• Bulletin of the Korean Chemical Society
• /
• 제24권3호
• /
• pp.325-333
• /
• 2003

An analysis of the electronic structure and bonding in the ternary silicide YNiSi₃is made, using extended Huckel tight-binding calculations. The YNiSi₃structure consists of Ni-capped Si₂dimer layers and Si zigzag chains. Significant bonding interactions are present between the silicon atoms in the structure. The oxidation state formalism of $(Y^{3+})(Ni^0)(Si^3)^{3-}$ for YNiSi₃constitutes a good starting point to describe its electronic structure. Si atoms receive electrons from the most electropositive Y in YNiSi₃, and Ni 3d and Si 3p states dominate below the Fermi level. There is an interesting electron balance between the two Si and Ni sublattices. Since the ${\pi}^*$ orbitals in the Si chain and the Ni d and s block levels are almost completely occupied, the charge balance for YNiSi₃can be rewritten as $(Y^{3+})(Ni^{2-})(Si^{2-})(Si-Si)^+$, making the Si₂layers oxidized. These results suggest that the Si zigzag chain contains single bonds and the Si₂double layer possesses single bonds within a dimer with a partial double bond character. Strong Si-Si and Ni-Si bonding interactions are important for giving stability to the structure, while essentially no metal-metal bonding exists at all. The 2D metallic behavior of this compound is due to the Si-Si interaction leading to dispersion of the several Si₂π bands crossing the Fermi level in the plane perpendicular to the crystallographic b axis.

• 한국자기학회지
• /
• 제22권3호
• /
• pp.73-78
• /
• 2012

본 연구에서는 Argyres-Sigel의 투영 연산자 방법을 단일 벽 탄소 나노튜브(SWNT)의 zigzag(10,0)에 직접 적용하여 이를 운동방정식의 형태로 만들어 선모양 함수를 구하는 방법을 사용하였다. 선모양 함수의 실수 부분인 선 너비는 저온 영역(T < 200K)에서 온도의 영향에 거의 무관한 것으로 조사되었다. 이는 온도에 관여하는 페르미-디랙 분포함수가 선모양 함수에 거의 영향을 작용하지 않기 때문인 것으로 생각된다. 고온 영역(T > 200K)에서는 선 너비가 다소 단조롭게 증가하는 것으로 나타났으며, 이는 음향 포논의 영향에 기인하는 것으로 보인다. 그리고 SWNT의 전자스핀이완 시간은 $1.4{\times}10^{-6}\;s$으로 계산되었다.

• Steel and Composite Structures
• /
• 제37권2호
• /
• pp.229-251
• /
• 2020

In this paper, dynamic buckling of a smart sandwich nanotube is studied. The nanostructure is composed of a carbon-nanotube with inner and outer surfaces coated with ZnO piezoelectric layers, which play the role of sensor and actuator. Nanotube is under magnetic field and ZnO layers are under electric field. The nanostructure is located in a viscoelastic environment, which is assumed to obey Visco-Pasternak model. Non-local piezo-elasticity theory is used to consider the small-scale effect, and Kelvin model is used to describe the structural damping effects. Surface stresses are taken into account based on Gurtin-Murdoch theory. Hamilton principle in conjunction with zigzag shear-deformation theory is used to obtain the governing equations. The governing equations are then solved using the differential quadrature method, to determine dynamic stability region of the nanostructure. To validate the analysis, the results for simpler case studies are compared with others reported in the literature. Then, the effect of various parameters such as small-scale, surface stresses, Visco-Pasternak environment and electric and magnetic fields on the dynamic stability region is investigated. The results show that considering the surface stresses leads to an increase in the excitation frequency and the dynamic stability region happens at higher frequencies.

• Advances in nano research
• /
• 제7권6호
• /
• pp.431-442
• /
• 2019

Vibration analysis of carbon nanotubes (CNTs) is very essential field owing to their many promising applications in tiny instruments. In current study, the Eringen's nonlocal elasticity theory with clamped-clamped and clamped-free end conditions is utilized for the vibration analysis of armchair and zigzag SWCNTs. The Fourier method is utilized to solve the ordinary differential equation. The motion equation for this system is developed using a novel wave propagation method. Complex exponential functions have been used and the axial model depends on BCs that has been described at the edges of CNTs. The behavior of different nonlocal parameters is considered to find the vibrational frequency of SWCNTs. It is exhibited that the effect of frequencies against aspect ratio by varying the bending rigidity. It has been investigated that by increasing the nonlocal parameter decreases the frequencies and on increasing the aspect ratio increases the frequencies for both the tubes. To generate the fundamental natural frequencies of SWCNTs, computer software MATLAB engaged. The numerical results are validated with existing open text. Since the percentage of error is negligible, the model has been concluded as valid.

• 대한조선학회논문집
• /
• 제57권1호
• /
• pp.52-59
• /
• 2020

This study aims to investigate the bow thruster performance of the research vessel "NARA" by full-scale maneuvering trials. The thruster test method refers to ITTC's recommended procedures and guidelines. Turning tests with the bow thruster are performed at speed conditions of 0, 2, and 4 knots. The test results indicate that the Rate of Turn (ROT) increased when the ship is in a higher speed condition. Due to the position of the propeller and the housing of the bow thruster, there is difference in the efficiency of the bow thruster according to the turning direction. Zigzag tests with the bow thruster were conducted at speed conditions of 2 and 4 knots. At speeds above 4 knots, it seems difficult to change the course only with the bow thruster.

• Structural Engineering and Mechanics
• /
• 제71권2호
• /
• pp.197-210
• /
• 2019

Probabilistic buckling behavior of sandwich panel considering random system parameters using a radial basis function (RBF) approach is presented in this paper. The random system properties result in an uncertain response of the sandwich structure. The buckling load of laminated sandwich panel is obtained by employing higher-order-zigzag theory (HOZT) coupled with RBF and probabilistic finite element (FE) model. The in-plane displacement variation of core as well as facesheet is considered to be cubic while transverse displacement is considered to be quadratic within the core and constant in the facesheets. Individual and combined stochasticity in all elemental input parameters (like facesheets thickness, ply-orientation angle, core thickness and properties of material) are considered to know the effect of different degree of stochasticity, ply- orientation angle, boundary conditions, core thickness, number of laminates, and material properties on global response of the structure. In order to achieve the computational efficiency, RBF model is employed as a surrogate to the original finite element model. The stiffness matrix of global response is stored in a single array using skyline technique and simultaneous iteration technique is used to solve the stochastic buckling equations.

• Structural Engineering and Mechanics
• /
• 제70권6호
• /
• pp.737-750
• /
• 2019

This paper investigates the static and dynamic behaviors of imperfect single walled carbon nanotube (SWCNT) modeled as a beam structure by using energy-equivalent model (EEM), for the first time. Based on EEM Young's modulus and Poisson's ratio for zigzag (n, 0), and armchair (n, n) carbon nanotubes (CNTs) are presented as functions of orientation and force constants. Nonlinear Euler-Bernoulli assumptions are proposed considering mid-plane stretching to exhibit a large deformation and a small strain. To simulate the interaction of CNTs with the surrounding elastic medium, nonlinear elastic foundation with cubic nonlinearity and shearing layer are employed. The equation governed the motion of curved CNTs is a nonlinear integropartial-differential equation. It is derived in terms of only the lateral displacement. The nonlinear integro-differential equation that governs the buckling of CNT is numerically solved using the differential integral quadrature method (DIQM) and Newton's method. The linear vibration problem around the static configurations is discretized using DIQM and then is solved as a linear eigenvalue problem. Numerical results are depicted to illustrate the influence of chirality angle and imperfection amplitude on static response, buckling load and dynamic behaviors of armchair and zigzag CNTs. Both, clamped-clamped (C-C) and simply supported (SS-SS) boundary conditions are examined. This model is helpful especially in mechanical design of NEMS manufactured from CNTs.

• Structural Engineering and Mechanics
• /
• 제70권3호
• /
• pp.269-277
• /
• 2019

Using the non-local elasticity theory, Timoshenko beam model is developed to study the non- local buckling of Triple-walled carbon nanotubes (TWCNTs) embedded in an elastic medium under axial compression. The chirality and small scale effects are considered. The effects of the surrounding elastic medium based on a Winkler model and van der Waals' (vdW) forces between the inner and middle, also between the middle and outer nanotubes are taken into account. Considering the small-scale effects, the governing equilibrium equations are derived and the critical buckling loads under axial compression are obtained. The results show that the critical buckling load can be overestimated by the local beam model if the small-scale effect is overlooked for long nanotubes. In addition, significant dependence of the critical buckling loads on the chirality of zigzag carbon nanotube is confirmed. Furthermore, in order to estimate the impact of elastic medium on the non-local critical buckling load of TWCNTs under axial compression, the use of these findings are important in mechanical design considerations, improve and reinforcement of devices that use carbon nanotubes.

• Nuclear Engineering and Technology
• /
• 제54권5호
• /
• pp.1874-1889
• /
• 2022

In this study, we evaluate the thermal-hydraulic performance and economics of Printed Circuit Heat Exchanger (PCHE) according to the channel types and associated shape variables for the design of recuperators with Sodium-cooled Fast Reactors (SFRs). To perform the evaluations with variables such as the Reynolds number, channel types, tube diameter, and shape variables, a code for the heat exchanger is developed and verified through a comparison with experimental results. Based on the code, the volume and pressure drop are calculated, and an economic assessment is conducted. The zigzag type, which has bending angle of 80° and a tube diameter of 1.9 mm, is the most economical channel type in a SFR using CO₂ as the working fluid. For a SFR using N₂, we recommend the airfoil type with vertical and horizontal numbers of 1.6 and 1.1, respectively. The airfoil type is superior when the mass flow rate is large because the operating cost changes significantly. When the mass flow rate is small, volume is a more important design parameter, therefore, the zigzag type is suitable. In addition, we conduct a sensitivity analysis based on the production cost of the PCHE to identify changes in optimal channel types.

• 대한조선학회논문집
• /
• 제58권6호
• /
• pp.415-423
• /
• 2021

There have been many experimental studies on the manoeuvrability of KRISO Container Ship (KCS). However, the scale ratio of the model ship and the test procedure for each institute are slightly different, so direct comparison for the data is technically difficult to perform. This paper presents the manoeuvrability of the ship with different scale ratios: 1/65.8, 1/42.0, and 1/31.6 in model scale. KRISO conducted Free Running Model Tests (FRMT): 35° turning circle tests and 20/20(10/10) zigzag manoeuvring tests. The test results indicated that advance and tactical diameter in turning circle tests were similar, and overshoot angles in two zigzag manoeuvring tests increased as the model ship size increased. In addition, a basic concept for the FRMT method with an auxiliary X-thrust device was proposed so that the scale effect could be considered in model ship tests.