional radiation pattern, respectively.