• Title/Summary/Keyword: Zinc ores

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Marmatite 鑛의 直接酸浸出에 關한 硏究 (第2報) ${\beta}$-ZnS Autoclave Leaching의 反應機構에 關한 硏究 (Direct acid Leaching of zinc from Marmatite ores 2 Kinetics of Autoclave Leaching of Synthetic ${\beta}$-ZnS)

  • 김재원
    • 대한화학회지
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    • 제11권1호
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    • pp.33-37
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    • 1967
  • The influence of impurities contained in Marmatite ores on leaching of zinc was investigated. The zinc sulfide having the same crystal structure of natural Sphalerite was prepared by heating the zinc sulfide chemically precipitated, at $650^{\circ}C$ in nitrogen atmosphere. The activation energy of the sample was 25.8 kcal per mole in the leach test when oxygen partial pressure was 5 atm. and the value was exceedingly high compared to that obtained in Marmatite ores. Synthetic zinc sulfides added with small amount of each impurities were treated in same procedure. As a result, it was found that the leaching velocity was accelerated sharply when about 1 percent of $Cu^{++}$ was blended to the sample. Larger amount of iron has also same effect but the effect was minor compared to the copper. The other impurities indicated no appreciable catalytic action.

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Identification of Pb-Zn ore under the condition of low count rate detection of slim hole based on PGNAA technology

  • Haolong Huang;Pingkun Cai;Wenbao Jia;Yan Zhang
    • Nuclear Engineering and Technology
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    • 제55권5호
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    • pp.1708-1717
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    • 2023
  • The grade analysis of lead-zinc ore is the basis for the optimal development and utilization of deposits. In this study, a method combining Prompt Gamma Neutron Activation Analysis (PGNAA) technology and machine learning is proposed for lead-zinc mine borehole logging, which can identify lead-zinc ores of different grades and gangue in the formation, providing real-time grade information qualitatively and semi-quantitatively. Firstly, Monte Carlo simulation is used to obtain a gamma-ray spectrum data set for training and testing machine learning classification algorithms. These spectra are broadened, normalized and separated into inelastic scattering and capture spectra, and then used to fit different classifier models. When the comprehensive grade boundary of high- and low-grade ores is set to 5%, the evaluation metrics calculated by the 5-fold cross-validation show that the SVM (Support Vector Machine), KNN (K-Nearest Neighbor), GNB (Gaussian Naive Bayes) and RF (Random Forest) models can effectively distinguish lead-zinc ore from gangue. At the same time, the GNB model has achieved the optimal accuracy of 91.45% when identifying high- and low-grade ores, and the F1 score for both types of ores is greater than 0.9.

고농도 PCE 및 1,1,1 TCA 제거를 위한 영가금속 선정 (Screening of Zero-Valent Metal for the Removal of High Concentration PCE and 1,1,1 TCA)

  • 권수열;김영
    • 한국습지학회지
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    • 제12권1호
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    • pp.23-31
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    • 2010
  • 본 연구는 고농도의 PCE 및 1,1,1-TCA가 단독 또는 혼합물로 오염된 지하수 복원을 위해 영가 금속을 이용한 탈염소환원공정을 적용할 때 기술적으로, 경제적으로 가장 적절한 영가금속 선정을 목표로 수행되었다. 고순도 영가철, 고순도 영가아연, 철광석, 고로 슬래그, 차수재용슬래그, 망간 광석 및 아연 광석 등을 대상으로 회분식 반응조 실험을 수행하였으며, PCE, 1,1,1-TCA 및 혼합물의 분해능 및 탈염소화율을 도출하고, 금속 단가 당 변환량을 포함한 경제성 등을 검토하여 최적의 금속광물을 선정하고자 하였다. 연구결과 단일물질 처리시 고순도 영가철과 고순도 영가아연에 의한 제거율 및 분해능이 가장 높게 나타났으며, 그 다음으로 아연광석에 의한 분해능이 양호하였다. 두 물질 제거를 위한 경제성 비교에서는 고순도 영가철과 고순도 영가아연에 비해 아연광석이 매우 양호한 것으로 나타났다. 두 물질의 혼합처리 시에는 단일 처리에 비해 분해능이 감소하는 것으로 나타났다. 이상의 결과로부터 단일 또는 혼합 1,1,1-TCA, PCE 처리를 위한 분해능, 처리특성 및 경제성 등을 고려하였을 때 아연광석이 가장 적절한 금속광물로 사료된다.

Marmatite 鑛의 直接酸浸出에 關한 硏究 (第3報) Marmatite 鑛의 酸浸出과 黃化物의 電極電位에 關한 硏究 (Direct Acid Leaching of Zinc from Marmatite Ores 3 Acid Leaching of Marmatite Ores and the Electrode Potential Behavior of Sulfides)

  • 김재원
    • 대한화학회지
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    • 제11권1호
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    • pp.38-43
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    • 1967
  • In order to explain the positive catalytic action of copper compound for the rate of leaching of zinc sulfide minerals, the electrode and redox potentials of both synthetic and natural sulfides were measured at various conditions of temperatures and pressures. The potentials of Chalcopyrite and copper sulfide were considerably higher than that of zinc sulfide, whereas lead sulfide and Galena had slightly lower potentials than that of zinc sulfide. At elevated temperatures and pressures, the same tendency was obtained. By means of comparing the calculated and measured values of potentials for sulfides, it was suggested that the electrode potentials in acid solution were generated by oxidation of sulfur ion. As a result, it was concluded that the catalytic action of copper compound in the leaching of synthetic zinc sulfide should be arised from the galvanic action between sulfides keeping intimate contact one another in which copper sulfide worked as cathodic and zinc sulfide as anodic part analogous to the metal corrosion under galvanic action.

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국내 비철금속 제련시설에서의 납 동위원소 배출특성 연구 (Characterization of lead isotope emission profiles in non-ferrous smelters in South Korea)

  • 박진주;김기준;박진수;유석민;박광수;석광설;신형선;송금주;김영희
    • 분석과학
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    • 제26권5호
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    • pp.333-339
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    • 2013
  • 납 동위원소 분석은 국지적 및 지구적 납 오염 특성 해석을 위한 유용한 기법으로 널리 활용되어왔다. 본 연구는 국내 환경 중 납 오염원을 추적하기 위해 주요 배출원별 납 동위원소 인벤토리 구축사업의 일환으로 수행되었다. 특히 비철금속 제련시설은 가장 중요한 인위적 납 오염원으로 알려져 있으며, 본 연구에서는 국내에서 가동 중인 아연 (2 개 시설), 납 및 구리 제련시설에서의 납 동위원소의 유입 및 배출특성을 조사하였다. 각 제련시설에서 사용 중인 정광, 슬러지 및 폐수, 배출가스, 부산물로 생산되는 황산 및 제련된 금속제품 중의 납 농도와 납 동위원소 조성을 조사하였다. 아연 제련시설에서의 아연광석의 납 동위원소 분포는 1.179~1.198의 높은 $^{206}Pb/^{207}Pb$ 값을, 아연 제련시설에서 배출되는 배출가스, 제품, 폐기물 등은 1.105~1.147의 낮은 $^{206}Pb/^{207}Pb$ 값을 나타냈다. 국내 수입되는 아연광석은 주로 호주 및 페루 등이 주요 산지로서, 아연 제련시설에서 배출되는 물질들의 납 동위원소 분포는 중남미산 광석 및 호주산 광석의 납 동위원소 비율이 혼합된 것으로 추정되었다. 납 제련시설에서 배출되는 납 동위원소 패턴은 호주산 광석 및 중남미산 광석의 혼합 형태를 보이며, 구리 제련시설은 중남미 지역의 광석패턴을 따르는 것으로 추정되었다.

자연광석을 이용한 염소계 지방족 탄화수소 혼합물 변환 특성 (Transformation Characteristics of Chlorinated Aliphatic Hydrocarbon (CAH) Mixtures by Natural Ores)

  • 손봉한;김남희;홍광표;윤준기;이채영;김영;권수열
    • 한국물환경학회지
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    • 제23권5호
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    • pp.712-722
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    • 2007
  • This study screened three natural ores (iron, mangenase, and zinc), two types of slags, and two elemental metals (elemental iron and zinc) to evaluate transformation characteristics of CAH mixtures [e.g. Carbontetrachloride (CT), 1,1,1-Trichloroethane (1,1,1-TCA), and Perchloroethene (PCE)]. To select an effective metal medium to treat the CAH mixtures, we measured transformation capacities (CAH mass ultimately transformed/mass of metal added) and the degree of dechlorination. We also considered economical efficiency of the metal media by comparing the value, CAH mass ultimately transformed divided by the price of metal medium added. A simplified mathematical model adapting CAH transformation capacity, first-order transformation kinetics, and available mass of metal transforming CAH was developed and used for estimating CAH transformation rate coefficient and longevity of the metal medium. CAH transformation capacity for elemental iron and elemental zinc were 4258~7129 and $4215{\sim}6330{\mu}g\;CAH\;transformed/g$ metal added, respectively, which are a factor of 80~200 higher than slags and natural ores. They also showed a factor of 1.1 to 2.2 greater degree of dechlorination than the others. Among natural ores and slags, Zinc ore showed the highest transformation capacity, $47{\sim}53{\mu}g\;CAH\;transformed/g$ metal added. Although zinc ore have smaller transformation capacity than elemental metals, economical efficiency of zinc ore is a factor of 10~20 greater than elemental metals tested. Consequently, zinc ore would be more economical medium than the others tested in this study. We estimated the pseudo first-order transformation rate of zinc ore was in the order of CT > 1,1,1-TCA > PCE.

장군광산(將軍鑛山) 아연정광(亞鉛精鑛) 저품위(低品位) 현상(現象)의 원인(原因)과 품위(品位) 상승(上昇) 방안(方案)에 대(對)한 광물학적(鑛物學的) 연구(硏究) (Mineralogical Study of Zinc Ores and Mill Products from the Janggun Mine (With Emphasis on the Cause of Low-grade Concentrate and the Scheme of Raising Its Grade))

  • 김수진
    • 자원환경지질
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    • 제10권3호
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    • pp.99-105
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    • 1977
  • Mineralogical study of original and crushed zinc ores as well as mill products was made in order to find out the cause of low-grade concentrate and the scheme of raising its grade. Low-grade concentrate is due to 1) the abundance of other independent sulfides (arsenopyrite, pyrrhotite, chalcopyrite, stannite) and silicate (quartz) in the zinc concentrate, 2) the presence of composite grains of sphalerite and other sulfides or silicate, 3) the presence of a lot of very fine-grained particle of stannite and chalcopyrite within the sphalerite grains, and 4) the high content of iron in sphalerite. It is proposed that further crushing and other appropriate processing should be made in order to increase the grade of zinc concentrate.

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Marmatite 鑛의 直接酸浸出에 關한 硏究 (第1報) 國産 Marmatite 鑛의 酸素加壓下에서의 酸浸出에 關한 硏究 (Direct Acid Leaching of Zinc from Marmatite Ores (1) Autoclave Treatment of Domestic Marmatite Ores with Sulfuric Acid Oxygen)

  • 김재원
    • 대한화학회지
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    • 제11권1호
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    • pp.28-32
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    • 1967
  • The direct acid leaching of domestic Marmatite concentrate at elevated temperatures and pressures was investigated. Almost 100 percent of zinc was extracted from the concentrate liberating free sulfur in 4 hours at $100^{\circ}C$ when the oxygen partial pressure was 5 atm. in sulfuric acid solution. By applying the Arrhenius equation to leach reaction in the range of $60^{circ}$ to $100^{\circ}C$ at the same oxygen partial pressure, 15.7 kcal per mole of activation energy was calculated. At the initial stage of leaching, the rate of reaction increased linearly by increasing temperature and pressure. The concentration of sulfuric acid gave minor effect to leaching velocity in the range of 5 to 20 percent. The particle size should be under 270 mesh for 100 percent extraction of zinc.

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유도결합 플라즈마 원자방출 분광법에 의한 아연광 중 Ga 및 In의 분석에 관한 연구 (Studies on Analysis of Gallium and Indium in Zinc Ores by Inductively Coupled Plasma Atomic Emission Spectrometry)

  • 황윤옥;심상권;성학제;양명권
    • 분석과학
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    • 제6권1호
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    • pp.131-139
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    • 1993
  • 아연광 중 미량으로 존재하는 갈륨 및 인듐을 유도결합 플라스마 원자방출분광법(ICP-AES)으로 분석할 때 간섭하는 아연 및 다른 이온들과 특히 Fe(III) 이온으로부터 이들을 분리하는 방법에 대해 연구하였다. 갈륨과 인듐을 tributyl phosphate(TBP)로 용매추출하였는데 이때 영향을 주는 산농도, 다른 이온들의 간섭, 수용액상/유기상의 비율, TBP의 농도 및 탈거율 등에 대하여 조사하였다. 갈륨과 인듐이 함유되어 있는 아연광을 녹인 5N 염산용액에서 100% TBP로 추출하여 아연 및 기타 간섭이온들로부터 분리하였으며, 이때 철(III)이온은 hydroxylamine hydrochloride를 사용하여 Fe(II)로 환원시켜 coetraction되는 것을 방지하였다. 유기상으로부터 갈륨과 인듐의 탈거는 0.02N 염산용액으로 역추출하여 이루어졌으며 이 용액을 ICP-AES로 측정하여 이들을 정량하였다. 전체적으로 추출률이 95% 이상으로 정량적이었다.

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한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割) (The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea)

  • 윤석규
    • 자원환경지질
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    • 제18권1호
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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