• Title/Summary/Keyword: ZnPc

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Property of Spin-sprayed ZnO Film on PC Substrate (스핀 스프레이법으로 PC 기판에 제작한 산화아연 박막의 특성)

  • Hoong, Jeongsoo;Matsushita, Nobuhiro;Katsumata, Ken-ichi;Park, Yongseo;Kim, Kyunghwan
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.27-30
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    • 2018
  • In this study, ZnO film was deposited on polycarbonate substrate by spin-spray method at low substrate temperature of $85^{\circ}C$. Surface morphology of ZnO films was changed by adding citrate from rod to dense structure. As-deposited ZnO film indicated high transmittance above 80%. In case of the resistivity, as-deposited ZnO film had high resistivity due to the existence of organic substance in the film. However, organic substance was removed and resistivity was decreased to $3.9{\times}10^{-2}{\Omega}{\cdot}cm$, after UV irradiation.

Solvent Sensing Properties of Thin Films Based on Zinc phthalocyanine (ZnPc) Compounds (Zinc phthalocyanine(ZnPc)화합물의 이용한 유기용제 센서)

  • Kim D.H.;Kang Y.G.;Kim J.H.;Roh S.C.;Kim H.J.
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.26-29
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    • 2005
  • In this paper, the solvent sensing properties of the metallophthalocyanine macrocyclic compounds(ZnPc) have been deposited as thin films by the spin-coated method and evaporated methods onto alumina substrates and quartz substrates. And then the spin-coated materials of Zinc phthalocyanine solutions blended with $N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,\;1-biphenyl-4,4'-diamine\;and/or\; Poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene-vinylene]$ solutions. The influences of the blended metallophthalocyanine macrocyclic compounds on the resistance have been measured and analysed in five different vapour organic compounds.

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Highly Luminescent (Zn0.6Sr0.3Mg0.1)2Ga2S5:Eu2+ Green Phosphors for a White Light-Emitting Diode

  • Jeong, Yong-Kwang;Cho, Dong-Hee;Kim, Kwang-Bok;Kang, Jun-Gill
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2523-2528
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    • 2012
  • Green phosphors $(Zn_{1-a-b}M_aM^{\prime}_b)_xGa_yS_{x+3y/2}:Eu^{2+}$ (M, M' = alkali earth ions) with x = 2 and y = 2-5 were prepared, starting from ZnO, MgO, $SrCO_3$, $Ga_2O_3$, $Eu_2O_3$, and S with a flux $NH_4F$ using a conventional solidstate reaction. A phosphor with the composition of $(Zn_{0.6}Sr_{0.3}Mg_{0.1})_2Ga_2S_5:Eu^{2+}$ produced the strongest luminescence at a 460-nm excitation. The observed XRD patterns indicated that the optimized phosphor consisted of two components: zinc thiogallate and zinc sulfide. The characteristic green luminescence of the $ZnS:Eu^{2+}$ component on excitation at 460 nm was attributed to the donor-acceptor ($D_{ZnGa_2S_4}-A_{ZnS}$) recombination in the hybrid boundary. The optimized green phosphor converted 17.9% of the absorbed blue light into luminescence. For the fabrication of light-emitting diode (LED), the optimized phosphor was coated with MgO using magnesium nitrate to overcome their weakness against moisture. The MgO-coated green phosphor was fabricated with a blue GaN LED, and the chromaticity index of the phosphor-cast LED (pc-LED) was investigated as a function of the wt % of the optimized phosphor. White LEDs were fabricated by pasting the optimized green (G) and the red (R) phosphors, and the commercial yellow (Y) phosphor on the blue chips. The three-band pc-WLED resulted in improved color rendering index (CRI) and corrected color temperature (CCT), compared with those of the two-band pc-WLED.

Dependence of Substrate Type on the Properties of ZnO Films deposited by r.f. magnetron sputtering (ZnO 박막의 기판종류에 따른 구조적, 광학적 특성)

  • Lee, Dong-Jin;Lee, Jae-Hyeong;Ju, Jung-Hun;Song, Jun-Tae;Lee, Kyu-Il;Yang, Kea-Joon;Lim, Dong-Gun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.125-126
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    • 2006
  • ZnO Films have been prepared on polycarbonate (PC), polyethylene terephthalate (PET), and Coming 7059 substrates by r.f. magnetron sputtering technique. A comparison of the properties of the films deposited on polymer and glass substrates was performed. In addition, the effect of the sputter power on the structural and optical properties of these films was evaluated.

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Electronic Structure of Organic/organic Interface Depending on Heteroepitaxial Growth Using Templating Layer

  • Lim, Hee Seon;Kim, Sehun;Kim, Jeong Won
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.351-356
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    • 2014
  • The electronic structure at organic-organic interface gives essential information on device performance such as charge transport and mobility. Especially, the molecular orientation of organic material can affect the electronic structure at interface and ultimately the device performance in organic photovoltaics. The molecular orientation is examined by the change in ionization potential (IP) for metal phthalocyanines (MPc, M=Zn, Cu)/fullerene ($C_{60}$) interfaces on ITO by adding the CuI templating layer through ultraviolet photoelectron spectroscopy measurement. On CuPc/$C_{60}$ bilayer, the addition of CuI templating layer represents the noticeable change in IP, while it hardly affects the electronic structure of ZnPc/$C_{60}$ bilayer. The CuPc molecules on CuI represent relatively lying down orientation with intermolecular ${\pi}-{\pi}$ overlap being aligned in vertical direction. Consequently, in organic photovoltaics consisting of CuPc and $C_{60}$ as donor and acceptor, respectively, the carrier transport along the direction is enhanced by the insertion of CuI templaing layer. In addition, optical absorption in CuPc molecules is increased due to aligned transition matrix elements. Overall the lying down orientation of CuPc on CuI will improve photovoltaic efficiency.

The Concentration of TSP and Heavy Metals in the Indoor Air of Local PC Rooms (지방 일개도시 PC방에서의 실내공기중 TSP농도와 TSP내 중금속 농도)

  • Cha Hyun Su
    • Journal of Korean Public Health Nursing
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    • v.16 no.1
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    • pp.190-200
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    • 2002
  • This study was carried out to investigate and analyze TSP of the PC rooms. The concentration of the total suspended particulate and heavy metals contained in the total suspended particulate of the 15 PC rooms located in one local city were measured. The statistical correlation coefficients between the total suspended particulate and factors of the indoor condition (number of fan or size of pc room, illumination), between the heavy metals and factors of the indoor condition were studied. The results are as follows: 1. The factors of the indoor condition of the 15 PC rooms are as follows. Average illumination was 24 luxes. Average number of computers installed were 37. Average number of the fans was 7. and the size of investigated PC rooms was $139.94m^2$. 2. The mean age of the subjects was 21.8 years old. they $(51.5\%)$ used the 15 pc rooms for fewer than 2 hours per one day. 3. The mean concentration of total suspended particulate (TSP) is lower in the evening ${139.085\;(2.462)\;{\mu}g/m^3}$ than the night ${166.216(2.609){\mu}g/m^3}$. 4. The mean concentration of total suspended particulate was industrial work area) residential area) commercial area. 5. The distribution of heavy metals were indicated as Zn>Cr>Pb>Cd in the indoor air at PC rooms. and the concentration rate of Zn was the highest among heavy metals. but this increase didn't show any relationship with many factors of indoor condition (number of fan or size of pc room, lighting) 6. The concentration of TSP & heavy metals didn't have any relationship between the factors of indoor environment (number of fans, size of pc room, lighting).

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Growth of $Cd_{1-x}Zn_xS $ Thin films Using Hot Wall Epitaxy Method and Their Photoconductive Characteristics (HWE에 의한 $Cd_{1-x}Zn_xS $박막의 성장과 광전도 특성)

  • 홍광준;유상하
    • Korean Journal of Crystallography
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    • v.9 no.1
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    • pp.53-63
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    • 1998
  • The Cd1-xZnxS thin films were grown on the Si(100) wafers by a hot wall epitaxy method (HWE). the source and substrate temperature are 600℃ and 440℃, respectively. The crystalline structure of epilayers was investigated by double crystal X-ray diffraction (DCXD). Hall effect on the sample was measured by the van der Pauw method and the carrier density and mobility dependence of Hall characteristics on temperature was also studied. In order to explore the applicability as a photoconductive cell, we measured the sensitivity (γ), the ratio of photocurrent to darkcurrent (pc/dc), maximum allowable power dissipation (MAPD), spectral response and response time. The results indicated that the best photoconductive characteristic were observed in the Cd0.53Zn0.47S samples annealed in Cu vapor comparing with in Cd, Se, air and vacuum vapour. Then we obtained the sensitivity of 0.99, the value of pc/dc of 1.65 × 107, the MAPD of 338mW, and the rise and decay time of 9.7 ms and 9.3 ms, respectively.

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Photovoltaic Properties of Organic Solar Cell using Zinc phthalocyanine(ZnPc)/$C_{60}$ devices (Zinc phthalocyanine(ZnPc)/$C_(60)$ 소자를 이용한 유기 광소자의 광기전특성)

  • Lee, Ho-Sik;Hur, Sung-Woo;Lee, Won-Jae;Shin, Hoon-Kyu;Kim, Tae-Wan;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1712-1714
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    • 2004
  • During the last 20 years organic semiconductors have attracted considerable attention due to their interesting physical properties followed by various technological applications in the area of electronics and opto-electronics. It has been a long time since organic solar cells were expected as a low-cost energy-conversion device. Although practical use of them has not been achieved, technological progress continues. Morphology of the materials, organic/inorganic interface, metal cathodes, molecular packing and structural properties of the donor and acceptor layers are essential for photovoltaic response. We have fabricated solar cell devices based on zinc-phthalocyanine(ZnPc) as donor(D) and fullerine($C_{60}$) as electron acceptor(A) with doped charge transport layers, $Alq_3$ as an electron transport or injection layer. We observed the photovoltaic characteristics of the solar cell devices using the Xe lamp as a light source.

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Frequency response of Photovoltaic Cell using ZnPc (ZnPc를 이용한 유기태양전지의 주파수 응답 특성)

  • Ahn, Joon-Ho;Kim, Ho-Sik;Park, Jae-Joon;Lee, Won-Jae;Jang, Kyung-Uk;Seo, Dae-Sik;Kim, Tae-Wan;Lee, Joon-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.285-286
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    • 2005
  • Organic photovoltaic properties were studied in ZnPc/$C_{60}$ heterojunction structure by varying the organic layer thicknesses and exiton blocking layer(EBL). Current density-voltage characteristics of organic photovoltaic cells were measured using Keithley 236 source-measure unit, a 500W xenon lamp (ORIEL 66021) for a light source and Agilent 4294A impedance analyzer in the range of 40 Hz $\sim$ 1 MHz. From the analyses of current-voltage characteristics such as short-circuit current density, open-circuit voltage and power conversion efficiency, optimum thickness of the organic layer were obtained and frequency response such as electrical conductance.

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Properties of Photovoltaic Cell using ZnPc/C60 Double Layer Devices

  • Lee, Ho-Sik;Seo, Dae-Shik;Lee, Won-Jae;Jang, Kyung-Uk;Kim, Tae-Wan;Lee, Sung-Il
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.3
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    • pp.124-127
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    • 2005
  • It has been a long time since organic solar cells were expected as a low-cost energy-conversion device. Although practical use of them has not been achieved, technological progress continues. Morphology of the materials, organic/inorganic interface, metal cathodes, molecular packing and structural properties of the donor and acceptor layers are essential for photovoltaic response. We have fabricated solar cell devices based on zinc-phthalocyanine(ZnPc) as donor(D) and fullerene$(C_60)$ as electron acceptor(A) with doped charge transport layers, and BCP and $Alq_3$ as an exciton blocking layer(EBL). We have measured the photovoltaic characteristics of the solar cell devices using the Xe lamp as a light source. We were use of $Alq_3$ layer leads to external power conversion efficiency was $2.65\%$ at illumination intensity $100\;mW/cm^2$. Also we confirmed the optimum thickness ratio of the DA hetero-junction is about 1:2.