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MOF-Derived FeCo-Based Layered Double Hydroxides for Oxygen Evolution Reaction

  • Fang Zheng;Mayur A. Gaikwad;Jin Hyeok Kim
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.377-384
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    • 2023
  • Exploring earth-abundant, highly effective and stable electrocatalysts for electrochemical water splitting is urgent and essential to the development of hydrogen (H2) energy technology. Iron-cobalt layered double hydroxide (FeCo-LDH) has been widely used as an electrocatalystfor OER due to its facile synthesis, tunable components, and low cost. However, LDH synthesized by the traditional hydrothermal method tends to easily agglomerate, resulting in an unstable structure that can change or dissolve in an alkaline solution. Therefore, studying the real active phase is highly significant in the design of electrochemical electrode materials. Here, metal-organic frameworks (MOFs) are used as template precursors to derive FeCo-LDH from different iron sources. Iron salts with different anions have a significant impact on the morphology and charge transfer properties of the resulting materials. FeCo-LDH synthesized from iron sulfate solution (FeCo-LDH-SO4) exhibits a hybrid structure of nanosheets and nanowires, quite different from other electrocatalysts that were synthesized from iron chloride and iron nitrate solutions. The final FeCo-LDH-SO4 had an overpotential of 247 mV with a low Tafel-slope of 60.6 mV dec-1 at a current density of 10 mA cm-2 and delivered a long-term stability of 40 h for the OER. This work provides an innovative and feasible strategy to construct efficient electrocatalysts.

Eco-Friendly Behavior of the Disposable Cup Deposit System: Focusing on Shadow Work, Perceived Efficacy, Environmental Consciousness, and Eco-guilt (일회용 컵 보증금 제도의 친환경행동: 그림자노동, 지각된 효능감, 환경의식, 에코 죄책감을 중심으로)

  • Zheng Yizhe;Joon Koh
    • Journal of Information Technology Services
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    • v.22 no.5
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    • pp.31-49
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    • 2023
  • Due to the outbreak of the COVID-19, self-service technology is widely used in Korea, and demand for disposable cups is increasing significantly. Waste and recycling of disposable cups have become a social concern for Koreans and Korea implemented the "Disposable Cup Deposit Systems" again in December 2022. Whether the emergence of this system can change the way people behave in environmental protection is a question to be examined in this study. Companies participating in the disposable cup deposit system are hoping that customers will actively recover cups through self-service in the process of collecting disposable cups. The government, along with businesses, transfers recovery work to customers through self-service technologies and schemes. Due to the increase in Shadow Work and the strengthening of consumer environmental protection consciousness, this paper focuses on how unmanned service types such as self-service technology can affect people's environmental protection behavior. An empirical analysis with 477 samples examined how the characteristics of shadow work, perceived efficacy, environmental awareness, and ecological guilt affect user's environmental protection behavior. Perceived efficacy that acts as a mediator and ecological guilt that plays as a moderator are investigated. Although there have been many studies on the effects of shadow work on customer behavioral intentions before, it has been very rare to study the effects of shadow work perceived by people on environmental behavioral intentions from an environmental protection perspective. This study shows that the higher the perceived efficacy of consumers, the more people prefer self-service technology and the stronger the environmental protection behavior. Also, consumers' ecological guilt significantly moderates the relationship between environmental consciousness and eco-friendly behavior. It is expected that companies and governments will be able to understand the impact of shadow work on consumers' environmental protection behavior and further promote environmental protection by appropriate policies and marketing strategies.

Transcriptome analysis revealed regulatory mechanisms of light and culture density on free-living sporangial filaments of Neopyropia yezoensis (Rhodophyta)

  • Bangxiang He;Zhenbin Zheng;Jianfeng Niu;Xiujun Xie;Guangce Wang
    • ALGAE
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    • v.38 no.4
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    • pp.283-294
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    • 2023
  • Previous research indicated that free-living sporangial filament keep hollow morph under high-culture density and form bipartite cells under low-culture density, while the following conchospore release was inhibited by high light. Here, we further explored the molecular bases of these affects caused by light and culture density using a transcriptome analysis. Many differentially expressed genes (DEGs) related to carbon dioxide concentration and fixation, photosynthesis, chlorophyll synthesis and nitrogen absorption were upregulated under high-light conditions compared with low-light conditions, indicating the molecular basis of rapid vegetative growth under the former. The stress response- and ion transport-related DEGs, as well as the gene encoding the vacuole formation-brefeldin A-inhibited guanine nucleotide exchange protein (BIG, py05721), were highly expressed under high-density conditions, indicating the molecular basis of the hollow morph of free-living sporangial filaments under high-culture density conditions. Additionally, the brefeldin A treatment indicated that the hollow morph was directly influenced by vacuole formation-related vesicle traffic. Others DEGs related to cell wall components, zinc-finger proteins, ASPO1527, cell cycle and cytoskeleton were highly expressed in the low density with low-light group, which might be related to the formation and release of conchospores. These results provide a deeper understanding of sporangial filaments in Neopyropia yezoensis and related species.

A study on the Performance of Hybrid Normal Mapping Techniques for Real-time Rendering

  • ZhengRan Liu;KiHong Kim;YuanZi Sang
    • International journal of advanced smart convergence
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    • v.12 no.4
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    • pp.361-369
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    • 2023
  • Achieving realistic visual quality while maintaining optimal real-time rendering performance is a major challenge in evolving computer graphics and interactive 3D applications. Normal mapping, as a core technology in 3D, has matured through continuous optimization and iteration. Hybrid normal mapping as a new mapping model has also made significant progress and has been applied in the 3D asset production pipeline. This study comprehensively explores the hybrid normal techniques, analyzing Linear Blending, Overlay Blending, Whiteout Blending, UDN Blending, and Reoriented Normal Mapping, and focuses on how the various hybrid normal techniques can be used to achieve rendering performance and visual fidelity. performance and visual fidelity. Under the consideration of computational efficiency, visual coherence, and adaptability in different 3D production scenes, we design comparative experiments to explore the optimal solutions of the hybrid normal techniques by analyzing and researching the code, the performance of different hybrid normal mapping in the engine, and analyzing and comparing the data. The purpose of the research and summary of the hybrid normal technology is to find out the most suitable choice for the mainstream workflow based on the objective reality. Provide an understanding of the hybrid normal mapping technique, so that practitioners can choose how to apply different hybrid normal techniques to the corresponding projects. The purpose of our research and summary of mixed normal technology is to find the most suitable choice for mainstream workflows based on objective reality. We summarized the hybrid normal mapping technology and experimentally obtained the advantages and disadvantages of different technologies, so that practitioners can choose to apply different hybrid normal mapping technologies to corresponding projects in a reasonable manner.

Use of Magnetic Resonance Neurography for Evaluating the Distribution and Patterns of Chronic Inflammatory Demyelinating Polyneuropathy

  • Xiaoyun Su;Xiangquan Kong;Zuneng Lu;Min Zhou;Jing Wang;Xiaoming Liu;Xiangchuang Kong;Huiting Zhang;Chuansheng Zheng
    • Korean Journal of Radiology
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    • v.21 no.4
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    • pp.483-493
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    • 2020
  • Objective: To evaluate the distribution and characteristics of peripheral nerve abnormalities in chronic inflammatory demyelinating polyneuropathy (CIDP) using magnetic resonance neurography (MRN) and to examine the diagnostic efficiency. Materials and Methods: Thirty-one CIDP patients and 21 controls underwent MR scans. Three-dimensional sampling perfections with application-optimized contrasts using different flip-angle evolutions and T1-/T2- weighted turbo spin-echo sequences were performed for neurography of the brachial and lumbosacral (LS) plexus and cauda equina, respectively. Clinical data and scores of the inflammatory Rasch-built overall disability scale (I-RODS) in CIDP were obtained. Results: The bilateral extracranial vagus (n = 11), trigeminal (n = 12), and intercostal nerves (n = 10) were hypertrophic. Plexus hypertrophies were observed in the brachial plexus of 19 patients (61.3%) and in the LS plexus of 25 patients (80.6%). Patterns of hypertrophy included uniform hypertrophy (17 [54.8%] brachial plexuses and 21 [67.7%] LS plexuses), and multifocal fusiform hypertrophy (2 [6.5%] brachial plexuses and 4 [12.9%] LS plexuses) was present. Enlarged and/or contrast-enhanced cauda equina was found in 3 (9.7%) and 13 (41.9%) patients, respectively. Diameters of the brachial and LS nerve roots were significantly larger in CIDP than in controls (p < 0.001). The largest AUC was obtained for the L5 nerve. There were no significant differences in the course duration, I-RODS score, or diameter between patients with and without hypertrophy. Conclusion: MRN is useful for the assessment of distribution and characteristics of the peripheral nerves in CIDP. Compared to other regions, LS plexus neurography is more sensitive for CIDP.

Experimental Evaluation on JGS Frost Susceptibility Testing Method (일본 동상민감성 판정 기준에 관한 고찰)

  • Jangguen Lee;Hyunwoo Jin;Zheng Gong
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.7
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    • pp.21-27
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    • 2024
  • Frost heave, a significant engineering aspect of frozen ground, leads to various damages in Korea during the winter. Both the United States and Japan, encompassing regions with frozen ground, have actively researched frost heave and possess standardized experimental methods. Particularly, the Japanese Geotechnical Society (JGS) has introduced a frost heave standard testing method, offering the advantage of relatively simple specimen preparation and experimental procedures. However, issues persist regarding the ambiguous engineering interpretation of frost heave test results and the lack of clear criteria for frost heave susceptibility assessment. This paper presents laboratory testing results following the JGS testing method on sand and silt mixtures using a triaxial temperature-controllable cell, and thoroughly analyzes the frost heave rate calculation process. Furthermore, it evaluates the applicability of frost heave susceptibility criteria proposed in the United States to frost heave rates based on the JGS testing method.

Correlation Analysis of Empirical Frost Heave Prediction Models (경험적 동상 예측 모델 간의 상관관계 분석)

  • Jangguen Lee;Hyunwoo Jin;Zheng Gong
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.7
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    • pp.29-34
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    • 2024
  • Frost heave is one of the significant engineering characteristics of frozen ground and causes severe damages on geo-structures. Although thermo-hydro coupled analyses have been developed to predict frost heave behavior, these analyses involve excessive input parameters and have primarily been validated for frost heave in clayey soils. Frost heave mainly occurs in silty soils, which have relatively higher permeability compared to clayey soils, necessitating careful attention. This study introduces empirical models and verifies their reliability for silty soils. By using the validated model, the correlation of key input parameters is derived, which is expected to enhance the applicability of thermal-mechanical analysis for geo-structures on frozen ground in the future.

Key technologies research on the response of a double-story isolated structure subjected to long-period earthquake motion

  • Liang Gao;Dewen Liu;Yuan Zhang;Yanping Zheng;Jingran Xu;Zhiang Li;Min Lei
    • Earthquakes and Structures
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    • v.26 no.1
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    • pp.17-30
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    • 2024
  • Earthquakes can lead to substantial damage to buildings, with long-period ground motion being particularly destructive. The design of high-performance building structures has become a prominent focus of research. The double-story isolated structure is a novel type of isolated structure developed from base isolated structure. To delve deeper into the building performance of double-story isolated structures, the double-story isolated structure was constructed with the upper isolated layer located in different layers, alongside a base isolated structure for comparative analysis. Nonlinear elastoplastic analyses were conducted on these structures using different ground motion inputs, including ordinary ground motion, near-field impulsive ground motion, and far-field harmonic ground motion. The results demonstrate that the double-story isolated structure can extend the structural period further than the base isolated structure under three types of ground motions. The double-story isolated structure exhibits lower base shear, inter-story displacement, base isolated layer displacement, story shear, and maximum acceleration of the top layer, compared to the base isolated structure. In addition, the double-story isolated structure generates fewer plastic hinges in the frame, causes less damage to the core tube, and experiences smaller overturning moments, demonstrating excellent resistance to overturning and a shock-absorbing effect. As the upper isolated layer is positioned higher, the compressive stress on the isolated bearings of the upper isolated layer in the double-story isolated structure gradually decreases. Moreover, the compressive stress on the isolated bearings of the base isolated layer is lower compared to that of the base isolated structure. However, the shock-absorbing capacity of the double-story isolated structure is significantly increased when the upper isolated layer is located in the middle and lower section. Notably, in regions exposed to long-period ground motion, a double-story isolated structure can experience greater seismic response and reduced shock-absorbing capacity, which may be detrimental to the structure.

An Efficient and Secure Authentication Scheme with Session Key Negotiation for Timely Application of WSNs

  • Jiping Li;Yuanyuan Zhang;Lixiang Shen;Jing Cao;Wenwu Xie;Yi Zheng;Shouyin Liu
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.18 no.3
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    • pp.801-825
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    • 2024
  • For Internet of Things, it is more preferred to have immediate access to environment information from sensor nodes (SNs) rather than from gateway nodes (GWNs). To fulfill the goal, mutual authentication scheme between user and SNs with session key (SK) negotiation is more suitable. However, this is a challenging task due to the constrained power, computation, communication and storage resources of SNs. Though lots of authentication schemes with SK negotiation have been designed to deal with it, they are still insufficiently secure and/or efficient, and some even have serious vulnerabilities. Therefore, we design an efficient secure authentication scheme with session key negotiation (eSAS2KN) for wireless sensor networks (WSNs) utilizing fuzzy extractor technique, hash function and bitwise exclusive-or lightweight operations. In the eSAS2KN, user and SNs are mutually authenticated with anonymity, and an SK is negotiated for their direct and instant communications subsequently. To prove the security of eSAS2KN, we give detailed informal security analysis, carry out logical verification by applying BAN logic, present formal security proof by employing Real-Or-Random (ROR) model, and implement formal security verification by using AVISPA tool. Finally, computation and communication costs comparison show the eSAS2kN is more efficient and secure for practical application.

Application of Virtual Studio Technology and Digital Human Monocular Motion Capture Technology -Based on <Beast Town> as an Example-

  • YuanZi Sang;KiHong Kim;JuneSok Lee;JiChu Tang;GaoHe Zhang;ZhengRan Liu;QianRu Liu;ShiJie Sun;YuTing Wang;KaiXing Wang
    • International Journal of Internet, Broadcasting and Communication
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    • v.16 no.1
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    • pp.106-123
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    • 2024
  • This article takes the talk show "Beast Town" as an example to introduce the overall technical solution, technical difficulties and countermeasures for the combination of cartoon virtual characters and virtual studio technology, providing reference and experience for the multi-scenario application of digital humans. Compared with the live broadcast that combines reality and reality, we have further upgraded our virtual production technology and digital human-driven technology, adopted industry-leading real-time virtual production technology and monocular camera driving technology, and launched a virtual cartoon character talk show - "Beast Town" to achieve real Perfectly combined with virtuality, it further enhances program immersion and audio-visual experience, and expands infinite boundaries for virtual manufacturing. In the talk show, motion capture shooting technology is used for final picture synthesis. The virtual scene needs to present dynamic effects, and at the same time realize the driving of the digital human and the movement with the push, pull and pan of the overall picture. This puts forward very high requirements for multi-party data synchronization, real-time driving of digital people, and synthetic picture rendering. We focus on issues such as virtual and real data docking and monocular camera motion capture effects. We combine camera outward tracking, multi-scene picture perspective, multi-machine rendering and other solutions to effectively solve picture linkage and rendering quality problems in a deeply immersive space environment. , presenting users with visual effects of linkage between digital people and live guests.