• Journal of the Korean Chemical Society
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• v.29 no.2
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• pp.73-79
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• 1985

The crystal and molecular structure of acetone 4-benzylthiosemicarbazone, $C_{11}H_{15}N_3S$, has been determined by the single crystal X-ray diffraction methods. The crystals are monoclinic, space group $P2_1/c$ with unit cell dimensions, a = 10.249(7), b = 11.403(9), c = 10.149(7)TEX>${\AA}$, ${\beta}$ = 90.9$(1)^0$ and z = 4. The intensities were collected on an automatic four-circle diffractometer with graphite-monochromated Mo-$K_{\alpha}$ radiation. The structure was solved by direct methods and refined by full matrix least-squares methods. The final R was 0.045 for 1554 observed reflections. S-C(8)-N(2)-N(3)-C(9)-C(10) atoms make a zigzag planar chain. There are no unusual bond lengths and angles. There are two independent hydrogen bonds in the crystal structure. One is N-H${\cdots}$S intermolecular hydrogen bond with the length of 3.555${\AA}$ and makes dimer-like units. The other is N-H${\cdots}$N intramolecular hydrogen bond with the length of 2.568${\AA}$. The structure was compared with those of other thiosemicarbazone derivatives.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07a
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• pp.314-317
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• 2002

Since the early work of Tersoff and Hamann on the theory of the scanning tunneling microscope (STM), many theoretical approaches have been developed in order to gain further physical insight into the real space image that this technique provides. In this Paper, the STM image of Carbon nanotubes (CNT's) was calculated through the theoretical study. The optimized structure of CNT's was simulated using Brenner's hydrocarbon potential. The structure of simulation is (5. 5) armchair CNT and (10. 0) zigzag CNT. Also we have used that the extended Huckel tight binding (EHTB) theory already provides a fairly good qualitative description of the main processes that control the final contrast in the STM image. we found that the shape of the calculated images is hardly dependent on the exact electronic charge distribution at the surface. The STM images are not too sensitive to the precise electronic structure but, rather, they reflect its qualitative features. As a result of the simulation, The STM images of CNT's and the electronic density distribution were investigated. It found that the EHTB theory is appropriate for STM image calculation and that the STM images are in agreement with the result of Experiment.

• Journal of Industrial Technology
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• v.19
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• pp.25-29
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• 1999

Rotary bending fatigue tests were carried out to investigate the fatigue behavior of high performance ductile cast iron experienced super rapid induction heat treatment. The effect of super rapid induction treatment on fatigue limit was experimentally examined with the special focus on the variation surface microstructure and the fatigue crack initiation and propagation through fractography. Main results obtained are as follows. By super rapid induction treatment in FCD500, the martensite structure obtained through conventional quenching heat treatment was confirmed on the specimen surface. The fatigue crack initiation in the hardened surface layer was restricted by the martensite structure and compressive residual stress. Thus, it could be interpreted that the initiation stress would be increased by the improvement of surface structure. The fatigue crack propagation in the hardened layer was retarded by the presence of the globular shape martensite around the graphite nodule and compressive residual stress. The crack propagation path has shown zigzag pattern in the hardened surface layer.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.4
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• pp.596-601
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• 2002

Rotary bending fatigue tests were carried out to investigate the fatigue characteristics of high performance ductile cast iron experienced super rapid induction treatment. The influence of super rapid induction treatment on fatigue limit was experimentally examined with the special focus on the variation of surface microstructure and the fatigue crack initiation and propagation through fractography. Main results obtained are as follows. By super rapid induction treatment in FCD500, the martensite structure obtained through conventional heat treatment was confirmed on the specimen surface. The fatigue crack initiation in the hardened surface layer was restricted by the martensite structure and compressive residual stress. Thus, it could be interpreted that the initiation stress would be increased by improved structure in the surface. The fatigue crack propagation in the hardened layer was retarded by the presence of the globular shape martensite around the graphite nodule and compressive residual stress and the crack propagation behavior has zigzag pattern in the hardened surface layer.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.15 no.10 s.89
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• pp.922-930
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• 2004

In this paper, the 3-dimensional microstrip antenna, where the lis is attached near the patch, on the pound and both patch and ground in zigzag, is designed and fabricated to miniaturize size of antenna. The path of surface current and permittivity in patch are increased because of attached Iris near the patch, on the pound and patch and found. In particula., the maximum size reduction effect among the three-type of $79.1\%$(17 mm$\times$90 mm) was presented in zigzag-type compared with the rectangular microstrip patch antenna(MPA) with a height of 9 mm at the resonant frequency of 1.575 GHz. The gain showed -1.15 dBd, -10 dB bandwidth showed 6.2$\%$(98 MHz), and HPBW of E-plane showed $154^{\circ}$. As that result we could confirm that the 3-dimensional structure with attached Irises is the proper form for the miniaturization of microstrip antenna.

• Advances in nano research
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• v.13 no.3
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• pp.207-216
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• 2022

In this paper, a novel model is developed for frequency behavior of single walled carbon nanotubes. The governing equation of motion is constructed method based on the Sander theory using Rayleigh-Ritz's method The frequencies enhances on increasing the power law index using simply supported, clamped and clamped free end conditions. The frequency curve for C-F is less than other conditions. It is due to the physical constraints which are applied on the edge of the CNT. It is observed that the C-F boundary condition have less frequencies from the other two conditions. The frequency phenomena for zigzag are insignificant throughout the aspect ratio. Moreover when index of power law is increased then frequencies increases for all boundary conditions. The natural frequency mechanism for the armchair (10, 10) for various values of power law index with different boundary conditions is investigated. Here frequencies decrease on increases the aspect ratio for all boundary conditions. The frequency curves of SS-SS edge condition is composed between the C-C and C-F conditions. The curves of frequency are less significant from small aspect ratio (L/d = 4.86 ~ 8.47) and decreases fast for greater ratios. It is found that the frequencies via aspect ratios, armchair (10, 10) have higher values from zigzag (10, 0). It is due to the material structure which is made by the carbon nanotubes. The power law index have momentous effect on the vibration of single walled carbon nanotubes. The present frequency result is also compared numerically experimentally with Raman Spectroscopy.

• Journal of the Korean Association of Geographic Information Studies
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• v.25 no.4
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• pp.32-48
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• 2022

This study presented a spatial data serialization technique that can efficiently store and transmit large amounts of spatial data for precision road maps was designed and implemented. For efficient serialization, a binary spatial data structure is defined, and a coordinate value encoding technique without loss of information is designed using the Zigzag-Z-order curve. The spatial data serialization technique designed for precision road maps was tested, and the data size and encoding/decoding speed after encoding were compared with Protocol buffer and Geobuff. As a result, it was confirmed that the designed serialization method was excellent in data weight reduction performance and encoding speed. However, the decoding speed was inferior to other serialization techniques in linestring and polygon type spatial data. Through this study, it was confirmed that spatial data can be efficiently encoded, stored, and transmitted using binary serialization techniques.

• Proceedings of the Korean Information Science Society Conference
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• 1999.10b
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• pp.259-261
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• 1999

본 논문은 MPEG-2 TM 5 video 부호기의 전체구조 및 처리과정을 기술한다. MPEG-2는 저장 매체, 통신, 방송 매체 등을 위한 동영상 압축이 표준이다. MPEG-2 압축 방법에는 공간적 압축과 시간적 압축 방법이 있다. 공간적 압축 방법에는 화면에서의 중복성을 줄이기 위한 표본화 주파수(4:4:4, 4:2:2, 4:2:0, format), DCT, scanning(zigzag 혹은 alternate scanning)과 quantization이 있고 시간적 압축 방법에는 움직임 예측(motion estimation)과 I, P, B-picture를 사용하는 방법이 있다. 본 논문에서는 MPEG-2 부호기의 핵심을 전체 구조, DPCM, MPEG bitstream syntax, MPEG-2 부호화 알고리즘, 움직임 예측, 움직임 벡터, rate control 그리고 가변길이 코딩(variable length coding)으로 구분하여 소개한다.

• Advances in nano research
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• v.8 no.3
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• pp.229-244
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• 2020

In this paper, modified Kelvin's model has been used to analyze the orthotropic vibration frequencies of single walled carbon nanotubes with clamped-clamped and clamped-free boundary conditions. For this system the governing equation is developed with wave propagation approach. Armchair, zigzag and chiral structures are considered for the vibrational analysis to investigate the effect of different modes, in-plane rigidity and mass density per unit lateral area. Throughout the computations, on decreasing the length-to-diameter ratios, the frequencies of said structure increases. In addition, by increasing three different value of in-plane rigidity resulting frequencies also increase and frequencies decrease on increasing mass density per unit lateral area. The results generated using computer software MATLAB to furnish the evidence regarding applicability of present model and also verified by available published literature.

• Korean Journal of Pharmacognosy
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• v.11 no.3_4 s.43
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• pp.153-162
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• 1980

1) The hydroxy-substitution in the simple phenolic compounds follows an additivity rule in the chemical shifts of their aromatic carbon atoms. In para-and ortho-effects is a good agreement between calculated and measured values, but the meta-effect is not certain. 2) The additivity rule was applied to assign the chemical shifts of catechins. 3) The nuclear overhauser effect was applied to assign the chemical shifts of C-8 and C-6 atoms of catechins and their polymer. The signal of C-8 is lower in intensity and appear in lower field than C-6. 4) The results of the NOE were applied to determine the bonding positions of catechin units in the catechin dimer and trimer. The bonding positions are C-8a and C-8b atoms of the second and third catechin units. 5) It was tried to determine the conformation of the catechin dimer and trimer by analysing the signal shapes of C-3' and C-4' atoms in the catechol moieties. The catechol moieties lie in opposite side in the dimer and trimer structure. A combined analysis of $^{13}C-and\;^1H-NMR$ results lead to the suggestion that such a catechin polymer is a zigzag planar form.