• Title/Summary/Keyword: Zinc white

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Corrosion Resistance of Galvanized Steel by Treating Modified Si Organic/Inorganic Hybrid Coating Solution (Si 변성 유/무기 하이브리드 코팅액에 의한 아연도금강판의 내식특성)

  • Seo, Hyun-Soo;Moon, Hee-Joon;Kim, Jung-Ryang;Kim, Jong-Soon;Ahn, Seok-Hwan;Moon, Chang-Kwon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.25 no.1
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    • pp.32-38
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    • 2011
  • Galvanized steel has gone through a chemical process to keep it from corroding. The steel gets coated in layers of zinc because rust will not attack this protective metal. For countless outdoor, marine, or industrial applications, galvanized steel is an essential fabrication component. The reduction of the corrosion rate of zinc is an important topic. In the past, a very popular way to reduce the corrosion rate of zinc was to use chemical conversion layers based on $Cr^{+6}$. However, a significant problem that has arisen is that the use of chromium salts is now restricted because of environmental protection legislation. Therefore, it is very important to develop new zinc surface treatments that are environmentally friendly to improve the corrosion resistance of zinc and adhesion with a final organic protective layer. In this study, a Urethane solution (only Urethane 20 wt.%; S-700) and an organic/inorganic solution with Si (Si polysilicate 10 wt.% + Urethane 10 wt.%; LRO-317) are used. Based on the salt spray test of 72 h, S-700 and LRO-317 had a superior effect for the corrosion resistance on EGI and HDGI, respectively.

Model Cut-edge Formed on Zinc Coated Steels by Laser Machining and Its Corrosion Behavior

  • Sakairi, Masatoshi;Kageyama, Akihiro;Kikuhchi, Tatsuya
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.29-33
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    • 2010
  • Laser machining technique, which is used focusing pulse YAG laser beam irradiation was applied to form area ratio controlled model cut-edge on pre painted Zn coated steels. A corrosion behavior of formed model cut-edge was investigated by rest potential measurement in 1 mol $m^{-3}$ NaCl with and without 0.5 kmol $m^{-3}$ $H_3BO_4$/0.05kmol$m^{-3}$ $Na_2B_4O_7$. The rest potential showed almost constant value with fluctuations. The amplitude of fluctuations increased with exposed area of steel surface. White corrosion products of zinc oxide and simonkollite was formed after the experiments at the formed model cut-edge.

Ingredients and cytotoxicity of MTA and 3 kinds of Portland cements (MTA와 포틀랜드 시멘트의 구성성분분석과 세포독성에 관한 연구)

  • Chang, Seok-Woo;Yoo, Hyun-Mi;Park, Dong-Sung;Oh, Tae-Seok;Bae, Kwang-Shik
    • Restorative Dentistry and Endodontics
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    • v.33 no.4
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    • pp.369-376
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    • 2008
  • The aim of this study was to compare the compositions and cytotoxicity of white ProRoot MTA (white mineral trioxide aggregate) and 3 kinds of Portland cements. The elements, simple oxides and phase compositions of white MTA (WMTA), gray Portland cement (GPC), white Portland cement (WPC) and fast setting cement (FSC) were measured by inductively coupled plasma atomic emission spectrometry (ICP-AES), X-ray fluorescence spectrometry (XRF) and X-ray diffractometry (XRD). Agar diffusion test was carried out to evaluate the cytotoxicity of WMTA and 3 kinds of Portland cements. The results showed that WMTA and WPC contained far less magnesium (Mg), iron (Fe), manganese (Mn), and zinc (Zn) than GPC and FSC. FSC contained far more aluminum oxide ($Al_2O_3$) than WMTA, GPC, and WPC. WMTA, GPC, WPC and FSC were composed of main phases. such as tricalcicium silicate ($3CaO{\cdot}SiO_2$), dicalcium silicate ($2CaO{\cdot}SiO_2$), tricalcium aluminate ($3CaO{\cdot}Al_2O_3$), and tetracalcium aluminoferrite ($4CaO{\cdot}Al_2O_3{\cdot}Fe_2O_3$). The significance of the differences in cellular response between WMTA, GPC, WPC and FSC was statistically analyzed by Kruskal-Wallis Exact test with Bonferroni' s correction. The result showed no statistically significant difference (p > 0.05). WMTA, GPC, WPC and FSC showed similar compositions. However there were notable differences in the content of minor elements. such as aluminum (Al), magnesium, iron, manganese, and zinc. These differences might influence the physical properties of cements.

Comparison of Food Components in Various Parts of White Muscle from Cooked Skipjack Tuna Katsuwonus pelamis as a Source of Diet Foods (다이어트 식품 소재로서 자숙 가다랑어(Katsuwonus pelamis) 백색육의 부위별 식품성분 특성)

  • Kim, Hyeon-Jeong;Kim, Min-Ji;Kim, Ki-Hyun;Ji, Seung-Jun;Lim, Kyung-Hun;Park, Kwon-Hyun;Shin, Joon-Ho;Heu, Min-Soo;Kim, Jin-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.45 no.4
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    • pp.307-316
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    • 2012
  • This study evaluated the possible use of white muscle from cooked skipjack tuna as a constituent of diet foods. White muscles from the belly and dorsal area of cooked skipjack tuna were identified as anterior, median, and posterior. The skipjack tuna white muscle contained more moisture and ash (except for part I in both the belly and dorsal muscles) than chicken muscle, while it had less crude protein and crude lipid (except for part II in belly muscle). The yield was the highest in part I of both the dorsal and belly parts among the various parts of white muscles. The skipjack tuna white muscle contained 14-18% fewer calories than chicken breast muscle. Part I from both the belly and dorsal muscles had higher total amino acid contents than the other parts, but lower contents than chicken breast muscle. White muscle of skipjack tuna was rich in minerals, such as phosphorus, iron, and zinc. The total free amino acid content of part I in the belly and dorsal muscles was 1,152.1 and 1,215.7 mg/100 g, respectively, and was 1.7-1.8 times higher than in chicken breast muscle. The major amino acids in the white muscles from skipjack tuna were taurine, histidine, anserine, and carnosine. Based on these results, if it is possible to mask the fish odor, all parts of the white muscle from skipjack tuna could be used as constituents of diet foods.

High-fat diet alters the thermogenic gene expression to β-agonists or 18-carbon fatty acids in adipocytes derived from the white and brown adipose tissue of mice

  • Seonjeong Park;Seung A Ock;Yun Jeong Park;Yoo-Hyun Lee;Chan Yoon Park;Sunhye Shin
    • Journal of Nutrition and Health
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    • v.57 no.2
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    • pp.171-184
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    • 2024
  • Purpose: Although activating thermogenic adipocytes is a promising strategy to reduce the risk of obesity and related metabolic disorders, emerging evidence suggests that it is difficult to induce adipocyte thermogenesis in obesity. Therefore, this study aimed to investigate the regulation of adipocyte thermogenesis in diet-induced obesity. Methods: Adipose progenitor cells were isolated from the white and brown adipose tissues of control diet (CD) or high-fat diet (HFD) fed mice, and fully differentiated white and brown adipocytes were treated with β-agonists or 18-carbon fatty acids for β-adrenergic activation or peroxisome proliferator-activated receptor (PPAR) activation. Results: Compared to the CD-fed mice, the expression of uncoupling protein 1 (Ucp1) was lower in the white adipose tissue of the HFD-fed mice; however, this was not observed in the brown adipose tissue. The expression of peroxisome proliferator-activated receptor gamma (Pparg) was lower in the brown adipose progenitor cells isolated from HFD-fed mice than in those isolated from the CD-fed mice. Norepinephrine (NE) treatment exerted lesser effect on peroxisome proliferator-activated receptor-γ coactivator (Pgc1a) upregulation in white adipocytes derived from HFD-fed mice than those derived from CD-fed mice. Regardless which 18-carbon fatty acids were treated, the expression levels of thermogenic genes including Ucp1, Pgc1a, and positive regulatory domain zinc finger region protein 16 (Prdm16) were higher in the white adipocytes derived from HFD-fed mice. Oleic acid (OLA) and γ-linolenic acid (GLA) upregulated Pgc1a expression in white adipocytes derived from HFD-fed mice. Brown adipocytes derived from HFD-fed mice had higher expression levels of Pgc1a and Prdm16 compared to their counterparts. Conclusion: These results indicate that diet-induced obesity may downregulate brown adipogenesis and NE-induced thermogenesis in white adipocytes. Also, HFD feeding may induce thermogenic gene expression in white and brown primary adipocytes, and OLA and GLA could augment the expression levels.

An Electrochemical Study on Photoluminescent and Electroluminescent Characteristics of $Zn(BOX)_{2}$ and $Zn(BTZ)_{2}$ (($Zn(BOX)_{2}$$Zn(BTZ)_{2}$의 광발광 특성 및 전계발광 특성에 대한 전기 화학적 연구)

  • Park, Jee-Young;Kwon, Oh-Kwan;Choi, Don-Soo;Kim, Young-Kwan;Sohn, Byoung-Chung;Ha, Yun-Kyoung
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.1
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    • pp.63-66
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    • 2000
  • Organic Electroluminescent devices(OELD) consisted of multilayer structures have been studied for the application the application to flat-panel display. Metal-chelate complexes, zinc bis(2-(2-hydroxyphenyl)benzoxazolate) ($Zn(BOX)_{2}$) and zinc bis(2-(2-hydroxyphenyl)benzothiazolate) ($Zn(BOX)_{2}$), have been intensively investigated as an white-light emitting layer and recognized to have good electroluminescent(EL) properties. In this study, ($Zn(BOX)_{2}$) and ($Zn(BTZ)_{2}$) were synthesized and characterized by FT-IR, $^{1}H-NMR$, UV-VIS and PL. Their EL properties were also studied and their ionization potential(IP) and electron affinity(EA) were also measured by cyclic voltammetry(CV).

Photoelectrochemical Properties of a Vertically Aligned Zinc Oxide Nanorod Photoelectrode (수직으로 정렬된 산화아연 나노막대 광전극의 광전기화학적 특성)

  • Park, Jong-Hyun;Kim, Hyojin
    • Journal of the Korean institute of surface engineering
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    • v.51 no.4
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    • pp.237-242
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    • 2018
  • We report on the fabrication and photoelectrochemical (PEC) properties of a ZnO nanorod array structure as an efficient photoelectrode for hydrogen production from sunlight-driven water splitting. Vertically aligned ZnO nanorods were grown on an indium-tin-oxide-coated glass substrate via seed-mediated hydrothermal synthesis method with the use of a ZnO nanoparticle seed layer, which was formed by thermally oxidizing a sputtered Zn metal thin film. The structural and morphological properties of the synthesized ZnO nanorods were examined using X-ray diffraction and scanning electron microscopy, as well as Raman scattering. The PEC properties of the fabricated ZnO nanorod photoelectrode were evaluated by photocurrent conversion efficiency measurements under white light illumination. From the observed PEC current density versus voltage (J-V) behavior, the vertically aligned ZnO nanorod photoelectrode was found to exhibit a negligible dark current and high photocurrent density, e.g., $0.65mA/cm^2$ at 0.8 V vs Ag/AgCl in a 1 mM $Na_2SO_4$ electrolyte. In particular, a significant PEC performance was observed even at an applied bias of 0 V vs Ag/AgCl, which made the device self-powered.

Analysis of Pigments in the Buseoksa Josadang Murals in Yeongju

  • Song, You Na;Lee, Han Hyoung;Baek, Na Yeon;Jung, Cham Hee;Park, Min Jeong;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.36 no.1
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    • pp.47-59
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    • 2020
  • Scientific analysis was conducted to identify the paint pigments used in the Buseoksa Josadang murals. optical microscopy(OM), X-ray fluorescence(XRF), XRF mapping, scanning electron microscopy-energy dispersive X-ray spectroscopy(SEM-EDS), and Raman spectroscopy were performed to examine the pigments. The results confirmed that the Josadang murals consist of two paint layers wherein the pigments were distinct for most colors. It was estimated that celadonite, white clay, red ochre, cinnabar and minium, synthetic green pigment containing tin and zinc paratacamite, or botallackite were used in the upper layer. In addition, bone white, celadonite, red ochre, azurite, cinnabar or vermilion, and gold were identified in the lower layer. In addition, as Zn and Sn were detected in the green pigments extracted from the top layer of the paint, it is believed that Josadang murals were repainted over the original paint layer at some point after the 17th century. In addition, white pigments containing calcium phosphate were found in all the colors in the bottom layer, which is the original paint layer. These results are significant because this is the first time that white pigments are found in Korean traditional paintings. Additionally, the information revealed about the pigments in this study will serve as areference for the pigments used in the Goryeo period.

Preparation and Characterization of Canned Oyster Crassostrea gigas in White Sauce (화이트소스를 첨가한 굴(Crassostrea gigas) 통조림의 제조 및 특성)

  • Cha, Jang Woo;Lee, Su Gwang;Park, Sun Young;Kang, Sang In;Kang, Young Mi;Kim, Jin-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.51 no.5
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    • pp.491-498
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    • 2018
  • The objective of this study was to investigate the composition of canned oyster Crassotrea gigas in white sauce (CO-WS). The proximate composition of CO-WS was 74.1% water, 10.4% crude protein, 4.9% crude lipid, and 3.1% ash. The energy converted based on these percentages was 112.2 kcal/100 g, while the salinity was 1.1 g/100 g. In a taste-intensity test using an electronic tongue, the CO-WS showed higher umami taste intensity than the control (canned oyster in commercial white sauce), whereas the intensities of the other tastes (salty, sour, bitter, and sweet) were lower. Because the odor intensity was low, CO-WS was considered to have a relatively weak odor and showed no difference in hardness compared to the control. Sensory evaluation of CO-WS by a panel yielded higher scores for appearance, taste, and texture, and a lower score for flavor compared to the control. The total amino acid content of CO-WS was 8.91 g/100 g, and its major amino acids were aspartic acid, glutamic acid, and leucine. With respect to mineral content, CO-WS had higher calcium and lower zinc contents than the control. These results suggest that CO-WS has excellent nutritional value.

Secondary Metabolites Production and Plant Growth Promotion by Pseudomonas chlororaphis and P. aurantiaca Strains Isolated from Cactus, Cotton, and Para Grass

  • Shahid, Izzah;Rizwan, Muhammad;Baig, Deeba Noreen;Saleem, Rahman Shahzaib;Malik, Kauser A.;Mehnaz, Samina
    • Journal of Microbiology and Biotechnology
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    • v.27 no.3
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    • pp.480-491
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    • 2017
  • Fluorescent pseudomonads have been isolated from halophytes, mesophytes, and xerophytes of Pakistan. Among these, eight isolates, GS-1, GS-3, GS-4, GS-6, GS-7, FS-2 (cactus), ARS-38 (cotton), and RP-4 (para grass), showed antifungal activity and were selected for detailed study. Based on biochemical tests and 16S rRNA gene sequences, these were identified as strains of P. chlororaphis subsp. chlororaphis and aurantiaca. Secondary metabolites of these strains were analyzed by LC-MS. Phenazine-1-carboxylic acid (PCA), 2-hydroxy-phenazine, Cyclic Lipopeptide (white line-inducing principle (WLIP)), and lahorenoic acid A were detected in variable amounts in these strains. P. aurantiaca PB-St2 was used as a reference as it is known for the production of these compounds. The phzO and PCA genes were amplified to assure that production of these compounds is not an artifact. Indole acetic acid production was confirmed and quantified by HPLC. HCN and siderophore production by all strains was observed by plate assays. These strains did not solubilize phosphate, but five strains were positive for zinc solubilization. Wheat seedlings were inoculated with these strains to observe their effect on plant growth. P. aurantiaca strains PB-St2 and GS-6 and P. chlororaphis RP-4 significantly increased both root and shoot dry weights, as compared with uninoculated plants. However, P. aurantiaca strains FS-2 and ARS-38 significantly increased root and shoot dry weights, respectively. All strains except PB-St2 and ARS-38 significantly increased the root length. This is the first report of the isolation of P. aurantiaca from cotton and cactus, P. chlororaphis from para grass, WLIP and lahorenoic acid A production by P. chlororaphis, and zinc solubilization by P. chlororaphis and P. aurantiaca.