• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.147-150
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• 1998

Since P-ELD(powders type electroluminescent device) phenomena were found by G.Destriau at first In 1936, lots of studying was performed in order to realize surface emission devices and flat panel display as a backlight. Due to the problem of low luminance and color and so on, it was delayed. Recently using electric field and thermal effect which can change it\`s molecular arrangement, it can be developed using photoelectric properties of P-ELD. P-ELD in this study was prepared by casting method. Basic structure is ITO/Phosphor/insulator/Al sheet, each layer was mixed by binder, which concentration 11p(poise) for phosphor, 8p(poise) fort insulator. Dielectric properties was investigated first and emission properties of P-ELD based on ZnS:Mn,Cu/ZnS:Cu,Br mixture. P-ELD prepared in this work exhibits about 100cd/㎡ 1-kHz simusoidal excitation.

• Molecules and Cells
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• 제28권5호
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• pp.479-487
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• 2009

Glutathione reductase (GR) is an enzyme that recycles a key cellular antioxidant molecule glutathione (GSH) from its oxidized form (GSSG) thus maintaining cellular redox homeostasis. A recombinant plasmid to overexpress a GR of Brassica rapa subsp. pekinensis (BrGR) in E. coli BL21 (DE3) was constructed using an expression vector pKM260. Expression of the introduced gene was confirmed by semi-quantitative RT-PCR, immunoblotting and enzyme assays. Purification of the BrGR protein was performed by IMAC method and indicated that the BrGR was a dimmer. The BrGR required NADPH as a cofactor and specific activity was approximately 458 U. The BrGR-expressing E. coli cells showed increased GR activity and tolerance to $H_2O_2$, menadione, and heavy metal ($CdCl_2$, $ZnCl_2$ and $AlCl_2$)-mediated growth inhibition. The ectopic expression of BrGR provoked the co-regulation of a variety of antioxidant enzymes including catalase, superoxide dismutase, glutathione peroxidase, and glucose-6-phosphate dehydrogenase. Consequently, the transformed cells showed decreased hydroperoxide levels when exposed to stressful conditions. A proteomic analysis demonstrated the higher level of induction of proteins involved in glycolysis, detoxification/oxidative stress response, protein folding, transport/binding proteins, cell envelope/porins, and protein translation and modification when exposed to $H_2O_2$ stress. Taken together, these results indicate that the plant GR protein is functional in a cooperative way in the E. coli system to protect cells against oxidative stress.

• 한국대기환경학회지
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• 제18권5호
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• pp.363-372
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• 2002

PM$_{10}$ aerosols were collected using low volume air sampler every month intervals from September 1992 to August 1991 in Seoul. These samples were analyzed for 20 trace elements (Al, As, Ba, Br, Ca, Cl, Co, Cr, Fe, K, Mn, Na, Ni, Pb, Sc, Se, Si, Ti, V and Zn) by INAA (instrumental neutron activation analysis), XRF (x-ray fuorescence spectrometer), and ICP (inductively coupled plasma). PM$_{10}$ mass concentrations higher than 70 $\mu$g/m$^3$ were 32% of 60 samples and had significantly higher concentrations in spring and winter than in summer and fall (p-value<0.001). The elements of As, Br, Cl, Ni, Pb, Se, V, and Zn are enriched by factors of 20 to 2,000 relative to their natural abundance in crustal soil. To further identify common sources of pollution-related trace elements, factor analysis was applied to the trace elements concentration data. Major sources that contribute to the atmospheric loading of these elements were found to include fossil fuel combustion, automobile and waste incineration (33.2%), metal processing industry (18.2%), and soil(29.8%).8%).

• 전력전자학회논문지
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• 제19권2호
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• pp.106-115
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• 2014

This paper proposes ESS DC-DC Converter using Redox Flow Battery (RFB) for stand-alone microgrid. Price, safety, expandability and dynamics are crucial in ESS. Reports show that Zinc-bromine (ZnBr) RFB is the best choice in ESS. Simple electrical ZnBr RFB model is obtained from charging test. DC-DC converter Inductor current-DClink Voltage model is proposed for the DC microgrid. For the controller design in z-domain, the K-factor method is by considering nature of the digital controller. The control performance has been verified with simulation and hardware experiments. Lastly 10kW DC microgrid using RFB test result is shown.

• Bulletin of the Korean Chemical Society
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• 제18권2호
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• pp.213-217
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• 1997

Magnesium reduction of Mo(N-C6H3-2,6-i-Pr2)2Cl2(DME) in the presence of trimethylphosphine led to a mixture of Mo(N-C6H3-2,6-i-Pr2)(PMe3)2Cl3, 1, and Mo2(PMe3)4Cl4, 2. In solution 1 is slowly air-oxidized to Mo(N-2,6-i-Pr2-C6H3)(OPMe3)(PMe3)Cl3, 3. 1 is chemically inert to carbon nucleophiles (ZnMe2, ZnEt2, AlMe3, AlEt3, LiCp, NaCp, TlCp, NaCp*, MeMgBr, EtMgBr), oxygen nucleophiles (LiOEt, LiO-i-Pr, LiOPh, LiOSPh), and hydrides (LiBEt3H, LiBEt3D). Crystal data for 1: orthorhombic space group P212121, a=11.312(3) Å, b=11.908(3) Å, c=19.381(6) Å, Z=4, R(wR2)=0.0463 (0.1067). Crystal data for 2: monoclinic space group Cc, a=18.384(3) Å, b=9.181(2) Å, c=19.118(3) Å, b=124.98(1)°, Z=4, R(wR2)=0.0228 (0.0568). Crystal data for 3: orthorhombic space group P212121, a=11.464(1) Å, b=14.081(2) Å, c=16.614(3) Å, Z=4, R(wR2)=0.0394 (0.0923).

• 한국환경과학회지
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• 제19권7호
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• pp.849-860
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• 2010

A new $N_3O_2$ pentadentate ligand, N,N'-Bis(2-hydroxybenzyl)-ethylenetriamine(H-BHET 3HCl) was synthesized. The hydrochloric acid salts of Br-BHET 3HCl, Cl-BHET 3HCl, $CH_3O$-BHET 3HCl and $CH_3$-BHET 3HCl containing Br-, Cl-, H-, $CH_3O-$ and $CH_3-$ groups at the para-site of the phenol group of the H-BHEP were synthesized. The structures of the ligands were confirmed by C. H. N. atomic analysis and $^1H$ NMR, $^{13}C$ NMR, UV-visible and mass spectra. The calculated stepwise protonation constants(${\logK_n}^H$) of the synthesized $N_3O_2$ ligands showed six steps of the proton dissociation. The orders of the overall protonation constants($\log{\beta}_p$) of the ligands were Br-BHET < Cl-BHET < H-BHET < $CH_3O$-BHET < $CH_3$-BHET. The orders agreed well with that of para Hammett substituent constants(${\delta}_p$). The calculated stability constants($\logK_{ML}$) between the ligands and heavy metal ions (Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II)) agreed well with the order of the overall proton dissociation constants of the ligands but they showed a reverse order in para Hammestt substituent constants(${\delta}_p$). The order of the stability constants between the heavy metal ions with the synthesized ligands were Co(II) < Ni(II) < Cu(II) > Zn(II) > Cd(II) > Pb(II).

• 한국식품영양과학회지
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• 제18권3호
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• pp.265-272
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• 1989

구황식품중 9종류를 감출감도가 높고 시료의 비파괴 분석이 가능한 방사화 분석법으로 무기질을 정량한 결과는 다음과 같다. 1. 부추에는 K 7099.1mg%, Cu 104.84ppm, Mo 45.45ppm, Br 40.40ppm으로 다른 식품에 비해 많은 함량을 갖고 있었다. 2. 개비름은 Zn 71.06ppm, Co 2.52ppm, La 1.4ppm 등 조혈 필수원소등을 많이 함유하였다. 3. 쑥은 Na, K, Fe, Cu, Co, Zn, Br등 대부분의 무기질이 많이 함유되어 있는 영양학적으로 우수한 식품이라 볼 수 있다. 4. 본 재료들의 K와 Na의 함량비는 부추가 796 : 1로 가장 크며 쑥, 마늘이 147 : 1, 118 : 1이고 그 이외에는 12 : $1{\sim}53$ : 1이다. 5. 부추 개비름 쑥에는 Fe와 더불어 Cu, Co가 많이 함유되어 있다. 6. 생강에는 Hg가 0.14ppm으로 다른 식품보다 $5{\sim}6$배 많았으며 Sc도 25ppb 함유하고 있다. 7. 식품속에서 극미량 존재하는 Au, Sm, Br, La, Sc등도 분석가능 하였다.

• E2M - 전기 전자와 첨단 소재
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• 제10권1호
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• pp.39-44
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• 1997

Bulk type radiation detector of Au/Cd$_{1-x}$ Zn$_{x}$Te(x=20%)/Au structure using Cd$_{1-x}$ Zn$_{x}$Te(x=20%) wafer(3x4xl mm$^{3}$) grown by high pressure Bridgman method has been developed. We etched wafer surfaces with 2% Br-methanol solution and coated gold thin film on the surfaces by electroless deposition method for 5 min. in 49/o HAuCI$_{3}$ 4H20 solution. Initial etch rates of Cd, Zn and Te were 46%, 12% and 42% respectively. After etched, the surface of wafer was slightly revealed to Te rich condition. The leakage current was increased with etch time, but it didn't exceed 3nA at 50volt. The thickness of Au film was about 100nm by Rutherford Backscattering Spectroscopy(RBS). The resolution were 6.7% for 22.1 keV photon from 109 $^{109}$ Cd and 8.2% for 59.5 keV photon from $^{241}$ Am. The radiation detector such as Au/Cd$_{1-x}$ Zn$_{x}$Te(x=20%)/Au structure was more effective to monitor the low energy gamma radiation.iation.

• 대한지하수환경학회지
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• 제3권1호
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• pp.37-49
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• 1996

이 연구에서는 난지도 매립지와 화성매립지를 연구대상으로하여 주변의 지하수 오염 정도를 파악하고, 오염물질들의 지연작용을 밝히며, 최적 오염지시인자를 도출하고자 하였다. 난지도, 김포, 화성 매립지에서 채취된 침출수에 대하여 현장측정과 실내 화학분석을 실시하여 침출수의 물리화학적 수리화학적 특성들을 파악한 결과 침출수는 높은 온도(31.7-40.1$^{\circ}C$)와 높은 전기전도도(14,650-32,800 $\mu$S/cm), 약 알칼리의 pH(7.58-8.45), 낮은 Eh값(-119.4-20.4 mV)을 특징적으로 보이며, 주성분 이온들로서 $Na^{＋}$, $K^{＋}$, $Ca^{2＋}$, $Mg^{2＋}$, HC $O_3$$^{－}$, C $l^{－}$ 등이, 부성분 이온들로서 Mn, S $r^{2＋}$, $Ba^{2＋}$, L $i^{＋}$, $F_{－}$, B $r^{－}$ 등이 부화되어 있다. 일반폐기물 매립지인 난지도.김포 매립지의 침출수와 산업폐기물 매립지인 화성매립지의 침출수는 S $O_4$$^{2－}$ , Fe 중금속 원소들의 함량으로 구분된다. 지표수와 지하수의 화학분석, Cl 표준화과정, WATEQ4F 분석 등을 종합하여 앞서 연구된 유선망 분석을 바탕으로 오염물질의 거동을 해석하였다. 또한 Contamination Factor를 통하여 최적의 오염지시인자를 도출하였다. 일반페기물 매립지인 난지도 매립지의 경우 K, Na, Ca, Mg, B, Zn, HC $O_3$, Cl, F, Br, TOC 등이 , 산업 폐기 물 매립지인 화성 매립지의 경우 K, Na, Ca, Mg, B, S $O_4$, HC $O_3$, Cl, F, Br, TOC 등이 뚜렷한 대조를 보이는 좋은 오염지시인자이며, 해안 매립지는 TOC가 가장 적합한 오염지시 인자이다.

• 대한화학회지
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• 제47권6호
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• pp.569-577
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• 2003

피리딘과 페놀을 포함하는 N2O계 세 자리 리간드 2-[(2-pyridine-2- ethylamino)-methyl]-phenol(H-PEMP)를 합성하였다. 또한 H-PEMP 페놀의 5-위치에 치환기로 브롬, 염소 및 메톡시를 가지는 Br-PEMP, Cl-PEMP 및 $CH_3O-PEMP$를, 그리고 2-hydroxy-1-naphthalene기를 가진 Naph-PEMP을 합성하였다. 합성된 각 리간드들을 수용액에서 전위차 적정 결과 양성자 해리는 3 단계로 일어났으며, 계산된 각 리간드의 총괄 양성자 해리상수(log${\beta}$) 값은 $CH_3O-PEMP$〉Naph-PEMP〉H-PEMP〉Br-PEMP〉Cl-PEMP의 순서로 Hammett식의 치환기 상수(${\sigma}_p$) 값 크기 순서와 일치하였다. 전이금속 이온들의 착물 안정도상수(logML 및 log$ML_2$) 값의 크기는 금속이온에 따라 Co(II)< Ni(II)< Cu(II)>Zn(II)의 순서이었고, 치환기에 따른 각 리간드의 착물 안정도상수 값은 리간드의 총괄 양성자 해리상수 값의 크기순서와 일치하였다.